The rank evaluation of South Brazilian Gondwana coals on the basis of different chemical and physical parameters     

Z.C. Corrêa Da Silva 《International Journal of Coal Geology》1989,13(1-4)

Rank evaluation of South Brazilian Gondwana coals according to the American (American Society for Testing and Materials, ASTM) and German (Deutsche Industrie Normen, DIN) standard specifications or on the basis of Alpern's Universal Classification has too often led to conflicting results.When any attempt is made to determine the rank of Brazilian coals by using methods established for the Northern Hemisphere coals, two sorts of difficulties arise: namely, (1) the reflectence measurements do not indicate the real degree of coalification of the organic matter because of the liptinitic impregnations of the vitrinites, and (2) random reflectance values (R_ran, moisture, volatile-matter and carbon contents as well as the calorific value do not correlate when plotted on the ASTM and DIN classification schemes.In addition, when rank determinations are carried out by using fluorescence measurements and geochemical analyses the results are at variance in relation to those determined by the conventional chemical and physical parameters.It is suggested that the rank evaluation of South Brazilian coals is far more meaningful if carried out by reflectance measurements on vitrinites along with fluorescence measurements on sporinites, alginites and coal extracts.  相似文献   

DISCUSSION OF "Modeling of Vapor Extraction and General Transport in the Presence of NAPL Mixtures and Nonideal Conditions," by David A. Benson, David Huntley, and Paul C. Johnson     

Gary R. Walter 《Ground water》1994,32(1):146-148

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Self-Organizing Systems in Geography: A Response to Peterman     

Lyle Courtney  Walter G. Hardwick 《The Professional geographer》1995,47(2):218-220

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Chemical structural units of macromolecular coal components     

Angela Jenisch  Hans Hermann Richnow  Walter Michaelis 《Organic Geochemistry》1990,16(4-6)

Chemical degradations of coal resins, coal asphaltenes and coal residues have been performed with selective, non-oxidative reagents. The coal comprise samples a rank interval 0.30–1.21 %R_m. Degraded low-molecular-weight compounds were analyzed by GC-MS. The distributions of pentacyclic terpanes, isoprenoids, n-alkanes, acids and alcohols obtained as degradation products illustrate a considerable variability between the macromolecular coal fractions. A structural study on the molecular level of the degraded compounds from coal resins and coal asphaltenes show their potential to generate hydrocarbons during coalification process.  相似文献   

Structure and origin of terpenoid hydrocarbons in some German coals     

Thomas Schulze  Walter Michaelis 《Organic Geochemistry》1990,16(4-6)

Hydrocarbon extracts of coal samples from major coal fields in West Germany have been investigated by gas chromatography-mass spectrometry (GC/MS). The samples are of Carboniferous and Tertiary age and derive from limnic and paralic environments, the Saar District, the Ruhr Area and the Lower Rhine Basin.Differences in facies, maturity and age reflected in the distribution patterns of the extracted alkylcyclohexanes. An unexpected occurrence of cyclic diterpenoid hydrocarbons in some samples of Carboniferous age has been found. The tetracyclic compounds mainly show phyllocladane type structures and can serve as source indicators.Hydrocarbons obtained from chemical degradation of the macromolecular material of the samples also revealed phyllocladane-type compounds which are normally associated to resins of modern and extinct familes of conifers. Origin and structural variations of this class of hydrocarbons are discussed in terms of maturity and palaeobotanical implications.  相似文献   

The accessibility of nodes in the Belgian road network     

Walter Lannoy  Dirk Oudheusden 《GeoJournal》1991,2(1):65-70

This paper presents an analysis of the accessibility of nodes in the Belgian road network. The intersection of roads are considered as the nodes and their connecting roads as the edges of a network. By means of the Dijkstra algorithm accessibility values are computed for each node by summing shortest travel times to a reference system of 158 nodes spread evenly over the Belgian territory. A comparison of the measured actual accessibility with that determined from an optimal situation provides an indication of the quality of directness of the Belgian road system. Accessibility and directness are shown cartographically. An isochronal map illustrates the access to Brussels.  相似文献   

Factors influencing the salinity regime of Lake Pontchartrain,Lousiana, a shallow coastal lagoon: Analysis of a long-term data set     

Walter B. Sikora  Björn Kjerfve 《Estuaries and Coasts》1985,8(2):170-180

Lake Pontchartrain., Louisiana is a 1,630 km² shallow brackish lagoon with a mean salinity from 1.2‰ in the west to 5.4‰ in the east., The construction of a 120 km long deep-water connection to the Gulf of Mexico in 1963, was expected to cause a 5‰ increase in lagoon salinity. However, the actual increase was everywhere in the lagoon less than 2‰ Analysis of 31 years of daily salinity and discharge records indicates that discharge is the most important factor controlling salinity variations in Lake Pontchartrain., Seventy-four percent of low-frequency salinity variations are explained by freshwater discharge and the completion of the deep-water canal. Lake Pont.-chartrain experiences annual variations of salinity as high as 8‰ This salinity signal has remained constant since the beginning of the salinity records in 1946. It appears that the deep-water canal is not responsible for observed die-back of freshwater swamps and retreat of lagoon shorelines.  相似文献   

The Application of Telemetry to Large-Scale Horizontal Anisotropic Permeability Determinations by Surface Tiltmeter Survey     

Walter W. Loo  Klaus Franz  Gary R. Holzhausen 《Ground Water Monitoring & Remediation》1984,4(4):124-130

An advanced two-way radio link (transceiver units) and data logging system have provided a powerful means of real-time series data collection and analysis. The application of this telemetry system to surface tiltmeter surveys provides significant cost savings for testing and analysis of deep, large-scale horizontal anisotropic permeability and heterogeneity determinations.
The determination of horizontal anisotropic properties requires one pumping well and eight to 10 tiltmeter monitoring stations. The validity of the depth of the test may reach 4,000 feet below land surface. With the addition of one partially penetrating observation well, the entire three-dimensional anisotropic permeability can be determined. With the addition of a fully penetrating well, the storage coefficient can be determined as well as leakage property (including vertical permeability of the confining layers). An example test case was analyzed for horizontal anisotropic permeability with remarkable success despite relatively unfavorable detection conditions.
A thorough understanding of the geology overlying the aquifer system must be made in order to assess the applicability of the surface tiltmeter survey to large-scale horizontal anisotropic permeability determinations.  相似文献   

Lower Cretaceous turbiditic sediments from the Rif chain (Northern Marocco) — palynology,stratigraphy and palaeogeographic setting     

Alfred A. Gübeli  Peter A. Hochuli  Walter Wildi 《International Journal of Earth Sciences》1984,73(3):1081-1114

The paper describes the palynology, stratigraphy, sedimentology and palaeogeographic setting of Lower Cretaceous turbiditic and terrigenous deep-sea sediments at the Tethyan margins of Africa and Alboran (External Domain of the Rif, and Flysch Nappes). During the Early Cretaceous terrigenous turbiditic deep-water sedimentation characterizes two different palaeogeographic domains in the southern part of the western Tethys:

In the northern area of the External Domain (Ketama Unit of the Rif) alternating turbiditic arenites and pelites are interpreted as sediments of a distal part of a fan system on the Tethyan margin of Africa. The main sources for the terrigenous material were situated in Central and Western Algeria; only little sand transited through the Prerif and the Mesorif zones of Morocco. The terrigenous sedimentation began in the Hauterivian, but the main turbiditic cycles are of Aptian to Lower and Middle Albian age.

The Flysch Domain probably was situated far to the Northeast with respect to the Rif basin, at the western and southern margins of the Alboran microplate. Relatively proximal turbidites form most of the Tisirène Nappe, whereas more distal turbidites constitute the series of the Melloussa and the Chouamat Nappes. The existence of two different source areas is demonstrated, one to the NE and the other to the NW of the depositional area. The turbidites probably were deposited on a E-W oriented fan system which progradated into a longitudinal trench-like trough. In the Central Rif area, the Tisirène Flysch is of Valanginian to Albian (pre-Vraconian) age. In the Western Rif and in the Melloussa and Chouamat Nappes of the whole area no sediments older than Aptian have been found.

The stratigraphy of the investigated series is based on a new tentative palynostratigraphic zonation, using pollen, spores and dinoflagellate cysts. Rich and well preserved assemblages have been found in the Western Rif only, whereas the samples of the Tisirène Nappe and the Chouamat Nappe in the Central and Eastern Rif have been affected by some thermal alteration. Black and mostly opaque palynomorphs from the Ketama Unit reflect the strong thermal influence in the External Domain of the Central and Eastern Rif.  相似文献   

Seasonal soil water storage changes beneath central Amazonian rainforest and pasture     

M. G. Hodnett  L. Pimentel da Silva  H. R. da Rocha  R. Cruz Senna 《Journal of Hydrology》1995,170(1-4):233-254

Evaporation and infiltration were compared for tropical rainforest and pasture, near to Manaus, Brazil from October 1990 to February 1992 using measurements of soil water storage over a depth of 2 m. The soil is a clayey oxisol of low water available capacity. In both of the dry seasons studied, the maximum change in soil water storage in the forest was 154 mm and in the pasture it was 131 and 112 mm. Similar behaviour of the soil water reservoir below forest and pasture in the wet season implied that differences in evaporation and drainage were small. In the dry season, soil water storage behaviour in the upper metre of the soil was similar but there were marked differences in the second metre. The pasture took up little water from below 1.5 m but the forest appeared to utilise all of the available water in the 2 m profile in both seasons.

The water balance of the 2 m profile showed that the pasture evaporation rate was equal to that of the forest until storage had decreased 80 mm from the maximum. There was then a decline in pasture evaporation rate to 1.2 mm day⁻¹ as the storage decreased by a further 50 mm. In contrast, the forest uptake rate remained above 3.5 mm day⁻¹ until storage had decreased 140 mm from the maximum (within 15 mm of the extraction limit), before declining abruptly to less than 1.5 mm day⁻¹. There was strong evidence that the forest was able to abstract water from depths greater than 3.6 m.

Spatial variability of soil water storage was significantly greater beneath the pasture than beneath the forest, particularly following rainfall events in the dry season. This was largely the result of redistribution of rainfall as local surface runoff. There was no evidence of redistribution or runoff in the forest.  相似文献