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111.
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Reductive immobilization of uranium by the stimulation of dissimilatory metal-reducing bacteria (DMRB) has been investigated as a remediation strategy for subsurface U(VI) contamination. In those environments, DMRB may utilize a variety of electron acceptors, such as ferric iron which can lead to the formation of reactive biogenic Fe(II) phases. These biogenic phases could potentially mediate abiotic U(VI) reduction. In this work, the DMRB Shewanella putrefaciens strain CN32 was used to synthesize two biogenic Fe(II)-bearing minerals: magnetite (a mixed Fe(II)-Fe(III) oxide) and vivianite (an Fe(II)-phosphate). Analysis of abiotic redox interactions between these biogenic minerals and U(VI) showed that both biogenic minerals reduced U(VI) completely. XAS analysis indicates significant differences in speciation of the reduced uranium after reaction with the two biogenic Fe(II)-bearing minerals. While biogenic magnetite favored the formation of structurally ordered, crystalline UO2, biogenic vivianite led to the formation of a monomeric U(IV) species lacking U-U associations in the corresponding EXAFS spectrum. To investigate the role of phosphate in the formation of monomeric U(IV) such as sorbed U(IV) species complexed by mineral surfaces, versus a U(IV) mineral, uranium was reduced by biogenic magnetite that was pre-sorbed with phosphate. XAS analysis of this sample also revealed the formation of monomeric U(IV) species suggesting that the presence of phosphate hinders formation of UO2. This work shows that U(VI) reduction products formed during in situ biostimulation can be influenced by the mineralogical and geochemical composition of the surrounding environment, as well as by the interfacial solute-solid chemistry of the solid-phase reductant.  相似文献   
113.
In the Variscan Western Tatra granites hybridization phenomena such as mixing and mingling can be observed at the contact of mafic precursors of dioritic composition and more felsic granitic host rocks. The textural evidence of hybridization include: plagioclase?CK-feldspar?Csphene ocelli, hornblende- and biotite-rimmed quartz ocelli, plagioclase with Ca-rich spike zonation, inversely zoned K-feldspar crystals, mafic clots, poikilitic plagioclase and quartz crystals, mixed apatite morphologies, zoned K-feldspar phenocrysts. The apparent pressure range of the magma hybridization event was calculated at 6.1?kbar to 4.6?kbar, while the temperature, calculated by independent methods, is in the range of 810°C?770°C. U-Pb age data of the hybrid rocks were obtained by in-situ LA-MC-ICP-MS analysis of zircon. The oscillatory zoned zircon crystals yield a concordia age of 368?±?8?Ma (MSWD?=?1.1), interpreted as the age of magma hybridization and timing of formation of the magmatic precursors. It is the oldest Variscan magmatic event in that part of the Tatra Mountains.  相似文献   
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Groundwater flow in granitic bedrock is of major interest for underground projects such as radioactive waste disposal. It is generally accepted that granitic rocks of the upper crust are characterized as faulted low-porosity rocks showing fault-related permeability. In this study, the influence of existing faults on the present-day water flow in the Grimsel Test Site (Switzerland), an underground rock laboratory situated in granitoid rocks, was investigated by mapping water discharges. As a result, the link between water flow and faults considering slip-tendency analysis and fault intersections is evaluated. Water-conducting features were combined in a structural-permeability favorability map. Faults and dykes occur as three orientation groups, NE–SW, E–W, and NW–SE trending, all steeply dipping southwards with fault intersections also steeply plunging southwards. In total, 100 water discharges were mapped in summer 2014 and 85 in winter 2016, which are located along faults or fault intersections. A comparison of water discharges with structures showed that high-slip-tendency metabasic dykes and fault or dyke intersections represent the dominant flow paths. Further, it could be demonstrated that higher slip-tendency tends to lead to enhanced average hydraulic conductivity and therefore more constant water flow. Based on water fluxes, fault intersections are inferred to represent first-order locations of water percolation followed by high-slip-tendency metabasic dykes. The combination of all water-conducting features into a structural-permeability map results in covering all water discharges. Therefore, the structural-permeability favorability map can serve as suitable representation for constraining water inflow in fractured granitoid host rocks.  相似文献   
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We report results of telescope polarimetric imaging of the Moon with a CCD LineScan Camera at large phase angles, near 88°. This allows measurements of the polarization degree with an absolute accuracy better than 0.3% and detection of features with polarization contrast as small as 0.1%. The measurements are carried out in two spectral bands centered near 0.65 and 0.42 μm. We suggest characterizing the lunar regolith with the parameter a(Pmax)A, where Pmax,A, and a are the degree of maximum polarization, albedo, and the parameter describing the linear regression of the correlation Pmax-A. The parameter bears significant information on the particle characteristic size and packing density of the lunar regolith. We also suggest characterizing the lunar regolith with color-ratio images obtained with a polarization filter at large phase angles. We here consider the color-ratios C||(0.65/0.42 μm) and C(0.65/0.42 μm). Using light scattering model calculations we show that the color-ratio images obtained with a polarization filter at large phase angles suggest a new tool to study the lunar surface. In particular, it turns out that the color-ratios C||(0.65/0.42 μm) and C(0.65/0.42 μm) are sensitive to somewhat different thicknesses of the surfaces of regolith particles. We consider the applicability of the Hubble Space Telescope, the Very Large Telescope (ESO), and a spacecraft on a lunar polar orbit for polarimetric observations of the lunar surface.  相似文献   
118.
The age and origin of alkaline rocks emplaced into the sediments of the rift‐related continental Lusitanian basin were investigated to constrain earliest magmatic activity occurring prior to oceanic plate formation between Iberia and Newfoundland. The U–Pb titanite ages are 146.5 ± 1.6 (2σSTERR), 145.3 ± 1.4 and 142.3 ± 1.0 Ma, and initial Pb isotopic ratios of feldspars lie at 18.418–18.978 for 206Pb/204Pb, at 15.594–15.925 for 207Pb/204Pb and at 37.105–39.216 for 208Pb/204Pb. Initial 87Sr/86Sr ratios measured in the same feldspar fractions lie at 0.705409–0.706462. This episode of magmatic activity lasting for at least 4.2 ± 2.6 Myr most likely marks a phase of maximum lithospheric thinning during which zones of weakness were created to allow deep magmas to reach the surface. Such zones are preferentially re‐activated Palaeozoic faults of the Iberian plate. The isotope data suggest that the dominant volume of alkaline magmas was generated by partial melting of the metasomatized subcontinental Iberian mantle.  相似文献   
119.
Abstract— We performed a comprehensive study of the He, Ne, and Ar isotopic abundances and of the chemical composition of bulk material and components of the H chondrites Dhajala, Bath, Cullison, Grove Mountains 98004, Nadiabondi, Ogi, and Zag, of the L chondrites Grassland, Northwest Africa 055, Pavlograd, and Ladder Creek, of the E chondrite Indarch, and of the C chondrites Hammadah al Hamra 288, Acfer 059, and Allende. We discuss a procedure and necessary assumptions for the partitioning of measured data into cosmogenic, radiogenic, implanted, and indigenous noble gas components. For stone meteorites, we derive a cosmogenic ratio 20Ne/22Ne of 0.80 ± 0.03 and a trapped solar 4He/3He ratio of 3310 ± 130 using our own and literature data. Chondrules and matrix from nine meteorites were analyzed. Data from Dhajala chondrules suggest that some of these may have experienced precompaction irradiation by cosmic rays. The other chondrules and matrix samples yield consistent cosmic‐ray exposure (CRE) ages within experimental errors. Some CRE ages of some of the investigated meteorites fall into clusters typically observed for the respective meteorite groups. Only Bath's CRE age falls on the 7 Ma double‐peak of H chondrites, while Ogi's fits the 22 Ma peak. The studied chondrules contain trapped 20Ne and 36Ar concentrations in the range of 10?6–10?9 cm3 STP/g. In most chondrules, trapped Ar is of type Q (ordinary chondritic Ar), which suggests that this component is indigenous to the chondrule precursor material. The history of the Cullison chondrite is special in several respects: large fractions of both CR‐produced 3He and of radiogenic 4He were lost during or after parent body breakup, in the latter case possibly by solar heating at small perihelion distances. Furthermore, one of the matrix samples contains constituents with a regolith history on the parent body before compaction. It also contains trapped Ne with a 20Ne/22Ne ratio of 15.5 ± 0.5, apparently fractionated solar Ne.  相似文献   
120.
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