Tracing suspended organic nitrogen from the Yangtze River catchment into the East China Sea   总被引：2，自引：0，他引：2  

Ying Wu  Thorsten Dittmar  Kai-Uwe Ludwichowski  Gerhard Kattner  Jing Zhang  Zhuo Y. Zhu  Boris P. Koch 《Marine Chemistry》2007

Total suspended matter was collected along the Yangtze River (Changjiang) and in the East China Sea in April to May and in September 2003, respectively, to study origin and fate of particulate organic nitrogen. Concentrations of particulate organic carbon (POC), nitrogen (PN) and hydrolyzable particulate amino acids (PAA; d- and l-enantiomers) were higher in the Yangtze Estuary than in the river and decreased offshore towards the shelf edge. In the coastal area, higher values of PAA were observed in the surface layer than in the bottom water. Stable carbon isotope ratios (δ¹³C) of POC increased from − 24.4‰ in the river to values around − 21‰ on the East China Sea Shelf. Dominant amino acids were aspartic acid + aspartine (Asx), glutamic acid + glutamine (Glx), glycine, alanine and serine. The proportions of Asx, Glx and isoleucine were higher in the marine than in the riverine samples contrary to the distributions of glycine, alanine, threonine and arginine. The proportions of d-amino acids were highest in the riverine suspended organic matter (6% of PAA) decreasing towards the shelf edge (1.5% of PAA). d-arginine, not reported in natural aquatic samples so far, was the most abundant d-amino acid in the river. The amino acid composition of the particulate organic matter (POM) in the Yangtze River indicates an advanced stage of degradation of POM. Highly degraded organic matter from soils is probably a main source of POM in the Yangtze River, but the relatively high δ¹³C values and low C/N ratios (7.7 ± 1.6) also indicate contribution from anthropogenic sources. The degraded riverine material was a dominant organic matter source in the estuary, where aquatic primary production had only a small overall contribution. In the East China Sea, gradual settling of riverine organic matter and the addition of fresher phytoplankton impacted the amino acid composition and δ¹³C values, and on the outer shelf relatively fresh phytoplankton-derived organic matter dominated.  相似文献   

Ion microprobe (SHRIMP) dating of detrital zircon grains from quartzites of the Eckergneiss Complex, Harz Mountains (Germany): implications for the provenance and the geological history     

Thorsten Geisler  Roland Vinx  Nergui Martin-Gombojav  Robert T. Pidgeon 《International Journal of Earth Sciences》2005,94(3):369-384

The Eckergneiss Complex (EGC) is a geologically unique medium- to high-grade metamorphic unit within the Rhenohercynian domain of the Mid-European Variscides. A previously, poorly defined conventional lower U–Pb intercept age of about 560 Ma from detrital zircons of metasedimentary rocks has led to speculations about an East Avalonian affinity of the EGC. In order to unravel the provenance and to constrain the age of the sediment protolith, we carried out sensitive high-resolution ion microprobe U–Pb analyses on detrital zircons from five different EGC quartzite occurrences. The obtained age spectrum indicates a SW Baltica provenance of the detritus. Sveconorwegian ages between 0.9–1.2 Ga are particularly well represented by analyses from metamorphic recrystallization/alteration zones penetrating into igneous zircon. Cadomian (Pan-African) ages, which might reflect a metamorphic event, could not be substantiated. Instead, zircons of igneous origin yielded concordant Lower Devonian and Silurian ages of 410±10, 419±10, and 436±6 Ma (1), implying that sedimentation of the EG protolith must have taken place after 410±10 Ma. The lower age limit of the EGC metamorphism is constrained by 295 Ma intrusion ages of the adjacent, nonmetamorphosed Harzburg Gabbronorite and Brocken Granite. Sedimentation and metamorphism must thus have taken place between about 410 Ma and 295 Ma. Given that this time span coincides with most of the sedimentation within the virtually nonmetamorphosed (lowest grade) Rhenohercynian in the Harz Mountains, including the direct vicinity of the EGC, along with the high-grade metamorphism, the EGC can hardly be seen as uplifted local basement. A possible candidate for the root region is an easterly, concealed marginal segment of the Rhenohercynian domain of the Variscides, which is tectonically overridden and suppressed by the Mid-German Crystalline Rise during continent collision. However, based on the concept of strike-slip movement of Variscan terranes with different P–T–t histories as a result of postaccretion intraplate deformation, the EGC could also represent a fault-bounded complex with an origin located far east or south east of the present location.

Thorsten GeislerEmail:

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Trends of persistent organic pollutants in the suspended matter of the River Rhine     

Thorsten Pohlert  Gudrun Hillebrand  Vera Breitung 《水文研究》2011,25(24):3803-3817

Recently amended European (EU) water policies call for an adequate monitoring of the chemical status of sediments and suspended matter (SM) in rivers. In this study, we focus on long‐term time series of particle‐bound hexachlorobenzene (HCB) and selected polychlorinated biphenyls (PCB‐138 and PCB‐153) that were monitored biweekly to monthly at eight stations in the River Rhine catchment. Our aims are (1) to detect trends in the concentration series HCB, PCB‐138 and PCB‐153, (2) to estimate the uncertainty of loads caused by SM collection techniques and load calculation procedures and (3) to detect trends in the subsequently calculated annual load series. HCB concentration in the SM for the period 1995–2008 significantly (p < 0·01) decreased at six of the eight monitoring stations. Decreasing PCB‐138 and PCB‐153 concentrations are significant at six of the eight and seven of the eight monitoring stations, respectively. A two‐way analysis of variance (ANOVA) that tested the effect of two collection techniques and four load calculation procedures on annual loads indicates homogeneity of the methods at four of the five monitoring stations. At Weil, only the loads of HCB, PCB‐138 and PCB‐153 are significantly affected by the collection technique. The trend analysis of an extended series (1985–2007) of annual HCB loads at Koblenz showed a significant decrease from about 110 kg year^?1 to about 15–23 kg year^?1; however, in the shorter period (1995–2007) only at two of the eight monitoring stations decreasing trends of annual contaminant load could be detected. We conclude that any of the tested load calculation procedures can be applied, as loads do no differ systematically. Although a high uncertainty in load estimation exists (e.g. maximum percentage error of E = [18·1, 122·5]% for HCB), the monitoring programme at the Rhine is adequate for analysing the long‐term chemical status of SM. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Surface density profiles of collisionless disc merger remnants     

Thorsten Naab  Ignacio Trujillo 《Monthly notices of the Royal Astronomical Society》2006,369(2):625-644

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Knowledge gaps in our perceptual model of Great Britain's hydrology     

Thorsten Wagener  Simon J. Dadson  David M. Hannah  Gemma Coxon  Keith Beven  John P. Bloomfield  Wouter Buytaert  Hannah Cloke  Paul Bates  Joseph Holden  Louise Parry  Rob Lamb  Nick A. Chappell  Matthew Fry  Gareth Old 《水文研究》2021,35(7):e14288

There is a no lack of significant open questions in the field of hydrology. How will hydrological connectivity between freshwater bodies be altered by future human alterations to the hydrological cycle? Where does water go when it rains? Or what is the future space–time variability of flood and drought events? However, the answers to these questions will vary with location due to the specific and often poorly understood local boundary conditions and system properties that control the functional behaviour of a catchment or any other hydrologic control volume. We suggest that an open, shared and evolving perceptual model of a region's hydrology is critical to tailor our science questions, as it would be for any other study domain from the plot to the continental scale. In this opinion piece, we begin to discuss the elements of and point out some knowledge gaps in the perceptual model of the terrestrial water cycle of Great Britain. We discuss six major knowledge gaps and propose four key ways to reduce them. While the specific knowledge gaps in our perceptual model do not necessarily transfer to other places, we believe that the development of such perceptual models should be at the core of the debate for all hydrologic communities, and we encourage others to have a similar debate for their hydrologic domain.  相似文献   

Continental rift-setting and evolution of Neoproterozoic Sindreth Basin in NW-India     

Stefan Schöbel  Kamal K Sharma  Thorsten Hörbrand  Theresa Böhm  Ines Donhauser  Helga de Wall 《Journal of Earth System Science》2017,126(6):90

The Neoproterozoic Sindreth Basin, NW India, and its surrounding area represent a half graben structure situated between the undeformed Malani Igneous Suite (MIS) in the west and a corridor of coeval Cryogenian ductile deformation, anatexis and granite intrusion in the east. The main lithologies observed in the basin are conglomerate, fanglomerate, debris flow and lake deposits derived from a nearby continental provenance, intercalated with concurrent mafic and felsic lava flows. Based on geological traverses across the strike of the basin, we propose a three-fold classification comprising Lower Clastic Unit and an Upper Clastic Unit and a Bimodal (basalt–rhyolite) Volcanic Unit separating the two. Tilting due to basin inversion and faulting has been observed; however, the rocks are unmetamorphosed and show undisturbed primary sedimentary features. The stratigraphic record of the basin is characteristic for deposition and magmatism in a fault-related continental setting. Implications of the findings have been discussed in the context of Neoproterozoic crustal dynamics in NW India. This study provides conclusive evidence for a continental setting for Sindreth Basin evolution and contests the recent models of active subduction setting (either back-arc basin or accretionary sediments over a subduction zone).  相似文献   

Three-dimensional modelling of folds,thrusts, and strike-slip faults in the area of Val de Ruz (Jura Mountains,Switzerland)     

Davood M. Yosefnejad  Thorsten J. Nagel  Nikolaus Froitzheim 《Swiss Journal of Geoscience》2017,110(2):613-630

The Val-de-Ruz syncline is a northeast-southwest trending, rhomb-shaped synclinal basin in the internal part of the central Jura Mountains. The Mesozoic sediment succession is decoupled from the basement by a décollement horizon in Middle Triassic evaporite-bearing layers at depth and folding is associated with southeast-dipping thrust splays rooting into this décollement. The folds and thrusts also interfere with a system of N-S striking, sinistral strike-slip faults. A 3D model was constructed from the following input data: A digital elevation model, the 1:25,000 geological map of Switzerland, published contours of the top of basement based on drilling and seismics, and nine newly constructed cross-sections. The latter are based on surface geology and published seismic data. Cross-sections parallel to the northwestward transport direction, i.e. perpendicular to the overall strike, are line balanced. Anticlines are interpreted as faulted detachment folds, which initiated by buckling and associated flow of evaporites from synclinal to anticlinal areas. Anticlines were later broken by northwest-vergent thrusts and subsequently developed into fault-propagation folds during décollement from the basement and northwestward translation. The model assumes no faulting in the pre-Mesozoic basement and no hidden flat-ramp tectonics in the subsurface in order to account for structurally high positions. As a consequence, the modelled cumulative, post-deformation thickness of Triassic strata locally exceeds 1500 m, which we find in accordance with regional observations. From the geological 3D model, new cross-sections in any desired orientation and tectonic thickness variations of the layers can be extracted. The three output cross-sections presented are in excellent agreement with published reflection seismic data. The most important features of our model are (1) large thickness variations due to lateral flow of evaporites, and (2) new and plausible explanation of structural highs in terms of accumulation of Triassic strata by lateral flow.  相似文献   

The mechanism of cation and oxygen isotope exchange in alkali feldspars under hydrothermal conditions   总被引：3，自引：1，他引：2  

Dominik R. D. Niedermeier  Andrew Putnis  Thorsten Geisler  Ute Golla-Schindler  Christine V. Putnis 《Contributions to Mineralogy and Petrology》2009,157(1):65-76

The mechanism of re-equilibration of albite in a hydrothermal fluid has been investigated experimentally using natural albite crystals in an aqueous KCl solution enriched in ¹⁸O at 600°C and 2 kbars pressure. The reaction is pseudomorphic and produces a rim of K-feldspar with a sharp interface on a nanoscale which moves into the parent albite with increasing reaction time. Transmission electron microscopy (TEM) diffraction contrast and X-ray powder diffraction (XRD) show that the K-feldspar has a very high defect concentration and a disordered Al, Si distribution, compared to the parent albite. Raman spectroscopy shows a frequency shift of the Si-O-Si bending vibration from ~476 cm⁻¹ in K-feldspar formed in normal ¹⁶O aqueous solution to ~457 cm⁻¹ in the K-feldspar formed in ¹⁸O-enriched solution, reflecting a mass-related frequency shift due to a high enrichment of ¹⁸O in the K-feldspar silicate framework. Raman mapping of the spatial distribution of the frequency shift, and hence ¹⁸O content, compared with major element distribution maps, show a 1:1 correspondence between the reaction rim formed by the replacement of albite by K-feldspar, and the oxygen isotope re-equilibration. The textural and chemical characteristics as well as the kinetics of the replacement of albite by K-feldspar are consistent with an interface-coupled dissolution-reprecipitation mechanism.  相似文献   

Reconciling theory with observations: elements of a diagnostic approach to model evaluation   总被引：2，自引：0，他引：2  

Hoshin V. Gupta  Thorsten Wagener  Yuqiong Liu 《水文研究》2008,22(18):3802-3813

This paper discusses the need for a well‐considered approach to reconciling environmental theory with observations that has clear and compelling diagnostic power. This need is well recognized by the scientific community in the context of the ‘Predictions in Ungaged Basins’ initiative and the National Science Foundation sponsored ‘Environmental Observatories’ initiative, among others. It is suggested that many current strategies for confronting environmental process models with observational data are inadequate in the face of the highly complex and high order models becoming central to modern environmental science, and steps are proposed towards the development of a robust and powerful ‘Theory of Evaluation’. This paper presents the concept of a diagnostic evaluation approach rooted in information theory and employing the notion of signature indices that measure theoretically relevant system process behaviours. The signature‐based approach addresses the issue of degree of system complexity resolvable by a model. Further, it can be placed in the context of Bayesian inference to facilitate uncertainty analysis, and can be readily applied to the problem of process evaluation leading to improved predictions in ungaged basins. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

Hf-W mineral isochron for Ca,Al-rich inclusions: Age of the solar system and the timing of core formation in planetesimals   总被引：1，自引：0，他引：1  

Christoph Burkhardt  Thorsten Kleine  Herbert Palme  Jon M. Friedrich 《Geochimica et cosmochimica acta》2008,72(24):6177-6197

Application of ¹⁸²Hf-¹⁸²W chronometry to constrain the duration of early solar system processes requires the precise knowledge of the initial Hf and W isotope compositions of the solar system. To determine these values, we investigated the Hf-W isotopic systematics of bulk samples and mineral separates from several Ca,Al-rich inclusions (CAIs) from the CV3 chondrites Allende and NWA 2364. Most of the investigated CAIs have relative proportions of ¹⁸³W, ¹⁸⁴W, and ¹⁸⁶W that are indistinguishable from those of bulk chondrites and the terrestrial standard. In contrast, one of the investigated Allende CAIs has a lower ¹⁸⁴W/¹⁸³W ratio, most likely reflecting an overabundance of r-process relative to s-process isotopes of W. All other bulk CAIs have similar ¹⁸⁰Hf/¹⁸⁴W and ¹⁸²W/¹⁸⁴W ratios that are elevated relative to average carbonaceous chondrites, probably reflecting Hf-W fractionation in the solar nebula within the first ∼3 Myr. The limited spread in ¹⁸⁰Hf/¹⁸⁴W ratios among the bulk CAIs precludes determination of a CAI whole-rock isochron but the fassaites have high ¹⁸⁰Hf/¹⁸⁴W and radiogenic ¹⁸²W/¹⁸⁴W ratios up to ∼14 ε units higher than the bulk rock. This makes it possible to obtain precise internal Hf-W isochrons for CAIs. There is evidence of disturbed Hf-W systematics in one of the CAIs but all other investigated CAIs show no detectable effects of parent body processes such as alteration and thermal metamorphism. Except for two fractions from one Allende CAI, all fractions from the investigated CAIs plot on a single well-defined isochron, which defines the initial ε¹⁸²W = −3.28 ± 0.12 and ¹⁸²Hf/¹⁸⁰Hf = (9.72 ± 0.44) × 10⁻⁵ at the time of CAI formation. The initial ¹⁸²Hf/¹⁸⁰Hf and ²⁶Al/²⁷Al ratios of the angrites D’Orbigny and Sahara 99555 are consistent with the decay from initial abundances of ¹⁸²Hf and ²⁶Al as measured in CAIs, suggesting that these two nuclides were homogeneously distributed throughout the solar system. However, the uncertainties on the initial ¹⁸²Hf/¹⁸⁰Hf and ²⁶Al/²⁷Al ratios are too large to exclude that some ²⁶Al in CAIs was produced locally by particle irradiation close to an early active Sun. The initial ¹⁸²Hf/¹⁸⁰Hf of CAIs corresponds to an absolute age of 4568.3 ± 0.7 Ma, which may be defined as the age of the solar system. This age is 0.5-2 Myr older than the most precise ²⁰⁷Pb-²⁰⁶Pb age of Efremovka CAI 60, which does not seem to date CAI formation. Tungsten model ages for magmatic iron meteorites, calculated relative to the newly and more precisely defined initial ε¹⁸²W of CAIs, indicate that core formation in their parent bodies occurred in less than ∼1 Myr after CAI formation. This confirms earlier conclusions that the accretion of the parent bodies of magmatic iron meteorites predated chondrule formation and that their differentiation was triggered by heating from decay of abundant ²⁶Al. A more precise dating of core formation in iron meteorite parent bodies requires precise quantification of cosmic-ray effects on W isotopes but this has not been established yet.  相似文献