Chemical characteristics of atmospheric bulk deposition in a semi-rural area of the <Emphasis Type="Bold">Po Valley</Emphasis> (Italy)     

Laura?Tositti  Linda?Pieri  Erika?BrattichEmail authorView author&#;s OrcID profile  Silvia?Parmeggiani  Francesca?Ventura 《Journal of Atmospheric Chemistry》2018,75(1):97-121

This study provides an analysis of a five-year time series chemical composition of the bulk deposition (2009–2013), collected within a farm surrounded by industrial and urban settlements in a semi-rural area of the Po Valley, with the aim of characterizing potential emission sources affecting precipitation composition at the site. Most monitoring efforts in this region, recognized as one of the most polluted in the world both due to the intense industrialisation and urbanisation as well as to frequent air stagnation conditions, are presently devoted more to gaseous and particulate pollutants than to precipitation chemistry. The bulk deposition samples were very concentrated in chemical species, both acidic and alkaline, high compared to other polluted sites in the world and to locations in the same district. The mean ions concentrations (in μeq l^?1) are: NO₃ ^? (243) > SO₄ ^2? (220) > PO₄ ^3? (176) > Cl^? (153) > NO₂ ^? (29) > F^? (2.6); NH₄ ⁺ (504) > Ca²⁺ (489) > K⁺ (151) > Na⁺ (127) > Mg²⁺ (127). pH data shows a trend toward slightly alkaline conditions attributed to the large presence of ammonium and crustal elements, in spite of high concentrations of nitrates and sulphates. The relevant concentrations of Ca²⁺ and Mg²⁺ further suggests that these alkaline conditions might be due to the correspondingly significant concentrations of carbonates/bicarbonates in our dataset. While back-trajectories analysis suggests the stronger importance of local resuspension over long-range transport, statistical analyses on ion composition highlight the key role exerted by agricultural activity, especially in the case of NH₄ ⁺, K⁺, Ca²⁺ and PO₄ ^3? (especially linked to fertilisation practices and soil resuspension due to mechanical operations). Apart from Na⁺ and Cl^? ions which correlate well as expected, indicating their likely common origin from marine salt, the identification of the origin of the other ions is very complex due to the contribution of diverse local sources, such as industrial and residential settlements.  相似文献   

Kinematic significance of mingling-rolling structures in lava flows: a case study from Porri Volcano (Salina, Southern Tyrrhenian Sea)     

Guido Ventura 《Bulletin of Volcanology》1998,59(6):394-403

 A basaltic andesite lava flow from Porri Volcano (Salina, Southern Tyrrhenian Sea) is composed of two different magmas. Magma A (51 vol.% of crystals) has a dacitic glass composition, and magma B (18 vol.% of crystals), a basaltic glass composition. Magma B is hosted in A and consists of sub-spherical enclaves and boudin-like, banding and rolling structures (RS). Four types of RS have been recognized: σ–type;δ–type; complex σ-δ–types and transitional structures between sub-spherical enclaves and rolling structures. An analysis of the RS has been performed in order to reconstruct the flow kinematics and the mechanism of flow emplacement. Rolling structures have been selected in three sites located at different distances from the vent. In all sites most RS show the same sense of shear. Kinematic analysis of RS allows the degree of flow non-coaxiality to be determined. The non-coaxiality is expressed by the kinematic vorticity number Wk, a measure of the ratio Sr between pure shear strain rate and simple shear strain rate. The values of Wk calculated from the measured shapes of microscopic RS increase with increasing distance from the vent, from approximately 0.5 to 0.9. Results of the structural analysis reveal that the RS formed during the early–intermediate stage of flow emplacement. They represent originally sub-spherical enclaves deformed at low shear strain. At higher strain, RS deformed to give boudin-like and stretched banding structures. Results of the kinematic analysis suggest that high viscosity lava flows are heterogeneous non-ideal shear flows in which the degree of non-coaxiality increases with the distance from the vent. In the vent area, deformation is intermediate between simple shear and pure shear. Farther from the vent, deformation approaches ideal simple shear. Lateral extension processes occur only in the near-vent zone, where they develop in response to the lateral push of magma extruded from the vent. Lateral shortening processes develop in the distal zone and record the gravity-driven movement of the lava. The lava flow advanced by two main mechanisms, lateral translation and rolling motion. Lateral translation equals rolling near the vent, while rolling motion prevailed in the distal zones. Received: 6 November 1997 / Accepted: 29 November 1997  相似文献   

Biochemical indicators of contaminant exposure in spotted pigfish (Orthopristis ruber) caught at three bays of Rio de Janeiro coast     

Ventura EC  Gaelzer LR  Zanette J  Marques MR  Bainy AC 《Marine environmental research》2002,54(3-5):775-779

The initial sampling in the Marine Monitoring Program (MOMAM), coordinated by the Ministry of Marine Affairs (IEAPM), was performed along the southeast coast of Brazil. Orthopristis ruber samples were collected at Guanabara, Sepetiba and Ilha Grande Bays. Microsomal CYP1A levels and cytosolic cholinesterase (ChE), catalase (CAT) and glutathione S-transferase (GST) activities were measured in the liver of these fish according to established procedures. CAT activity and CYP1A content were significantly higher (P < or = 0.05) in fish caught at Guanabara Bay, which might be due to higher levels of peroxisome proliferators and Ah receptor agonists, respectively, at this site compared to the other sites. Also, lower GST activity was observed in fish from this site, which may possibly be related to the presence of oxidative-stress inducing compounds.  相似文献   

Biochemical responses in farmed mussel Perna perna transplanted to contaminated sites on Santa Catarina Island, SC, Brazil.   总被引：3，自引：0，他引：3  

A C Bainy  E A Almeida  I C Müller  E C Ventura  I D Medeiros 《Marine environmental research》2000,50(1-5):411-416

The effects of contaminants on the biochemical parameters of the intensively farmed mussel Perna perna, are unknown. The aim of this study was to compare biochemical responses in mussels held in clean and contaminated sites in Santa Catarina Island, Brazil. Mussels were transplanted from a farming area, Ratones Grande Island (RGI), to two contaminated sites, Itacorubi (ITAC) and Hercílio Luz Bridge (HLB). A reference group was kept at RGI. After 150 and 180 days of exposure, the digestive glands of the mussels were analyzed for catalase, glucose 6-phosphate dehydrogenase (G6PDH) and glutathione S-transferase (GST) activities. No changes were observed in the catalase activity, in both periods. Low G6PDH activity was observed in mussels transplanted for 150 days at the ITAC site. Increased GST activity was observed in mussels from ITAC and HLG sites after 180 days. These responses are probably related to the augmented discharges of domestic effluents associated with elevated rainfall index.  相似文献   

Provenance record of late Maastrichtian–late Palaeocene Andean Mountain building in the Amazonian retroarc foreland basin (Madre de Dios basin,Peru)          下载免费PDF全文

Mélanie Louterbach  Martin Roddaz  Pierre‐Olivier Antoine  Laurent Marivaux  Sylvain Adnet  Julien Bailleul  Elton Dantas  Roberto Ventura Santos  Farid Chemale Jr  Patrice Baby  Caroline Sanchez  Ysabel Calderon 《地学学报》2018,30(1):17-23

Biostratigraphic, sedimentological and provenance analyses suggest that a proto‐Andean Cordillera already existed in southern Peru by late Maastrichtian–late Palaeocene times. A 270‐m‐thick stratigraphic section shows changes in depositional environments from shallow marine (early Maastrichtian) to non‐marine (late Maastrichtian) then back to estuarine (late Palaeocene) conditions. An erosional surface separates lower Maastrichtian from upper Maastrichtian deposits. Above this surface, the late Maastrichtian unit exhibits moderately developed palaeosols and syn‐sedimentary normal faults. The sedimentary evolution is accompanied by a decrease in sedimentation rate and by changes in provenance. Shallow marine lower Maastrichtian deposits have a cratonic provenance as shown by their low εNd(0) values (?15 to ?16) and the presence of Precambrian inherited zircon grains. The upper Maastrichtian deposits have a mixed Andean and cratonic origin with εNd(0) values of ~12.6 and yield the first Cretaceous and Permo‐Triassic zircon grains. Estuarine to shallow marine upper Palaeocene deposits have an Andean dominant source as attested by higher εNd(0) values (?6 to ?10) and by the presence of Palaeozoic and Late Cretaceous zircon grains. The changes in depositional environments and sedimentation rates, as well as the shift in detrital provenance, are consistent with a late Maastrichtian–late Palaeocene period of Andean mountain building. In agreement with recently published studies, our data suggest that an Andean retroarc foreland basin was active by late Maastrichtian–late Palaeocene times.  相似文献   

The Catalão I niobium deposit, central Brazil: Resources, geology and pyrochlore chemistry     

Pedro Filipe de Oliveira Cordeiro  José Affonso Brod  Matheus Palmieri  Claudinei Gouveia de Oliveira  Elisa Soares Rocha Barbosa  Roberto Ventura Santos  José Carlos Gaspar  Luis Carlos Assis 《Ore Geology Reviews》2011,41(1):112-121

The Catalão I alkaline–carbonatite–phoscorite complex contains both fresh rock and residual (weathering-related) niobium mineralization. The fresh rock niobium deposit consists of two plug-shaped orebodies named Mine II and East Area, respectively emplaced in carbonatite and phlogopitite. Together, these orebodies contain 29 Mt at 1.22 wt.% Nb₂O₅ (measured and indicated). In closer detail, the orebodies consist of dike swarms of pyrochlore-bearing, olivine-free phoscorite-series rocks (nelsonite) that can be either apatite-rich (P2 unit) or magnetite-rich (P3 unit). Dolomite carbonatite (DC) is intimately related with nelsonite. Natropyrochlore and calciopyrochlore are the most abundant niobium phases in the fresh rock deposit. Pyrochlore supergroup chemistry shows a compositional trend from Ca–Na dominant pyrochlores toward Ba-enriched kenopyrochlore in fresh rock and the dominance of Ba-rich kenopyrochlore in the residual deposit. Carbonates associated with Ba-, Sr-enriched pyrochlore show higher δ¹⁸O_SMOW than expected for carbonates crystallizing from mantle-derived magmas. We interpret both the δ¹⁸O_SMOW and pyrochlore chemistry variations from the original composition as evidence of interaction with low-temperature fluids which, albeit not responsible for the mineralization, modified its magmatic isotopic features. The origin of the Catalão I niobium deposit is related to carbonatite magmatism but the process that generated such niobium-rich rocks is still undetermined and might be related to crystal accumulation and/or emplacement of a phosphate–iron-oxide magma.  相似文献   

1-D and 2-D analyses of weak motion data in Fraser Delta from 1966 Duvall earthquake     

W. D. Liam Finn  E. Zhai  T. Thavaraj  X. -S. Hao  C. E. Ventura 《Soil Dynamics and Earthquake Engineering》2003,23(4):323-329

The 1996 Duvall earthquake in Washington State triggered ground motion stations in the Fraser Delta, British Columbia, located on varying depths of Holocene and Pleistocene soils to a maximum depth of 800 m and one station on bedrock. Recorded ground motions were used to examine the applicability of 1-D and 2-D site response analyses for amplification studies in the Delta. 1-D response analysis gave a good indication of the period of peak response. Response spectra computed by 1-D analysis did not compare well with recorded spectra except at very deep sites. The use of 2-D analyses to include buried topography generally improved the predictions of site response spectra at the shallow sites. However, for the shallow earth sites, the recorded motions showed a strong spectral response at short periods in the range of 0.1–0.25 s. Neither 1-D nor 2-D analysis predicted this response.  相似文献   

Quantitative analysis of H2O and CO2 in cordierite using polarized FTIR spectroscopy     

Giancarlo Della Ventura  Francesco Radica  Fabio Bellatreccia  Andrea Cavallo  Francesco Capitelli  Simon Harley 《Contributions to Mineralogy and Petrology》2012,164(5):881-894

We report a FTIR (Fourier transform infrared) study of a set of cordierite samples from different occurrence and with different H₂O/CO₂ content. The specimens were fully characterized by a combination of techniques including optical microscopy, single-crystal X-ray diffraction, EMPA (electron microprobe analysis), SIMS (secondary ion mass spectrometry), and FTIR spectroscopy. All cordierites are orthorhombic Ccmm. According to the EMPA data, the Si/Al ratio is always close to 5:4; X _Mg ranges from 76.31 to 96.63, and additional octahedral constituents occur in very small amounts. Extraframework K and Ca are negligible, while Na reaches the values up to 0.84 apfu. SIMS shows H₂O up to 1.52 and CO₂ up to 1.11 wt%. Optically transparent single crystals were oriented using the spindle stage and examined by FTIR micro-spectroscopy under polarized light. On the basis of the polarizing behaviour, the observed bands were assigned to water molecules in two different orientations and to CO₂ molecules in the structural channels. The IR spectra also show the presence of small amounts of CO in the samples. Refined integrated molar absorption coefficients were calibrated for the quantitative microanalysis of both H₂O and CO₂ in cordierite based on single-crystal polarized-light FTIR spectroscopy. For H₂O the integrated molar coefficients for type I and type II water molecules (ν₃ modes) were calculated separately and are ^[I]ε?=?5,200?±?700?l?mol^?1?cm^?2 and ^[II]ε?=?13,000?±?3,000?l?mol^?1?cm^?2, respectively. For CO₂ the integrated coefficient is $ \varepsilon_{{{\text{CO}}_{ 2} }} $ ?=?19,000?±?2,000?l?mol^?1?cm^?2.  相似文献   

Effects of spatial aggregation approaches on classified satellite imagery     

Hong S. He  Stephen J. Ventura  David J. Mladenoff 《International journal of geographical information science》2013,27(1):93-109

Spatial aggregations of raster data based on the majority rule have been typically used in landscape ecological studies. It is generally acknowledged that (1) dominant classes increase in abundance while minor classes decrease in abundance or even disappear through aggregation processes; and (2) spatial patterns also change with aggregations. In this paper, we examined an alternative, random rule-based aggregation and its effects on cover type abundance and landscape patterns, in comparison with the majority rule-based aggregation. We aggregated a classified TM imagery (about 1.5 million ha) from 30m (4231 × 3717 pixels) incrementally to 990m resolution (132 pixels × 116 pixels). Cover type proportion, mean patch size ratio, aggregation index (AI), and fractal dimension (FD) were used to assess the effects of aggregation. To compare landscapes under different resolutions, we assumed that the landscapes were least distorted if (1) the cover type proportions and mean patch size ratios among classes were maintained, and (2) all cover types responded in the same way for a given index as aggregation levels increased. For example, distortion is introduced by aggregation if some cover types increase their AI values with increasing aggregation levels while other cover types decrease. Our study indicated that the two spatial aggregation techniques led to different results in cover type proportions and they altered spatial pattern in opposite ways. The majority rule-based aggregations caused distortions of cover type proportions and spatial patterns. Generally, the majority rule-based aggregation filtered out minor classes and produced clumped landscapes. Such landscape representations are relatively easy for interpreting and, therefore, are suitable for land managers to conceptualize spatial patterns of a study region. By contrast, the random rule-based aggregations maintained cover type proportions accurately, but tended to make spatial patterns change toward disaggregation. Overall, the measurements of landscape indices used in this study indicated that  相似文献   

Age and sources of gold mineralization in the Marmato mining district, NW Colombia: A Miocene–Pliocene epizonal gold deposit     

Colombo Celso Gaeta Tassinari  Fabio Diaz Pinzon  Juaquin Buena Ventura 《Ore Geology Reviews》2008,33(3-4):505-518

Epigenetic gold mineralization occurs in the Marmato mining district, within the Calima Terrain of the Setentrional Andes, Colombia. Regional rocks associated with this mineralization include: graphite- and chlorite-schists of the Arquia Complex; metamorphosed during the Cretaceous, Miocene sandstones, shales and conglomerates of the Amagá Formation; as well as pyroclastic rocks (clasts of basalt, andesites and mafic lavas) and subvolcanic andesitic/dacitic bodies of the Combia Formation (9 to 6 Ma). The subvolcanic Marmato stock hosts mesothermal and epithermal low-sulfidation Au–Ag ores in the form of distensional veins, stockwork, and quartz veinlets within brecciated zones. Ore minerals are pyrite, sphalerite and galena with subordinate chalcopyrite, arsenopyrite, pyrrhotite, argentite and native gold/electrum.Sericitized plagioclase from a porphyry dacite yielded a K–Ar age of 5.6 ± 0.6 Ma, interpreted as the age of ore deposition. This is in close agreement with the age of reactivation of the Cauca–Romeral Fault System (5.6 ± 0.4 Ma), which bounds the Calima Terrain. A porphyry andesite–dacite (6.7 ± 0.1 Ma), hosting the Au–Ag veins, shows a measured ⁸⁷Sr/⁸⁶Sr between 0.70440 and 0.70460, ε_Nd between + 2.2 and + 3.2 and ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb ratios of 18.964 to 19.028; 15.561 to 15.570; and 38.640 to 38.745, respectively. The ⁸⁷Sr/⁸⁶Sr and ε_Nd values of rocks from the Arquia Group range from 0.70431 to 0.73511 and − 12.91 to + 10.0, respectively, whereas the corresponding Pb isotopic ratios (²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb) range from 18.948 to 19.652; 15.564 to 15.702; and 38.640 to 38.885, respectively. ⁸⁷Sr/⁸⁶Sr and ε_Nd values obtained on sulfides from the gold quartz veins, which occur at shallow and intermediate levels, range from 0.70500 to 0.71210 and from − 1.11 to + 2.40. In the deepest veins, ε_Nd values lie between + 1.25 and + 3.28 and the ⁸⁷Sr/⁸⁶Sr of calcite and pyrite fall between 0.70444 and 0.70930. The ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb ratios of all mineralization are in the ranges 18.970 to 19.258; 15.605 to 15.726 and 38.813 to 39.208, respectively. Carbonates have an average ⁸⁷Sr/⁸⁶Sr ratio of 0.70445, which is within the range of values measured in the host dacite. The Sr isotopic data indicate that carbonic fluids have a restricted hydrothermal circulation within the host igneous body, while the Sr, Pb and Nd isotopic compositions of the sulfides suggest that the fluids not only circulated within the Marmato stock, but also throughout the Arquia Complex, inferring that these rocks offer a potential target for mineral exploration. Based on geological and geochronological evidence, the epizonal Marmato gold ores formed during the Miocene to Pliocene, as a result of cooling of the Marmato stock and reactivation along a crustal-scale fault zone related to thermal processes in an accretionary oceanic–continental plate orogen.  相似文献