Kerogen,Insoluble Organic Matter from Sedimentary Rocks | B. Durand (Editor), 1980. Editions Technip,Paris, XXVIII + 519 pp., FF 490.00     

Walter H. Fertl 《Earth》1982,18(1):87-88

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A climate-related oxidizing event in deep-sea sediment from the Bering Sea     

James V. Gardner  Walter E. Dean  David H. Klise  Jack G. Baldauf 《Quaternary Research》1982,18(1):91-107

Many cores from the deep basins of the Bering Sea have a thin oxidized zone within otherwise reduced sediment. This oxidized zone began to form about 6000 yr ago and represents an interval of about 3200 yr. Mineralogically, the oxidized and reduced sediments are similar, but chemically they differ. Concentrations of Fe and C are lower, and concentrations of Mn, Ba, Co, Mo, and Ni are higher in the oxidized than in the reduced sediment. Mn is enriched about 10-fold in the oxidized zone relative to its concentration in the reduced sediment, Mo about threefold, and Ba, Co, and Ni about twofold. These data suggest that the oxidized zone developed diagenetically as the result of the balance between the flux of organic matter and the available dissolved oxygen in bottom and interstitial waters.We propose that the Bering Sea was substantially ice covered when global glacial conditions prevailed. during the transition to global interglacial conditions, seasonal meltwater from thawing sea ice formed a lens of fresh water that decreased organic productivity. During the winter seasons, however, sea ice reformed and caused downwelling of dense, oxygen-rich waters to recharge bottom waters. The combination of lower organic productivity and more oxygen-rich bottom water allowed oxidized sediment to accumulate. Once full interglacial conditions were established, the volume of sea ice produced was insufficient to affect either productivity or the supply of dissolved oxygen and so bottom conditions again became reducing.Similar events probably occurred during the onset of global glacial conditions, and similar oxidized layers probably formed at these times. Such oxidized zones are highly unstable, however, in a reducing environment and, once buried beyond the influence of bacterial and infaunal activities, are depleted of their available oxygen and converted to reduced sediment.  相似文献   

A Repeated Pulse Technique for Determining the Hydraulic Properties of Tight Formations   总被引：1，自引：0，他引：1  

G. R. Walter  G. M. Thompson 《Ground water》1982,20(2):186-193

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Zur Viruseliminierung bei Trinkwasseraufbereitungsverfahren     

St. Rüdiger  G. A. Bagdasaryan  H.-J. Dobberkau  R. Walter 《洁净——土壤、空气、水》1982,10(4):377-389

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Wind wave climate change: Impacts on the littoral processes at the Northern Buenos Aires Province Coast, Argentina     

Walter C. Dragani  Paula B. Martin  Guadalupe Alonso  Jorge O. Codignotto  Bárbara E. Prario  Guido Bacino 《Climatic change》2013,121(4):649-660

Several works reported wind-wave climate changes at Buenos Aires Province continental shelf. The aim of this work is to investigate the impact of these changes in the coastal processes of the region. This study is carried out by means of visual wave parameters gathered at the surf zone of Pinamar and by a conveniently implemented and validated numerical wave model (SWAN). Numerical results corresponding to a grid point located 30 km off Pinamar show a significant increase of wave heights from the S and SSE directions and in the frequency of occurrence of waves coming from the S, SSE and E. It is shown that these slight offshore appreciated trends would not have significant effects on the breaker heights observed at the surf zone at Pinamar. On the contrary, the slight positive trend observed offshore in the frequency of occurrence could be affecting the incidence of waves onshore, producing an increase in the number of cases of normal incidence at the surf zone and, consequently, a significant decrease in the alongshore wave energy flux assessed at Pinamar. This reduction in the alongshore wave energy flux could be responsible for some coastal changes detected in the region as, for instance, the remarkable shortening of Punta Rasa spit located 70 km northward Pinamar.  相似文献   

Origin of sub-lithospheric diamonds from the Juina-5 kimberlite (Brazil): constraints from carbon isotopes and inclusion compositions     

A.?R.?ThomsonEmail author  S.?C.?Kohn  G.?P.?Bulanova  C.?B.?Smith  D.?Araujo  EIMF  M.?J.?Walter 《Contributions to Mineralogy and Petrology》2014,168(6):1081

Forty-one diamonds sourced from the Juina-5 kimberlite pipe in Southern Brazil, which contain optically identifiable inclusions, have been studied using an integrated approach. The diamonds contain <20 ppm nitrogen (N) that is fully aggregated as B centres. Internal structures in several diamonds revealed using cathodoluminescence (CL) are unlike those normally observed in lithospheric samples. The majority of the diamonds are composed of isotopically light carbon, and the collection has a unimodal distribution heavily skewed towards δ¹³C ~ ?25 ‰. Individual diamonds can display large carbon isotope heterogeneity of up to ~15 ‰ and predominantly have isotopically lighter cores displaying blue CL, and heavier rims with green CL. The light carbon isotopic compositions are interpreted as evidence of diamond growth from abiotic organic carbon added to the oceanic crust during hydrothermal alteration. The bulk isotopic composition of the oceanic crust, carbonates plus organics, is equal to the composition of mantle carbon (?5 ‰), and we suggest that recycling/mixing of subducted material will replenish this reservoir over geological time. Several exposed, syngenetic inclusions have bulk compositions consistent with former eclogitic magnesium silicate perovskite, calcium silicate perovskite and NAL or CF phases that have re-equilibrated during their exhumation to the surface. There are multiple occurrences of majoritic garnet with pyroxene exsolution, coesite with and without kyanite exsolution, clinopyroxene, Fe or Fe-carbide and sulphide minerals alongside single occurrences of olivine and ferropericlase. As a group, the inclusions have eclogitic affinity and provide evidence for diamond formation at pressures extending to Earth’s deep transition zone and possibly the lower mantle. It is observed that the major element composition of inclusions and isotopic compositions of host Juina-5 diamonds are not correlated. The diamond and inclusion compositions are intimately related to subducted material and record a polybaric growth history across a depth interval stretching from the lower mantle to the base of the lithosphere. It is suggested that the interaction of slab-derived melts and mantle material combined with subsequent upward transport in channelised networks or a buoyant diapir explains the formation of Juina-5 diamonds. We conclude that these samples, despite originating at great mantle depths, do not provide direct information about the ambient mantle, instead, providing a snapshot of the Earth’s deep carbon cycle.  相似文献   

Origin of the Okrouhlá Radouň episyenite-hosted uranium deposit,Bohemian Massif,Czech Republic: fluid inclusion and stable isotope constraints     

Zdeněk Dolníček  Miloš René  Sylvie Hermannová  Walter Prochaska 《Mineralium Deposita》2014,49(4):409-425

The Okrouhlá Radouň shear zone hosted uranium deposit is developed along the contact of Variscan granites and high-grade metasedimentary rocks of the Moldanubian Zone of the Bohemian Massif. The pre-ore pervasive alteration of wall rocks is characterized by chloritization of mafic minerals, followed by albitization of feldspars and dissolution of quartz giving rise to episyenites. The subsequent fluid circulation led to precipitation of disseminated uraninite and coffinite, and later on, post-ore quartz and carbonate mineralization containing base metal sulfides. The fluid inclusion and stable isotope data suggest low homogenization temperatures (～50–140 °C during pre-ore albitization and post-ore carbonatization, up to 230 °C during pre-ore chloritization), variable fluid salinities (0–25 wt.% NaCl eq.), low fluid δ¹⁸O values (?10 to +2 ‰ V-SMOW), low fluid δ¹³C values (?9 to ?15 ‰ V-PDB), and highly variable ionic composition of the aqueous fluids (especially Na/Ca, Br/Cl, I/Cl, SO₄/Cl, NO₃/Cl ratios). The available data suggest participation of three fluid endmembers of primarily surficial origin during alteration and mineralization at the deposit: (1) local meteoric water, (2) Na–Ca–Cl basinal brines or shield brines, (3) SO₄–NO₃–Cl–(H)CO₃ playa-like fluids. Pre-ore albitization was caused by circulation of alkaline, oxidized, and Na-rich playa fluids, whereas basinal/shield brines and meteoric water were more important during the post-ore stage of alteration.  相似文献   

Field evidence of hydraulic connections between bedrock aquifers and overlying granular aquifers: examples from the Grenville Province of the Canadian Shield   总被引：1，自引：0，他引：1  

Sandra K. Richard  Romain Chesnaux  Alain Rouleau  Roger Morin  Julien Walter  Silvain Rafini 《Hydrogeology Journal》2014,22(8):1889-1904

Field evidence of hydraulic connections between a bedrock aquifer and an overlying granular aquifer in the Canadian Shield (Grenville Province) is presented. This issue is rarely considered and investigated despite its important hydraulic and chemical consequences and its widespread occurrence worldwide. The methodology employed is based on complementary field tests conducted at specific experimental sites instrumented both in the rock and in the overlying deposits. One of the bedrock sites revealed a natural hydraulic connection with the overlying granular aquifer caused by the weathered surface of the uppermost bedrock. Another site revealed an artificial hydraulic connection between the bedrock and the granular aquifer created by an improperly sealed casing. A regional study showed that hydraulic connections yield an erroneous interpretation of the true hydraulic properties of the tested aquifer. The detection of hydraulic connections is therefore essential to properly define well-capture areas and contamination conditions. It is recommended to practitioners that pumping tests be performed as well as hydrochemical comparisons of each existing aquifer unit. Falling-head permeability tests are also helpful in verifying the quality of the seal at the bedrock–casing contact. More effective procedural controls and better well-construction practices are necessary to reduce the risks of cross-contamination induced by defective seals.  相似文献   

Experimental determination of the solubility of natural wollastonite in pure water up to pressures of 5 GPa and at temperatures of 400-800 °C     

Thomas Fockenberg  Michael Burchard  Walter V. Maresch 《Geochimica et cosmochimica acta》2006,70(7):1796-1806

The solubility of natural, near-end-member wollastonite-I (>99.5% CaSiO₃) has been determined at temperatures from 400 to 800 °C and pressures between 0.8 and 5 GPa in piston-cylinder apparatus with the weight-loss method. Chemical analysis of quench products and optical monitoring in a hydrothermal diamond anvil cell demonstrates that no additional phases form during dissolution. Wollastonite-I, therefore, dissolves congruently in the pressure-temperature range investigated. The solubility of CaSiO₃ varies between 0.175 and 13.485 wt% and increases systematically with both temperature and pressure up to 3.0 GPa. Above 3.0 GPa wollastonite-I reacts rapidly to the high-pressure modification wollastonite-II. No obvious trends are evident in the solubility of wollastonite-II, with values between 1.93 and 10.61 wt%. The systematics of wollastonite-I solubility can be described well by a composite polynomial expression that leads to isothermal linear correlation with the density of water. The molality of dissolved wollastonite-I in pure water is then