Oxygen and carbon isotope ratios in the martian atmosphere     

Vladimir A. Krasnopolsky  Jean Pierre Maillard  Tobias C. Owen  Robert A. Toth  Michael D. Smith 《Icarus》2007,192(2):396-403

Oxygen and carbon isotope ratios in the martian CO₂ are key values to study evolution of volatiles on Mars. The major problems in spectroscopic determinations of these ratios on Mars are uncertainties associated with: (1) equivalent widths of the observed absorption lines, (2) line strengths in spectroscopic databases, and (3) thermal structure of the martian atmosphere during the observation. We have made special efforts to reduce all these uncertainties. We observed Mars using the Fourier Transform Spectrometer at the Canada–France–Hawaii Telescope. While the oxygen and carbon isotope ratios on Mars were byproducts in the previous observations, our observation was specifically aimed at these isotope ratios. We covered a range of 6022 to 6308 cm⁻¹ with the highest resolving power of ν/δν=3.5×10⁵ and a signal-to-noise ratio of 180 in the middle of the spectrum. The chosen spectral range involves 475 lines of the main isotope, 184 lines of ¹³CO₂, 181 lines of CO¹⁸O, and 119 lines of CO¹⁷O. (Lines with strengths exceeding 10⁻²⁷ cm at 218 K are considered here.) Due to the high spectral resolution, most of the lines are not blended. Uncertainties of retrieved isotope abundances are in inverse proportion to resolving power, signal-to-noise ratio, and square root of the number of lines. Laboratory studies of the CO₂ isotope spectra in the range of our observation achieved an accuracy of 1% in the line strengths. Detailed observations of temperature profiles using MGS/TES and data on temperature variations with local time from two GCMs are used to simulate each absorption line at various heights in each part of the instrument field of view and then sum up the results. Thermal radiation of Mars' surface and atmosphere is negligible in the chosen spectral range, and this reduces errors associated with uncertainties in the thermal structure on Mars. Using a combination of all these factors, the highest accuracy has been achieved in measuring the CO₂ isotope ratios: ¹³C/¹²C = 0.978 ± 0.020 and ¹⁸O/¹⁶O = 1.018 ± 0.018 times the terrestrial standards. Heavy isotopes in the atmosphere are enriched by nonthermal escape and sputtering, and depleted by fractionation with solid-phase reservoirs. The retrieved ratios show that isotope fractionation between CO₂ and oxygen and carbon reservoirs in the solid phase is almost balanced by nonthermal escape and sputtering of O and C from Mars.  相似文献   

Models of the REE distribution in the black shale Bazhenov Formation of the West Siberian marine basin,Russia     

Yuri N. Zanin  Vika G. Eder  Al’bina G. Zamirailova  Vladimir O. Krasavchikov 《Chemie der Erde / Geochemistry》2010,70(4):363-376

Rare-earth elements abundance in black shales of the Upper Jurassic (Tithonian Stage)–Lower Cretaceous (Berriassian Stage) Bazhenov Formation is discussed. This formation is the principal oil source rocks of West Siberia. The deposits within the formation can be subdivided into two main marine groups: (a) moderately hemipelagic deposits (clayey-siliceous, including phosphatic and carbonate rocks) and low-density distal clayey turbidites (argillites), both are considered as normal and (b) silty argillites and clayey-silt rocks, which are channel deposits and considered as anomalous. The hemipelagic rocks of normal sections, which are enriched in the rare-earth elements (REE), accumulated under both slow rates of sedimentation (clayey-siliceous rocks) and faster rates of sedimentation (argillites). The channel deposits of anomalous sections, which are impoverished in the REE, accumulated exclusively under fast rates of sedimentation.Within the hemipelagic group the rate of sedimentation of the argillites was faster than of the clayey-siliceous rocks, but the REE concentration in the former rocks (140.4 ppm) is higher than in the latter group (97.4 ppm). The argillites are more than twice enriched in clayey material than clayey-siliceous rocks. It is likely that the clay fraction was the main carrier of REE in these rocks. In the channel group of rocks, the REE abundance in clayey-silt rocks (21.2 ppm) is lower than in the silty argillite (84.6 ppm), in which the clay content is elevated.With respect to redox potential the Bazhenov Formation rocks can be subdivided further into three groups, based on the degree of pyritization index (DOP): (1) the highly reducing clayey-siliceous rocks of normal sections, with high DOP; (2) the substantially reducing argillites and carbonate rocks of normal sections, with intermediate DOP; (3) the moderately reducing rocks of anomalous sections with low DOP. The rocks with the high DOP (group 1) are characterized by ΣLREE/Σ(M+H)REE ratios between 7.37 and 7.5, whereas the rocks with the lower DOP (group 2 and 3) are characterized by ΣLREE/Σ(M+H)REE ratios between 12.8 and 13.5. Negative Ce anomalies are either small or absent in all deposits, which is typical for reducing conditions.Thus, the Bazhenov Formation exemplifies the complex depositional conditions that influence the REE concentration in black shale. However, it is this very complexity that has contributed to the development of six separate depositional models (REE contents in ppm are given in brackets). (1) Phosphatic clayey-siliceous rocks of normal sections (367.95); (2) argillites of normal sections (130.73); (3) clayey-siliceous rocks of normal sections (85.97); (4) carbonate rocks, largely dolomites of normal sections (23.23); (5) silty argillites of anomalous sections (78.7) and (6) clayey-silt rocks of anomalous sections (19.66).  相似文献   

Geochemistry of igneous rocks associated with ultramafic–mafic-hosted Cu (Co, Ni, Au) VMS deposits from the Main Uralian Fault (Southern Urals, Russia)     

Paolo Nimis  Paolo Omenetto  Bernd Buschmann  Peter Jonas  Vladimir A. Simonov 《Mineralogy and Petrology》2010,100(3-4):201-214

Ultramafic–mafic- and ultramafic-hosted Cu (Co, Ni, Au) volcanogenic massive sulfide (VMS) deposits from ophiolite complexes of the Main Uralian Fault, Southern Urals, are associated with island arc-type igneous rocks. Trace element analyses show that these rocks are geochemically analogous to Early Devonian boninitic and island arc tholeiitic rocks found at the base of the adjacent Magnitogorsk volcanic arc system, while they are distinguished both from earlier, pre-subduction volcanic rocks and from later volcanic products that were erupted in progressively more internal arc settings. The correlation between the sulfide host-rocks and the earliest volcanic units of the Magnitogorsk arc suggests a connection between VMS formation and infant subduction-driven intraoceanic magmatism.  相似文献   

Methods of Three-part Quantitative Assessments of Undiscovered Mineral Resources: Examples from Victoria,Australia   总被引：1，自引：0，他引：1  

Vladimir Lisitsin 《Mathematical Geosciences》2010,42(5):571-582

Quantitative mineral resource assessments following the 3-part form rely on grade and tonnage models and probabilistic estimates of the number of undiscovered deposits. Assessments completed in Victoria, Australia, indicate that undiscovered mineral resources can be effectively estimated using grade and tonnage sub-models constructed using only medium- and large-tonnage deposits. Numbers of undiscovered deposits can be estimated on the basis of expert judgement or entirely by statistical means. Appropriate mathematical aggregation of individual expert views, expressed at interactive expert workshops, provides robust estimates of the number of undiscovered deposits. Underestimation of uncertainty, which is common in expert judgement, can be compensated by the statistical modification of individual interval estimates. In this study, the linear opinion pool was used as a simple and robust method of mathematical aggregation of multiple expert estimates of the number of undiscovered deposits. A general regression model, which estimates numbers of undiscovered deposits based on the size of the geologically permissive area and the median deposit tonnage, provided results generally compatible with those based on expert judgement or local deposit density models.  相似文献   

The improvement of greenhouse gas inventory as a tool for reduction emission uncertainties for operations with oil in the Russian Federation   总被引：2，自引：0，他引：2  

Nina E. Uvarova  Vladimir V. Kuzovkin  Sergey G. Paramonov  Michael L. Gytarsky 《Climatic change》2014,124(3):535-544

The high quality inventory is an important step to greenhouse gas emission mitigation. The inventory quality is estimated by means of the uncertainty analysis. The level of uncertainty depends upon the reliability of activity data and the parameters used. An attempt has been made to improve the accuracy of the estimates through a shift from production-based method (IPCC Tier 1) (IPCC 2000) to enhanced combination of production-based and mass balance methods (IPCC Tier 2) (IPCC 2006) in the estimation of emissions from operations with oil that are key in the national greenhouse gas inventory of the Russian Federation. The IPCC Tier 2 (IPCC 2006) was adapted for the national conditions. The greenhouse gas emissions were calculated for 1990 to 2009 with the use of both methods. The quantitative uncertainty assessment of the calculations was performed, and the outcomes were compared. The comparison showed that the estimates made with the use of higher tier method resulted in higher accuracy and lower uncertainties (26 % respectively compared to previously derived 54 %).  相似文献   

The variability of the East Asian summer monsoon and its relationship to ENSO in a partially coupled climate model     

Hui Ding  Richard J. Greatbatch  Wonsun Park  Mojib Latif  Vladimir A. Semenov  Xuguang Sun 《Climate Dynamics》2014,42(1-2):367-379

The variability of the East Asian summer monsoon (EASM) is studied using a partially coupled climate model (PCCM) in which the ocean component is driven by observed monthly mean wind stress anomalies added to the monthly mean wind stress climatology from a fully coupled control run. The thermodynamic coupling between the atmospheric and oceanic components is the same as in the fully coupled model and, in particular, sea surface temperature (SST) is a fully prognostic variable. The results show that the PCCM simulates the observed SST variability remarkably well in the tropical and North Pacific and Indian Oceans. Analysis of the rainfall-SST and rainfall-SST tendency correlation shows that the PCCM exhibits local air-sea coupling as in the fully coupled model and closer to what is seen in observations than is found in an atmospheric model driven by observed SST. An ensemble of experiments using the PCCM is analysed using a multivariate EOF analysis to identify the two major modes of variability of the EASM. The PCCM simulates the spatial pattern of the first two modes seen in the ERA40 reanalysis as well as part of the variability of the first principal component (correlation up to 0.5 for the model ensemble mean). Different from previous studies, the link between the first principal component and ENSO in the previous winter is found to be robust for the ensemble mean throughout the whole period of 1958–2001. Individual ensemble members nevertheless show the breakdown in the relationship before the 1980’s as seen in the observations.  相似文献   

Erratum to: Measurements of volcanic SO2 and CO2 fluxes by combined DOAS,Multi-GAS and FTIR observations: a case study from Turrialba and Telica volcanoes     

Vladimir Conde  Philippe Robidoux  Geoffroy Avard  Bo Galle  Alessandro Aiuppa  Angélica Muñoz  Gaetano Giudice 《International Journal of Earth Sciences》2014,103(8):2349-2349

  相似文献   

Preservation of diagenetic products of β-carotene in sedimentary rocks from the Lopare Basin (Bosnia and Herzegovina)     

Nenad Grba  Aleksandra Šajnović  Ksenija Stojanović  Vladimir Simić  Branimir Jovančićević  Goran Roglić  Vladisav Erić 《Chemie der Erde / Geochemistry》2014

Sedimentary rocks from the saline formation of the Lopare Basin were investigated. Sediments contain a moderate amount of immature to marginally mature algal organic matter deposited under slightly reducing to anoxic and slightly saline to hypersaline conditions. Almost all of the samples contain β-carotane in a relatively high quantity, and in some, it represents the most abundant compound in the total distribution of hydrocarbons. The objective of the study was to determine the conditions that are favourable to precursors of β-carotene and/or the preservation of the carotenoid hydrocarbon skeleton. Moreover, the dominant transformation pathways of β-carotene under different redox and salinity conditions, which lead to the formation of aromatic carotenoids were defined.  相似文献   

On the modeling of ground-motion field for assessment of multiple-location hazard,damage, and loss: example of estimation of electric network performance during scenario earthquake     

Vladimir Sokolov  Friedemann Wenzel 《Natural Hazards》2014,74(3):1555-1575

Consideration of within-earthquake ground-motion correlation is essential for the estimation of seismic hazards, damage, and loss for spatially distributed systems. In many seismically active regions, the strong motion data of real engineering significance are completely unavailable or very scarce. The absence of necessary data does not allow developing regional empirical correlation models, and the models obtained for other regions should be used with correspondent sensitivity analysis. The level of within-earthquake correlation may vary in broad range; therefore, development of correspondent criteria for selection from available models is important. In this paper, we analyzed the performance of a system of critical elements of electric power network (substations) depending on variations in within-earthquake correlation. The performance is described as probability of different levels of non-functionality, i.e., percentage of area suffering power outage, and probability of expected number of customers without power. We have shown that the proper choice of the within-earthquake correlation model is critical in comprehensive estimations of functionality of substations in electrical power system. Skipping the ground-motion variability and within-earthquake correlation may lead to unreliable results. Relevance of geology-based within-earthquake correlation models has been demonstrated, and a scheme, which allows reducing uncertainty in the choice of realistic correlation, has been proposed.  相似文献   

An Integrated Study to Analyze Salt Lake Microbial Community Structure(Novosibirsk Oblast,Russia)     

Alla BRYANSKAYA  Alexey ROZANOV  Tatyana MALUP  Taisiya ALESHINA  Elena LAZAREVA  Oxana TARAN  Tatyana GORYACHKOVSKAYA  Vladimir IVANISENKO  Sergey PELTEK 《《地质学报》英文版》2014,88(Z1):61-62

正Salt Lake is one of the lakes in the system,consisting of a huge amount of salt and bitter-salty lakes in Novosibirsk Oblast and Altai Krai.These lakes are unique and highly unstable systems where the parameters of geochemical  相似文献