The equation of state of the solar interior: A comparison of results from two competing formalisms     

Werner Däppen  Yveline Lebreton  Forrest Rogers 《Solar physics》1990,128(1):35-47

A recently developed treatment of partition functions in the equation of state (Mihalas, Hummer, Däppen, MH&D) has led to a substantial improvement in the agreement between observed and theoretically predicted solar p-mode oscillation frequencies. The MH&D equation of state is a realization of the free-energyminimization method, based on the so-called chemical picture, in which ionization and dissociation reactions are assumed to be those that maximize entropy, or equivalently, minimize the free energy. An alternative equation of state has recently been developed at Livermore. It realizes a virial expansion of pressure, and is based on the physical picture, in which explicitly only fundamental species (i.e., electrons and nuclei) appear. Results of a first comparison between thermodynamic quantities of the MH&D and Livermore equations of state are presented. For simplicity, a mixture with only hydrogen and helium (90% H and 10% He by number) is chosen. The comparison is made for a low-density and a high-density case. In the first case, the conditions are those of the hydrogen and helium ionization zones of the Sun, in the second case those of the solar centre. In both cases, the MH&D and Livermore results agree strikingly, despite the very different formalisms they are based on.  相似文献   

准噶尔盆地头屯河地区侏罗系沉积环境与构造意义     

W.施奈德  F.马丁  赵霞飞  赵永胜  龙能礼 《新疆地质》1992,(3)

准噶尔盆地头屯河地区侏罗系陆相层序包含4种沉积:(1)冲积扇平原湿地中的砾石质河流沉积(八遭湾组),其特征提示在湿地中发育了规模不同的大河道(深3—5m,宽1OOm左右)及较小的分流或决口河道(深2m以下,宽6—30m)。(2)沙质低弯度河沉积,晚三工河、早西山窑、头屯河及齐古组沉积期的河流沉积属之。其特点是河道相与河间相间的界线清楚,提示河道在某一段时期固定于平原的特定地带;河道规模受古气候和构造的制约;气候干旱化和构造抬升(如头屯河组沉积时期),侵蚀基面降低,河流动力增加,因而河流规模变大,反之变小;晚头屯河组沉积期的干旱气候存在暂时性河道。(3)三角洲前缘沉积(河口中坝),见于八道湾、三工河及喀拉扎组中。(4)开阔湖相沉积,以三工河组厚的页岩层序为代表。 砂岩成分逆向反映源区剥蚀顺序。下侏罗统富含泥质岩屑,表示天山上古生界浅变质及沉积层系被剥蚀。自下而上,碎屑中稳定矿物增加,粒度变细,反映源区由于剥蚀而后退。中—上侏罗统砂岩成分演化方向不同于下侏罗统,可能与三工河组沉积末期盆地边缘构造回春有关。在Q-F-L三角图中,侏罗系样品大都落在构造区之间,反映陆相盆地充填物的混合来源。下—中侏罗统的煤既有原地生成,亦有重要的他生类型。  相似文献   

Early diagenetic influences on iron transformations in a freshwater lake sediment   总被引：4，自引：0，他引：4  

Paul Wersin  Patrick H  hener  Rudolf Giovanoli  Werner Stumm 《Chemical Geology》1991,90(3-4):233-252

Iron transformations in a calcium carbonate rich fresh-water sediment were studied by analyzing the relevant constituents of both interstitial water and solid matter. Analysis of interstitial water shows that the observed redox sequence NO⁻₃/NH⁺₄, MnO₂/Mn(II), FeOOH/Fe(II), SO²⁻₄/S(−II) is roughly in agreement with that predicted by the Gibbs Free Energy for the corresponding reactions. In contrast to marine sediments, these redox transitions occur in the uppermost sediments, i.e., at depths of 0–4 cm.

Deeper in the sedimentary sequence, the depth profile for dissolved iron exhibits a steady non-linear increase up to 400 μmol dm⁻³. In this anoxic zone, according to thermodynamic predictions, iron (II)-minerals such as iron sulfide, siderite, and vivianite should precipitate while Fe(III) oxides should be completely dissolved. However, microscopic analysis showed that Fe(III) oxides were present throughout the studied sediment. Furthermore, scanning electron microscope/energy dispersive spectroscopy analysis suggests the presence of iron sulfide could be verified but not that of siderite or vivianite. These observations indicate kinetic control of iron transformations.

We have investigated the importance of kinetic control of iron distribution in anoxic sediments using a diagenetic model for dissolved iron(II). A rough estimate of time scales for dissolution and precipitation rates was made by imposing limiting boundary conditions. Using the calculated rate constant, we established that more than 1000 years would be required for the complete dissolution of Fe(III) oxides, which is agreement with our observations and experimental data from the literature. Calculated precipitation rates of Fe(II) for a given mineral phase such as siderite yield a maximum value of 3 μg_(FeCO3) g⁻¹_{(dry sediment)} yr⁻¹. Such low rates would explain the absence of siderite and vivianite.

Finally, it can be inferred from the Mn_T/Fe_T ratio in the sediments that this ratio depends on the redox conditions of the sediment-water interface at the time of deposition. Thus, this ratio can be used as “paleo-redox indicator” in lacustrine sediments.  相似文献   

Geomaterials related to photovoltaics: a nanostructured Fe-bearing kuramite,Cu<Subscript>3</Subscript>SnS<Subscript>4</Subscript>     

Francesco Di Benedetto  Ilaria Bencistà  Francesco D’Acapito  Silvia Frizzera  Andrea Caneschi  Massimo Innocenti  Alessandro Lavacchi  Giordano Montegrossi  Werner Oberhauser  Maurizio Romanelli  Herbert Dittrich  Luca A. Pardi  Gerold Tippelt  Georg Amthauer 《Physics and Chemistry of Minerals》2016,43(8):535-544

The successful synthesis of nanoparticles of Fe-bearing kuramite, (Cu,Fe)₃SnS₄, is reported in this study. Nanocrystalline powders were obtained through a mild, environmentally friendly and scalable solvothermal approach, in a single run. The sample was the object of a multidisciplinary investigation, including X-ray diffraction and absorption, scanning electron microscopy and microanalysis, electron paramagnetic resonance, diffuse reflectance and Mössbauer spectroscopy as well as SQUID magnetometry. The nanoparticles consist of pure Fe-bearing kuramite, exhibiting tetragonal structure. The valence state of the metal cations was assessed to be Cu⁺, Sn⁴⁺ and Fe³⁺. The material presents a band gap value of 1.6 eV, which is fully compatible with solar cell applications. The uptake of Fe by nanokuramite opens a compositional field where the physical properties can be tuned. We thus foster the application of Fe-bearing nanokuramite for photovoltaics and energy storage purposes.  相似文献   

The International Radiation Symposium 2016     

Nicholas Edkins  Werner Schmutz  Luca Egli  Roger Davies  Teruo Aoki  Greg Mcfarquhar 《大气科学进展》2016,33(12):1325-1328

正1.Overview The 2016 International Radiation Symposium,a joint venture between the IRC(International Radiation Commission)and IAMAS(International Association of Meteorology and Atmospheric Sciences),took place at the University of Auckland from April 16th to 22nd.The wide scope of atmospheric radiation research was apparent,with focuses rang-  相似文献   

Infrared observations of Comet Kohoutek (1973f)     

I. Gatley  E.E. Becklin  G. Neugebauer  M.W. Werner 《Icarus》1974,23(4):561-565

Comet Kohoutek has been observed at wavelengths between 1.25 μm and 12.5 μm before and after perihelion passage extending to comet-Sun distance 1 AU. The luminosity and the variation of brightness with comet-Sun distance in the infrared are extraordinarily similar to those of Comet Ikeya-Seki (1965f). Apart from an apparent “silicate” emission feature near 10 μm, the spectrum of the comet between 3.5 μm and 12.5 μm is close to that expected from emission by grey particles. Hotter particles and scattered sunlight produce the bulk of the 1.25- to 3.5 μm emission.  相似文献   

Die Mittleren Geschwindigkeiten Der Sterne In 58 Kugelförmigen Sternhaufen     

Werner Lohmann 《Astrophysics and Space Science》1975,32(1):153-163

The mean velocities of the stars in 58 globular clusters are derived from the photometric measurements of Kron and Mayall (1960). The mass-visual brightness ratio is used. The velocities are falling in the interval 2.9v11.6 km s^–1, their mean value is 6.75 km s^–1.

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Mitteilungen Serie A.  相似文献   

Zur Kristallehemie des Zinnsteins (Kassiterit)     

Dr. Werner Noll 《Contributions to Mineralogy and Petrology》1949,1(5-6):593-625

Zusammenfassung Im Gegensatz zum künstlichen, reinen, kristallinen SnO₂ sind die natürlichen Zinnsteine fast alle mehr oder weniger tief gefärbt bis beinahe undurchsichtig. Über die Ursachen dieser Färbung was bisher nichts Sicheres bekannt, doch konnte nach den bisherigen Schrifttumsangaben vermutet werden, daß. sie irgendwie mit Gehalten an Fe, Mn, Ti, Nb und Ta in irgendeiner unbekannten Form in Beziehung zu bringen sei. Da anzunehmen war, daß diese Fremdstoffgehalte im Zinnstein auch von erheblicher Bedeutung für sein magnetisches und Oberflächenverhalte sein würden, erschien es wünschenswert, die Frage der Zinnsteinfärbung und damit die der genannten Fremdbeimengungen zu klären. Diese Aufgabe bildet den Gegenstand der vorliegenden Untersuchung.Als Dissertation von der Chemischen Fakultät der Technischen Hochschule Darmstadt angenommen am 4. 7. 1944.  相似文献   

Untersuchungen zur Auffindung verborgener nicht-sinusförmiger Periodizitäten in Schwingungsaufzeichnungen     

Dr. Werner Meyer-Eppler 《Pure and Applied Geophysics》1951,20(1):1-14

Zusammenfassung Die Spektralanalyse von Schwingungsvorgängen basierte bisher ausschliesslich auf der Fourierschen Funktionaltransformation. Es wird gezeigt, dass diese Art der spektralen Zerlegung nur ein Sonderfall einer allgemeinen Zerlegungsart ist, die auf dem in der periodographischen Analyse vielbenutzten Exhaustionsprinzip beruht. Dieses Prinzip wird auf kontinuierlich variable Verschiebungsweiten ausgedehnt und führt dann zu einer Integraltransformation, die der Fourier-Transformation analog gebildet ist, aber an Stelle der Cosinusfunktion eine Summe von gleichabständigenDirac-Funktionen enthält. Es wird ein Periodograph beschrieben, der eine kontinuierliche Exhaustionsanalyse von Oszillogrammschablonen nach dem optischen Projektionsverfahren ermöglicht.

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Summary In the past, spectral analysis of oscillations was based upon the Fourier transform almost exclusively. This spectral decomposition is shown to be merely a special case of a more general type of decomposition which is based upon the concept of exhaustion largely used in periodographic analysis. The exhaustion principle is extended to continuous variable shift periods, the result being an integral transform similar to the Fourier transform, with the exception that the cosine function is replaced by a series of equidistantDirac functions. A periodograph is described which permits continuous exhaustion analysis of oscillogram patterns by means of an optical projection device.

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2. Kristallographische und röntgenographische Bestimmungen am „Wittichenit von Sadisdorf”     

Werner Borchert  Robert Schroeder 《Contributions to Mineralogy and Petrology》1947,1(1):112-117

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