EPR and magnetism of the nanostructured natural carbonaceous material shungite     

Maria Aldona Augustyniak-Jabłokow  Yurii V. Yablokov  Bartłomiej Andrzejewski  Wojciech Kempiński  Szymon Łoś  Krzysztof Tadyszak  Mikhail Y. Yablokov  Valentin A. Zhikharev 《Physics and Chemistry of Minerals》2010,37(4):237-247

The X-band EPR and magnetic susceptibility in the temperature range 4.2–300 K study of the shungite-I, natural nanostructured material from the deposit of Shunga are reported. Obtained results allow us to assign the EPR signal to conduction electrons, estimate their number, N _P, and evaluate the Pauli paramagnetism contribution to shungite susceptibility. A small occupation (~5%) of the localized nonbonding π states in the zigzag edges of the open-ended graphene-like layers and/or on σ (sp ^2+x ) orbitals in the curved parts of the shungite globules has been also revealed. The observed temperature dependence of the EPR linewidth can be explained by the earlier considered interaction of conduction π electrons with local phonon modes associated with the vibration of peripheral carbon atoms of the open zigzag-type edges and with peripheral carbon atoms cross-linking different nanostructures. The relaxation time T ₂ and diffusion time T _D are found to have comparable values (2.84 × 10⁻⁸ and 1.73 × 10⁻⁸ s at 5.2 K, respectively), and similar dependence on temperature. The magnetic measurements have revealed the suppression of orbital diamagnetism due to small amount of large enough fragments of the graphene layers.  相似文献   

Normal Modes of the Global Oceans—A Review     

Braulio Valentin Sanchez 《Marine Geodesy》2013,36(3):181-212

This paper deals with the normal modes of the global oceans. More specifically, it reviews some of the work done in association with the modeling, detection, and application of the barotropic, basin-wide normal modes. The paper presents some results obtained by means of the Proudman-Rao method. The fields of tidal synthesis from a set of normal modes, and paleotides, in the context of normal modes and the evolution of the Earth-Moon system, are surveyed as well. Works associated with the detection of normal modes are discussed also. The paper closes with an analysis of possible future developments.  相似文献   

Use of geoprocessing in the study of land degradation in urban environments: the case of the city of São Carlos,state of São Paulo,Brazil     

Nívea Adriana Dias Pons  Osni José Pejon  Lázaro Valentin Zuquette 《Environmental Geology》2007,53(4):727-739

This paper presents a methodology for the geological engineering survey of land degradation in urban environments using both remote sensing and geoprocessing tools. The area under study was the city of São Carlos, state of São Paulo, Brazil (urban and expansion area). The data presented here were obtained from earlier studies, photointerpretation and geological engineering mapping. The Envi 4.1 software package was used to prepare the digital orthophotos that served as a reference base for the information. Orthorectification of the Ikonos image (PSM, 1 m) was done and compared with other orthophotos from studies of environmental degradation in urban areas. The evolution of land degradation processes was analyzed based on the photointerpretation of aerial photographs taken on different dates and using Ikonos image. This study allowed to conclude that most of the degradation occurring in the city has been caused by unplanned land occupation, in disregard of environmental conditions, resulting in environmental degradation and thus impacting the quality of life of the urban population.  相似文献   

Engineering geological mapping developed in the Fortaleza Metropolitan Region, State of Ceara, Brazil     

Lzaro Valentin Zuquette  Osni Jos Pejon  Jaime Quintas dos Santos Collares 《Engineering Geology》2004,71(3-4):227-253

Engineering geological mapping was carried out, at a scale of 1:100,000, in the Fortaleza Metropolitan Region, located in northeastern Brazil, to provide engineering geological information as an aid in planning land use and occupation. In this study, eight basic maps were produced drawing: urban areas, lithology, unconsolidated materials in addition to geomorphological map showing slopes, water resources, engineering geological zoning and distribution of geological–geotechnical environmental problems based on information collected through field and laboratory investigations. The region was divided into nine engineering geological zones analyzed in terms of geohazard susceptibility and foundation, excavation and waste disposal conditions.  相似文献   

Analogue models of caldera collapse in strike-slip tectonic regimes     

Eoghan P. Holohan  Benjamin van Wyk de Vries  Valentin R. Troll 《Bulletin of Volcanology》2008,70(7):773-796

Regional-scale faulting, particularly in strike-slip tectonic regimes, is a relatively poorly constrained factor in the formation of caldera volcanoes. To examine interactions between structures associated with regional-tectonic strike-slip deformation and volcano-tectonic caldera subsidence, we made scaled analogue models. Tabular (sill-like) inclusions of creamed honey in a sand/gypsum mix replicated shallow-level granitic magma chambers in the brittle upper crust. Lateral motion of a base plate sited below half the sand/gypsum pack allowed simulation of regional strike-slip deformation. Our experiments modelled: (1) strike-slip deformation of a homogeneous brittle medium; (2) strike-slip deformation of a brittle medium containing a passive magma reservoir; (3) caldera collapse into sill-like magma reservoirs without regional strike-slip deformation; and (4) caldera collapse into sill-like magma reservoirs after regional strike-slip deformation. Our results show that whilst the magma chamber shape principally influences the development and geometry of volcano-tectonic collapse structures, regional-tectonic strike-slip faults (Riedel shears and Y-shears) may affect a caldera’s structural evolution in two main ways. Firstly, regional strike-slip faults above the magma chamber may form a pre-collapse structural grain that is exploited and reactivated during subsidence. Our experiments show that such faults may preferentially reactivate where tangential to the collapse area and coincident with the chamber margins. In this case, volcano-tectonic extension in the caldera periphery tends to localise on regional-tectonic faults that lie just outside the chamber margins. In addition, volcano-tectonic reverse faults may link with and reactivate pre-collapse regional-tectonic faults that lie just inside the chamber margins. Secondly, where regional-tectonic strike-slip faults define corners in the magma chamber margin, they may halt the propagation of volcano-tectonic reverse faults. The experiments also highlight the potential difficulties in assessing the relative contributions of volcano-tectonic and regional-tectonic subsidence processes to the final caldera structure seen in the field. Disruption of the pre-collapse surface by regional-tectonic faulting was preserved during coherent volcano-tectonic subsidence to produce a caldera floor of differentially-subsided fault blocks. Without definitive evidence for syn-eruptive growth faulting, thickness changes in caldera fill across such regional-tectonic fault blocks in nature could be mistaken as evidence for piecemeal volcano-tectonic collapse.  相似文献   

Observations on New Approaches for the Determination of Platinum-Group Elements, Gold and Silver in Different Geochemical Samples from Siberia and the Far East   总被引：1，自引：0，他引：1  

Valentina G. Tsimbalist  Gennady N. Anoshin  Valentin N. Mitkin  Ljudmila I. Razvorotneva  Nadezhda P. Golovanova 《Geostandards and Geoanalytical Research》2000,24(2):171-182

Some recent experiments on the determination of Au and the platinum-group elements (PGE) in geochemical samples are reviewed. Emphasis is given to the determination of ultra-low levels of PGE concentrations in resistant matrices, including chromites, molybdenites and ultrabasic ores. The problems and features of PGE determination in samples of various chemical composition are considered. For each sample type studied, a series of sample preparation techniques are proposed. These techniques included acid digestion, fusion with sodium peroxide, cold sintering with an oxidizing mixture of Na₂O₂+ Na₂CO₃ and also oxidizing fluorination with bromine trifluoride. A new approach for preparing geochemical material prior to digestion, based on mechano-chemical activation with simultaneous hyperfine grinding, is proposed and studied. The instrumental determination of PGE contents was carried out directly by AAS from extracted organic phases. It was found that a combination of digestion processes was required to achieve geochemical background levels of Au and PGE concentrations with the following detection limits: Pd, Rh - 1 ng g⁻¹, Pt, Ru - 10 ng g⁻¹, Au - 0.2 ng g⁻¹, Ag - 0.1 ng g^−1. The uncertainty in PGE and Au determination in geochemical samples is dependent on metal concentration, and also on their distribution in samples. The total analytical uncertainty of the proposed method is between 15-30%.  相似文献   

Numerical study of tides in Ontario Lacus,a hydrocarbon lake on the surface of the Saturnian moon Titan     

David Vincent  Özgur Karatekin  Valentin Vallaeys  Alexander G. Hayes  Marco Mastrogiuseppe  Claudia Notarnicola  Véronique Dehant  Eric Deleersnijder 《Ocean Dynamics》2016,66(4):461-482

In the context of the emergence of extra-terrestrial oceanography, we adapted an existing oceanographic model, SLIM (www.climate.be/slim), to the conditions of Titan, a moon of Saturn. The tidal response of the largest southern lake at Titan’s surface, namely Ontario Lacus, is simulated. SLIM solves the 2D, depth-averaged shallow water equations on an unstructured mesh using the discontinuous Galerkin finite element method, which allows for high spatial resolution wherever needed. The impact of the wind forcing, the bathymetry, and the bottom friction is also discussed. The predicted maximum tidal range is about 0.56 m in the southern part of the lake, which is more than twice as large as the previous estimates (see Tokano, Ocean Dyn 60:(4) 803–817 10.1007/s10236-010-0285-3 (Tokano 2010)). The patterns and magnitude of the current are also markedly different from those of previous studies: the tidal motion is not aligned with the major axis of the lake and the speed is larger nearshore. Indeed, the main tidal component rotates clockwise in an exact period of one Titan day and the tidal currents can reach 0.046 ms ^?1 close to the shores depending on the geometry and the bathymetry. Except for these specific nearshore regions, the current speed is less than 0.02 ms ^?1. Circular patterns can be observed offshore, their rotational direction and size varying along the day.  相似文献   

The REE-Ti mineral chevkinite in comenditic magmas from Gran Canaria,Spain: a SYXRF-probe study   总被引：2，自引：0，他引：2  

Valentin?R.?TrollEmail author  Peter?M.?Sachs  Hans-Ulrich?Schmincke  Mari?Sumita 《Contributions to Mineralogy and Petrology》2003,145(6):730-741

The REE-Ti silicate chevkinite has been recognised previously in Miocene ignimbrites from Gran Canaria, and in correlative offshore syn-ignimbrite turbidites. We have estimated the partition coefficients of REE, Y, Zr and Nb for chevkinite and co-existing peralkaline rhyolitic (comendite) glass using synchrotron-XRF-probe analyses (SYXRF) in order to evaluate the role of this mineral in the REE budget of felsic peralkaline magmas. The Zr/Nb ratio of the chevkinite is 1.55–1.7, strongly contrasting with Zr/Nb of 6.5 in the associated glass. Zr shows a three-fold enrichment in chevkinite relative to the residual melt, whereas Nb is enriched by a factor >10. The enrichment of Ce and La in chevkinite is even more significant, namely 19 wt(%) Ce and 12 wt(%) La, compared to 236 ppm Ce and 119 ppm La in the glass. Chevkinite/glass ratios are 988±30 for La, 806±30 for Ce, 626±30 for Pr, 615±40 for Nd, 392±50 for Sm, 225±30 for Eu, 142±25 for Gd, 72±20 for Dy. For trace elements, we derived Kd_TE of 74±25 for Y, >8 for Hf, >50 for Th, 15±5 for Nb and 3.55±0.4 for Zr. Mineral/glass ratios for co-existing titanite are 28±10 for La, 86±20 for Ce, 98±30 for Pr, 134±35 for Nd, 240±50 for Sm, 50±20 for Eu, 96±25 for Gd, 82±25 for Dy, 99±30 for Y, 45±10 for Nb and 3±0.5 for Zr. Based on these data, the removal of only 0.05 wt% of chevkinite from a magma with initially 300 ppm Ce would deplete the melt by 93 ppm to yield 207 ppm Ce in the residual liquid. Chevkinite thus appears, when present, to be the controlling mineral within the LREE budget of evolved peralkaline magmas.Editorial responsibility: I. Parsons

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Valentin R. TrollEmail: Phone: +353-1-6083856Fax: +353-1-6081199

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An Origin for Harrisitic and Granular Olivine in the Rum Layered Suite, NW Scotland: a Crystal Size Distribution Study   总被引：2，自引：0，他引：2  

O'Driscoll  Brian; Donaldson  Colin H.; Troll  Valentin R.; Jerram  Dougal A.; Emeleus  C. Henry 《Journal of Petrology》2007,48(2):253-270

Dendritic crystal morphologies occur in a number of igneousrocks and are thought to originate from the rapid growth ofcrystals, yet many examples of dendritic morphologies are foundin plutonic igneous rocks where cooling rates should be low.Results from crystal size distribution (CSD) measurements onharrisitic olivines from Rum, Scotland, combined with estimatedolivine growth rates, suggest that the characteristic skeletalhopper and branching olivines of harrisitic cumulates that areup to centimetres long, may have exceptionally short crystalgrowth times (several hours to several hundreds of days). This,together with very low calculated nucleation densities for harrisiticolivine, supports the interpretation of harrisite being a disequilibriumtexture, developed in response to supersaturation of the magmain olivine. We propose that this supersaturation arose throughundercooling of thin picrite sheets emplaced along the Rum magmachamber floor, beneath cooler resident magma. It is envisagedthat the picrite sheets were largely free of suspended olivinecrystals. Coupled with the olivine-enriched composition of themelt and the increasing cooling rate, this allowed homogeneousnucleation of olivine to set in at deeper undercooling and greaterolivine supersaturation than if there had been plentiful suspendedolivines to act as heterogeneous nuclei. The enhanced supersaturationcaused rapid growth of olivine once nucleation began, with skeletaland dendritic shapes. It is suggested that the observed, interlayeredsequences of harrisite and cumulus peridotite found throughoutthe Rum Layered Suite are a result of multiple episodes of harrisitecrystallization resulting from picrite emplacement that alternatedwith periods of crystal growth and accumulation in the mainbody of magma at lesser degrees of undercooling. KEY WORDS: crystal size distribution; harrisite; crystal growth rates; Rum Layered Suite  相似文献   

Carbonate Assimilation at Merapi Volcano, Java, Indonesia: Insights from Crystal Isotope Stratigraphy   总被引：2，自引：0，他引：2  

Chadwick  Jane P.; Troll  Valentin R.; Ginibre  Catherine; Morgan  Daniel; Gertisser  Ralf; Waight  Tod E.; Davidson  Jon P. 《Journal of Petrology》2007,48(9):1793-1812

Recent basaltic andesite lavas from Merapi volcano contain abundant,complexly zoned, plagioclase phenocrysts, analysed here fortheir petrographic textures, major element composition and Srisotope composition. Anorthite (An) content in individual crystalscan vary by as much as 55 mol% (An_40–95) across internalresorption surfaces with a negative correlation between highAn mol% (>70), MgO wt% and FeO wt%. In situ Sr isotope analysesof zoned plagioclase phenocrysts show that the ⁸⁷Sr/⁸⁶Sr ratiosof individual zones range from 0·70568 to 0·70627.The upper end of this range is notably more radiogenic thanthe host basaltic andesite whole-rocks (< 0·70574).Crystal zones with the highest An content have the highest ⁸⁷Sr/⁸⁶Srvalues, requiring a source or melt with elevated radiogenicSr, rich in Ca and with lower Mg and Fe. Recent Merapi eruptiverocks contain abundant xenoliths, including metamorphosed volcanoclasticsediment and carbonate country rock (calc-silicate skarns) analysedhere for petrographic textures, mineralogy, major element compositionand Sr isotope composition. The xenoliths contain extremelycalcic plagioclase (up to An₁₀₀) and have whole-rock ⁸⁷Sr/⁸⁶Srratios of 0·70584 to 0·70786. The presence ofthese xenoliths and their mineralogy and geochemistry, coupledwith the ⁸⁷Sr/⁸⁶Sr ratios observed in different zones of individualphenocrysts, indicate that magma–crust interaction atMerapi is potentially more significant than previously thought,as numerous crystal cores in the phenocrysts appear to be inheritedfrom a metamorphosed sedimentary crustal source. This has potentiallysignificant consequences for geochemical mass-balance calculations,volatile saturation and flux and eruptive behaviour at Merapiand similar island arc volcanic systems elsewhere. KEY WORDS: assimilation; isotopes; Merapi; xenolith; calc-silicate  相似文献