Oxidation and metal-insertion in molybdenite surfaces: evaluation of charge-transfer mechanisms and dynamics     

CV Ramana  U Becker  V Shutthanandan  CM Julien 《Geochemical transactions》2008,9(1):8

Molybdenum disulfide (MoS₂), a layered transition-metal dichalcogenide, has been of special importance to the research community of geochemistry, materials and environmental chemistry, and geotechnical engineering. Understanding the oxidation behavior and charge-transfer mechanisms in MoS₂ is important to gain better insight into the degradation of this mineral in the environment. In addition, understanding the insertion of metals into molybdenite and evaluation of charge-transfer mechanism and dynamics is important to utilize these minerals in technological applications. Furthermore, a detailed investigation of thermal oxidation behavior and metal-insertion will provide a basis to further explore and model the mechanism of adsorption of metal ions onto geomedia.  相似文献   

Spatiotemporal Patterns of Subtidal Benthic Microalgal Biomass and Community Composition in Galveston Bay,Texas, USA     

James L. Pinckney  Alyce R. Lee 《Estuaries and Coasts》2008,31(2):444-454

Many Gulf of Mexico estuaries have low ratios of water volume to bottom surface area, and benthic processes in these systems likely have a major influence on system structure and function. The purpose of this study was to determine the spatiotemporal distribution of biomass and community composition of subtidal benthic microalgal (BMA) communities in Galveston Bay, TX, USA, compare BMA community composition and biomass to phytoplankton in overlying waters, and estimate the potential contribution of BMA to the trophodynamics in this shallow, turbid, subtropical estuary. The estimates of BMA biomass (mean = 4.21 mg Chl a m⁻²) for Galveston Bay were within the range of the reported values for similar Gulf of Mexico estuaries. BMA biomass in the central part of the bay was essentially homogeneous, whereas biomass at the seaward and upper bay ends of the transect were significantly lower. Peridinin, fucoxanthin, and alloxanthin were the three carotenoids with the highest concentrations, with fucoxanthin having the highest mean concentration (1.82 mg m⁻²). The seaward and landward ends of the transect differed from the central region of the bay with respect to the relative abundances of chlorophytes, cyanobacteria, and photosynthetic bacteria. Benthic microalgal community composition also showed a gradual shift over time due to changes in the relative abundances of photosynthetic bacteria, cryptophytes, dinoflagellates, and cyanobacteria. Major changes in community composition occurred in the spring months (March to April). On an areal basis, BMA biomass in Galveston Bay occurred at minor concentrations (16.5%) relative to phytoplankton. Furthermore, the concentrations of carotenoid pigments for phytoplankton and BMA (fucoxanthin, alloxanthin, and zeaxanthin) were correlated (r = 0.48 to 0.61), suggesting a close linkage between microalgae in the water column and sediments. The contribution of BMA to the primary productivity of the deeper waters (>2 m) of Galveston Bay is probably very small in comparison to shallower waters along the bay margins. The significant similarities in the community composition of phytoplankton and BMA illustrate the potential importance of deposition and resuspension processes in this turbid, shallow estuary.  相似文献   

Macrofaunal Spatial Patterns in Relationship to Environmental Variables in the Richibucto Estuary,New Brunswick,Canada   总被引：1，自引：0，他引：1  

Lin Lu  Jon Grant  Jeffrey Barrell 《Estuaries and Coasts》2008,31(5):994-1005

Estuarine macrobenthos respond to a variety of environmental gradients such as sediment type and salinity, and organic enrichment. A relatively new influence, organic loading from suspended bivalve culture, has the potential to alter this response. A study on soft-bottom macrobenthic communities was carried out in the Richibucto estuary (46°40′N, 64°50′W), New Brunswick, Canada, with samples collected from 18 stations in late September and early October 2006. The site consisted of a large tidal channel originating upstream in a small river. The channel was punctuated by bag culture of oysters along its length. A total of 88 species were recorded. The mean values of abundance, species richness, and diversity (H′) of macrofauna were 11,199 ind. m⁻² (ranged from 4,371 to 19,930 ind. m⁻²), 23.4 species grab⁻¹ and 3.29 grab⁻¹, respectively. In general species richness and H′ increased from the upper estuary to the estuarine mouth. Multivariate analyses clearly exhibited the spatial distribution in community structure, which coincided with the locations along the estuary (the upper, the lower and the mouth), as well as inside and outside the channel. Species richness and diversity H′ showed strong positive correlations with salinity (21.2–25.2 ppt), and abundance was positively correlated with water depth (1.0–4.5 m). Abundance and species richness were negatively correlated with both of silt–clay fraction (3.3–24.8%) and sorting (σ_I). Species richness was also negatively correlated with organic content (1.9–12.7%). The BIO-ENV analyses identified silt–clay fraction, σ_I and salinity as the major environmental variable combination influencing the macrofaunal patterns, and silt–clay fraction as the single best-correlated variable.  相似文献   

Dissolved Nutrient Fluxes through a Sandy Estuarine Beachface (Cape Henlopen,Delaware, U.S.A.): Contributions from Fresh Groundwater Discharge,Seawater Recycling,and Diagenesis     

Rebecca L. Hays  William J. Ullman 《Estuaries and Coasts》2008,31(3):606-606

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Spatial Heterogeneity Created by Burrowing Crabs Affects Human Impact on Migratory Shorebirds     

Florencia Botto  Agustina Mendez-Casariego  Macarena Valiñas  Oscar Iribarne 《Estuaries and Coasts》2008,31(1):134-143

We show that, as previously described, there are conflicts between areas used by people and shorebirds. However, we propose that burrowing organisms add complexity to the shorebird–human interaction that should be taken into account for management and conservation. This is because SW Atlantic mudflats are dominated by high densities (up to 60 crabs m⁻²) of a strong bioturbator, the burrowing crab Neohelice granulata (=Chasmagnathus granulatus). These crabs affect the habitat use and foraging performance of shorebird species. The two-banded plover Charadrius falklandicus feed more in burrow areas whereas the yellowlegs Tringa spp. and the white-rumped sandpiper Calidris fuscicollis tend to avoid burrow areas. We evaluated the effect of human recreational activities on shorebirds, taking into account shorebird–crab interaction, during shorebird migratory periods (November to April) of 2001, 2002, and 2003. This study was performed at the Mar Chiquita coastal lagoon (37° 40′ S, Argentina). Results showed that people only rarely used the extensive soft bottom intertidals dominated by burrowing assemblages of N. granulata because the soft sediments make walking difficult. Therefore, human impact is reduced for the two-banded plover. However, for several migratory shorebirds that also avoid burrow areas, these areas act as suboptimal alternative areas when human impact is important in their preferred habitats. When human activity is low, shorebirds remain foraging in the area but they decrease their feeding intakes. The extensions of burrow areas differ among estuaries and are likely to generate between-estuaries differences as stopover sites for shorebirds. Also, other species that form large burrowing assemblages can have a similar impact on shorebird–human interactions.  相似文献   

Light Requirements for Growth and Survival of Eelgrass (<Emphasis Type="Italic">Zostera marina</Emphasis> L.) in Pacific Northwest (USA) Estuaries     

Ronald M. Thom  Susan L. Southard  Amy B. Borde  Peter Stoltz 《Estuaries and Coasts》2008,31(5):969-980

We developed light requirements for eelgrass in the Pacific Northwest, USA, to evaluate the effects of short- and long-term reductions in irradiance reaching eelgrass, especially related to turbidity and overwater structures. Photosynthesis-irradiance experiments and depth distribution field studies indicated that eelgrass productivity was maximum at a photosynthetic photon flux density (PPFD) of about 350–550 μmol quanta m⁻² s⁻¹. Winter plants had approximately threefold greater net apparent primary productivity rate at the same irradiance as summer plants. Growth studies using artificial shading as well as field monitoring of light and eelgrass growth indicated that long-term survival required at least 3 mol quanta m⁻² day⁻¹ on average during spring and summer (i.e., May-September), and that growth was saturated above about 7 mol quanta m⁻² day⁻¹. We conclude that non-light-limited growth of eelgrass in the Pacific Northwest requires an average of at least 7 mol quanta m⁻² day⁻¹ during spring and summer and that long-term survival requires a minimum average of 3 mol quanta m⁻² day⁻¹.  相似文献   

江西长江河道演变及其对水患灾害形成的影响   总被引：1，自引：0，他引：1  

马逸麟  张然  诸葛春  王志强 《地质灾害与环境保护》2008,19(2):24-28

对江西长江河道的演变特征进行了详细研究,基本查清了近代江西长江河道的发展演变历程。自清代以来未发生重大的变迁事件,但其也处于不断演变中,其演变主要表现在河道的冲淤作用,即岸线的冲刷侧蚀后退和边滩的淤胀,江心洲、心滩、浅滩的增生淤胀、消亡和移动,河道的淤塞等。为研究洪涝灾害成生背景、致灾作用,以及防灾治灾提供科学依据。  相似文献   

Fluid Geochemistry as Indicator of Tectonically-Related,Deep Water Circulations in the Sardinian Rift-Campidano Graben (Italy): New Insights from Environmental Isotopes     

Elisa Sacchi  Gian Maria Zuppi  Luca Pizzino  Fedora Quattrocchi  Salvatore Lombardi 《Aquatic Geochemistry》2008,14(4):301-319

The EC funded Geochemical Seismic Zonation program (EEC GSZ Project 1996–1998) chose Sardinia as a low-seismicity site, in which the relationships between fluid geochemistry and seismo-tectonics had to be investigated and results compared with outcomes from other selected high-seismicity sites. A first article, examining the role of fault segmentation and seismic quiescence on the geochemical composition of groundwaters and gases, has already been presented (Angelone et al. 2005). This article deals with environmental isotopes which, together with selected hydrochemical data, give hints on tectonically-related fluid circulations. Four water-dominated hydrothermal systems were considered, all located along regional fault systems and discharging groundwaters belonging to the Na–HCO₃ and Na–Cl facies. In the considered systems, groundwater circulation takes place, principally, in the Palaeozoic Crystalline Basement (PCB), with the exception of the Logudoro system, where hydrological circuits develop in the Mesozoic Carbonate Platform (MCP). The high CO₂ contents, the non-attainment of fluid-rock equilibrium and the large lithological variability prevent the construction of a unique hydrogeological–geochemical conceptual model. In this case, stable isotopes provide a useful tool to describe the origin of fluids and their subterranean movements. Stable isotopes of water, integrated with hydrochemical data, indicate that fluids are derived from three main end members. The dominant component is a relatively recent local meteoric water; the second one is marine water; and the third one is a fossil freshwater, depleted in heavy isotopes with respect to modern rains. The latter end member entered the aquifer system in the past, when climatic conditions were greatly different from today. At least two circulation systems can be recognised, namely a shallow cold system and a deep hydrothermal system, as well as two distinct hydrological processes: (1) gravity-controlled descent of cold water towards greater depths and (2) convection linked to a thermal gradient, causing deep fluids to rise up from the hydrothermal reservoir towards the surface. The highly variable δ¹³C_TDIC values suggest the presence of two distinct CO₂ sources, namely, a biogenic one and a thermogenic one. The relation between the isotopic compositions of CO₂ and He indicates an increased mantle signature in uprising CO₂-rich fluids.  相似文献   

Dynamic data integration for structural modeling: model screening approach using a distance-based model parameterization   总被引：2，自引：0，他引：2  

Satomi Suzuki  Guillaume Caumon  Jef Caers 《Computational Geosciences》2008,12(1):105-119

This paper proposes a novel history-matching method where reservoir structure is inverted from dynamic fluid flow response. The proposed workflow consists of searching for models that match production history from a large set of prior structural model realizations. This prior set represents the reservoir structural uncertainty because of interpretation uncertainty on seismic sections. To make such a search effective, we introduce a parameter space defined with a “similarity distance” for accommodating this large set of realizations. The inverse solutions are found using a stochastic search method. Realistic reservoir examples are presented to prove the applicability of the proposed method.  相似文献   

Geochemical Eccentricity of Ground Water Allied to Weathering of Basalts from the Deccan Volcanic Province,India: Insinuation on CO<Subscript>2</Subscript> Consumption     

N. J. Pawar  J. B. Pawar  Suyash Kumar  Ashwini Supekar 《Aquatic Geochemistry》2008,14(1):41-71

Analyses of 72 samples from Upper Panjhara basin in the northern part of Deccan Plateau, India, indicate that geochemical incongruity of groundwater is largely a function of mineral composition of the basaltic lithology. Higher proportion of alkaline earth elements to total cations and HCO₃>Cl + SO₄ reflect weathering of primary silicates as chief source of ions. Inputs of Cl, SO₄, and NO₃ are related to rainfall and localized anthropogenic factors. Groundwater from recharge area representing Ca + Mg–HCO₃ type progressively evolves to Ca + Na–HCO₃ and Na–Ca–HCO₃ class along flow direction replicates the role of cation exchange and precipitation processes. While the post-monsoon chemistry is controlled by silicate mineral dissolution + cation exchange reactions, pre-monsoon variability is attributable chiefly to precipitation reactions + anthropogenic factors. Positive correlations between Mg vs HCO₃ and Ca + Mg vs HCO₃ supports selective dissolution of olivine and pyroxene as dominant process in post-monsoon followed by dissolution of plagioclase feldspar and secondary carbonates. The pre-monsoon data however, points toward the dissolution of plagioclase and precipitation of CaCO₃ supported by improved correlation coefficients between Na + Ca vs HCO₃ and negative correlation of Ca vs HCO₃, respectively. It is proposed that the eccentricity in the composition of groundwater from the Panjhara basin is a function of selective dissolution of olivine > pyroxene followed by plagioclase feldspar. The data suggest siallitization (L < R and R _k) as dominant mechanism of chemical weathering of basalts, stimulating monosiallitic (kaolinite) and bisiallitic (montmorillonite) products. The chemical denudation rates for Panjhara basin worked out separately for the ground and surface water component range from 6.98 to 36.65 tons/km²/yr, respectively. The values of the CO₂ consumption rates range between 0.18 × 10⁶ mol//km²/yr (groundwater) and 0.9 × 10⁶ mol/km²/yr (surface water), which indicates that the groundwater forms a considerable fraction of CO₂ consumption, an inference, that is, not taken into contemplation in most of the studies.  相似文献