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81.
82.
In the Sandıklı (Afyon) region, western Taurides, the Late Proterozoic rocks of the Sandıklı basement complex are composed of low-grade meta-sedimentary rocks (Güvercinoluk Formation) intruded by felsic rocks (Kestel Cayı Porphyroid Suite, KCPS). The KCPS is a deformed and highly sheared, dome-shaped rhyolitic body with a granitic core. Quartz porphyry dikes intrude both the slightly metamorphic igneous and the sedimentary rocks of the basement complex. Both the quartz porphyries and rhyolites were converted into mylonites with relict igneous textures. Geochemical data show that these felsic igneous rocks are subalkaline and mainly granitic in composition with SiO2 >72 wt% and Al2O3 >11.5 wt%. The chondrite-normalized incompatible trace element patterns are characterized by distinct negative Rb, Nb, Sr, P, Ti, and Eu with enrichment in Th, U, La, Ce, Nd, Sm, and Zr. The REE patterns of the felsic rocks indicate a strong enrichment in LREE but display slightly flat HREE patterns. According to geochemical characteristics and petrogenetic modeling, extrusive and intrusive rocks of the KCPS were probably derived from an upper continental crustal source (partial melting of granites/felsic rocks) by 18–20% fractional melting plus 18–20% Rayleigh fractional crystallization, which seems to be the most effective igneous process during the crystallization of the KCPS. Single zircon age data from the granitoids and fossils from the disconformably overlying sedimentary successions indicate that the metamorphism and the igneous event in the Taurides are related to the Cadomian orogeny. Based on the geological, geochemical and petrogenetic correlation of the post-collisional granitoids it is further suggested that the Tauride belt in western central Turkey was in a similar tectonic setting to the Gondwanan terranes in North Africa (Younger Granitoids) and southern Europe (Spain, France, Bohemia, Brno Massifs) during the Late Cadomian period. 相似文献
83.
The formation of colloids during the weathering of phyllite was investigated by exposing ground phyllite to Milli-Q water. Secondary mineral colloids of 101–102 nm were detected in significant concentrations. At pH of about 8.5, the solution concentration of these colloids reached up to 10 mg/L (however, acidification to pH 4.0 prevented the formation of the colloids). The mineralogical composition of the secondary mineral colloids is assumed to be a mixture of ferrihydrite, manganese oxyhydroxides, aluminosilicates, amorphous Al(OH)3 and gibbsite with possible additions of iron silicates and␣iron-alumino silicates. The colloids were stable over longer periods of time (at least several weeks), even in the presence of suspended ground rock. Direct formation of iron-containing secondary mineral colloids at the rock–water interface by the weathering of rock material is an alternative to the well-known mechanism of iron colloid formation in the bulk of water bodies by mixing of different waters or by aeration of anoxic waters. This direct mechanism is of relevance for colloid production during the weathering of freshly crushed rock in the unsaturated zone as for instance crushed rock in mine waste rock piles. Colloids produced by this mechanism, too, can influence the transport of contaminants such as actinides because these colloids have a large specific surface area and a high sorption affinity. 相似文献
84.
85.
In this study, hydrogeologic and hydrochemical information from the Mersin-Erdemli groundwater system were integrated and
used to determine the main factors and mechanisms controlling the chemistry of groundwaters in the area and anthropogenic
factors presently affecting them. The PHREEQC geochemical modeling demonstrated that relatively few phases are required to
derive water chemistry in the area. In a broad sense, the reactions responsible for the hydrochemical evolution in the area
fall into four categories: (1) silicate weathering reactions; (2) dissolution of salts; (3) precipitation of calcite, amorphous
silica and kaolinite; (4) ion exchange. As determined by multivariate statistical analysis, anthropogenic factors show seasonality
in the area where most contaminated waters related to fertilizer and fungicide applications that occur during early summer
season. 相似文献
86.
Two cases of on-ice and off-ice air flow characterizing the opposite weather situations over the ice-edge zone in the northern Baltic Sea are analysed on the basis of aircraft observations, and modelled using atwo-dimensional mesoscale model. The stable boundary layer (SBL) during theon-ice flow exhibited little thermal modification, but a low-level jet (LLJ) was generated at the 250-m high top of the SBL. In the model, the LLJ was associated with inertial oscillations in space, while the baroclinicity explained the shape of the wind profile well above the SBL. Although the observed LLJ was most pronounced over the ice, the modelling suggests that it was not generated by the ice edge but by the coastline some 400 km upwind of the ice edge, where a much more drastic change in the thermal stratification and surface roughness took place. The generation, maintenance, and strength of the LLJ were very sensitive to the parameterization of turbulent mixing in the SBL. In the case of the off-ice flow, the modification of the air mass and the development of a convective boundary layer (CBL) both over the ice and open sea were reasonably well modelled. Sensitivity runs suggested that it was essential to take into account the effects of subgrid-scale leads, a forest in the archipelago (which was crossed by the air flow), and water vapour condensationinto ice crystals. The heat flux from leads was particularly important for the heatbudget of the CBL, and the observed growth of the CBL was partly due to theeffective mixing over the rough and relatively warm forest. 相似文献
87.
Laurent Desmurs Othmar Müntener Gianreto Manatschal 《Contributions to Mineralogy and Petrology》2002,144(3):365-382
Exhumation of subcontinental mantle rocks and its exposure at the seafloor is known from different magma-poor passive continental margins. However, the transition from largely amagmatic passive rifting to seafloor spreading is still poorly documented. In this contribution we use MOR-type gabbroic and basaltic rocks to characterize the magmatism associated with the formation of an ancient ocean-continent transition preserved in the Platta nappe, eastern Switzerland. Gabbros form individual small intrusions into exhumed serpentinized subcontinental mantle rocks. Mineral and bulk-rock chemistry and simple modeling indicate that each gabbro body records different magmatic processes ranging from predominantly fractional crystallization to solidification without fractionation. Mg numbers and Ni contents of equilibrium olivine calculated from basalts and gabbros indicate that few mafic rocks are primary melts but most represent fractionated compositions ranging from T- to N-MORB. Whereas most mafic rocks may be explained by low to moderate degrees of melting of an N-MORB-type mantle, the source of some basalt is enriched in incompatible elements. This compositional variation seems to correlate with the spatial distribution of the mafic rocks within the ocean-continent transition whereby mafic rocks with T-MORB signatures occur close to the continental margin whereas N-MORB signatures are predominantly found oceanwards. As in an opening system time and space are closely linked, the chemical evolution of the mafic rocks along the ocean-continent transitions suggests continuous thinning of the subcontinental mantle and associated uplift of the underlying asthenosphere during the time between the crustal and the lithospheric breakup. 相似文献
88.
In South Africa attempts are being made to address the socio-spatial distortions of the apartheid era through a more equitable
distribution of resources, and the re-drawing of municipal geographical boundaries. However, boundaries are not neutral geographic
lines. Boundary changes are often associated with a redistribution of political power and resources. The aim of this paper
is to analyse the effects of the contemporary territorial and administrative restructuring on urban dynamics in South Africa.
More specifically, the focus is on how the process of territorial restructuring impacted on metropolitan areas as well as
on secondary cities and their hinterlands. Examining and elucidating the manner in which various social, economic and political
forces have manifested themselves in the process of boundary delimitation in a major metropolitan centre as well as adjacent
rural areas is a central theme of this paper. There were considerable contestations over the delimitation of new local government
boundaries. Affluent metro authorities like that in Durban were opposed to the spatial extension of their boundaries because
of the costs of the providing services and infrastructure in the deprived margins. Similarly, there was concern that incorporation
of rural areas will result in increased municipal service charges being imposed on these communities. Tensions were heightened
between urban and rural regions because traditional leaders believed that their territorial jurisdiction and authority were
being undermined. In other parts of the country, the merger of traditionally white and black fragments of secondary cities
often resulted in many black locations continuing to be marginalized. There appears to be neither the political will nor the
economic capacity to upgrade these zones of marginalized urban communities. While the Municipal Demarcation Board was largely
successful in eliminating the political geography of apartheid at a macro- scale, this paper suggests that the greater challenge
for government and policy makers is to reduce the socio-spatial and economic inequalities which appears to be still very high
and perhaps increasing.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
89.
90.