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71.
72.
Temporal variations in the geographic distribution of surface mass cause surface displacements. Surface displacements derived from GRACE gravity field coefficient time series also should be observed in GPS coordinate time series, if both time series are sufficiently free of systematic errors. A successful validation can be an important contribution to climate change research, as the biggest contributors to mass variability in the system Earth include the movement of oceanic, atmospheric, and continental water and ice. In our analysis, we find that if the signals are larger than their precision, both geodetic sensor systems see common signals for almost all the 115 stations surveyed. Almost 80% of the stations have their signal WRMS decreased, when we subtract monthly GRACE surface displacements from those observed by GPS data. Almost all other stations are on ocean islands or small peninsulas, where the physically expected loading signals are very small. For a fair comparison, the data (79 months from September 2002 to April 2009) had to be treated appropriately: the GPS data were completely reprocessed with state-of-the-art models. We used an objective cluster analysis to identify and eliminate stations, where local effects or technical artifacts dominated the signals. In addition, it was necessary for both sets of results to be expressed in equivalent reference frames, meaning that net translations between the GPS and GRACE data sets had to be treated adequately. These data sets are then compared and statistically analyzed: we determine the stability (precision) of GRACE-derived, monthly vertical deformation data to be ~1.2 mm, using the data from three GRACE processing centers. We statistically analyze the mean annual signals, computed from the GPS and GRACE series. There is a detailed discussion of the results for five overall representative stations, in order to help the reader to link the displayed criteria of similarity to real data. A series of tests were performed with the goal of explaining the remaining GPS–GRACE residuals.  相似文献   
73.
The stable carbon and oxygen isotope compositions of fossil ostracods are powerful tools to estimate past environmental and climatic conditions. The basis for such interpretations is that the calcite of the valves reflects the isotopic composition of water and its temperature of formation. However, calcite of ostracods is known not to form in isotopic equilibrium with water and different species may have different offsets from inorganic precipitates of calcite formed under the same conditions. To estimate the fractionation during ostracod valve calcification, the oxygen and carbon isotope compositions of 15 species living in Lake Geneva were related to their autoecology and the environmental parameters measured during their growth. The results indicate that: (1) Oxygen isotope fractionation is similar for all species of Candoninae with an enrichment in 18O of more than 3‰ relative to equilibrium values for inorganic calcite. Oxygen isotope fractionation for Cytheroidea is less discriminative relative to the heavy oxygen, with enrichments in 18O for these species of 1.7 to 2.3‰. Oxygen isotope fractionations for Cyprididae are in-between those of Candoninae and Cytheroidea. The difference in oxygen isotope fractionation between ostracods and inorganic calcite has been interpreted as resulting from a vital effect. (2) Comparison with previous work suggests that oxygen isotope fractionation may depend on the total and relative ion content of water. (3) Carbon isotope compositions of ostracod valves are generally in equilibrium with DIC. The specimens’ δ13C values are mainly controlled by seasonal variations in δ13CDIC of bottom water or variation thereof in sediment pore water. (4) Incomplete valve calcification has an effect on carbon and oxygen isotope compositions of ostracod valves. Preferential incorporation of at the beginning of valve calcification may explain this effect. (5) Results presented here as well as results from synthetic carbonate growth indicate that different growth rates or low pH within the calcification site cannot be the cause of oxygen isotope ‘vital effects’ in ostracods. Two mechanisms that might enrich the 18O of ostracod valves are deprotonation of that may also contribute to valve calcification, and effects comparable to salt effects with high concentrations of Ca and/or Mg within the calcification site that may also cause a higher temperature dependency of oxygen isotope fractionation.  相似文献   
74.
Rare earth elements (REE), while not essential for the physiologic functions of animals, are ingested and incorporated in ppb concentrations in bones and teeth. Nd isotope compositions of modern bones of animals from isotopically distinct habitats demonstrate that the 143Nd/144Nd of the apatite can be used as a fingerprint for bedrock geology or ambient water mass. This potentially allows the provenance and migration of extant vertebrates to be traced, similar to the use of Sr isotopes. Although REE may be enriched by up to 5 orders of magnitude during diagenesis and recrystallization of bone apatite, in vivo143Nd/144Nd may be preserved in the inner cortex of fossil bones or enamel. However, tracking the provenance of ancient or extinct vertebrates is possible only for well-preserved archeological and paleontological skeletal remains with in vivo-like Nd contents at the ppb-level. Intra-bone and -tooth REE analysis can be used to screen for appropriate areas. Large intra-bone Nd concentration gradients of 101-103 are often measured. Nd concentrations in the inner bone cortex increase over timescales of millions of years, while bone rims may be enriched over millenial timescales. Nevertheless, εNd values are often similar within one εNd unit within a single bone. Larger intra-bone differences in specimens may either reflect a partial preservation of in vivo values or changing εNd values of the diagenetic fluid during fossilization. However, most fossil specimens and the outer rims of bones will record taphonomic 143Nd/144Nd incorporated post mortem during diagenesis. Unlike REE patterns, 143Nd/144Nd are not biased by fractionation processes during REE-uptake into the apatite crystal lattice, hence the εNd value is an important tracer for taphonomy and reworking. Bones and teeth from autochthonous fossil assemblages have small variations of ±1 εNd unit only. In contrast, fossil bones and teeth from over 20 different marine and terrestrial fossil sites have a total range of εNd values from -13.0 to 4.9 (n = 80), often matching the composition of the embedding sediment. This implies that the surrounding sediment is the source of Nd in the fossil bones and that the specimens of this study seem not to have been reworked. Differences in εNd values between skeletal remains and embedding sediment may either indicate reworking of fossils and/or a REE-uptake from a diagenetic fluid with non-sediment derived εNd values. The latter often applies to fossil shark teeth, which may preserve paleo-seawater values. Complementary to εNd values, 87Sr/86Sr can help to further constrain the fossil provenance and reworking.  相似文献   
75.
This paper describes a multidisciplinary study approach (petrography and rock magnetism) conducted on samples collected from the study area to characterise the magnetic mineralogy and to determine if the magnetisation of both lithologies were induced or retain a remnant component. Petrophysical, mineralogical and geochemical analyses confirm bimodal aspects, particularly in basic rocks; the two magnetic modes depend essentially on the mineralogical and geochemical characteristics of the samples. The ultramafic rocks comprise a highly altered primary mineralogy with chromite and magnetite as magnetic phases. The second type is of mafic composition with a less altered primary mineralogy and essentially magnetite and/or (hemo-ilmenite) as a carrier of magnetic mineralisation. Sulphides are characterised by high concentrations of Cu, Zn and Pb. The mineralogy is composed mainly of pyrrhotite (85% to 90%), sphalerite, galena, chalcopyrite, arsenopyrite and, occasionally, stannite. Monocline pyrrhotite seems to be the magnetic carrier of magnetisation in both Draa Sfar and Koudiat Aïcha. However, we suspect a different amount of hexagonal pyrrhotite as the cause of different magnetic behaviour. Paleomagnetic and thermomagnetic analyses reveal different. The calculated characteristic direction of natural remnant magnetisation for sulphides was used to model the magnetic anomaly of Draa Sfar. The proposed model match the geological features concluded from geological mapping and boreholes. Results from this work can be very useful for any modelling processes of magnetic anomalies suspected due to a sulphide mineralisation in an area with poor outcrops and no presence of boreholes information or of any geological or geochemical data.  相似文献   
76.
The closed Tangra Yumco Basin underwent the strongest Quaternary lake-level changes so far recorded on the Tibetan Plateau. It was hitherto unknown what effect this had on local Holocene vegetation development. A 3.6-m sediment core from a recessional lake terrace at 4,700 m a.s.l., 160 m above the present lake level of Tangra Yumco, was studied to reconstruct Holocene flooding phases (sedimentology and ostracod analyses), vegetation dynamics and human influence (palynology, charcoal and coprophilous fungi analyses). Peat at the base of the profile proves lake level was below 4,700 m a.s.l. during the Pleistocene/Holocene transition. A deep-lake phase started after 11 cal ka BP, but the ostracod record indicates the level was not higher than ~4,720 m a.s.l. (180 m above present) and decreased gradually after the early Holocene maximum. Additional sediment ages from the basin suggest recession of Tangra Yumco from the coring site after 2.6 cal ka BP, with a shallow local lake persisting at the site until ~1 cal ka BP. The final peat formation indicates drier conditions thereafter. Persistence of Artemisia steppe during the Holocene lake high-stand resembles palynological records from west Tibet that indicate early Holocene aridity, in spite of high lake levels that may have resulted from meltwater input. Yet pollen assemblages indicate humidity closer to that of present potential forest areas near Lhasa, with 500–600 mm annual precipitation. Thus, the early mid-Holocene humidity was sufficient to sustain at least juniper forest, but Artemisia dominance persisted as a consequence of a combination of environmental disturbances such as (1) strong early Holocene climate fluctuations, (2) inundation of habitats suitable for forest, (3) extensive water surfaces that served as barriers to terrestrial diaspore transport from refuge areas, (4) strong erosion that denuded the non-flooded upper slopes and (5) increasing human influence since the late glacial.  相似文献   
77.
Many studies in continental areas have successfully used the oxygen isotope composition of fossil ostracod valves to reconstruct past hydrological conditions associated with large changes in climate. Yet, ostracods are known to crystallise their valves out of isotopic equilibrium for oxygen and they generally have higher 18O contents compared to inorganic calcite grown at equilibrium under the same conditions. A review of vital offsets determined for continental ostracods indicates that vital offsets might change from site to site, questioning a potential influence of environmental conditions on oxygen isotope fractionation in ostracods. Results from the literature suggest that pH has no influence on ostracod vital offset. A re-evaluation of results from Li and Liu (J Paleolimnol 43:111–120, 2010) suggests that salinity may influence oxygen isotope fractionation in ostracods, with lower vital offsets for higher salinities. Such a relationship was also observed for the vital offsets determined by Chivas et al. (The ostracoda—applications in quaternary research. American Geophysical Union, Washington, DC, 2002). Yet, when results of all studies are compiled, the correlation between vital offsets and salinity is low while the correlation between vital offsets and host water Mg/Ca is higher, suggesting that ionic composition of water and/or relative abundance of major ions may also control oxygen isotope fractionation in ostracods. Lack of data on host water ionic composition for the different studies precludes more detailed examination at this stage. Further studies such as natural or laboratory cultures done under strictly controlled conditions are needed to better understand the potential influence of varying environmental conditions on oxygen isotope compositions of ostracod valves.  相似文献   
78.
We present a diatom record from a well-dated 15.25 m composite sedimentary core from Verlorenvlei, a shallow coastal lake on the west coast of South Africa. We show that fluctuations in the diatom record occur in response to changes in sea level, ocean–atmosphere interactions and latitudinal shifts in the wind belts. During the early to mid-Holocene, the system primarily responds to sea level changes. A marine community that favours high nutrients is evident, particularly during 9200–8000, 7420–7000 and 6200–5600 cal a bp , corroborating periods of Benguela upwelling linked to fluctuations in the southeast trade winds. Increases in bioproductivity (%TOC, C/N) and fresher-water diatoms are associated with wetter conditions over the region and the northward migration of the southern westerly wind belt, most notably between 8000 and 7500 cal a bp and over the last 700 years. The latter trends are concomitant with changes in the extent of Antarctic sea ice and availability of moisture in southern South America. During the late Holocene, as sea levels stabilised to modern levels, climate variability is more strongly evident. The body of evidence further reveals the sensitivity of the region to high-latitude atmospheric mechanisms, but also showcases the significance of the southeast trade winds.  相似文献   
79.
80.
Species belonging to the same ecological guild can coexist only if there are differences in their responses to limiting resources. Thus, competitor introductions may modify the niches of the resident competitors, but empirical studies are rare. The extent of niche modification might further depend on the species’ trophic specialisation along the specialists-to-generalists axis. In this study, we performed a semi-natural experiment by introducing a trophically specialised piscivorous fish (pikeperch) to the resident predator guild of a trophic generalist (perch) and a trophic specialist (pike) in a temperate freshwater lake. Individual diet data were used to calculate total niche hypervolume and inter- and intraspecific dietary niche overlap to evaluate strength of competitive interactions before and after pikeperch introduction. In both pike and perch, there was a moderate niche compression in response to pikeperch stocking. Furthermore, whereas perch diet hypervolume did not overlap at all with that of pikeperch, the intersection of niche space between the two trophic specialists was highly asymmetrical in favour of pike due to its less specialised diet composition in comparison with pikeperch. The intraspecific dietary niche overlap between perch size classes reflected an enhanced partitioning, whereas that of pike size classes was found almost unchanged in response to pikeperch stocking. These empirical results corroborate that competitive interactions and the degree of specialisation may strongly shape the success of introductions of top-predators in freshwater ecosystems. The most specialised species may persist only if the competitors belong rather to the generalists along the specialisation continuum.  相似文献   
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