Petrography,mineralogy, and geochemistry of lunar meteorite Sayh al Uhaymir 300     

Weibiao HSU  Aicheng ZHANG  Rainer BARTOSCHEWITZ  Yunbin GUAN  Takayuki USHIKUBO  Urs KRÄHENBÜHL  Rainer NIEDERGESAESS  Rudolf PEPELNIK  Ulrich REUS  Thomas KURTZ  Paul KURTZ 《Meteoritics & planetary science》2008,43(8):1363-1381

Abstract— We report here the petrography, mineralogy, and geochemistry of lunar meteorite Sayh al Uhaymir 300 (SaU 300). SaU 300 is dominated by a fine‐grained crystalline matrix surrounding mineral fragments (plagioclase, pyroxene, olivine, and ilmenite) and lithic clasts (mainly feldspathic to noritic). Mare basalt and KREEPy rocks are absent. Glass melt veins and impact melts are present, indicating that the rock has been subjected to a second impact event. FeNi metal and troilite grains were observed in the matrix. Major element concentrations of SaU 300 (Al₂O₃ 21.6 wt% and FeO 8.16 wt%) are very similar to those of two basalt‐bearing feldspathic regolith breccias: Calcalong Creek and Yamato (Y‐) 983885. However, the rare earth element (REE) abundances and pattern of SaU 300 resemble the patterns of feldspathic highlands meteorites (e.g., Queen Alexandra Range (QUE) 93069 and Dar al Gani (DaG) 400), and the average lunar highlands crust. It has a relatively LREE‐enriched (7 to 10 x CI) pattern with a positive Eu anomaly (?11 x CI). Values of Fe/Mn ratios of olivine, pyroxene, and the bulk sample are essentially consistent with a lunar origin. SaU 300 also contains high siderophile abundances with a chondritic Ni/Ir ratio. SaU 300 has experienced moderate terrestrial weathering as its bulk Sr concentration is elevated compared to other lunar meteorites and Apollo and Luna samples. Mineral chemistry and trace element abundances of SaU 300 fall within the ranges of lunar feldspathic meteorites and FAN rocks. SaU 300 is a feldspathic impact‐melt breccia predominantly composed of feldspathic highlands rocks with a small amount of mafic component. With a bulk Mg# of 0.67, it is the most mafic of the feldspathic meteorites and represents a lunar surface composition distinct from any other known lunar meteorites. On the basis of its low Th concentration (0.46 ppm) and its lack of KREEPy and mare basaltic components, the source region of SaU 300 could have been within a highland terrain, a great distance from the Imbrium impact basin, probably on the far side of the Moon.  相似文献   

On the morphological characteristics of overdeepenings in high‐mountain glacier beds          下载免费PDF全文

Wilfried Haeberli  Andreas Linsbauer  Alejo Cochachin  Cesar Salazar  Urs H. Fischer 《地球表面变化过程与地形》2016,41(13):1980-1990

Overdeepenings, i.e. closed topographic depressions with adverse slopes in the direction of flow, are characteristic for glacier beds and glacially sculpted landscapes. Quantitative information about their morphological characteristics, however, has so far hardly been available. The present study provides such information by combining the analysis of (a) numerous bed overdeepenings below still existing glaciers of the Swiss Alps and the Himalaya‐Karakoram region modelled with a robust shear stress approximation and (b) detailed bathymetries from recently exposed lakes in the Peruvian Andes. The investigated overdeepenings exist where glacier surface slopes are low (< 5°–10°), occur in bedrock or morainic material and are most commonly a fraction of a kilometre squared in surface area, hundreds of metres long, about half the length in width and tens of metres deep. They form under conditions of low to high basal shear stresses, at cirque, confluence, trunk valley and terminus positions. The most striking phenomenon, however, is the high variability of their geometries: Depths, surface areas, lengths and widths of the overdeepenings vary over orders of magnitude and are only weakly – if at all – interrelated. Inclinations of adverse slopes do not differ significantly from those of forward slopes and are in many cases higher than so far assumed theoretical limits for supercooling of ascending water and corresponding closure of sub‐glacial channels. Such steep adverse slopes are a robust observation and in support of recently developed new concepts concerning the question about where supercooling of sub‐glacial water and closure of ice channels can or must occur. However, the question of when and under what climatic, topographic and ice conditions the overdeepenings had formed remains unanswered. This open question constitutes a key problem concerning the interpretation of observed overdeepenings, the understanding of the involved glacio‐hydraulic processes and the possibility of realistic predictive modelling of overdeepening formation. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

First results of operating and monitoring an innovative design of a permeable reactive barrier for the remediation of chromate contaminated groundwater     

Bettina Flury  Urs EggenbergerUrs Mäder 《Applied Geochemistry》2009

An innovative setup of a permeable reactive barrier (PRB) was installed in Willisau, Switzerland to remediate chromate contaminated groundwater. Instead of a conventional continuous barrier, this PRB consists of cylinders installed in rows: a single row for lower expected Cr^VI-concentrations and an offset double row for higher expected Cr^VI-concentrations. The cylinders are filled with reactive grey cast-Fe shavings mixed with gravel to prevent extensive precipitation of secondary phases in the pore space. The treatment of the contaminants takes place both within the cylinders and in the dissolved Fe^II plume generated downstream of the barrier. Monitoring of the contamination situation over a period of 3 a provided evidence of the mobilization, transport and behavior of the contaminants in the aquifer. Groundwater and reactive material were sampled upstream, within and downstream of the barrier by a Multi-Port Sampling System (MPSS) that revealed the geochemical processes as a function of time and space. Comprehensive chemical analyses included sensitive parameters such as Cr^VI, Fe^II/Fe^III, redox potential, dissolved O₂ and pH. Several campaigns using multiple optical tracers revealed a rather complex hydrological regime at different scales, thereby complicating the barrier performance.  相似文献   

Accuracy of Laser Ablation U-Pb Zircon Dating: Results from a Test Using Five Different Reference Zircons   总被引：2，自引：0，他引：2  

Urs Klötzli  Eva Klötzli  Zekeriya Günes  Jan Kosler 《Geostandards and Geoanalytical Research》2009,33(1):5-15

Using a state‐of‐the‐art 193 nm‐LA‐MC‐ICP‐MS system and with careful control of analytical procedures, the long term external reproducibility and accuracy of the ages Phanerozoic zircons measured over a period of months using calibrator bracketing for the ²⁰⁶Pb/²³⁸U and ²⁰⁷Pb/²⁰⁶Pb ages were ca. 1% (2 RSD) if a single reference zircon was used for the matrix‐matched calibration. When different reference zircons were used for the calibration, suspicious systematic shifts in the obtained ages were observed and thus a reduction in the overall accuracy of the dating method became obvious. Such shifts were within a few percent range of the U‐Pb and Pb/Pb ages and seemed to vary independently of zircon age and composition. A “test of accuracy” experiment was conducted reducing instrumental effects as far as possible by analysing five different reference zircons mounted on a single mount eight times during the same session. An identical protocol was used for all analyses, with unchanged instrument parameters and with ion beam intensities kept as identical as possible. For data reduction, every zircon served consecutively as the reference zircon for calibration, with the others in the batch treated as unknowns. The known reference age and the four calculated ages obtained using the four other RMs for calibration were then compared. Even using such a strict analytical protocol, shifts in ²⁰⁶Pb/²³⁸U, ²⁰⁷Pb/²³⁵U and ²⁰⁷Pb/²⁰⁶Pb ratios were still present. They varied non‐systematically and ranged from ?4.35% to 3.08% for the investigated age range (1065 Ma to 226 Ma). Assuming the absence of instrumental effects (i.e., memory, dead‐time correction, non‐linearity of ion counters and interdetector calibration, crystallographic orientation, ablation cell geometry and setup, gas flows), the observed shifts were attributed to matrix and/or ablation related effects. It is proposed that non‐spectral matrix effects in the Ar plasma torch resulted in non‐uniform signal enhancement (or depression?) leading to shifts both in elemental and Pb isotopic ratios. Additionally, the ablated particle size distribution could be an important factor controlling plasma conditions and thus mass bias and fractionation. Until such effects are well understood and controlled, it would seem that any LA‐ICP‐MS zircon U‐Pb and ²⁰⁷Pb/²⁰⁶Pb age determination cannot be meaningfully interpreted at below a ca. 3% to 4% (2 RSD) confidence level.  相似文献   

Earthquakes in Switzerland and surrounding regions during 2008     

Nicolas Deichmann  John Clinton  Stephan Husen  Florian Haslinger  Donat Fäh  Domenico Giardini  Philipp Kästli  Urs Kradolfer  Iris Marschall  Stefan Wiemer 《Swiss Journal of Geoscience》2009,102(3):505-514

This report of the Swiss Seismological Service summarizes the seismic activity in Switzerland and surrounding regions during 2008. During this period, 451 earthquakes and 75 quarry blasts were detected and located in the region under consideration. The three strongest events occurred in the Valais, near Lac des Toules (M_L 3.6), and in Graubünden, near Ilanz (M_L 3.7) and Paspels (M_L 4.0). Although felt by the population, they were not reported to have caused any damage. However, with a total of only 15 events with M_L ≥ 2.5, the seismic activity in the year 2008 was far below the average over the previous 33 years.  相似文献   

U-Pb and Pb-Pb zircon dating of the older orthogneiss suite in the Silvretta nappe,eastern Alps: Cadomian magmatism in the upper Austro-Alpine realm     

Bernhard Müller  Urs Stefan Klötzli  Markus Flisch 《International Journal of Earth Sciences》1995,84(3):457-465

Two orthogneiss suites dominate the Silvretta nappe. Primary crystallization of the larger suite (younger orthogneisses) is assumed to be Ordovician in age. The second, adjacent magmatic suite consists of older, alkaline to calc-alkaline, ultrabasic, basic to intermediate and granitic rocks known as older orthogneisses. U-Pb data of multigrain zircon fractions, as well as single zircon stepwise evaporation ²⁰⁷Pb/²⁰⁶Pb results suggest a latest Proterozoic to early Cambrian intrusion age for the protoliths of the older orthogneisses as both dating methods yield early Cambrian crystallization ages of 526±7 and 519±7 Ma for an alkaline granite gneiss; similar results were obtained for two neighbouring calc-alkaline orthogneisses (²⁰⁷Pb/²⁰⁶Pb ages of 533 ± 4 and 568 ± 6 Ma, respectively). The crystal habitus corresponds to P5, S19 and S9 zircons of magmatic origin. Whole-rock initial Sr isotope ratios indicate a primitive source. The igneous protoliths of these older orthogneisses represent a fragment of a Cadomian (Pan-African) crust found in places within the basement of the European Hercynides.  相似文献   

Earthquakes in Switzerland and surrounding regions during 2011     

Nicholas Deichmann  John Clinton  Stephan Husen  Benjamin Edwards  Florian Haslinger  Donat F?h  Domenico Giardini  Philipp K?stli  Urs Kradolfer  Stefan Wiemer 《Swiss Journal of Geoscience》2012,105(3):463-476

This report of the Swiss Seismological Service summarizes the seismic activity in Switzerland and surrounding regions during 2011. During this period, 522 earthquakes and 92 quarry blasts were detected and located in the region under consideration. With a total of only 10 events with M _L????2.5, the seismic activity in the year 2011 was far below the average over the previous 36?years. Most noteworthy were the earthquake sequence of Sierre (VS) in January, with two events of M _L 3.3 and 3.2, the M _L 3.3 earthquake at a depth of 31?km below Bregenz, and the M _L 3.1 event near Delémont. The two strongest events near Sierre produced shaking of intensity IV.  相似文献   

Thermodynamics of AFm-(I₂, SO₄) solid solution and of its end-members in aqueous media     

Laure Aimoz  Dmitrii A. Kulik  Erich Wieland  Enzo Curti  Barbara Lothenbach  Urs Mäder 《Applied Geochemistry》2012

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Timing and rate of granulite facies metamorphism and cooling from multi-mineral chronology on migmatitic gneisses,Sierras de La Huerta and Valle Fértil,NW Argentina     

Florian Gallien  Aberra Mogessie  Ernesto Bjerg  Sergio Delpino  Brigida Castro de Machuca  Martin Thöni  Urs Klötzli 《Lithos》2010,114(1-2):229-252

Migmatitic paragneisses of the Valle Fértil–La Huerta Ranges at the Western margin of the Sierras Pampeanas are composed of garnet–cordierite–plagioclase–biotite–quartz-bearing units that experienced peak metamorphic conditions of ca. 800 °C at 6–7 kbar. Based on petrological studies, pseudosection modeling and petrographic observations, an anticlockwise P–T path with a small pressure increment is proposed. Rare earth element LA-ICP-MS patterns acquired from rutile bearing garnets suggest a single stage of garnet growth at high-T at pressures above the ilmenite–rutile transition. U–Pb dating of zircon rims from the migmatites indicates two distinct metamorphic U–Pb ages of 525 ± 9 Ma and 478 ± 9 Ma. The older age is suggested to record an amphibolite facies event of the Pampean orogeny. The younger metamorphic age is contemporary with igneous zircons from metatonalites and pegmatites that yield 478 ± 4 Ma. We suggest that the prograde high-T metamorphic Famatinian event is associated with the emplacement of large magmatic bodies in which large-scale magmatic activity gave rise to an increased geothermal gradient of about 35 °C/km. Sm–Nd garnet ages of 447 ± 3 Ma indicate a time span of around 30 Ma for which temperatures above the garnet closure temperature prevailed. Using U–Pb, Sm–Nd and Rb–Sr isotope systems, a cooling rate of 3 to 6 °C/Myr is inferred.  相似文献   

The chemical variation of moldavite tektites: Simple mixing of terrestrial sediments     

Thomas MEISEL  Jan-Michael LANGE  Urs KRHENBÜHL 《Meteoritics & planetary science》1997,32(4):493-502

Abstract— To test different hypotheses of moldavite formation, a major and trace-element study of 25 moldavite tektites and Sm-Nd isotope measurement of three moldavite tektites was completed. The samples were selected from the classical substrewnfields and the newly described locations in Lusatia (Saxony, Germany). Samples with unusual bulk composition were also included. The results confirm earlier studies that the variation in the chemical composition can be explained by single impact and through incomplete mixing of at least three lithographical components dominated by one of the three minerals or mineral groups: dolomite, clay minerals and quartz. An additional endmember, possibly a rare Earth's mantle component, containing high Co, Cr and Ni concentrations is also needed to explain the observed variations in compatible elements of some tektites. Volatile element abundances are low but not necessarily the result of selective volatilization.  相似文献