Spectra of CO<Subscript>2</Subscript> and Water Vapour in the Marine Atmospheric Surface Layer   总被引：1，自引：1，他引：0  

Erik Sahlée  Ann-Sofi Smedman  Anna Rutgersson  Ulf Högström 《Boundary-Layer Meteorology》2008,126(2):279-295

Spectra of CO₂ and water vapour fluctuations from measurements made in the marine atmospheric surface layer have been analyzed. A normalization of spectra based on Monin–Obukhov similarity theory, originally developed for wind speed and temperature, has been successfully extended also to CO₂ and humidity spectra. The normalized CO₂ spectra were observed to have somewhat larger contributions from low frequencies compared to humidity spectra during unstable stratification. However, overall, the CO₂ and humidity spectra showed good agreement as did the cospectra of vertical velocity with water vapour and CO₂ respectively. During stable stratification the spectra and cospectra displayed a well-defined spectral gap separating the mesoscale and small-scale turbulent fluctuations. Two-dimensional turbulence was suggested as a possible source for the mesoscale fluctuations, which in combination with wave activity in the vertical wind is likely to explain the increase in the cospectral energy for the corresponding frequency range. Prior to the analysis the turbulence time series of the density measurements were converted to time series of mixing ratios relative to dry air. Some differences were observed when the spectra based on the original density measurements were compared to the spectra based on the mixing ratio time series. It is thus recommended to always convert the density time series to mixing ratio before performing spectral analysis.  相似文献   

Storm surges in the Western Baltic Sea: the present and a possible future   总被引：3，自引：1，他引：2  

Ulf Gr?we  Hans Burchard 《Climate Dynamics》2012,39(1-2):165-183

Globally-coupled climate models are generally capable of reproducing the observed trends in the globally averaged atmospheric temperature or mean sea level. However, the global models do not perform as well on regional/local scales. Here, we present results from four 100-year ocean model experiments for the Western Baltic Sea. In order to simulate storm surges in this region, we have used the General Estuarine Transport Model (GETM) as a high-resolution local model (spatial resolution ≈ 1?km), nested into a regional atmospheric and regional oceanic model in a fully baroclinic downscaling approach. The downscaling is based on the global model ECHAM5/MPI-OM. The projections are imbedded into two greenhouse-gas emission scenarios, A1B and B1, for the period 2000–2100, each with two realisations. Two control runs from 1960 to 2000 are used for validation. We use this modelling system to statistically reproduce the present distribution of surge extremes. The usage of the high-resolution local model leads to an improvement in surge heights of at least 10% compared to the driving model. To quantify uncertainties associated with climate projections, we investigate the impact of enhanced wind velocities and changes in mean sea levels. The analysis revealed a linear dependence of surge height and mean sea level, although the slope parameter is spatially varying. Furthermore, the modelling system is used to project possible changes within the next century. The results show that the sea level rise has greater potential to increase surge levels than does increased wind speed. The simulations further indicate that the changes in storm surge height in the scenarios can be consistently explained by the increase in mean sea level and variation in wind speed.  相似文献   

Precise electron microprobe age determination in altered uraninite: consequences on the intrusion age and the metallogenic significance of the Kirchberg granite (Erzgebirge,Germany)   总被引：6，自引：0，他引：6  

Ulf?KempeEmail author 《Contributions to Mineralogy and Petrology》2003,145(1):107-118

An integral method of data evaluation for chemical dating of accessory uraninite by electron microprobe analysis and electron microscopy is proposed. The internal structure of uraninite grains, the contents of Si, Ca, and Fe, and tests for loss or gain of Pb and U are suitable criteria to decide whether or not a given crystal area was affected by secondary alteration. The method was applied to uraninite from the Kirchberg granite, Erzgebirge, Germany, and an age of 330LJ Ma (DŽ†) was constrained. This result supports earlier assumptions that there were at least two events of Hercynian granite magmatism separated by a time gap of about 40 Ma, and that the magmatic evolution of the Kirchberg granite is not related to the formation of the W mineralisation developed in the endocontact of this granite. Secondary alteration of uraninite is probably closely related to the formation of U deposits in the vicinity of the Kirchberg massif which was extensively mined in the past.  相似文献   

Calculation of sensible and latent heat fluxes,and surface resistance from profile data     

Adrian DeHeer-Amissah  Ulf Högström  Ann-Sofi Smedman-Högström 《Boundary-Layer Meteorology》1981,20(1):35-49

A set of semi-continuous measurements of temperature, wind and moisture gradients as well as of net radiation and ground heat flux covering a period of about one and a half years has been analysed to give a corresponding set of complete surface energy balance data on an hourly basis. An analysis of the evaporation data so obtained is given.It is shown that surface resistance r _S exhibits a diurnal trend: values are smallest (ca. 150 s m^-1) a few hours before noon and increase to as much as 800 s m^-1 towards dusk. The minimum values tend to be higher during dry periods when the soil moisture is low. There is also some indication that r _S decreases rapidly soon after rainfall.An exponential relation is found between the fraction of available energy used as evaporative flux, , and r _S for values of r _I/r_S <0.70, where r _I is the climatological resistance. On the other hand, the ratio of r _I to r _S is linearly correlated with , implying that an equilibrium state is established between the grass surface and the atmosphere, at least from mid-morning to mid-afternoon when the leaves are dry. Near-noon values calculated by Stewart and Thom for Thetford Forest also follow a linear trend.The above two regression results (In (r _S) versus r _I/r_S versus ) are combined to obtain an empirical relation of the form r _I=m exp (a-b) which is used to estimate evaporative flux. The estimates are found to be within 20% of calculated values.Guest Scientist from Department of Physics, University of Cape Coast, Cape Coast, Ghana.  相似文献   

Turbulence characteristics in a near neutrally stratified urban atmosphere   总被引：4，自引：1，他引：4  

Ulf Högström  Hans Bergström  Hans Alexandersson 《Boundary-Layer Meteorology》1982,23(4):449-472

Turbulence measurements from the city of Uppsala, Sweden, are analysed. Measurements were taken at two sites: one in the central area, ca. 6 m above roof level, the average building height being ca. 15 m; the other at ca. 8 and 50 m above the ground on a tower situated 100 m downwind of a sharp discontinuity between the densely built-up urban area and flat grass-covered land. The average stability was close to neutral, the range being -0.2 < z/L < 0.2. The main emphasis of the study is on the non-dimensional standard deviations of the velocity components _i /u _*t and on the corresponding non-dimensional energy spectra, u _*t being a local velocity scale defined as _i /( _l is the local momentum flux). Comparison with results obtained from surface-layer measurements at ideal sites (with u _*, being the ordinary friction velocity) shows good general agreement. The most complete agreement is found for the tower 50 m measurements, a result which is notable as this measurement point is found to be within a distinctly transitional zone between the urban and post-urban boundary layers. The results from the central city measurement point are also fairly close to the ideal results, the deviations found being small in view of the fact that the site is probably inside the layer in which the roughness elements (the buildings) have direct influence. The measurements at the tower 8 m level show certain distinct deviations from ideal results: all three _i /u _*l , are higher by ca. 10%, the excessive energy being found at the low frequency end of the spectrum. Arguments are presented for this feature to be due to a spectral lag effect.  相似文献   

Spectroscopic studies on natural chloritoids     

Ulf Hålenius  Hans Annersten  Klaus Langer 《Physics and Chemistry of Minerals》1981,7(3):117-123

Room temperature and low temperature Mössbauer and optical absorption spectroscopic data on six natural chloritoids characterized by means of electron microprobe and X-ray powder diffraction techniques are presented. Two narrow quadrupole doublets with widths of 0.25–0.29 mm/s assigned to Fe²⁺ in a relatively large octahedral site and Fe³⁺ in a smaller octahedral site, are observed in the Mössbauer spectra. Polarized optical absorption spectra reveal three main absorption bands. A broad absorption band at 16,300 cm^?1, which is strongly polarized in E‖X and E‖Y and shows a linear increase in integral absorption with increasing [Fe²⁺] [Fe³⁺] concentration product, is assigned to a Fe²⁺+Fe³⁺→Fe³⁺+Fe²⁺ charge transfer transition. This band displays also a temperature dependence different from that of single ion d?d transitions. Two absorption bands at 10,900 cm^?1 and 8,000 cm^?1 are, on the basis of compositional dependence and energy, assigned to Fe²⁺ in the large M(1B) octahedra of the brucite-type layer in chloritoid. Combined spectroscopic evidence and structural and chemical considerations support a distribution scheme for ferrous and ferric iron which orders the Fe²⁺ ions in the M(1B) octahedra and the Fe³⁺ ions in the small M(1A) octahedral sites. Both types of octahedra are found in the brucite type layer of chloritoid.  相似文献   

The Marsta micro-meteorological field project. Profile measurement system and some preliminary data     

Ann-Sofi Smedman-Högström  Ulf Högström 《Boundary-Layer Meteorology》1973,5(3):259-273

A micro-meteorological installation for accurate continuous measurements is described. Air temperature differences are obtained to ±0.02°C. Humidity is measured with the psychrometric method; an accuracy of ±0.03 mb in difference measurements has been obtained after having taken extensive measures to overcome heat conduction and radiation errors. A heating system enables humidity profiles to be obtained during freezing conditions. A number of humidity profiles obtained in connection with turbulent flux measurements have been properly nondimensionalized and plotted against z/L. The result is in clear favour of Monin-Obukhov similarity for the nondimensionalized humidity profiles.  相似文献   

Eutrophication and some European waters of restricted exchange   总被引：1，自引：0，他引：1  

Paul Tett  Linda Gilpin  Harald Svendsen  Carina P. Erlandsson  Ulf Larsson  Susanne Kratzer  Eric Fouilland  Carol Janzen  Jae-Young Lee  Christian Grenz  Alice Newton  Joo Gomes Ferreira  Teresa Fernandes  Serge Scory 《Continental Shelf Research》2003,23(17-19):1635

Regions of Restricted Exchange (RREs) are an important feature of the European coastline. They are historically preferred sites for human settlement and aquaculture and their ecosystems, and consequent human use, may be at risk from eutrophication. The OAERRE project (EVK3-CT1999-0002) concerns ‘Oceanographic Applications to Eutrophication in Regions of Restricted Exchange’. It began in July 2000, and studies six sites. Four of these sites are fjords: Kongsfjorden (west coast of Spitzbergen); Gullmaren (Skagerrak coast of Sweden); Himmerfjärden (Baltic coast of Sweden); and the Firth of Clyde (west coast of Scotland). Two are bays sheltered by sand bars: Golfe de Fos (French Mediterranean); and Ria Formosa (Portuguese Algarve). Together they exemplify a range of hydrographic and enrichment conditions. The project aims to understand the physical, biogeochemical and biological processes, and their interactions, that determine the trophic status of these coastal marine RRE through the development of simple screening models to define, predict and assess eutrophication. This paper introduces the sites and describes the component parts of a basic screening model and its application to each site using historical data. The model forms the starting point for the OAERRE project and views an RRE as a well-mixed box, exchanging with the sea at a daily rate E determined by physical processes, and converting nutrient to phytoplankton chlorophyll at a fixed yield q. It thus uses nutrient levels to estimate maximum biomass; these preliminary results are discussed in relation to objective criteria used to assess trophic status. The influence of factors such as grazing and vertical mixing on key parameters in the screening model are further studied using simulations of a complex ‘research’ model for the Firth of Clyde. The future development of screening models in general and within OAERRE in particular is discussed. In addition, the paper looks ahead with a broad discussion of progress in the scientific understanding of eutrophication and the legal and socio-economic issues that need to be taken into account in managing the trophic status of RREs.  相似文献   

Bonding of methyl mercury to reduced sulfur groups in soil and stream organic matter as determined by x-ray absorption spectroscopy and binding affinity studies     

Jin Qian  Ulf Skyllberg  Wolfgang FrechWilliam F Bleam  Paul R Bloom  Pierre Emmanuel Petit 《Geochimica et cosmochimica acta》2002,66(22):3873-3885

We combined synchrotron-based X-ray absorption near edge structure (XANES) spectroscopy, extended X-ray absorption fine structure (EXAFS) spectroscopy and binding affinity studies to determine the coordination, geometry, and strength of methyl mercury, CH₃Hg (II), bonding in soil and stream organic matter. Samples of organic soil (OS), potentially soluble organic substances (PSOS) from the soil, and organic substances from a stream (SOS) draining the soil were taken along a short “hydrological transect.” We determined the sum of concentrations of highly reduced organic S groups (designated Org-S_RED), such as thiol (RSH), disulfane (RSSH), sulfide (RSR), and disulfide (RSSR), using sulfur K-edge XANES. Org-S_RED varied between 27% and 64% of total S in our samples. Hg L_III-edge EXAFS analysis were determined on samples added CH₃Hg (II) to yield CH₃Hg (II)/Org-S_RED ratios in the range 0.01-1.62. At low ratios, Hg was associated to one C atom (the methyl group) at an average distance of 2.03 ± 0.02 Å and to one S atom at an average distance of 2.34 ± 0.03 Å, in the first coordination shell. At calculated CH₃Hg(II)/Org-S_RED ratios above 0.37 in OS, 0.32 in PSOS, and 0.24 in SOS, the organic S sites were saturated by CH₃Hg⁺, and O (and/or N) atoms were found in the first coordination shell of Hg at an average distance of 2.09 ± 0.01 Å. Based on the assumption that RSH (and possibly RSSH) groups take part in the complexation of CH₃Hg⁺, whereas RSSR and RSR groups do not, approximately 17% of total organic S consisted of RSH (+ RSSH) functionalities in the organic soil. Corresponding figures for samples PSOS and SOS were 14% and 9%, respectively. Competitive complexation of CH₃Hg⁺ by halide ions was used to determine the average binding strength of native concentrations of CH₃Hg (II) in the OS sample. Using data for Org-S_RED, calculated surface complexation constants were in the range from 10^16.3 to 10^16.7 for a model RSH site having an acidity constant of mercaptoacetic acid. These values compare favorably with identically defined stability constants (log K₁) for the binding of methyl mercury to thiol groups in well-defined organic compounds.  相似文献   

The wind regime in coastal areas with special reference to results obtained from the Swedish wind energy program     

Ulf Högström  Ann-Sofi Smedman-Högström 《Boundary-Layer Meteorology》1984,30(1-4):351-373

The paper describes various aspects of the wind regime in coastal areas as obtained from several experimental programs along the Baltic coast of Sweden. The studies include the change with distance inland of mean wind structure as well as the turbulence structure in various conditions. It is found that wind spectra are usually well described by local similarity in its high frequency part, even in complex terrain. The low frequency parts of the spectra show clear spectral lag effects. The effects of a small slope, ca 5 m height change over 300 m travel distance, is clearly seen in some spectra, and it is shown that current flow over a hill theory can be used to account for it. The change of mean wind speed throughout the entire boundary layer as the wind passes a low but wooded island (Gotland), ca 30 km wide, has been studied in a series of relatively strong wind, near neutral cases. Some unexpected features are found; in particular the wind speed decreases more rapidly with distance inland than predicted by current numerical models. Two cases with a low level jet are discussed in some detail. Arguments are presented for the phenomenon to be caused by frictional decoupling at the Latvian coast, about 200 km upwind — the jet being thus an analogy in space to the classical Blackadar nocturnal jet frequently observed in continental areas.  相似文献