Application of Gibbs Energy Minimization to ModelEarly-Diagenetic Solid-Solution Aqueous-Solution EquilibriaInvolving Authigenic Rhodochrosites in Anoxic BalticSea Sediments     

Dmitrii A. Kulik  Michael Kersten  Uwe Heiser  Thomas Neumann 《Aquatic Geochemistry》2000,6(2):147-199

The natural early-diagenetic environment ``anoxicporewater – authigenic mineral phases' has beencharacterized in sediment of the Gotland Deep,Baltic Sea, by a closed-system model. Occurrence ofcarbonate precipitates as thin almost pure whitelaminae was considered as a natural experiment forlong-term equilibration between these phases andporewater. Plots of distribution coefficientsindicate that metastable equilibrium exists betweenporewater and the authigenic Ca-rich rhodochrositephases below 7 cm depth. A thermodynamic model ofporewater geochemistry at in situ P = 25 barand T = 5 °C was developed using the Gibbsenergy minimization (GEM) approach. The values of isobaric-isothermal potentials of Mn, Ca, Fe, Mg,Sr, Ba, C, and O, calculated from the porewatercomposition, were used in a new ``dual thermodynamic'calculation approach to estimate solid activitycoefficients of the end-members in the non-idealsolid solution (Mn, Ca, Mg, Sr, Ba, Fe)CO₃,i.e., at full major and minor multi-componentcomplexity. The regular Margules interactionparameters for the composing binaries estimated bythis model were _Mn-Ca = 1.9 ± 0.5,_Mn-Mg = 0.6,_Ca-Mg = 3.7,_Mn-Fe = 0.2,_Ca-Fe = 2.8,_Mn-Sr = 9.7,_Ca-Sr = 2.15,_Mn-Ba = 4.0,_Ca-Ba = 1.4,validating the theoretical predictions given byLippmann in his pioneering 1980's paper. Thestrictly thermodynamic equilibrium model is not onlyable to match both the measured porewater andcarbonate solid-solution composition, but also topredict that the porewater pH, pe, alkalinity, anddissolved Mn, Fe, and S concentrations arecontrolled by the authigenic mineral bufferingassemblage mackinawite-greigite-rhodochrosite. Ourmodel is only compatible with the idea of ACRformation with typical composition (X_Mnbetween 70–75%) in the topmost sediment layerwhich, however, needs a major source ofMn_aq ^II. This is provided by reduction ofparticulate Mn oxides precipitated in significantamounts in the water column upon major inflow eventsin the Baltic Sea. The model enables also to set upscenarios of changing environmental conditions, e.g.,to predict the non-linear response of the carbonatesolid-solution composition to changes in Mn loading,alkalinity and salinity of the sediment-watersystem. The results suggest that the major andespecially minor element contents (Sr, Mg, Ba) inauthigenic carbonates can be applied as anenvironmental paleoproxy.  相似文献   

Geostandards and Geoanalytical Research Bibliographic Review 2009     

Klaus P. Jochum  Xiaohong Wang  Regina Mertz-Kraus  Uwe Nohl  Steffen Schmidt  Beate Schwager  Brigitte Stoll  Qichao Yang  Ulrike Weis 《Geostandards and Geoanalytical Research》2010,34(4):407-410

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The atmospheric lead record preserved in lagoon sediments at a remote equatorial Pacific location: Palmyra Atoll, northern Line Islands     

Collen JD  Baker JA  Dunbar RB  Rieser U  Gardner JP  Garton DW  Christiansen KJ 《Marine pollution bulletin》2011,62(2):251-257

Anthropogenic lead (Pb) inputs to the atmosphere increased greatly over the past century and now dominate Pb supply to the oceans. However, the Pb content of sediments across the equatorial Pacific region is relatively unknown, and data exist only for deep sea sites where Pb deposition lags surface water inputs by up to a century. Here we present ICP-MS analyses of Pb of a core from a lagoon at Palmyra Atoll, northern Line Islands, that spans approximately the past 160 years. The non-bioturbated sediments of the euxinic lagoon, coupled with rapid rates of deposition, provide a unique fine-scale record of atmospheric Pb supply at a remote Pacific location. These first observations of historic Pb sedimentation in an atoll lagoon reveal a 63-fold increase in Pb flux to sediments during the past century and correlate directly with the North American consumption of leaded gasoline that began in 1926.  相似文献   

Ground motion spatial variability effects on seismic response control of cable-stayed bridges     

Shehata E. Abdel Raheem  Toshiro Hayashikawa  Uwe Dorka 《地震工程与工程振动(英文版)》2011,10(1):37-49

The spatial variability of input ground motion at supporting foundations plays a key role in the structural response of cable-stayed bridges (CSBs); therefore, spatial variation effects should be included in the analysis and design of effective vibration control systems. The control of CSBs represents a challenging and unique problem, with many complexities in modeling, control design and implementation, since the control system should be designed not only to mitigate the dynamic component of the structural response but also to counteract the effects of the pseudo-static component of the response. The spatial variability effects on the feasibility and efficiency of seismic control systems for the vibration control of CSBs are investigated in this paper. The assumption of uniform earthquake motion along the entire bridge may result in quantitative and qualitative differences in seismic response as compared with those produced by uniform motion at all supports. A systematic comparison of passive and active system performance in reducing the structural responses is performed, focusing on the effect of the spatially varying earthquake ground motion on the seismic response of a benchmark CSB model with different control strategies, and demonstrates the importance of accounting for the spatial variability of excitations.  相似文献   

On the potential for automated realtime detection of nonlinear internal waves from seafloor pressure measurements     

Uwe Stöber  James N. Moum 《Applied Ocean Research》2011,33(4):275-285

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Typhoon-induced precipitation impact on nutrient and suspended matter dynamics of a tropical estuary affected by human activities in Hainan,China     

Lucia S. Herbeck  Daniela Unger  Uwe Krumme  Su Mei Liu  Tim C. Jennerjahn 《Estuarine, Coastal and Shelf Science》2011

Typhoons regularly hit the coasts along the northern South China Sea during summer monsoon. However, little is known on the effects of typhoon-related heavy precipitation on estuarine dynamics and coastal ecosystems. We analyzed physico-chemical characteristics, and concentrations and composition of dissolved and suspended matter in the Wenchang/Wenjiao Estuary (WWE) on the tropical island of Hainan, China, prior to and after typhoon Kammuri in August 2008. Before the typhoon, the estuary displayed vertical and horizontal gradients. High nutrient inputs from agriculture and widespread aquaculture were to a large extent converted into biomass inside the estuarine lagoon resulting in low export of nutrients to coastal waters and a mainly autochthonous origin of total suspended matter (TSM). Heavy typhoon-associated precipitation increased river runoff, which moved the location of the estuarine salinity gradient seaward. It resulted in an export of dissolved and particulate matter to coastal waters one day after the typhoon. Dissolved nutrients increased by up to an order of magnitude and TSM increased approximately twofold compared to pre-typhoon values. Lower δ¹³C_org and δ¹⁵N and elevated C/N ratios of TSM together with lower chlorophyll a (chl a) concentrations indicated an increased contribution of terrestrial material originating from typhoon-induced soil erosion. Local uptake of excess nutrients inside the lagoon was inhibited because of reduced water transparency and the lack of phytoplankton, which had been washed out by the initial freshwater pulse. Two weeks after the typhoon, TSM concentration and composition had almost returned to pre-typhoon conditions. However, physico-chemical properties and nutrients were still different from pre-typhoon conditions indicating that the estuarine system had not fully recovered. Unusually high chl a concentrations in the coastal zone indicated a phytoplankton bloom resulting from the typhoon-induced nutrient export. The typhoon-induced flushing of the WWE resulted in hyposalinity, reduced water transparency, siltation, as well as temporary eutrophication of coastal waters. These are physiological stressors, which are known to impair the performance of adjacent seagrass meadows and coral reefs. The predicted increase in typhoon frequency and intensity will lead to a frequently recurring exposure of coastal ecosystems to these threats, particularly in the South China Sea region where aquaculture is widespread and tropical cyclone frequency is at a maximum.  相似文献   

Decadal fingerprints of freshwater discharge around Greenland in a multi-model ensemble   总被引：2，自引：2，他引：0  

Didier Swingedouw  Christian B. Rodehacke  Erik Behrens  Matthew Menary  Steffen M. Olsen  Yongqi Gao  Uwe Mikolajewicz  Juliette Mignot  Arne Biastoch 《Climate Dynamics》2013,41(3-4):695-720

The recent increase in the rate of the Greenland ice sheet melting has raised with urgency the question of the impact of such a melting on the climate. As former model projections, based on a coarse representation of the melting, show very different sensitivity to this melting, it seems necessary to consider a multi-model ensemble to tackle this question. Here we use five coupled climate models and one ocean-only model to evaluate the impact of 0.1 Sv (1 Sv = 10⁶ m³/s) of freshwater equally distributed around the coast of Greenland during the historical era 1965–2004. The ocean-only model helps to discriminate between oceanic and coupled responses. In this idealized framework, we find similar fingerprints in the fourth decade of hosing among the models, with a general weakening of the Atlantic Meridional Overturning Circulation (AMOC). Initially, the additional freshwater spreads along the main currents of the subpolar gyre. Part of the anomaly crosses the Atlantic eastward and enters into the Canary Current constituting a freshwater leakage tapping the subpolar gyre system. As a consequence, we show that the AMOC weakening is smaller if the leakage is larger. We argue that the magnitude of the freshwater leakage is related to the asymmetry between the subpolar-subtropical gyres in the control simulations, which may ultimately be a primary cause for the diversity of AMOC responses to the hosing in the multi-model ensemble. Another important fingerprint concerns a warming in the Nordic Seas in response to the re-emergence of Atlantic subsurface waters capped by the freshwater in the subpolar gyre. This subsurface heat anomaly reaches the Arctic where it emerges and induces a positive upper ocean salinity anomaly by introducing more Atlantic waters. We found similar climatic impacts in all the coupled ocean–atmosphere models with an atmospheric cooling of the North Atlantic except in the region around the Nordic Seas and a slight warming south of the equator in the Atlantic. This meridional gradient of temperature is associated with a southward shift of the tropical rains. The free surface models also show similar sea-level fingerprints notably with a comma-shape of high sea-level rise following the Canary Current.  相似文献   

Impact controversies: Impact recognition criteria and related issues     

Wolf Uwe Reimold  Ludovic Ferrière  Alex Deutsch  Christian Koeberl 《Meteoritics & planetary science》2014,49(5):723-731

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New mineralogical and chemical data on the Machinga (L6) chondrite,Malawi     

Christian Koeberl  Wolf Uwe Reimold  Hanna E. Horsch  Roland K. W. Merkle 《Meteoritics & planetary science》1990,25(1):23-26

Abstract— The Machinga, southern Malawi, Africa, L6 chondrite (observed fall, 22 January 1981) contains accessory phases of metal, troilite, chromite, and native Cu (which is associated with limonite and found in zones of aqueous alteration). Rare accessory phases are apatite and pentlandite, which are uncommon in L6 chondrites. Major mineral constituents (olivine, orthopyroxene, and plagioclase) indicate shock effects at a level of about 15–20 GPa shock pressure. The meteorite is thus classified to be of L6d type. Melt pockets of widely variable composition are abundant.  相似文献   

Geophysical signature of the Pretoria Saltpan impact structure and a possible satellite crater     

Dion Brandt  Wolf Uwe Reimold  Raymond J. Durrheim 《Meteoritics & planetary science》1994,29(3):379-384

Abstract— The genesis of the 1.13-km-diameter Pretoria Saltpan crater has long been the focus of a controversy. Its origin has been explained by either meteorite impact or “cryptoexplosive” volcanic activity, but it was recently confirmed, through detailed petrographic and chemical analysis of a breccia layer forming part of the crater fill, that the crater was formed by impact. As the limited previous geophysical work failed to support an impact origin, a more detailed gravity and magnetic study was conducted. A possible 400-m-diameter circular crater located 3 km to the southwest of the main crater was also investigated with geophysical methods, including resistivity, seismics and ground-probing radar. The gravity signature of the main crater is compatible with that of a simple impact crater and the magnetic signature (no magnetic anomaly could be detected) rules out the possibility of a central magnetic volcanic body below the crater-fill sediments. The results for the possible twin or satellite crater are inconclusive. As it is the only such feature in the entire region, it should not be overlooked. A drilling program may reveal interesting results.  相似文献