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981.
The Petit-Rhône Fan Valley (north-western Mediterranean) is a broad, sinuous, filled valley that is deeply incised by a narrow, sinuous thalweg. The valley fill is differentiated into three seismic subunits on high-resolution seismic-reflection profiles. The lower chaotic subunit probably consists of channel lag deposits that seem to be in lateral continuity with high-amplitude reflections representing levee facies. The intermediate transparent subunit, which has an erosional base and clearly truncates levee deposits, is interpreted to be mass-flow deposits resulting from the disintegration of the fan-valley flanks. The upper bedded subunit shows an overall lens-shaped geometry and the seismic reflections onlap either onto the top of the underlying transparent subunit or onto the Rhône levees. Piston core data show that the upper few meters of this upper subunit consist of thin turbidites, probably deposited by overflow processes. The few available 14C ages suggest that the upper stratified subunit filled the Petit-Rhône Fan Valley between 21 and 11 kyr BP. The upper bedded subunit is deposited within the Petit-Rhône Fan Valley downslope of a major decrease in slope gradient. This upper subunit and the thalweg are genetically related and represent a small channel/levee system confined within the fan valley. Previous studies interpreted this thalweg to be an erosional feature resulting from a recent avulsion of the major channel course. Our interpretation implies that the thalweg is not a purely erosional feature but a depositional/erosional channel. This small channel/levee system is superimposed on a large muddy channel/levee system after the sediment supply changed from thick muddy flows during the main phase of aggradation of the Rhône Fan levees, to thin, mixed (sand and mud) flows at the end of Isotope Stage 2 (~16–18 ka BP). The pre-existing morphology of the Petit-Rhône Fan Valley played a determinant role in the sediment dispersal leading to the creation of this small and confined channel/levee system. These mixed flows have undergone flow stripping resulting from the changes in the slope gradient along the thalweg course. The finer sediment overflowed from the thalweg and were deposited in the Petit-Rhône Fan Valley. Coarser channelled sediment remaining in the thalweg were deposited as a ‘sandy’lobe (Neofan). As indicated by 14C dating, sedimentation on this lobe continued until very recently, suggesting a further evolution of the turbidity flows from small mixed flows to small sandy flows. the deposition of this study lobe and the sedimentary fill of the Petit-Rhône Fan Valley may be related to widespread shelf edge and canyon wall failures with a resulting downslope evolution of failed sediment into turbidity currents.  相似文献   
982.
The Pliocene-early Pleistocene history of the ancestral Rio Grande and Quaternary history of the Rio Mimbres in the southern Rio Grande rift, New Mexico, illustrate how axial rivers may alternately spill into and subsequently abandon extensional basins. Three types of spillover basins are recognized, based on the angle at which the axial river enters the basin and whether it descends the hanging wall dip slope or footwall scarp to reach the basin floor. In the Mimbres basin type, the axial river enters and flows through the spillover basin nearly parallel to the footwall scarp, resulting in a narrow belt of basin-axis-parallel channel sand bodies located near the footwall scarp. In contrast, an axial river may enter a spillover basin at a high angle to its axis, either descending the hanging wall dip slope (Columbus basin type) or footwall scarp (Tularosa basin type), and construct a fluvial fan, consisting of radiating distributary channels orientated nearly perpendicular to the basin axis. Faulting exerts significant control on river spillover by creating the topographic gaps through which the axial river moves and by terminating spillover by subsequently uplifting or tilting the gap. Spillover may also be autocyclic in origin as a result of aggradation to the level of a pre-existing gap, headward erosion creating and/or intersecting a gap, or simple river avulsion upstream of a gap. Predicting facies architecture in the three types of spillover basins is critical to successful subsurface exploration for hydrocarbon reservoirs, groundwater aquifers or placer mineral deposits.  相似文献   
983.
Anatectic migmatites in medium- to low-pressure granulite facies metasediments exposed in the Larsemann Hills, East Antarctica, contain leucosomes with abundant quartz and plagioclase and minor interstitial K-feldspar, and assemblages of garnet–cordierite–spinel–ilmenite–sillimanite. Qualitative modelling in the system K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–O2, in conjunction with various PT calculations indicate that the high-grade retrograde evolution of the terrane was dominated by decompression from peak conditions of c. 7 kbar at c. 800 °C to 4–5 kbar at c. 750 °C. Extensive partial melting during decompression involved the replacement of biotite by the assemblage cordierite–garnet–spinel within the leucosomes. These leucosomes represent the site of partial melt generation, the cordierite–garnet–spinel–ilmenite assemblage representing the solid products and excess reactants from the melting reaction. The extraction and accumulation of this decompression-generated melt led to the formation of syntectonic pegmatites and extensive granitic plutons. Leucosome development and terrane decompression proceeded during crustal transpression, synchronous with upper crustal extension, during a progressive Early Palaeozoic collisional event. Subsequent retrograde evolution was characterized by cooling, as indicated by the growth of biotite replacing spinel and garnet, thin mantles of cordierite replacing spinel and quartz within metapelites, and garnet replacing orthopyroxene and hornblende within metabasites. P–T calculations on late mylonites indicate lower grade conditions of formation of c. 3.5 kbar at c. 650 °C, consistent with the development of late cooling textures.  相似文献   
984.
A ternary solid solution model for omphacite with the end-members jadeite (NaAlSi2O6), diopside (CaMgSi2O6) and hedenbergite (CaFeSi2O6) was derived from experimental data from the literature. The subregular solution model, fitted by linear programming, is best suited to omphacites with very little aegirine component in common eclogites. Applying this solution model to the calculation of equilibrium phase diagrams of eclogites from the Adula nappe (Central Alps, Switzerland) results in large stability fields for common eclogite assemblages (garnet+omphacite+quartz+H2O±kyanite). Within this field the compositions of garnet and omphacite show very little variation. A precise determination of the peak-pressure and temperature is not possible. The occurrence of amphibole, overgrowing the peak-pressure assemblage in fresh eclogite, suggests retrograde re-equilibration, still under eclogite facies conditions. The computation of isopleths for garnet and pyroxene end-members allows the estimation of the pressure and temperature conditions of this re-equilibration event (19–21  kbar, c .  700 °C).  相似文献   
985.
A study of ether-linked moieties in macromolecular bound residues of polycyclic aromatic hydrocarbons (PAH) generated in bioremediation experiments was performed using high temperature hydrolysis degradation with subsequent analysis of the products by GC-MS. This hydrolysis reaction was specifically designed to cleave ether bonds including relatively stable diarylether structures. Among the reaction products, aromatic alcohols representing typical microbiologically derived metabolites of PAH were found in addition to natural compounds. Thus, parts of the bound residues appeared to be linked within the macromolecular material by ether bonds. Model experiments with an oxidoreductase enzyme and aromatic alcohols indicate the formation of these ether bonds to be an enzyme-catalysed process.  相似文献   
986.
Organic-rich from the Schei Point group (middle to late Triassic in age) and the Ringnes formation (late Jurassic) from the Sverdrup basin of the Canadian arctic archipelago have been geochemically evaluated for source rock characterization. Most samples from the Schei Point group are organic-rich (> 2% TOC and are considered as immature to mature oil-prone source rocks [kerogen types I, I–II (IIA) and II (IIA)]. These kerogen types contain abundant AOM1, AOM2 and alginite (Tasmanales, Nostocopsis, Leiosphaeridia, acritarch and dinoflagellate) with variable amounts of vitrinite, inertinite and exinite. Samples from the Ringnes formation contain dominant vitrinite and inertinite with partially oxidized AOM2, alginite and exinite forming mostly immature to mature condensate- and gas-prone source rocks [kerogen type II–III (IIB), III and a few II (IIA)]. Schei Point samples contain higher bitumen extract, saturate hydrocarbons and saturate/ aromatic ratio than the Ringnes samples. Triterpane and sterane (dominant C30) distribution patterns and stable carbon isotope of bitumen and kerogen suggest that the analyzed samples from the Schei Point group are at the onset of oil generation and contain a mixture of sapropelic (algal) and minor terrestrial humic organic matter. Sterane carbon number distributions in the Ringnes formation also suggest a mixed algal and terrestrial organic matter type. There are some variations in hopane carbon number distributions, but these are apparently a function of thermal maturity rather than significant genetic differences among samples. Pyrolysis-gas chromatography/mass spectrometry of the two samples with similar maturity shows that the Schei Point sample generates three times more pyrolyzate than the Ringnes sample. Both samples have a dominant aliphatic character, although the Ringnes sample contains phenol and an aromaticity that is higher than that of the Schei Point sample.  相似文献   
987.
Cu-bearing pyroxene, Mg(Cu.56,Mg.44)Si2O6, has been synthesized by a flux method and crystal structure refinement has been performed by single crystal X-ray diffraction. It is found that the crystal structure is orthorhombic (space group Pbca) with unit cell dimensions of a=18.221(4), b=8.890(1), c=5.2260(7)Å and the cell volume of 846.5( )3Å3. In the M2-site one of the M-O bonds(M-O3B) is extremely expanded from 2.444(2) in enstatite to 2.732(2), thus the coordination polyhedron around M2-site is regarded as square pyramidal rather than square planar or octahedral. It is also found that the M1-site in the pyroxene structure is occupied almost exclusively by Mg, while the M2-site is almost evenly occupied by Mg and Cu. The observed extreme site preference shown by Cu2+ is unusual among the divalent cations with similar ionic sizes.  相似文献   
988.
Patterns in the hydrogen and trace element compositions of mantle olivines   总被引:1,自引:0,他引:1  
 The concentrations of hydrogen and the other trace elements in olivines from mantle xenoliths have been determined by secondary ion mass spectrometry (SIMS) for clarifying the incorporation mechanism and the behavior of the hydrogen. The hydrogen contents in olivines from mantle xenoliths range from 10 to 60 ppm wt. H2O and the concentration range is consistent with the previous infrared (IR) spectroscopic data. IR spectra of the olivine crystals show no effects of the weathering or secondary alteration. The hydrogen is distributed homogeneously among olivine grains in each mantle xenolith. However, the hydrogen contents of the olivine crystals are less than those for the olivine phenocrysts crystallized from the host magma. Olivine inclusions in diamonds also show similar hydrogen contents to the xenolithic olivines. Thus the hydrogen content of xenolithic olivines does not attain equilibrium with water in the host magma during the transportation from the Earth's mantle to the surface, and is taken as a reflection of the hydrogen condition in the mantle. Correlations of hydrogen with trivalent cation contents in garnet peridotitic olivines indicate the incorporation of hydrogen into mantle olivines by a coupled substitution mechanism, with the hydrogen present in the form of hydroxyl in oxygen positions adjacent to the M site vacancies. The hydrogen content of xenolithic olivines increases with pressure but decreases with increasing temperature, suggesting importance of olivine as a water reservoir at low temperature regions such as in subducting slabs. Received August 15, 1995/Revised, accepted November 19, 1996  相似文献   
989.
Samples of the estuarine-spawning teleostAcanthopagrus butcheri were collected from nine estuaries and a coastal lake, located in the Pilbara and South-western drainage divisions of Western Australia and distributed along a coastline covering a distance of nearly 2,000 km. The patterns of allozyme variation in these samples were used to explore the extent to which there was variation in the genetic compositions of black bream assemblages in geographically-isolated estuarine systems, and whether or not any such variation could be related to the geographical location or type of estuary. Although only three of 36 scorable loci (Gpi-1, Ldh andMdh-2) exhibited variation that could be used for analysis, there was considerable variation in allele frequencies at these loci among the different samples (mean FST=0.166). Much of the detected variation was attributable to differences between the samples collected from the two drainage divisions, which are located in very different climatic regions. Furthermore, the genetic compositions of samples from neighbouring estuaries were typically more similar to each other than to those of samples collected from more distantly-located systems. However, the assemblages in one west coast and two south coast estuaries, that are closed to the ocean for extensive periods of time during the year, all showed very similar genetic compositions. Nevertheless, it is crucial to recognise that, pairwise comparisons of samples collected from the different estuaries, both within and between the two drainage divisions, almost invariably showed statistically significant differences in allele frequencies at one or more loci. Thus, our results indicate that the local populations of black bream in individual estuaries are genetically distinct, which is probably a consequence of both a limited movement by individuals between estuaries and the effects of differences in regional and local environmental conditions.  相似文献   
990.
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