Dissolution of hausmannite (Mn₃O₄) in the presence of the trihydroxamate siderophore desferrioxamine B     

Jasquelin Peña  Owen W. Duckworth  Garrison Sposito 《Geochimica et cosmochimica acta》2007,71(23):5661-5671

That microbial siderophores may be mediators of Mn(III) biogeochemistry is suggested by recent studies showing that these well known Fe(III)-chelating ligands form very stable Mn(III) aqueous complexes. In this study, we examine the influence of desferrioxamine B (DFOB), a trihydroxamate siderophore, on the dissolution of hausmannite, a mixed valence Mn(II, III) oxide found in soils and freshwater sediments. Batch dissolution experiments were conducted both in the absence (pH 4-9) and in the presence of 100 μM DFOB (pH 5-9). In the absence of the ligand, there is a sharp decrease in the extent of proton-promoted dissolution above pH 5 and no appreciable dissolution above pH 8. The resulting aqueous Mn²⁺ activities were in good agreement with previous studies, indirectly supporting the accepted two-step mechanism involving the formation of manganite and reprecipitation of hausmannite. Desferrioxamine B enhanced hausmannite dissolution over the entire pH range investigated, both via the formation of a Mn(III) complex and through surface-catalyzed reductive dissolution. Above pH 8, non-reductive ligand-promoted dissolution dominated, whereas below pH 8, dissolution was non-stoichiometric with respect to DFOB. Concurrent proton-promoted, ligand-promoted, reductive, and induced dissolution was observed, with Mn release by either reductive or induced dissolution increasing linearly with decreasing pH. The fast kinetics of the DFOB-promoted dissolution of hausmannite, as compared to iron oxides, suggest that the siderophore-promoted dissolution of Mn(III)-bearing minerals may compete with the siderophore-promoted dissolution of Fe(III)-bearing minerals.  相似文献   

The geopotential value <Emphasis Type="Italic">W</Emphasis><Subscript>0</Subscript> for specifying the relativistic atomic time scale and a global vertical reference system     

Milan Burša  Steve Kenyon  Jan Kouba  Zdislav Šíma  Viliam Vatrt  Vojtěch Vítek  Marie Vojtíšková 《Journal of Geodesy》2007,81(2):103-110

The TOPEX/Poseidon (T/P) satellite alti- meter mission marked a new era in determining the geopotential constant W ₀. On the basis of T/P data during 1993–2003 (cycles 11–414), long-term variations in W ₀ have been investigated. The rounded value W ₀ = 62636856.0 ± 0.5) m ² s ⁻² has already been adopted by the International Astronomical Union for the definition of the constant L _G = W ₀/c ² = 6.969290134 × 10⁻¹⁰ (where c is the speed of light), which is required for the realization of the relativistic atomic time scale. The constant L _G , based on the above value of W ₀, is also included in the 2003 International Earth Rotation and Reference Frames Service conventions. It has also been suggested that W ₀ is used to specify a global vertical reference system (GVRS). W ₀ ensures the consistency with the International Terrestrial Reference System, i.e. after adopting W ₀, along with the geocentric gravitational constant (GM), the Earth’s rotational velocity (ω) and the second zonal geopotential coefficient (J ₂) as primary constants (parameters), then the ellipsoidal parameters (a,α) can be computed and adopted as derived parameters. The scale of the International Terrestrial Reference Frame 2000 (ITRF2000) has also been specified with the use of W ₀ to be consistent with the geocentric coordinate time. As an example of using W ₀ for a GVRS realization, the geopotential difference between the adopted W ₀ and the geopotential at the Rimouski tide-gauge point, specifying the North American Vertical Datum 1988 (NAVD88), has been estimated.  相似文献   

Morphometric indices as indicators of tectonic,fluvial and karst processes in calcareous drainage basins,South Menorca Island,Spain     

Francesca S. Segura  Josep E. Pardo‐Pascual  Vicenç M. Rosselló  Joan J. Fornós  Bernadí Gelabert 《地球表面变化过程与地形》2007,32(13):1928-1946

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Rigid element model for in‐plane dynamics of masonry walls considering hysteretic behaviour and damage     

Siro Casolo  Fernando Peña 《地震工程与结构动力学》2007,36(8):1029-1048

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Persistence of lutetium disilicate     

María D. Alba  Pablo Chaín 《Applied Geochemistry》2007

RE₂Si₂O₇ is one of the final products of the chemical interaction of radioactive cation simulators and the silicates used in the engineered barrier of deep geological repositories. The aim of this paper is to study the chemical and structural behaviour of Lu₂Si₂O₇ (Lu as actinide tripositive state simulator) in several different chemical systems. The conditions expected at the repositories are simulated in the laboratory with solutions of different compositions and pH. Both the solid products and remnant solutions were analyzed using techniques that give information on the short- and long-range structural order. The results show good stability of Lu₂Si₂O₇, under the studied conditions, and, therefore, encapsulation of the radioactive actinide cations as a disilicate phase could be considered a viable method to ensure the long-term safety of the repositories.  相似文献   

Impact of coherent eddies on airborne measurements of vertical turbulent fluxes     

Marie Lothon  Fleur Couvreux  Sylvie Donier  Françoise Guichard  Pierre Lacarrère  Donald H. Lenschow  Joël Noilhan  Frédérique Saïd 《Boundary-Layer Meteorology》2007,124(3):425-447

During the Hydrological-Atmospheric Pilot Experiment (HAPEX)-Sahel, which took place in Niger in the transitional period between the wet and dry seasons, two French aircraft probed the Sahelian boundary layer to measure sensible and latent heat fluxes. The measurements over the Niamey area often revealed organised structures of a few km scale that were associated with both thermals and dry intrusions. We study the impact of these coherent structures using a single day’s aircraft-measured fluxes and a numerical simulation of that day with a mesoscale model. The numerical simulation at high horizontal resolution (250 m) contains structures that evolve from streaks in the early morning to cells by noon. This simulation shows distribution, variance and skewness similar to the observations. In particular, the numerical simulation shows dry intrusions that can penetrate deeply into the atmospheric boundary layer (ABL), and even reach the surface in some cases, which is in accordance with the observed highly negatively skewed water vapour fluctuations. Dry intrusions and thermals organised at a few km scale give skewed flux statistics and can introduce large errors in measured fluxes. We use the numerical simulation to: (i) evaluate the contribution of the organised structures to the total flux, and (ii) estimate the impact of the organised structures on the systematic and random errors resulting from the 1D sampling of the aircraft as opposed to the 2D numerical simulation estimate. We find a significant contribution by the organised structures to the total resolved fluxes. When rolls occur, and for a leg length of about 30 times the ABL depth, the 1D sampled flux is shown to be sometimes 20% lower than the corresponding 2D flux when the 1D sampling direction is the same as the main axis of the rolls, whereas the systematic error is much lower when the direction of the leg is transverse to the rolls. In the case of cells, an underestimate of around 10% can still be observed with the 1D approach independent of direction, due to poor sampling of the energy-containing scales.  相似文献   

A Matrix Approach Coupled with Monte Carlo Techniques for Solving the Net Radiative Balance of the Urban Block   总被引：2，自引：0，他引：2  

Marta J. N. Oliveira Panão  Helder J. P. Gonçalves  Paulo M. C. Ferrão 《Boundary-Layer Meteorology》2007,122(1):217-241

A new method is developed for solving the shortwave and longwave net radiative balance of a three-dimensional urban structure, represented by parallelepiped blocks uniformly distributed in each direction. The method is based on a novel approach to determine the shape factors among surfaces, which are estimated by Monte Carlo techniques due to the complex geometry associated with the three-dimensional urban structure. Then, a set of linear equations is solved to quantify the radiative balance, in order to obtain their exact solution, considering all the inter-reflections among surfaces. The comparison between the new and the ray-tracing tracking methods resulted in a Pearson correlation coefficient of 0.996. However, by integrating the linear equations’ exact solution with Monte Carlo techniques, the new method reduces by a factor of 36 the central processing unit (CPU) time used to perform the calculations of the ray-tracing tracking method. The use of the model for a sensitivity study allows us to verify the effective absorptance and emittance increases with the canyon aspect ratio of the urban layout. An urban structure formed by square cross-sectional blocks absorbs more solar radiation than an urban structure formed by rectangular cross-sectional blocks. The approximation of a specific geometry for an equivalent bi-dimensional infinite street can be applied for rectangular cross-sectional blocks, where the width is 11 times or more greater than the depth dimension.  相似文献   

Sources and Transport of Urban and Biomass Burning Aerosol Black Carbon at the South–West Atlantic Coast     

H. Evangelista  J. Maldonado  R. H. M. Godoi  E. B. Pereira  D. Koch  K. Tanizaki-Fonseca  R. Van Grieken  M. Sampaio  A. Setzer  A. Alencar  S. C. Gonçalves 《Journal of Atmospheric Chemistry》2007,56(3):225-238

The total extent of the atmospheric impacts associated to the aerosol black carbon (BC) emissions from South America is not completed described. This work presents results of BC monitored during three scientific expeditions (2002, 2003 and 2004) on board of a Brazilian oceanographic vessel Ary Rongel that covered the South–West Atlantic coast between 22–62°S. This latitudinal band encloses major urban regions of South America and the outflow region of the SACZ (South Atlantic Convergent Zone), which is an important mechanism of advective transport of heat, moisture, minor gases and aerosols from the South America continental land to the Southern Atlantic Ocean. Our results showed that aerosol BC enhanced concentrations from urban/industrial origin can be transported to the South–West Atlantic Ocean due to the migration of sub-polar fronts that frequently reach tropical/subtropical regions. Despite the decrease of aerosol BC concentrations southwards (from ∼1,200 ng m⁻³ at latitude 22°S to ∼10 ng m⁻³ at latitude 62°S), several observed peak events were attributed to regional urban activities. Most of such events could be explained by the use of air mass back trajectories analysis. In addition, a global model simulation is presented (Goddard Institute for Space Studies – GISS GCM BC simulation) to explore the origins of aerosol BC in the South–West Atlantic. The model allowed isolating the biomass emissions from South America and Africa and industrial (non-biomass) pollution from other regions of the globe. This model suggests that the apportionment of about half of the aerosol BC at the South–West Atlantic may derive from South American biomass burning.  相似文献   

Earthquake ground motion in Mexico City: An analysis of data recorded at Roma array     

Martín Crdenas-Soto  Francisco J. Chvez-García 《Soil Dynamics and Earthquake Engineering》2007,27(5):475-486

We analysed in detail three earthquakes recorded in a small-aperture accelerometric array in Mexico City, using the correlation of the records as a function of time along the accelerogram and frequency. Ground response is strongly conditioned by the fundamental period of the soft soils at the site of the array (T₀). Energy at periods longer than 2T₀ is guided by the crustal structure (with a thickness of 45 km). The wave field at periods between T₀ and 2T₀ also consists of surface waves but guided by the upper 2–3 km of volcanic sediments in central Mexico. For periods smaller than T₀, ground motion is uncorrelated among the stations. Our results indicate that seismic response of Mexico City, including its very long duration, results from deeply guided surface waves (between 2 and 45 km depth) interacting with the very local response of the soft surficial clay layer.  相似文献   

Community structure and phenology of chironomids (Insecta: Chironomidae) in a Patagonian Andean stream     

Patricia Elizabeth García  Diego Alejandro An Surez 《Limnologica》2007,37(1):109-117

In this paper, we studied the assemblage of Chironomidae from headwaters of Ñireco stream by recording drifting pupal exuviae caught in the debris close to the shore. Samples were collected in three stations along 18 km of the stream every 2 weeks during spring–summer months and monthly during autumn–winter over a year. A total of 15949 exuviae were collected and 55 taxa were identified. The most abundant taxa were Cricotopus spp. with highest numbers of exuviae recorded in each station over the study period. Subfamily Orthocladiinae was the most abundant taxa, followed by Chironominae and Podonominae. The emergence period in the stream occurred between December 1998 and March 1999. Most of the dominant and frequent species were univoltine. The emergence peaks at each sampling station occurred at the highest temperature of the water recorded.  相似文献