Sulfur sources of sedimentary “buckshot” pyrite in the Auriferous Conglomerates of the Mesoarchean Witwatersrand and Ventersdorp Supergroups,Kaapvaal Craton,South Africa     

B. M. Guy  S. Ono  J. Gutzmer  Y. Lin  N. J. Beukes 《Mineralium Deposita》2014,49(6):751-775

Large rounded pyrite grains (>1 mm), commonly referred to as “buckshot” pyrite grains, are a characteristic feature of the auriferous conglomerates (reefs) in the Witwatersrand and Ventersdorp supergroups, Kaapvaal Craton, South Africa. Detailed petrographic analyses of the reefs indicated that the vast majority of the buckshot pyrite grains are of reworked sedimentary origin, i.e., that the pyrite grains originally formed in the sedimentary environment during sedimentation and diagenesis. Forty-one of these reworked sedimentary pyrite grains from the Main, Vaal, Basal, Kalkoenkrans, Beatrix, and Ventersdorp Contact reefs were analyzed for their multiple sulfur isotope compositions (δ³⁴S, Δ³³S, and Δ³⁶S) to determine the source of the pyrite sulfur. In addition, five epigenetic pyrite samples (pyrite formed after sedimentation and lithification) from the Middelvlei and the Ventersdorp Contact reefs were measured for comparison. The δ³⁴S, Δ³³S, and Δ³⁶S values of all 41 reworked sedimentary pyrite grains indicate clear signatures of mass-dependent and mass-independent fractionation and range from ?6.8 to +13.8?‰, ?1.7 to +1.7?‰, and ?3.9 to +0.9?‰, respectively. In contrast, the five epigenetic pyrite samples display a very limited range of δ³⁴S, Δ³³S, and Δ³⁶S values (+0.7 to +4.0?‰, ?0.3 to +0.0?‰. and ?0.3 to +0.1?‰, respectively). Despite the clear signatures of mass-independent sulfur isotope fractionation, very few data points plot along the primary Archean photochemical array suggesting a weak photolytic control over the data set. Instead, other factors command a greater degree of influence such as pyrite paragenesis, the prevailing depositional environment, and non-photolytic sulfur sources. In relation to pyrite paragenesis, reworked syngenetic sedimentary pyrite grains (pyrite originally precipitated along the sediment-water interface) are characterized by negative δ³⁴S and Δ³³S values, suggesting open system conditions with respect to sulfate supply and the presence of microbial sulfate reducers. On the contrary, most reworked diagenetic sedimentary pyrite grains (pyrite originally precipitated below the sediment-water interface) show positive δ³⁴S and negative Δ³³S values, suggesting closed system conditions. Negligible Δ³³S anomalies from epigenetic pyrite suggest that the sulfur was sourced from a mass-dependent or isotopically homogenous metamorphic/hydrothermal fluid. Contrasting sulfur isotope compositions were also observed from different depositional environments, namely fluvial conglomerates and marine-modified fluvial conglomerates. The bulk of the pyrite grains from fluvial conglomerates are characterized by a wide range of δ³⁴S values (?6.2 to +4.8?‰) and small Δ³³S values (±0.3?‰). This signature likely represents a crustal sulfate reservoir derived from either volcanic degassing or from weathering of sulfide minerals in the hinterland. Reworked sedimentary pyrite grains from marine-modified fluvial conglomerates share similar isotope compositions, but also produce a positive Δ³³S/δ³⁴S array that overlaps with the composition of Archean barite, suggesting the introduction of marine sulfur. These results demonstrate the presence of multiple sources of sulfur, which include atmospheric, crustal, and marine reservoirs. The prevalence of the mass-dependent crustal sulfur isotope signature in fluvial conglomerates suggests that sulfate concentrations were probably much higher in terrestrial settings in comparison to marine environments, which were sulfate-deficient. However, the optimum conditions for forming terrestrial sedimentary pyrite were probably not during fluvial progradation but rather during the early phases of flooding of low angle unconformities, i.e., during retrogradational fluvial deposition, coupled in some cases with marine transgressions, immediately following inflection points of maximum rate of relative sea level fall.  相似文献   

Assessment of rainfall-induced shallow landslides in Phetchabun and Krabi provinces,Thailand     

Keisuke Ono  So Kazama  Chaiwat Ekkawatpanit 《Natural Hazards》2014,74(3):2089-2107

Shallow landslides are a common type of rainfall-induced landslide, and various methods are currently used to predict their occurrence on a regional scale. Physically based models, such as the shallow landslide instability prediction (SLIP) model, have many advantages because these models can assess the hazards of shallow landslides dynamically, based on physical stability equations that consider rainfall as a triggering factor. The main objective of this research is to test the SLIP model’s potential to predict shallow landslide hazards in Thailand. To achieve this goal, the SLIP model was applied to two massive landslide events in Thailand. The results predicted by the SLIP model for the two study areas are outlined, and the model prediction capabilities were evaluated using the receiver operating characteristic plot. The Phetchabun results showed that the western part of the catchment had the lowest factor of safety (F _S) value, whereas the Krabi results showed that the slopes surrounding the peak of Khao Panom Mountain had the lowest F _S value, explaining the highest potentials for shallow landslides in each area. The SLIP model showed good performance: The global accuracies were 0.828 for the Phetchabun area and 0.824 for the Krabi area. The SLIP model predicted the daily time-varying percentage of unstable areas over the analyzed periods. The SLIP model simulated a negligible percentage of unstable areas over all considered periods, except for expected dates, suggesting that the prediction capability is reasonably accurate.  相似文献   

ASCA Observations of X-ray Emission from Ultra-luminous Infrared Galaxies     

Takao Nakagawa  Tsuneo Kii  Ryuichi Fujimoto  Toshiyuki Miyazaki  Hajime Inoue  Yasushi Ogasaka  Ryohei Kawabe 《Astrophysics and Space Science》1999,266(1-2):43-48

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Optical depth,size distribution and flux of dust from Owens Lake,California     

Tezz C. Niemeyer  Dale A. Gillette  John J. DeLuisi  Young J. Kim  William F. Niemeyer  Trevor Ley  Thomas E. Gill  Duane Ono 《地球表面变化过程与地形》1999,24(5):463-479

A joint United States/Russian/French collaborative experiment was undertaken in March 1993 and March 1996. Projects LODE I and II (Lake Owens Dust Experiments) took place on the anthropogenically desertified playa (dry lakebed) and surrounding regions of Owens Lake, in east-central California. One of the five parts of Project LODE was to determine relationships between optical depth and flux of dust emitted from the dry lake. Project LODE II included subsequent dust plume measurements and size distributions obtained through April 1996, to further refine the flux measurements for distinct mineral aerosol source regions at Owens Lake. Size distributions of dust aerosol were determined and aerosol optical depths were calculated from sunphotometer solar extinction measurements taken downwind in plumes coming from the emissive areas of Owens Lake. This source was visually observed for 10 measured dust storms. The plume mass was calculated to be 1·5 × 10⁹ g using ground-based measurements and ≥1·6 × 10⁹ g from satellite data. Project LODE II results were found to be consistent with LODE I results for the south end of the playa, but flux values were found to be reduced for the northeastern portion of the playa by comparison. Vertical flux values estimated by sunphotometry were found to be consistent with values estimated via a micrometeorological method. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

Response uncertainty and time-variant reliability analysis for hysteretic MDF structures     

Y. G. Zhao  T. Ono  H. Idota 《地震工程与结构动力学》1999,28(10):1187-1213

Response uncertainty evaluation and dynamic reliability analysis corresponding to classical stochastic dynamic analysis are usually restricted to the uncertainties of the excitation. The inclusion of the parameter uncertainties contained in structural properties and excitation characteristics has become an increasingly important problem in many areas of dynamics. In the present paper, a point estimate procedure is proposed for the evaluation of stochastic response uncertainty, and a response surface approach procedure in standard normal space is proposed for analysis of time-variant reliability analysis for hysteretic MDF structures having parameter uncertainties. Using the proposed procedures, the response uncertainties and time-variant reliability can be easily obtained by several repetitions of stochastic response analysis under given parameters without conducting sensitivity analysis, which is considered to be one of the primary difficulties associated with conventional methods. In the time-variant reliability analysis, the failure probability can be readily obtained by improving the accuracy of the first-order reliability method using the empirical second-order reliability index. The random variables are divided into two groups, those with CDF and those without CDF. The latter are included via the high-order moment standardization technique. A numerical example of a 15F hysteretic MDF structure that takes into account uncertainties of four structural parameters and three excitation characteristics is performed, based on which the proposed procedures are investigated and the effects of parameter uncertainties are discussed. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

Magnetic detection of heated soils at paleolithic sites in Japan     

Hayao Morinaga  Hiroo Inokuchi  Hideki Yamashita  Akira Ono  Takashi Inada 《Geoarchaeology》1999,14(5):377-399

We present a methodological approach to detect heated soil on ancient sites, using magnetic measurements. The method is based on changes in magnetic signals of soil by heating. The following three types of soil were used for testing the method: silty soil (SS), weathered volcanic ash (WVA, = loam) and fairly fresh volcanic ash (VA) called Odori tephra. On heating above 250–600°C, the magnetic susceptibility and remanent magnetization intensity increased for the SS and WVA samples, reflecting chemical alteration of magnetic minerals (from goethites to magnetites through hematites). The VA sample showed no susceptibility change suggesting the absence of goethites within it. On heating below 250°C, only the intensities of all the samples increased. This is possibly due to acquisition of thermal remanent magnetization. The largest change of the magnetic signals was identified for the SS sample and the smallest one was seen for the VA sample. Therefore, the in situ susceptibility measurement, which is the nondestructive and indirect method, seems to be effective to detect heated soil for sites of aqueous deposits as the SS. On the other hand, for sites of aeolian deposits as the WVA (loam) and VA, the intensity measurement of collected soils seems to be the most reliable method to detect evidence of heating. The degree of the magnetic stability (coercivity) against progressive alternating-field demagnetization was also an important parameter, indicating whether the investigated soils were heated or unheated. © 1999 John Wiley & Sons, Inc.  相似文献