Leaching mechanisms of oxyanionic metalloid and metal species in alkaline solid wastes: A review     

Geert Cornelis  C. Anette Johnson  Tom Van Gerven  Carlo Vandecasteele 《Applied Geochemistry》2008

An overview is presented on possible mechanisms that control the leaching behaviour of the oxyanion forming elements As, Cr, Mo, Sb, Se, V and W in cementituous systems and alkaline solid wastes, such as municipal solid waste incinerator bottom ash, fly ash and air pollution control residues, coal fly ash and metallurgical slags. Although the leachability of these elements generally depends on their redox state, speciation measurements are not common. Therefore, experimental observations available in the literature are combined with a summary of the thermal behaviour of these elements to assess possible redox states in freshly produced alkaline wastes, given their origin at high temperature. Possible redox reactions occurring at room temperature, on the other hand, are reviewed because these may alter the initial redox state in alkaline wastes and their leachates. In many cases, precipitation of oxyanions as a pure metalate cannot provide a satisfactory explanation for their leaching behaviour. It is therefore highly likely that adsorption and solid solution formation with common minerals in alkaline waste and cement reduce the leachate concentration of oxyanions below pure-phase solubility.  相似文献   

Deep-seated gravitational slope deformations and their influence on consequent mass movements (case studies from the highest part of the Czech Carpathians)   总被引：3，自引：0，他引：3  

Jan Hradecký  Tomáš Pánek 《Natural Hazards》2008,45(2):235-253

Gravitational spreading of mountain ridges displays primary disequilibrium of flysch mountain areas of the Czech Carpathians. The progression of various types of mass movements is a product of long-term ridge disintegration and is predisposed by the geological structure of the area and the upper Tertiary-Quaternary morphogenesis of the mountain area. Deep-seated slope deformations are spatially interconnected by the occurrence of some other types of slope deformations (e.g. debris flows, debris slides, slumps, rock avalanches, etc.), which pose a considerable risk for the existence of human society. An important causative factor in these dynamically developing hazardous processes is, among other factors, the way in which land has been used in the last three centuries. Therefore, the occurrence of various types of slope deformations is studied in terms of their relation to deep-seated gravitational deformations and in terms of other limiting factors (structural geological, morphological and climatic factors, manmade impacts, etc.). The paper presents several case studies of slope deformations (Velká Čantoryje Mt, Lysá hora Mt, Ropice Mt and Smrk Mt) in the area of the Outer Carpathians within the territory of the Czech Republic and also adverts to some consequences in terms of the socioeconomic structure of the landscape.  相似文献   

Lower Tertiary volcanic rocks off Kristiansund — Mid Norway     

Tom Bugge  Tore Prestvik  Kåre Rokoengen 《Marine Geology》1980,35(4):277-286

Grab samples from the Norwegian continental shelf show that diapiric structures occurring within a sequence of Mesozoic and Tertiary sediments represent volcanic rocks consisting of porphyritic olivine-nephelinite. The KAr age of 55.7 ± 0.9 m.y. shows that the area affected by Lower Tertiary magmatism in the North Atlantic region also included the continental shelf off Mid Norway. The highly undersaturated nature of these volcanic rocks, however, indicates that they are unlikely to be closely related to the widespread tuff horizons of the same age known from the North Sea.  相似文献   

Simultaneous exposure of English sole (Parophrys vetulus) to sediment-associated xenobiotics: Part 1—uptake and disposition of ¹⁴C-polychlorinated biphenyls and ³H-benzo[a]pyrene     

John E. Stein  Tom Hom  Usha Varanasi 《Marine environmental research》1984,13(2):97-119

English sole (Parophrys vetulus) were exposed to environmentally realistic levels of sediment-associated ³H-benzo[a]pyrene (3 μg BaP/g sediment, dry weight) and ¹⁴C-Aroclor 1254 (1 μg PCBs/g), separately and together, for up to 10 days. BaP and its metabolites in tissues reached steady-state concentrations by the first day of the exposure, whereas PCBs did not approach steady-state concentrations until the tenth day of exposure. Simultaneous exposure of sole to BaP and PCBs, relative to separate exposure to the xenobiotics, significantly increased the concentrations of BaP-derived radioactivity and decreased the concentrations of PCB-derived radioactivity in some tissues and bile. Accumulation of PCB-derived radioactivity, estimated as the burden in tissues, was significantly greater (4- to 13-fold) than that of BaP-derived radioactivity throughout the experiments and regardless of the type of exposure. The rank of the concentrations of PCB-derived radioactivity in tissues and bile was: bile ～ liver > brain > kidney ～ gill > skin ～ blood ～ muscle and for BaP-derived radioactivity the order was: bile > liver > gill > kidney > skin ～ blood > muscle > brain. BaP-derived radioactivity in liver and bile was present primary (85–99%) as metabolites, whereas PCB-derived radioactivity was present equally as parent compounds and metabolites in bile and primarily (98 %) as parent compounds in liver. Hydrolysis of bile from PCB/BaP-exposed sole with β-glucuronidase/arylsulfatase released 35 % of the BaP-derived radioactivity and 32 % of the PCB-derived radioactivity as primary metabolites. A much higher proportion of the BaP-derived radioactivity (64 %) than the PCB-derived radioactivity (13 %) in bile was unaffected by the enzyme treatment, indicating differences in the conjugation of the primary metabolites of PCBs and BaP. The results suggest that in contaminated environments the tissue to sediment concentration ratios for PCBs would exceed that for BaP and its metabolites; however, BaP would be continually absorbed and metabolized by sole to potentially carcinogenic and mutagenic compounds. In addition, the tissue levels of these toxic compounds may be increased by simultaneous exposure to PCBs.  相似文献   

Artificial Reefs in the Low Productive Marine Environments of the Southeastern Mediterranean   总被引：1，自引：0，他引：1  

E. Spanier    M. Tom    S. Pisanty  G. Almog-Shtayer   《Marine Ecology》1990,11(1):61-75

Abstract. Fishery yields in the oligotrophic waters of the Southeastern Mediterranean arc low due to habitat and food limitations. A four year study of a complex of artificial structures established in the coastal waters of Israel points to several possible solutions to these problems. One approach is the artificial enrichment of the man-made reef with trash fish. This, together with the configuration of the reef, caused a significant increase in the abundance of fish predators such as groupers of the genus Epinephclus. Omnivores and herbivores were attracted only by the presence of artificial structures. Some species, such as the slipper lobster Scyllurides lulus, only use the man-made reef for shelter during part of the day or season; they forage over a much larger area the rest of the time and are important "importers" of food to the artificial habitat. Artificial kelp were effective in recruiting juveniles and small fishes to the site.  相似文献   

A giant three-stage submarine slide off Norway   总被引：8，自引：0，他引：8  

Tom Bugge  Stein Befring  Robert H. Belderson  Tor Eidvin  Eystein Jansen  Neil H. Kenyon  Hans Holtedahl  Hans Petter Sejrup 《Geo-Marine Letters》1987,7(4):191-198

One of the largest submarine slides known, The Storegga Slide, is located on the Norwegian continental margin. The slide is up to 450 m thick and has a total volume of about 5,600 km3. The headwall of the slide scar is 290 km long and the total run-out distance is about 800 km. The slide involved sediments of Quaternary to Early Tertiary age and occurred in three stages. Earthquakes combined with decomposition of gas hydrates are believed to be the main triggering agents for the slides. The first slide event is tentatively dated to be about 30,000 to 50,000 years B.P. and the two last major events are dated to be at 6,000 to 8,000 years B.P.  相似文献   

Variation in the catchability of yellow perch (Perca flavescens) in the fisheries of Lake Erie using a Bayesian error-in-variable approach     

Jiao  Yan; Reid  Kevin; Nudds  Tom 《ICES Journal of Marine Science》2006,63(9):1695-1704

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The metabolism and disposition of 17β-estradiol in english sole exposed to a contaminated sediment extract     

John E. Stein  Tom Hom  Herb Sanborn  Usha Varanasi 《Marine environmental research》1988,24(1-4)

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Centurial and decadal oceanographic influences on changes in northern gannet populations and diets in the north-west Atlantic: implications for climate change   总被引：1，自引：1，他引：1  

Montevecchi  W. A.; Myers  R. A. 《ICES Journal of Marine Science》1997,54(4):608-614

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Giant ancient landslide in the Alma water gap (Crimean Mountains,Ukraine): notes to the predisposition,structure, and chronology     

Tomáš Pánek  Jan Hradecký  Veronika Smolková  Karel Šilhán 《Landslides》2008,5(4):367-378

Large-scale ancient landslides of the area of more than 5 km² and volume exceeding 200 × 10⁶ m³ are characteristic features of the valleys incised in the northern periphery of the Crimean Mountains (Ukraine). The largely affected area is located in the outermost cuesta range of the Crimean Mountains which consists of rigid Sarmatian limestones overlying weak Middle Miocene and Upper Palaeogene deposits. A giant landslide arose in the Alma water gap as a reflection of several coincident preparatory factors such as suitable bedrock stratification, smectite-rich bedrock exposed to swelling activity, presence of faults parallel to the valley trend, and river capture event which preceded the landslide event. The occurrence of such ancient megaslides is particularly interesting in the area which is characterized by low precipitation (<500 mm/year) and weak contemporary seismicity. It probably reflects a more dynamic environment in humid phases of the Holocene; however, seismic triggering along the Mesozoic suture zone cannot be rejected. Compressional features such as gravitational folds in the central and distal parts of the landslide, which probably correlate with the whole landslide genesis or its significant reactivation, arose, according to the radiocarbon dating, during the Holocene climatic optimum in the Atlantic period. The slope deformation has been relatively quiescent since that time, except minor historic reactivization which took place in the frontal part of the landslide. We suppose that the studied landslide could be classified as a transitional type of slope deformation with some signs of spreading and translational block slides.  相似文献