Petrogenetic evolution of Late Paleozoic rhyolites of the Harvey Group,southwestern New Brunswick (Canada) hosting uranium mineralization     

J. Dostal  T. R. van Hengstum  J. G. Shellnutt  J. J. Hanley 《Contributions to Mineralogy and Petrology》2016,171(6):59

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Lead Removal from Aqueous Solution by Natural and Pretreated Zeolites     

Ismael S. Ismael  Ahmed Melegy  Tomas Kratochvíl 《Geotechnical and Geological Engineering》2012,30(1):253-262

Hazardous metal cations enter water through the natural geochemical route or from the industrial wastes. Their separation and removal can be achieved by adsorptive accumulation of the cations on a suitable adsorbent. In the present work, toxic Pb(II) ions are removed from water by accumulating it on the surface of natural zeolite in three different forms; one untreated and two treated samples, one sample treated with 2 M HCI solution and other is treated with 3 M NaOH solution. Natural zeolite is mainly composed of clinoptilolite, and mordenite, with amount of non-zeolite phase (smectite and illite) and C and CT opal. The adsorption experiments are carried out using a batch process in environments of different pH, initial Pb(II) concentration, interaction time and amount of zeolites. Treated zeolite samples show high exchange capacity for Pb(II) compared to untreated sample, however, acid-treated sample shows an exceedingly good exchange capacity. Equilibrium data fitted well with the Langmuir isotherm model with maximum adsorption capacity of 115, 126, and 132 mg g⁻¹ of untreated natural zeolites, alkali-treated zeolites and acid-treated zeolites respectively. The rates of adsorption were found to confirm to pseudo-first order kinetic with good correlation and the overall rate of lead ions uptake.  相似文献   

Provenance of the Greater Himalayan sequence: Evidence from mafic granulites and amphibolites in NW Bhutan     

Joyia Chakungal  Jaroslav Dostal  Djordje Grujic  Stéphanie Duchêne  Kharka S. Ghalley 《Tectonophysics》2010,480(1-4):198-212

Mafic granulites and amphibolites in the Masang Kang area of NW Bhutan Himalaya have been investigated for their geochemical and isotopic characteristics in order to determine their protolith history. Bulk-rock major and trace element geochemistry indicate that the rocks were originally tholeiitic and alkali basalts with minor ultramafics. U–Pb zircon SIMS data suggest an age of 1742 ± 39 Ma for mafic magmatism. The age-corrected ε_Nd(1742) values of the rocks are highly variable, ranging from high positive (+ 8.4) to negative (? 3.3). The positive value suggests a primitive magma source, similar to that of rift-related tholeiites. We suggest that the rocks of the Masang Kang suite were produced during a major late Paleoproterozoic thermal event that caused the mobilization and enrichment of the sub-continental lithospheric mantle beneath the north Indian margin. The geochemical signature of these rift-related metabasic rocks may have been produced during an earlier episode of oceanic underplating or subduction from which the fluid required to mobilize and enrich the overlying sub-lithospheric mantle may have been derived. Though their occurrence is rare, Paleoproterozoic igneous rocks within the Greater Himalayan Sequence (GHS), in addition to sources identified throughout the LHS, may have contributed to the detrital zircon population that form the 1.7–1.9 Ga peak in the age spectra of the Lesser Himalayan Sequence (LHS). In addition, the coeval Paleoproterozoic magmatism in both LHS and GHS suggests that the two lithotectonic units may have belonged to the same continental plate at that time period.  相似文献   

Basic physiological biomarkers in adult female perch (Perca fluviatilis) in a chronically polluted gradient in the Stockholm recipient (Sweden)     

Linderoth M  Hansson T  Liewenborg B  Sundberg H  Noaksson E  Hanson M  Zebühr Y  Balk L 《Marine pollution bulletin》2006,53(8-9):437-450

By measuring a battery of basic physiological biomarkers and the concentration of SigmaDDT in adult female perch (Perca fluviatilis), an assumed aquatic pollution gradient was confirmed, with the city of Stockholm (Sweden) as a point source of anthropogenic substances. The investigation included an upstream gradient, westwards through Lake M?laren (46 km), and a downstream gradient, eastwards through the Stockholm archipelago (84 km). The results indicated a severe pollution situation in central Stockholm, with poor health status of the perch: retarded growth, increased frequency of sexually immature females, low gonadosomatic index, and disturbed visceral fat metabolism. SigmaDDT, measured as a pollution indicator, was 10-28 times higher than the background in perch from the Baltic Proper. Besides the main gradient other sources of pollution also influenced the response pattern of the measured biomarkers. In particular, there were strong indications of pollution coming from the Baltic Sea.  相似文献   

Geochronology, geochemistry and petrogenesis of mafic and ultramafic rocks from Southern Beishan area, NW China: Implications for crust–mantle interaction     

Yuanyuan Zhang  Jaroslav Dostal  Zehui Zhao  Chang Liu  Zhaojie Guo 《Gondwana Research》2011,20(4):816-830

The Liuyuan mafic and ultramafic rocks are exposed in Southern Beishan, which is along the southern branch of the Central Asian Orogenic Belt (CAOB). Zircon SHRIMP U–Pb dating showed that Liuyuan gabbros intruded during the early Permian (~ 270–295 Ma) coeval with the basalts and the ultramafic rocks were emplaced at about 250 Ma. The basalts are within–plate tholeiites with slight enrichment in light rare earth elements (LREE) relative to heavy rare earths (HREE) and small negative anomalies of Nb and Ta. Gabbros including olivine gabbros, olivine gabbronorites and troctolites are grouped into two: the cumulate gabbros are depleted in LREE and show small negative Nb and Ta anomalies but distinct positive Sr and Eu anomalies; non–cumulate gabbros resemble tholeiitic basalts. Lamprophyres and cumulate ultramafic rocks are characterized by large enrichment of LREE relative to HREE with depletion in Nb and Ta. The enriched Sr–Nd isotopic trend from DM towards the EM II end member component implies that the lithospheric mantle was progressively enriched with depth by the involvement of subducted crustal material due to the delamination of thickened mantle lithosphere after collision. The digestion of subducted crustal material into the mantle resulting in the metasomatized and enriched mantle is inferred to be an important process during crust–mantle interaction.  相似文献   

The galaxy population of intermediate-redshift clusters     

Tomas Dahlén †  Claes Fransson  Göran Östlin  Magnus Näslund 《Monthly notices of the Royal Astronomical Society》2004,350(1):253-266

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Highly depleted oceanic lithosphere in the Rheic Ocean: Implications for Paleozoic plate reconstructions     

J. Brendan Murphy  Brian L. Cousens  James A. Braid  Rob A. Strachan  Jaroslav Dostal  J. Duncan Keppie  R. Damian Nance 《Lithos》2011,123(1-4):165-175

The Rheic Ocean formed at ca. 500 Ma, when several peri-Gondwanan terranes (e.g. Avalonia and Carolinia) drifted from the northern margin of Gondwana, and were consumed during the Late Carboniferous collision between Laurussia and Gondwana, a key event in the formation of Pangea. Several mafic complexes ranging in age from ca. 400–330 Ma preserve many of the lithotectonic and/or chemical characteristics of ophiolites. They are characterized by anomalously high εNd values that are typically either between or above the widely accepted model depleted mantle curves. These data indicate derivation from a highly depleted (HD) mantle and imply that (i) the mantle source of these complexes displays time-integrated depletion in Nd relative to Sm, and (ii) depletion is the result of an earlier melting event in the mantle from which basalt was extracted. The extent of mantle depletion indicates that this melting event occurred in the Neoproterozoic, possibly up to 500 million years before the Rheic Ocean formed. If so, the mantle lithosphere that gave rise to the Rheic Ocean mafic complexes must have been captured from an adjacent, older oceanic tract. The transfer of this captured lithosphere to the upper plate enabled it to become preferentially preserved. Possible Mesozoic–Cenozoic analogues include the capture of the Caribbean plate or the Scotia plate from the Pacific to the Atlantic oceanic realm. Our model implies that virtually all of the oceanic lithosphere generated during the opening phase of the Rheic Ocean was consumed by subduction during Laurentia–Gondwana convergence.  相似文献   

geneGIS: Geoanalytical Tools and Arc Marine Customization for Individual‐Based Genetic Records     

Dorothy M. Dick  Shaun Walbridge  Dawn J. Wright  John Calambokidis  Erin A. Falcone  Debbie Steel  Tomas Follett  Jason Holmberg  C. Scott Baker 《Transactions in GIS》2014,18(3):324-350

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Shock experiments in range of 10–45 GPa with small multidomain magnetite in porous targets     

Tomas KOHOUT  Lauri J. PESONEN  Alexander DEUTSCH  Kai WÜNNEMANN  Daniela NOWKA  Ulrich HORNEMANN  Erkki HEIKINHEIMO 《Meteoritics & planetary science》2012,47(10):1671-1680

Abstract– Physical properties of multidomain magnetite‐bearing porous pellets shocked up to 45 GPa were measured. The results show general magnetic softening as a result of shock. However, a relative magnetic hardening trend and slight magnetic susceptibility decrease is observed with increasing pressure among shocked samples. Initially, the shock also seems to cause a slight decrease in porosity, but at higher shock pressures macroscopic porosity increases progressively in our pellets. The microscopic porosity remains almost unchanged. Since our samples have distinctly higher initial porosity compared with samples used in previous studies, our results may be representative for impacts into highly porous magnetite‐bearing sedimentary or volcanic rocks and are relevant to impacts into such target rocks on Earth and Mars.  相似文献   

Petrology and zircon U–Pb dating of well‐preserved eclogites from the Thongmön area in central Himalaya and their tectonic implications     

Qingyun Li  Lifei Zhang  Bin Fu  Tomas Bader  Huanglu Yu 《Journal of Metamorphic Geology》2019,37(2):203-226

The discovery of eclogites is reported within the Great Himalayan Crystalline Complex in the Thongmön area, central Himalaya, and their metamorphic evolution is deciphered by petrographic studies, pseudosection modelling, and zircon dating. For the first time, omphacite has been found in the matrix of eclogites taken from a metamorphic mafic lens. Two groups of garnet have been identified in the Thongmön eclogites on the basis of major and rare earth elements and mineral inclusions. Core and intermediate sections of garnet represent Grt I, in which the major elements (Ca, Mg, and Fe) show a nearly homogenous distribution with little or weak zonation. This Grt I displays an almost flat chondrite‐normalized HREE pattern, and the main inclusions are amphibole, apatite, quartz, and abundant omphacite. Grt II, forms thin rims on large garnet grains, and is characterized by rim‐ward Ca decrease and Mg increase and MREE enrichment relative to HREE and LREE. No amphibole inclusions are found in Grt II, indicating the decomposition of amphibole contributed to its MREE enrichment. Two metamorphic stages, recorded by matrix minerals and inclusions in garnet and zircon, outline the burial of the Thongmön eclogites and progressive metamorphic processes to the pressure peak: (a) the assemblage of amphibole–garnet–omphacite–phengite–rutile–quartz, with the phengite interpreted as having been replaced by Bt+Pl symplectites, represents the prograde amphibole eclogite facies stage M1₍₁₎, (b) in the peak eclogite facies [stage M1₍₂₎], amphibole was lost and melting started. Based on the compositions of garnet and omphacite inclusions, M1₍₁₎ is constrained to 19–20 kbar and 640–660°C and M1₍₂₎ occurred at >21 kbar, >750°C, with appearance of melt and its entrapment in metamorphic zircon. SHRIMP U–Pb dating of zircon from two eclogite samples yielded consistent metamorphic ages of 16.7 ± 0.6 Ma and 17.1 ± 0.4 Ma respectively. The metamorphic zircon grew concurrently with Grt II in the peak eclogite facies. Thongmön eclogites characterized by the prograde metamorphism from amphibolite facies to eclogite facies were formed by the continuing continental subduction of Indian plate beneath the Euro‐Asian continent in the Miocene.  相似文献