Europium retention onto clay minerals from 25 to 150 °C: Experimental measurements, spectroscopic features and sorption modelling     

E. Tertre  G. Berger  S. Castet  M. Loubet 《Geochimica et cosmochimica acta》2006,70(18):4563-4578

The sorption of Eu(III) onto kaolinite and montmorillonite was investigated up to 150 °C. The clays were purified samples, saturated with Na in the case of montmorillonite. Batch experiments were conducted at 25, 40, 80 and 150 °C in 0.5 M NaClO₄ solutions to measure the distribution coefficients (Kd) of Eu as a trace element (<10⁻⁶ mol/L) between the solution and kaolinite. For the Na-montmorillonite, we used Kd results from a previous study [Tertre, E., Berger, G., Castet, S., Loubet, M., Giffaut, E., 2005. Experimental study of adsorption of Ni²⁺, Cs⁺ and Ln³⁺ onto Na-montmorillonite up to 150 °C. Geochim. Cosmochim. Acta69, 4937-4948] obtained under exactly the same conditions. The number and nature of the Eu species sorbed onto both clay minerals were investigated by time resolved laser fluorescence spectroscopy (TRLFS) in specific experiments in the same temperature range. We identified a unique inner-sphere complex linked to the aluminol sites in both clays, assumed to be AlOEu²⁺ at the edge of the particles, and a second exchangeable outer-sphere complex for montmorillonite, probably in an interlayer position. The Kd values were used to adjust the parameters of a surface complexation model (DLM: diffuse layer model) from 25 to 150 °C. The number of Eu complexes and the stoichiometry of reactions were constrained by TRLFS. The acidity constants of the amphoteric aluminol sites were taken from another study [Tertre, E., Castet, S., Berger, G., Loubet, M., Giffaut, E. Acid/base surface chemistry of kaolinite and Na-montmorillonite at 25 and 60 °C: experimental study and modelling. Geochim. Cosmochim. Acta, in press], which integrates the influence of the negative structural charge of clays on the acid/base properties of edge sites as a function of temperature and ionic strength. The results of the modelling show that the observed shift of the sorption edge towards low pH with increasing temperature results solely from the contribution of the AlOEu²⁺ edge complexes. Finally, we successfully tested the performance of our model by confronting the predictions with experimental Kd data. We used our own data obtained at lower ionic strength (previous study) or higher suspension density and higher starting concentration (TRLFS runs, this study), as well as published data from other experimental studies [Bradbury, M.H., Baeyens, B., 2002. Sorption of Eu on Na and Ca-montmorillonite: experimental investigations and modeling with cation exchange and surface complexation. Geochim. Cosmochim. Acta66, 2325-2334; Kowal-Fouchard, A., 2002. Etude des mécanismes de rétention des ions U(IV) et Eu(III) sur les argiles: influence des silicates. Ph.D. Thesis, Université Paris Sud, France, 330p].  相似文献   

Holocene climate evolution of the Ugii Nuur basin,Mongolia     

Wolfgang SCHWANGHART  Brigitta SCH  "UTT  Michael WALTHER 《大气科学进展》2008,25(6):986-998

In order to evaluate the Holocene palaeoenvironmental evolution of the Ugii Nuur basin, central Mongolia, investigations on chemical and mineralogical properties of lacustrine sediments were carried out on a 630 cm sediment core from lake Ugii Nuur. The interpretation of the record is based on a principal component analysis （PCA） of the elemental composition of the samples. The results show that lacustrine deposition started at 10.6 kyr BP. Low lake level conditions were identified during the Early Holocene （10.6-7.9 kyr BP）. The Mid Holocene （7.9-4.2 kyr BP） was characterized by generally higher lake levels and thus higher moisture supply, but it experienced strong climatic fluctuations. Arid conditions prevailed from 4.2-2.8 kyr BP and were followed by a stable, more humid phase until today.  相似文献   

An Integrated Assessment of changes in the thermohaline circulation   总被引：1，自引：0，他引：1  

Till Kuhlbrodt  Stefan Rahmstorf  Kirsten Zickfeld  Frode Bendiksen Vikebø  Svein Sundby  Matthias Hofmann  Peter Michael Link  Alberte Bondeau  Wolfgang Cramer  Carlo Jaeger 《Climatic change》2009,96(4):489-537

This paper discusses the risks of a shutdown of the thermohaline circulation (THC) for the climate system, for ecosystems in and around the North Atlantic as well as for fisheries and agriculture by way of an Integrated Assessment. The climate model simulations are based on greenhouse gas scenarios for the 21st century and beyond. A shutdown of the THC, complete by 2150, is triggered if increased freshwater input from inland ice melt or enhanced runoff is assumed. The shutdown retards the greenhouse gas-induced atmospheric warming trend in the Northern Hemisphere, but does not lead to a persistent net cooling. Due to the simulated THC shutdown the sea level at the North Atlantic shores rises by up to 80 cm by 2150, in addition to the global sea level rise. This could potentially be a serious impact that requires expensive coastal protection measures. A reduction of marine net primary productivity is associated with the impacts of warming rather than a THC shutdown. Regional shifts in the currents in the Nordic Seas could strongly deteriorate survival chances for cod larvae and juveniles. This could lead to cod fisheries becoming unprofitable by the end of the 21st century. While regional socioeconomic impacts might be large, damages would be probably small in relation to the respective gross national products. Terrestrial ecosystem productivity is affected much more by the fertilization from the increasing CO₂ concentration than by a THC shutdown. In addition, the level of warming in the 22nd to 24th century favours crop production in northern Europe a lot, no matter whether the THC shuts down or not. CO₂ emissions corridors aimed at limiting the risk of a THC breakdown to 10% or less are narrow, requiring departure from business-as-usual in the next few decades. The uncertainty about THC risks is still high. This is seen in model analyses as well as in the experts’ views that were elicited. The overview of results presented here is the outcome of the Integrated Assessment project INTEGRATION.  相似文献   

Global non-axisymmetric perturbation configurations in a composite disc system with an isopedic magnetic field: relation between dark matter halo and magnetic field     

Meng Xiang-Gruess  Yu-Qing Lou  Wolfgang J. Duschl 《Monthly notices of the Royal Astronomical Society》2009,397(2):815-836

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Detection of non-radial pulsation and faint companion in the symbiotic star CH Cyg     

E. Pedretti †  J. D. Monnier  S. Lacour  W. A. Traub  W. C. Danchi  P. G. Tuthill  N. D. Thureau  R. Millan-Gabet  J.-P. Berger  M. G. Lacasse  P. A. Schuller  F. P. Schloerb  N. P. Carleton 《Monthly notices of the Royal Astronomical Society》2009,397(1):325-334

We have detected asymmetry in the symbiotic star CH Cyg through the measurement of precision closure phase with the Integrated Optics Near-Infrared Camera (IONIC) beam combiner, at the infrared optical telescope array interferometer. The position of the asymmetry changes with time and is correlated with the phase of the 2.1-year period found in the radial velocity measurements for this star. We can model the time-dependent asymmetry either as the orbit of a low-mass companion around the M giant or as an asymmetric, 20 per cent change in brightness across the M giant. We do not detect a change in the size of the star during a 3-year monitoring period neither with respect to time nor with respect to wavelength. We find a spherical dust shell with an emission size of 2.2 ± 0.1 D _* full width at half-maximum around the M giant star. The star to dust flux ratio is estimated to be 11.63 ± 0.3. While the most likely explanation for the 20 per cent change in brightness is non-radial pulsation, we argue that a low-mass companion in close orbit could be the physical cause of the pulsation. The combined effect of pulsation and low-mass companion could explain the behaviour revealed by the radial velocity curves and the time-dependent asymmetry detected in the closure-phase data. If CH Cyg is a typical long secondary period variable then these variations could be explained by the effect of an orbiting low-mass companion on the primary star.  相似文献   

Spectral analysis of the 91bg-like Type Ia SN 2005bl: low luminosity, low velocities, incomplete burning     

Stephan Hachinger  Paolo A. Mazzali  Stefan Taubenberger  Rüdiger Pakmor  Wolfgang Hillebrandt 《Monthly notices of the Royal Astronomical Society》2009,399(3):1238-1254

The properties of underluminous Type Ia supernovae (SNe Ia) of the 91bg subclass have yet to be theoretically understood. Here, we take a closer look at the structure of the dim SN Ia 2005bl. We infer the abundance and density profiles needed to reproduce the observed spectral evolution between −6 d and  +12.9 d  with respect to B maximum. Initially, we assume the density structure of the standard explosion model W7; then we test whether better fits to the observed spectra can be obtained using modified density profiles with different total masses and kinetic energies. Compared to normal SNe Ia, we find a lack of burning products especially in the rapidly expanding outer layers  ( v ≳ 15 000 km s⁻¹)  . The zone between ∼8500 and 15 000 km s⁻¹ is dominated by oxygen and includes some amount of intermediate-mass elements. At lower velocities, intermediate-mass elements dominate. This holds down to the lowest zones investigated in this work. This fact, together with negligible-to-moderate abundances of Fe-group elements, indicates large-scale incomplete Si burning or explosive O burning, possibly in a detonation at low densities. Consistently with the reduced nucleosynthesis, we find hints of a kinetic energy lower than that of a canonical SN Ia: the spectra strongly favour reduced densities at  ≳13 000 km s⁻¹  compared to W7, and are very well fitted using a rescaled W7 model with original mass  (1.38 M_⊙)  , but a kinetic energy reduced by ∼30 per cent (i.e. from  1.33 × 10⁵¹  to  0.93 × 10⁵¹ erg  ).  相似文献   

Geochemical constraints on the modes of carbonate precipitation in peridotites from the Logatchev Hydrothermal Vent Field and Gakkel Ridge     

Benjamin Eickmann  Wolfgang Bach  Martin Rosner  Jrn Peckmann 《Chemical Geology》2009,268(1-2):97-106

The ultramafic-hosted Logatchev Hydrothermal Field (LHF) at 15°N on the Mid-Atlantic Ridge and the Arctic Gakkel Ridge (GR) feature carbonate precipitates (aragonite, calcite, and dolomite) in voids and fractures within different types of host rocks. We present chemical and Sr isotopic compositions of these different carbonates to examine the conditions that led to their formation. Our data reveal that different processes have led to the precipitation of carbonates in the various settings. Seawater-like ⁸⁷Sr/⁸⁶Sr ratios for aragonite in serpentinites (0.70909 to 0.70917) from the LHF are similar to those of aragonite from the GR (0.70912 to 0.70917) and indicate aragonite precipitation from seawater at ambient conditions at both sites. Aragonite veins in sulfide breccias from LHF also have seawater-like Sr isotope compositions (0.70909 to 0.70915), however, their rare earth element (REE) patterns show a clear positive europium (Eu) anomaly indicative of a small (< 1%) hydrothermal contribution. In contrast to aragonite, dolomite from the LHF has precipitated at much higher temperatures (~ 100 °C), and yet its ⁸⁷Sr/⁸⁶Sr ratios (0.70896 to 0.70907) are only slightly lower than those of aragonite. Even higher temperatures are calculated for the precipitation of deformed calcite veins in serpentine–talc fault schists form north of the LHF. These calcites show unradiogenic ⁸⁷Sr/⁸⁶Sr ratios (0.70460 to 0.70499) indicative of precipitation from evolved hydrothermal fluids. A simple mixing model based on Sr mass balance and enthalpy conservation indicates strongly variable conditions of fluid mixing and heat transfers involved in carbonate formation. Dolomite precipitated from a mixture of 97% seawater and 3% hydrothermal fluid that should have had a temperature of approximately 14 °C assuming that no heat was transferred. The much higher apparent precipitation temperatures based on oxygen isotopes (~ 100 °C) may be indicative of conductive heating, probably of seawater prior to mixing. The hydrothermal calcite in the fault schist has precipitated from a mixture of 67% hydrothermal fluid and 33% seawater, which should have had an isenthalpic mixing temperature of ~ 250 °C. The significantly lower temperatures calculated from oxygen isotopes are likely due to conductive cooling of hydrothermal fluid discharging along faults. Rare earth element patterns corroborate the results of the mixing model, since the hydrothermal calcite, which formed from waters with the greatest hydrothermal contribution, has REE patterns that closely resemble those of vent fluids from the LHF. Our results demonstrate, for the first time, that (1) precipitation from pure seawater, (2) conductive heating of seawater, and (3) conductive cooling of hydrothermal fluids in the sub-seafloor all can lead to carbonate precipitation within a single ultramafic-hosted hydrothermal system.  相似文献   

Formation and alteration of plagiogranites in an ultramafic-hosted detachment fault at the Mid-Atlantic Ridge (ODP Leg 209)     

Niels Jöns  Wolfgang Bach  Timothy Schroeder 《Contributions to Mineralogy and Petrology》2009,157(5):625-639

We examined small-scale shear zones in drillcore samples of abyssal peridotites from the Mid-Atlantic Ridge. These shear zones are associated with veins consisting of chlorite + actinolite/tremolite assemblages, with accessory phases zircon and apatite, and they are interpreted as altered plagiogranite melt impregnations, which originate from hydrous partial melting of gabbroic intrusion in an oceanic detachment fault. Ti-in-zircon thermometry yields temperatures around 820°C for the crystallization of the evolved melt. Reaction path modeling indicates that the alteration assemblage includes serpentine of the adjacent altered peridotites. Based on the model results, we propose that formation of chlorite occurred at higher temperatures than serpentinization, thus leading to strain localization around former plagiogranites during alteration. The detachment fault represents a major pathway for fluids through the oceanic crust, as evidenced by extremely low δ¹⁸O of altered plagiogranite veins (+3.0–4.2‰) and adjacent serpentinites (+ 2.6–3.7‰). The uniform oxygen isotope data indicate that fluid flow in the detachment fault system affected veins and adjacent host serpentinites likewise. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

Fe-Ni-Co-O-S Phase Relations in Peridotite-Seawater Interactions   总被引：4，自引：0，他引：4  

Klein  Frieder; Bach  Wolfgang 《Journal of Petrology》2009,50(1):37-59

Serpentinization of abyssal peridotites is known to produceextremely reducing conditions as a result of dihydrogen (H₂,aq)release upon oxidation of ferrous iron in primary phases toferric iron in secondary minerals by H₂O. We have compiled andevaluated thermodynamic data for Fe–Ni–Co–O–Sphases and computed phase relations in fO₂,g–fS₂,g andaH₂,aq–aH₂S,aq diagrams for temperatures between 150 and400°C at 50 MPa. We use the relations and compositions ofFe–Ni–Co–O–S phases to trace changesin oxygen and sulfur fugacities during progressive serpentinizationand steatitization of peridotites from the Mid-Atlantic Ridgein the 15°20'N Fracture Zone area (Ocean Drilling ProgramLeg 209). Petrographic observations suggest a systematic changefrom awaruite–magnetite–pentlandite and heazlewoodite–magnetite–pentlanditeassemblages forming in the early stages of serpentinizationto millerite–pyrite–polydymite-dominated assemblagesin steatized rocks. Awaruite is observed in all brucite-bearingpartly serpentinized rocks. Apparently, buffering of silicaactivities to low values by the presence of brucite facilitatesthe formation of large amounts of hydrogen, which leads to theformation of awaruite. Associated with the prominent desulfurizationof pentlandite, sulfide is removed from the rock during theinitial stage of serpentinization. In contrast, steatitizationindicates increased silica activities and that high-sulfur-fugacitysulfides, such as polydymite and pyrite–vaesite solidsolution, form as the reducing capacity of the peridotite isexhausted and H₂ activities drop. Under these conditions, sulfideswill not desulfurize but precipitate and the sulfur contentof the rock increases. The co-evolution of fO₂,g–fS₂,gin the system follows an isopotential of H₂S,aq, indicatingthat H₂S in vent fluids is buffered. In contrast, H₂ in ventfluids is not buffered by Fe–Ni–Co–O–Sphases, which merely monitor the evolution of H₂ activitiesin the fluids in the course of progressive rock alteration.The co-occurrence of pentlandite–awaruite–magnetiteindicates H₂,aq activities in the interacting fluids near thestability limit of water. The presence of a hydrogen gas phasewould add to the catalyzing capacity of awaruite and would facilitatethe abiotic formation of organic compounds. KEY WORDS: serpentinization; ODP Expedition 209; sulfide; oxygen fugacity; sulfur fugacity; hydrothermal system; metasomatism; Mid-Atlantic Ridge  相似文献   

Atlantic Water flow through the Barents and Kara Seas   总被引：2，自引：0，他引：2  

Ursula Schauer  Harald Loeng  Bert Rudels  Vladimir K. Ozhigin  Wolfgang Dieck 《Deep Sea Research Part I: Oceanographic Research Papers》2002,49(12)

The pathway and transformation of water from the Norwegian Sea across the Barents Sea and through the St. Anna Trough are documented from hydrographic and current measurements of the 1990s. The transport through an array of moorings in the north-eastern Barents Sea was between 0.6 Sv in summer and 2.6 Sv in winter towards the Kara Sea and between zero and 0.3 Sv towards the Barents Sea with a record mean net flow of 1.5 Sv. The westward flow originates in the Fram Strait branch of Atlantic Water at the Eurasian continental slope, while the eastward flow constitutes the Barents Sea branch, continuing from the western Barents Sea opening.About 75% of the eastward flow was colder than 0°C. The flow was strongly sheared, with the highest velocities close to the bottom. A deep layer with almost constant temperature of about −0.5°C throughout the year formed about 50% of the flow to the Kara Sea. This water was a mixture between warm saline Atlantic Water and cold, brine-enriched water generated through freezing and convection in polynyas west of Novaya Zemlya, and possibly also at the Central Bank. Its salinity is lower than that of the Atlantic Water at its entrance to the Barents Sea, because the ice formation occurs in a low salinity surface layer. The released brine increases the salinity and density of the surface layer sufficiently for it to convect, but not necessarily above the salinity of the Atlantic Water. The freshwater west of Novaya Zemlya primarily stems from continental runoff and at the Central Bank probably from ice melt. The amount of fresh water compares to about 22% of the terrestrial freshwater supply to the western Barents Sea. The deep layer continues to the Kara Sea without further change and enters the Nansen Basin at or below the core depth of the warm, saline Fram Strait branch. Because it is colder than 0°C it will not be addressed as Atlantic Water in the Arctic Ocean.In earlier decades, the Atlantic Water advected from Fram Strait was colder by almost 2 K as compared to the 1990s, while the dense Barents Sea water was colder by up to 1 K only in a thin layer at the bottom and the salinity varied significantly. However, also with the resulting higher densities, deep Eurasian Basin water properties were met only in the 1970s. The very low salinities of the Great Salinity Anomaly in 1980 were not discovered in the outflow data. We conclude that the thermal variability of inflowing Atlantic water is damped in the Barents Sea, while the salinity variation is strongly modified through the freshwater conditions and ice growth in the convective area off Novaya Zemlya.  相似文献