31P solid-state nuclear magnetic resonance spectroscopy of aluminum phosphate minerals     

William F. Bleam  Philip E. Pfeffer  James S. Frye 《Physics and Chemistry of Minerals》1989,16(5):455-464

This study examines the links between ³¹P solidstate NMR studies of aluminum phosphate minerals and their crystallographic structures. We found that ³¹P isotropic chemical shift values, _iso, carry little information about mineral structures. There seems to be no relation between the chemical shift anisotropy, =₃₃–₁₁ (₃₃>₂₂> ₁₁), and indicies of phosphate-tetrahedra distortion. ³¹P¹H heteronuclear magnetic dipole interactions, on the other hand, carry important information about hydrous phosphate mineral structures, information that should prove to be quite valuable in studies of phosphate adsorbed on mineral surfaces. This interaction can be measured through a variety of qualitative and quantitative experiments. It appears that spin diffusion is so rapid that subtle differences in hydrogen-bonding environments cannot be resolved.  相似文献   

One-dimensional baroclinically unstable waves on the Gulf Stream potential vorticity gradient near Cape Hatteras     

William E. Johns 《Dynamics of Atmospheres and Oceans》1988,11(3-4)

Application of linear baroclinic instability theory to the observed distributions of velocity, stratification, and potential vorticity in the Gulf Stream near 74° W is successful in predicting the time and length scales of the most rapidly growing disturbances. A continuously-stratified, one-dimensional model with realistic bottom slope predicts propagation speeds of 10–50 cm s⁻¹ associated with two regimes of rapid temporal growth centered at periods of 28 days and 5–7 days. This prediction is consistent with observations of the propagation and growth of Gulf Stream meanders derived from inverted echo sounder measurements in this region. The instability model also predicts that for realistic bottom slopes the baroclinic energy transfer should be weakly negative (eddy-to-mean) in deep water, but for low-frequency waves should change to significant positive (mean-to-eddy) transfer above depths of 1500 m, consistent with observations.  相似文献   

Introduction to the dedicated issue     

William S. Marshall 《Estuaries and Coasts》1994,17(1):1-2

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Editors’ preface     

John E. Moore  Clifford I. Voss  William E. Wilson 《Hydrogeology Journal》1994,2(1):3-5

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Internet listservers of interest to paleolimnologists     

William M. Last 《Journal of Paleolimnology》1995,13(3):295-296

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Computer applications to paleolimnology: Getting ready for the next century     

John P. Smol  William M. Last 《Journal of Paleolimnology》1995,13(1):1-2

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Agricultural policy reforms and sustainable land management: a New Zealand case study     

William Smith  Lindsay Saunders 《The Australian geographer》1995,26(2):112-118

This paper examines the link between poverty and land management within the context of New Zealand's almost total removal of subsidies to agriculture since 1984. The impact of these policy changes is explored through the findings from a detailed study of sixteen farms in the North Island hill country. Stress is identified as a primary link between social damage and environmental degradation. This link reinforces the impact of other linkages expressed in reduced production, lower stocking rates, and reduced capital inputs. Deregulation is claimed to be good. This paper shows that in certain circumstances this is not so.  相似文献   

An apparent moratorium on the greenhouse warming due to the deep ocean     

William W. Kellogg 《Climatic change》1993,25(1):85-88

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Changes in post world war ii distribution and status of monsoon rainforests in the Darwin area     

William J. Panton 《The Australian geographer》1993,24(2):50-59

Monsoon rainforests in the Darwin area occur as isolated patches ranging in size from 2 to 112 ha. Aerial photographic records over a 45 year period indicate a 60 per cent reduction in the cover of pre‐1945 rainforest. Urban development, cyclone damage, weed invasion and wildfire were identified as the major causes of this contraction. Urban development contributed 40 per cent of the total rainforest loss during this period. Rainforests occurring on dry substrates have been most affected by urban development. Cyclonic storm damage and indirect human affects such as weed invasion and anthropogenic fires continue to disturb the remaining rainforest patches. Although the largest expanses of rainforest presently occur within parks and reserves, providing adequate protection from further urban encroachment, smaller remnants occurring on vacant crown land are vulnerable to changes in land use. As well as the introduction of appropriate legislation, the control of fire and weeds should be given the highest priority by land managers to ensure the stability and long‐term maintenance of this remnant vegetation.  相似文献   

Responses of marsh fishes and breeding wading birds to low temperatures: A possible behavioral link between predator and prey     

Peter C. Frederick  William F. Loftus 《Estuaries and Coasts》1993,16(2):216-222

In the Everglades of southern Florida, several species of spring- and winter-nesting wading birds (Ciconiiformes) often abandon their nests in response to periods of cold or wet and windy weather. Using stepwise logistic regression of a variety of hydrologic and meteorologic variables on the probability of great egret nest failure, we found that cold temperatures and high wind speeds were most closely associated with nest failure in the Everglades. Water level fluctuation was not a significant correlate of failure. Quantitative visual surveys in the field showed that even moderate cooling events (15°C minimum daily temperature) dramatically altered the observed densities of marsh fishes. In controlled conditions in the laboratory, we observed centrarchid, poeciliid, and cyprinodontid fishes during normal high (19–23°C) and simulated cold snap (8–11°C) temperatures. At low temperatures, the fishes exhibited reduced activity, sought refuge by hiding in vegetation and/or substrate, and fled our approach to the tank at much greater distances. Threshold temperatures for these behaviors varied considerably between the laboratory (9–11°C) and field (15–20°C), and may be explained by differences in the previous thermal experience of the two groups of fishes. We hypothesize that the temperature-induced scarcity of fishes during spring cold snaps is an important cause of disruption of nesting for several species of wading birds in the Everglades.  相似文献