Factors affecting preservation of coesite in ultrahigh‐pressure metamorphic rocks: Insights from TEM observations of dislocations within kyanite     

Tomoki Taguchi  Yohei Igami  Akira Miyake  Masaki Enami 《Journal of Metamorphic Geology》2019,37(3):401-414

To understand the preservation of coesite inclusions in ultrahigh‐pressure (UHP) metamorphic rocks, an integrated petrological, Raman spectroscopic and focussed ion beam (FIB) system–transmission electron microscope (TEM) study was performed on a UHP kyanite eclogite from the Sulu belt in eastern China. Coesite grains have been observed only as rare inclusions in kyanite from the outer segment of garnet and in the matrix. Raman mapping analysis shows that a coesite inclusion in kyanite from the garnet rim records an anisotropic residual stress and retains a maximum residual pressure of ~0.35 GPa. TEM observations show quartz is absent from the coesite inclusion–host kyanite grain boundaries. Numerous dislocations and sub‐grain boundaries are present in the kyanite, but dislocations are not confirmed in the coesite. In particular, dislocations concentrate in the kyanite adjacent to the boundary with the coesite inclusion, and they form a dislocation concentration zone with a dislocation density of ~10⁹ cm^?2. A high‐resolution TEM image and a fast Fourier transform‐filtered image reveal that a tiny dislocation in the dislocation concentration zone is composed of multiple edge dislocations. The estimated dislocation density in most of the kyanite away from the coesite inclusion–host kyanite grain boundaries is ~10⁸ cm^?2, being lower than that in kyanite adjacent to the coesite. In the case of a coesite inclusion in a matrix kyanite, using Raman and TEM analyses, we could not identify any quartz at the grain boundaries. Dislocations are not observed in the coesite, but numerous dislocations and stacking faults are developed in the kyanite. The estimated overall dislocation density in the coesite‐bearing matrix kyanite is ~10⁸ cm^?2, but a high dislocation density region of ~10⁹ cm^?2 is also present near the coesite inclusion–host kyanite grain boundaries. Inclusion and matrix kyanite grains with no coesite have dislocation densities of ≤10⁸ cm^?2. Dislocation density is generally reduced during an annealing process, but our results show that not all dislocations in the kyanite have recovered uniformly during exhumation of the UHP rocks. Hence, one of the key factors acting as a buffer to inhibit the coesite to quartz transformation is the mechanical interaction between the host and the inclusion that lead to the formation of dislocations in the kyanite. The kyanite acts as an excellent pressure container that can preserve coesite during the decompression of rocks from UHP conditions. The search for and study of inclusions in kyanite may be a more suitable approach for tracing the spatial distribution of UHP metamorphic rocks.  相似文献   

Interdecadal changes of the Indian Ocean subtropical dipole mode     

Yoko Yamagami  Tomoki Tozuka 《Climate Dynamics》2015,44(11-12):3057-3066

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Effects of bedrock groundwater discharge on spatial variability of dissolved carbon,nitrogen, and phosphorous concentrations in stream water within a forest headwater catchment     

Tomohiro Egusa  Tomo'omi Kumagai  Tomoki Oda  Nobuhito Ohte 《水文研究》2021,35(1):e13993

The quantitative evaluation of the effects of bedrock groundwater discharge on spatial variability of stream dissolved organic carbon (DOC), dissolved inorganic nitrogen (DIN) and dissolved inorganic phosphorous (DIP) concentrations has still been insufficient. We examined the relationships between stream DOC, DIN and DIP concentrations and bedrock groundwater contribution to stream water in forest headwater catchments in warm-humid climate zones. We sampled stream water and bedrock springs at multiple points in September and December 2013 in a 5 km² forest headwater catchment in Japan and sampled groundwater in soil layer in small hillslopes. We assumed that stream water consisted of four end members, groundwater in soil layer and three types of bedrock groundwater, and calculated the contributions of each end member to stream water from mineral-derived solute concentrations. DOC, DIN and DIP concentrations in stream water were compared with the calculated bedrock groundwater contribution. The bedrock groundwater contribution had significant negative linear correlation with stream DOC concentration, no significant correlation with stream DIN concentration, and significant positive linear correlation with stream DIP concentration. These results highlighted the importance of bedrock groundwater discharge in establishing stream DOC and DIP concentrations. In addition, stream DOC and DIP concentrations were higher and lower, respectively, than those expected from end member mixing of groundwater in soil layer and bedrock springs. Spatial heterogeneity of DOC and DIP concentrations in groundwater and/or in-stream DOC production and DIP uptake were the probable reasons for these discrepancies. Our results indicate that the relationships between spatial variability of stream DOC, DIN and DIP concentrations and bedrock groundwater contribution are useful for comparing the processes that affect stream DOC, DIN and DIP concentrations among catchments beyond the spatial heterogeneity of hydrological and biogeochemical processes within a catchment.  相似文献   

Effect of bedrock flow on catchment rainfall‐runoff characteristics and the water balance in forested catchments in Tanzawa Mountains,Japan     

Tomoki Oda  Masakazu Suzuki  Tomohiro Egusa  Yoshimi Uchiyama 《水文研究》2013,27(26):3864-3872

In this paper, we examined the role of bedrock groundwater discharge and recharge on the water balance and runoff characteristics in forested headwater catchments. Using rigorous observations of catchment precipitation, discharge and streamwater chemistry, we quantified net bedrock flow rates and contributions to streamwater runoff and the water balance in three forested catchments (second‐order to third‐order catchments) underlain by uniform bedrock in Japan. We found that annual rainfall in 2010 was 3130 mm. In the same period, annual discharge in the three catchments varied from 1800 to 3900 mm/year. Annual net bedrock flow rates estimated by the chloride mass balance method at each catchment ranged from ?1600 to 700 mm/year. The net bedrock flow rates were substantially different in the second‐order and third‐order catchments. During baseflow, discharge from the three catchments was significantly different; conversely, peak flows during large storm events and direct runoff ratios were not significantly different. These results suggest that differences in baseflow discharge rates, which are affected by bedrock flow and intercatchment groundwater transfer, result in the differences in water balance among the catchments. This study also suggests that in these second‐order to third‐order catchments, the drainage area during baseflow varies because of differences between the bedrock drainage area and surface drainage area, but that the effective drainage area during storm flow approaches the surface drainage area. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Variation in lunar sodium exosphere measured from lunar orbiter SELENE (Kaguya)     

M. Kagitani  M. Taguchi  I. Yoshikawa  K. Yoshioka  S. Okano 《Planetary and Space Science》2010,58(12):1660-1664

Resonant scattering of the lunar sodium exosphere was measured from the lunar orbiter SELENE (Kaguya) from December 2008 to June 2009. Variations in line-of-sight integrated intensity measured on the night-side hemisphere of the Moon could be described as a spherical symmetric distribution of the sodium exosphere with a temperature of 2400-6000 K. Average surface density of sodium atoms in February is well above that in the other months by about 30%. A clear variation in surface density related to the Moon’s passage across the Earth’s magnetotail could not be seen, although sodium density gradually decreased (by 20±8%) during periods from the first through the last quarter of two lunar cycles. These results suggest that the supra-thermal components of the sodium exosphere are not mainly produced by classical sputtering of solar wind. The variation in sodium density (which depends on lunar-phase angle) is possibly explained by the presence of an inhomogeneous source distribution of photon-stimulated desorption (PSD) on the surface.  相似文献   

Noble gases in enstatite chondrites released by stepped crushing and heating     

Ryuji OKAZAKI  Nobuo TAKAOKA  Keisuke NAGAO  Tomoki NAKAMURA 《Meteoritics & planetary science》2010,45(3):339-360

Abstract– Enstatite chondrites (ECs) were subjected to noble gas analyses using stepped crushing and pyrolysis extraction methods. ECs can be classified into subsolar gas‐carrying and subsolar gas‐free ECs based on the ³⁶Ar/⁸⁴Kr/¹³²Xe ratios. For subsolar gas‐free ECs, elemental ratios, and Xe isotopic compositions indicate that Q gas is the dominant trapped component, the Q gas concentration can be correlated with the petrologic type, reasonably explained by gas release from a common EC parental material during subsequent heating. Atmospheric Xe with sub‐Q elemental ratios is found in Antarctic E3s at 600–800 °C and through crushing. The ¹³²Xe released in these fractions accounts for 30–60% of the bulk concentrations. Hence, the sub‐Q signature is generally due to contamination of elementally fractionated atmosphere. Subsolar gas is mainly released (up to 78% of the bulk ³⁶Ar) at 1300–1600 °C and through crushing, suggesting that enstatite and friable phases are the host phases. Subsolar gas is isotopically identical to solar gas, but elementally fractionated. These observations are consistent with a previous study, which suggested that subsolar gas could be fractionated solar wind having been implanted into chondrule precursors ( Okazaki et al. 2001 ). Unlike subsolar gas‐free ECs, the primordial gas concentrations of subsolar gas‐carrying ECs are not simply correlated with the petrologic type. It is inferred that subsolar gas‐rich chondrules were heterogeneously distributed in the solar nebula and accreted to form subsolar gas‐carrying ECs. Subsequent metamorphic and impact‐shock heating events have affected noble gas compositions to various degrees.  相似文献   

Suspended sediment discharge in subsurface flow from the head hollow of a small forested watershed,northern Japan     

Tomomi Terajima  Tomoki Sakamoto  Yuichiro Nakai  Kenzo Kitamura 《地球表面变化过程与地形》1997,22(11):987-1000

Surface flow and suspended sediment discharge from the head hollow of the Jozankei Experimental Watershed in Hokkaido, northern Japan, were measured to clarify the implications of subsurface hydrology for soil movement. Subsurface discharges during the extremely large storms of 1993 to 1994 were measured in a V-notch weir installed at a natural spring near the bottom of the head hollow, and shallow groundwater levels were observed in the wells excavated in the hollow. Sediment samples whose particle size range from 0·001 to 0·1 mm were manually and automatically collected at 15 to 60 min intervals, by use of 1 or 21 polyethylene bottles. Maximum concentration and flux of suspended sediment during the storms preceded the peak discharge of subsurface flow by several hours. Neither the changes in concentration (mg l⁻¹) nor flux (mg s⁻¹) of suspended sediment coincided with those in subsurface discharge (l s⁻¹). Furthermore, sediment concentration was poorly correlated with the rate of change in subsurface discharge (l s⁻²) during the rising limb of the hydrograph. Suspended sediment flux during the acceleratory limb, however, was closely correlated with the rate of change in subsurface discharge. The relationship between suspended sediment flux and rate of change in subsurface discharge were in inverse proportion to initial subsurface discharge before the storm runoff and they represented rare seasonal variation. Subsurface hydraulic erosion and transport of suspended sediment resulting from changes in rate of change in subsurface discharge actively occur during the acceleratory rising limb of the hydrograph. Accordingly, subsurface hydraulic erosion during the acceleratory rising limb of the hydrograph can be physically understood by analysing suspended sediment flux associated with rate of change in subsurface discharge and initial subsurface discharge. © 1997 John Wiley & Sons, Ltd.  相似文献   

Energy balance above a boreal coniferous forest: a difference in turbulent fluxes between snow‐covered and snow‐free canopies     

Yuichiro Nakai  Tomoki Sakamoto  Tomomi Terajima  Kenzo Kitamura  Tomoki Shirai 《水文研究》1999,13(4):515-529

To evaluate the interactive effects of snow and forest on turbulent fluxes between the forest surface and the atmosphere, the surface energy balance above a forest was measured by the eddy correlation method during the winter of 1995–1996. The forest was a young coniferous plantation comprised of spruce and fir. The study site, in Sapporo, northern Japan, had heavy and frequent snowfalls and the canopy was frequently covered with snow during the study period. A comparison of the observed energy balance above the forest for periods with and without a snow‐covered canopy and an analysis using a single‐source model gave the following results: during daytime when the canopy was covered with snow, the upward latent heat flux was large, about 80% of the net radiation, and the sensible heat flux was positive but small. On the other hand, during daytime when the canopy was dry and free from snow, the sensible heat flux was dominant and the latent heat flux was minor, about 10% of the net radiation. To explain this difference of energy partition between snow‐covered and snow‐free conditions, not only differences in temperature but also differences in the bulk transfer coefficients for latent heat flux were necessary in the model. Therefore, the high evaporation rate from the snow‐covered canopy can be attributed largely to the high moisture availability of the canopy surface. Evaporation from the forest during a 60‐day period in midwinter was estimated on a daily basis as net radiation minus sensible heat flux. The overall average evaporation during the 60‐day period was 0·6 mm day⁻¹, which is larger than that from open snow fields. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

Combining IR and X‐ray microtomography data sets: Application to Itokawa particles and to Paris meteorite     

Zelia Dionnet  Rosario Brunetto  Alice Alon‐Toppani  Stefano Rubino  Donia Baklouti  Ferenc Borondics  Anne‐Ccile Buellet  Zahia Djouadi  Andrew King  Tomoki Nakamura  Alessandra Rotundi  Christophe Sandt  David Troadec  Akira Tsuchiyama 《Meteoritics & planetary science》2020,55(7):1645-1664

In the near future, a new generation of sample return missions (Hayabusa2, OSIRIS‐REx, MMX, etc.) will collect samples from small solar system bodies. To maximize the scientific outcome of laboratory studies and minimize the loss of precious extraterrestrial samples, an analytical sequence from less destructive to more destructive techniques needs to be established. In this work, we present a combined X‐ray and IR microtomography applied to five Itokawa particles and one fragment of the primitive carbonaceous chondrite Paris. We show that this analytical approach is able to provide a 3‐D physical and chemical characterization of individual extraterrestrial particles, using the measurement of their 3‐D structure and porosity, and the detection of mineral and organic phases, and their spatial co‐localization in 3‐D. We propose these techniques as an efficient first step in a multitechnique analytical sequence on microscopic samples collected by space missions.  相似文献   

Visualising Crime Clusters in a Space‐time Cube: An Exploratory Data‐analysis Approach Using Space‐time Kernel Density Estimation and Scan Statistics     

Tomoki Nakaya  Keiji Yano 《Transactions in GIS》2010,14(3):223-239

For an effective interpretation of spatio‐temporal patterns of crime clusters/hotspots, we explore the possibility of three‐dimensional mapping of crime events in a space‐time cube with the aid of space‐time variants of kernel density estimation and scan statistics. Using the crime occurrence dataset of snatch‐and‐run offences in Kyoto City from 2003 to 2004, we confirm that the proposed methodology enables simultaneous visualisation of the geographical extent and duration of crime clusters, by which stable and transient space‐time crime clusters can be intuitively differentiated. Also, the combined use of the two statistical techniques revealed temporal inter‐cluster associations showing that transient clusters alternatively appeared in a pair of hotspot regions, suggesting a new type of “displacement” phenomenon of crime. Highlighting the complementary aspects of the two space‐time statistical approaches, we conclude that combining these approaches in a space‐time cube display is particularly valuable for a spatio‐temporal exploratory data analysis of clusters to extract new knowledge of crime epidemiology from a data set of space‐time crime events.  相似文献