Experimental investigation of cephapirin adsorption to quartz filter sands and dune sands     

Jonathan W. Peterson  Theresa A. O’Meara  Michael D. Seymour 《Hydrogeology Journal》2008,16(5):879-892

Batch experiments were performed to investigate cephapirin (a widely used veterinary antibiotic) adsorption on various size sands of low total organic carbon content (0.08–0.36 wt%). In the aqueous concentration range investigated (11–112 μmol/L cephapirin), adsorption to nearly pure quartz filter sands (0.50–3.35 mm diameter) is low. Isotherms are S-shaped and most display a region of minimum adsorption, where decreased adsorption occurs with increasing solution concentration, followed by increased adsorption at higher concentrations. Cephapirin adsorption to quartz-rich, feldspar-bearing dune sands (0.06–0.35 mm diameter), and the smallest quartz filter sand investigated (0.43–0.50 mm), can be described by linear sorption isotherms over the range of concentrations investigated. Distribution coefficients (K _d) range from 0.94 to 3.45 L/kg. No systematic relationship exists between grain size and amount of adsorption for any of the sands investigated. Cephapirin adsorption is positively correlated to the feldspar ratio (K-feldspar/(albite + Ca-plagioclase). Feldspar-ratio normalization of distribution coefficients was more effective than organic carbon normalization at reducing variability of K _d values in the dune sands investigated.  相似文献   

A Comparison of the International Charters on Geographical Education     

Theresa Bourke  Rod Lane 《The Journal of geography》2018,117(4):174-180

This article uses discourse analysis techniques associated with Foucauldian archaeology to examine the two international charters developed by the International Geographical Union Commission on Geographical Education (IGU-CGE), the original one in 1992 and the revised version endorsed in 2016 at the Beijing conference. The examination considers the consultation and development processes before outlining similarities and differences in the messages communicated and how discourses have changed through time. The article concludes with recommendations for the geography education community for the future.  相似文献   

Chandrakanth MG | Water resource economics     

Maike Groeschke  Theresa Frommen 《Environmental Earth Sciences》2016,75(14):1097

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The importance of tides for sediment dynamics in the deep sea—Evidence from the particulate-matter tracer 234Th in deep-sea environments with different tidal forcing     

Florian Peine  Robert Turnewitsch  Christian Mohn  Theresa Reichelt  Barbara Springer  Manfred Kaufmann 《Deep Sea Research Part I: Oceanographic Research Papers》2009,56(7):1182-1202

Key aspects of deep-ocean fluid dynamics such as basin-scale (residual) and tidal flow are believed to have changed over glacial/interglacial cycles, with potential relevance for climatic change. To constrain the mechanistic links, magnitudes and temporal succession of events analyses of sedimentary paleo-records are of great importance. Efforts have been underway for some time to reconstruct residual-flow patterns from sedimentary records. Attempts to reconstruct tidal flow characteristics from deep-sea sediment deposits, however, are at a very early stage and first require a better understanding of the reflection of modern tides in sediment dynamics. In this context internal (baroclinic) tides, which are formed by the surface (barotropic) tide interacting with seafloor obstacles, are believed to play a particularly important role. Here we compare two modern deep-sea environments with respect to the effect of tides on sediment dynamics. Both environments are influenced by kilometre-scale topographic features but with vastly different tidal forcing: (1) two sites in the Northeast Atlantic (NEA) being surrounded by, or located downstream of, fields of short seamounts (maximum barotropic tidal current velocities ～5 cm s^?1); and (2) a site next to the Anaximenes seamount in the Eastern Mediterranean (EMed) (maximum barotropic tidal current velocities ～0.5 cm s^?1). With respect to other key fluid-dynamical parameters both environments are very similar. Signals of sedimentary particle dynamics, as influenced by processes taking place in the bottom boundary layer, were traced by the vertical water-column distribution of radioactive disequilibria (daughter/parent activity ratios≠1) between the naturally occurring, short-lived (half-life: 24.1 d) particulate-matter tracer ²³⁴Th relative to its very long-lived and non-particle-reactive parent nuclide ²³⁸U. Activity ratios of ²³⁴Th/²³⁸U<1 in water samples collected near the seafloor indicate fast ²³⁴Th scavenging onto particles followed by fast settling of these particles from the sampled parcel of water and, therefore, imply active sediment resuspension and dynamics on time scales of up to several weeks. In the Northeast Atlantic study region tides (in particular internal tides) are very likely to locally push total current velocities near the seafloor across the critical current velocity threshold for sediment erosion or resuspension whereas in the Eastern Mediterranean the tides are much too weak for this to happen. This difference in tidal forcing is reflected in a difference of the frequency of the occurrence of radioactive disequilibria <1 between total ²³⁴Th and ²³⁸U: In the near-bottom water column of the Northeast Atlantic region 59% of samples had detectable ²³⁴Th/²³⁸U disequilibria whereas at the Eastern Mediterranean site this fraction was only 7% (including a few disequilibria >1). The results of this study, therefore, add to the evidence suggesting that tides in the deep sea of the open oceans are more important for sediment dynamics than previously thought. It is hypothesised that (a) tide/seamount interactions in the deep open ocean control the local distribution of erosivity proxies (e.g., distributions of sediment grain sizes, heavy minerals and particle-reactive radionuclides) in sedimentary deposits and (b) the aforementioned topographically controlled sedimentary imprints of (internal) tides are useful in the reconstruction of past changes of tidal forcing in the deep sea.  相似文献   

Larval Pacific Herring (Clupea pallasi) Survival in Suspended Sediment     

Frederick J. Griffin  Theresa DiMarco  Karl L. Menard  Joe A. Newman  Edmund H. Smith  Carol A. Vines  Gary N. Cherr 《Estuaries and Coasts》2012,35(5):1229-1236

Pacific herring early life stages provide good model systems for studying effects of suspended sediments on estuarine organisms. To investigate effects on the herring larval stage, we used environmentally relevant particle concentrations for San Francisco Bay (200?C400?mg/L of particles <50???m in size) and exposure times of 16?h in a novel two-pump sediment suspension mesocosm. There were no mortalities during the 16-h suspended sediment incubation. Following sediment exposure, larvae were cultured in sediment-free water for up to 10?days during which survival and condition were measured. None were affected by previous sediment treatment. Four criteria for larval condition included growth, heart rate, prey capture, and critical swimming velocity. These results provide a framework for implementing regulatory decisions on anthropogenic activities such as dredging.  相似文献   

Control of regional structural styles and faulting on Northeast Mexico spring distribution     

Brad David Wolaver  Theresa M. Diehl 《Environmental Earth Sciences》2011,62(7):1535-1549

Groundwater-dependent, spring-fed ecosystems of the Cuatrociénegas Basin, Coahuila, Mexico, host >70 endemic species. These desert springs occur primarily aligned along the base of an anticline that bisects the Cuatrociénegas Basin, but the hydrogeologic controls of the springs are poorly understood. The hypothesis that spring locations are controlled by subsurface geology, such as buried anticlines or faulting, versus stratigraphic controls is tested by evaluating: (1) regional structural styles; (2) fracture models of analogous structures; (3) hydrogeologic data; and (4) geophysical surveys. Jurassic and Cretaceous siliciclastic and carbonate rocks deposited on the Coahuila Block west of the Cuatrociénegas Basin have dips <10° and lack faults because of a structurally rigid granodiorite basement. To the east of the Coahuila Block and around the Cuatrociénegas Basin, the Coahuila Folded Belt has anticlines associated with basement-involved faults, 10–25° backlimb dips, and forelimb dips up to vertical or slightly overturned. Springs in the western sub-basin that represent 85% of total basin discharge are located on zones of highest anticipated fracture density predicted by fracture models of analogous anticlines. Spring waters reveal elevated temperature (32–35°C) and low tritium (<1 tritium unit). Gravimetry and time-domain electromagnetic surveys correspond with a best-fit Cuatrociénegas Basin hydrogeologic model of fractures associated with reverse faulting controlling spring locations in the western Cuatrociénegas Basin. Springs in the eastern sub-basin are located where ephemeral streams have eroded through confining beds along the base of alluvial fans and lack faulting. Regional variations in structural style are an important control on the location of springs in the Cuatrociénegas Basin.  相似文献   

Investigation of runoff generation in a pristine,poorly gauged catchment in the Chilean Andes I: A multi‐method experimental study     

Theresa Blume  Erwin Zehe  Dominik E. Reusser  Andrés Iroumé  Axel Bronstert 《水文研究》2008,22(18):3661-3675

Catchment scale hydrological process studies in southern Chile are of special interest as little research at this scale has been carried out in this region. In particular, the young volcanic ash soils, which are typical for this area, are not well understood in their hydrological behaviour. In addition, extensive land use changes require detailed knowledge of hydrological processes in disturbed as well as undisturbed catchments in order to estimate resulting risks of erosion, eutrophication, floods and droughts. This study focuses on data collection and experimental determination of relevant processes in an undisturbed forested catchment in the Andes of southern Chile. The here gained understanding of runoff generation can serve as a reference for comparison with sites subject to human intervention, improving estimation of the effects of land use change. Owing to the lack of long‐term data for this catchment it was necessary to replace long time series by a multitude of experimental methods covering as many aspects of the runoff generation process as possible. The methods used in this investigation include: measurements of streamflow, rainfall, throughfall, water chemistry, soil water dynamics, groundwater dynamics, soil physics, soil mineralogy, geo‐electrical sounding, and tracer techniques. Methods and equipment used during field campaigns are described and evaluated for usefulness versus expenditure (labour and financial costs). Selected results and the hypotheses developed from these findings are presented. The results suggest the importance of fast processes for rainfall runoff response on the one hand as well as considerable dampening effects of a large subsurface storage on the other hand. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

Jim Glassman,Bounding the Mekong: The Asian Development Bank,China, and Thailand     

Theresa Wong 《Singapore journal of tropical geography》2012,33(2):271-273

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The impact of sewage-contaminated river water on groundwater ammonium and arsenic concentrations at a riverbank filtration site in central Delhi,India     

Maike Groeschke  Theresa Frommen  Thomas Taute  Michael Schneider 《Hydrogeology Journal》2017,25(7):2185-2197

The groundwater abstracted at a well field near the Yamuna River in Central Delhi, India, has elevated ammonium (NH₄ ⁺) concentrations up to 35 mg/L and arsenic (As) concentrations up to 0.146 mg/L, constituting a problem with the provision of safe drinking and irrigation water. Infiltrating sewage-contaminated river water is the primary source of the NH₄ ⁺ contamination in the aquifer, leading to reducing conditions which probably trigger the release of geogenic As. These conclusions are based on the evaluation of six 8–27-m deep drillings, and 13 surface-water and 69 groundwater samples collected during seven field campaigns (2012–2013). Results indicate that losing stream conditions prevail and the river water infiltrates into the shallow floodplain aquifer (up to 16 m thickness), which consists of a 1–2-m thick layer of calcareous nodules (locally known as kankar) overlain by medium sand. Because of its higher hydraulic conductivity (3.7 × 10^?3 m/s, as opposed to 3.5 × 10^?4 m/s in the sand), the kankar layer serves as the main pathway for the infiltrating water. However, the NH₄ ⁺ plume front advances more rapidly in the sand layer because of its significantly lower cation exchange capacity. Elevated As concentrations were only observed within the NH₄ ⁺ plume indicating a causal connection with the infiltrating reducing river water.  相似文献   

Permeability changes in layered sediments: impact of particle release   总被引：8，自引：0，他引：8  

Blume T  Weisbrod N  Selker JS 《Ground water》2002,40(5):466-474

One of the mechanisms of sudden particle release from grain surfaces in natural porous media is a decrease in salt concentration of the permeating fluid to below the critical salt concentration. Particle release can cause a change in hydraulic conductivity of the matrix, either by washing out the fines and thus increasing the pore sizes or by the plugging of pore constrictions. The phenomenon of permeability changes as a result of particle detachment was investigated in a series of column experiments. Coarse and fine sediments from the Hanford Formation in southeast Washington were tested. Columns were subject to a pulse of highly saline solution (NaNO3) followed by a fresh water shock causing particle release. Outflow rates and changes in hydraulic head as well as electric conductivity and pH were monitored over time. No permeability decrease occurred within the coarse matrix alone. However, when a thin layer of fine sediment was embedded within the coarse material (mimicking field conditions at the Hanford site), permeability irreversibly decreased to 10% to 20% of the initial value. Evidence suggests that most of this permeability decrease was a result of particles detached within the fine layer and its subsequent clogging. An additional observation was a sudden increase in pH in the outflow solution, generated in situ during the fresh water shock. Because layered systems are common in natural settings, our results suggest that alteration between sodium solution and fresh water can lead to particle release and subsequently reduce the overall permeability of the matrix.  相似文献