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61.
Gas exchange experiments were conducted in the tropical Atlantic Ocean during a ship expedition with FS Meteor using a small rubber raft. The temporal change of the mixing ratios of CO, H2, CH4 and N2O in the headspace of a floating glass box and the concentrations of these gases in the water phase were measured to determine their transfer velocities across the ocean-atmosphere interface. The ocean acted as a sink for these gases when the water was undersaturated with respect to the mixing ratio in the headspace. The transfer velocities were different for the individual gases and showed still large differences even when normalized for diffusivity. Applying the laminar film model, film thicknesses of 20 to 70 m were calculated for the observed flux rates of the different gas species. When the water was supersaturated with respect to atmospheric CO, H2, CH4 and N2O, the transfer velocities of the emission process were smaller than those determined for the deposition process. In case of H2 and CH4, emission was even not calculable although, based on the observed gradient, the laminar film model predicted significant fluxes at the air-sea interface. The results are interpreted by destruction processes active within the surface microlayer.  相似文献   
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The Jewel seam of the Cadomin area is complexly folded and cut by several thrust faults. Vitrinite reflectance anisotropy was determined from twenty oriented coal blocks, collected from various structural positions. Five of the blocks have uniaxial anisotropies, five have biaxial positive anisotropies, the remaining ten are biaxial negative. The biaxial coals display maximum reflectance axes parallel to nearby fold axes, which suggests a relationship between vitrinite anisotropy and deformation. The biaxial vitrinite reflectance ellipsoids result from superposition of tectonic strains on a primary, sedimentary burial related, uniaxial anisotropy. A tectonic stress field was probably present during the later stages of sedimentary burial and subsequent deformation.Coalification resulted largely from pre-deformational, sedimentary burial, but the final coalification stage was syn-deformational, as illustrated by the intersection of isorank surfaces and the Jewel seam and the biaxial vitrinite reflectance anisotropy.  相似文献   
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A field study on the geochemical properties of a chemically-stressed limnic environment was performed in Lake Silbersee, which receives leachate water of high inorganic loading from an upgradient landfill site. The highly concentrated sulfate ion in groundwater, when entering the pore water system of the lake, gives rise to an intensive microbial sulfate reduction. A diagenetic approach was used to explain the existence of a marine-like aqueous system within a geologically slightly acidic aquifer, consisting of a well-buffered lake water and an alkalinity producing, excess sulphide containing sediment pore water system.  相似文献   
66.
Photoelectric detectors for the measurement of photolysis frequencies of different trace gases in the atmosphere are described. They exhibit uniform response characteristics over one hemisphere (2 sr) and wavelength characteristics closely matched to those of the photolysis frequencies J O1D, J NO2, and J NO3, respectively. Absolute calibration of the J O1D detector was performed by chemical actinometry with an accuracy of ±16 percent. Simultaneous measurements of J NO2 and J O1D are presented.  相似文献   
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Eight box cores from the tropical Atlantic were studied in detail with regard to foraminiferal oxygen isotopes, radiocarbon, and Globorotalia menardii abundance. A standard Atlantic oxygen-isotope signal was reconstructed for the last 20,000 yr. It is quite similar to the west-equatorial Pacific signal published previously. Deglaciation is seen to occur in two steps which are separated by a pause. Onset of deglaciation is after 15,000 yr B.P. The pause is centered between 11,000 and 12,000 yr B.P., but may be correlative with the Younger Dryas (10,500 yr B.P.) if allowance is made for a scale shift due to mixing processes on the sea floor. Step 2 is centered near 10,000 yr B.P. and is followed by a brief excursion toward light oxygen values. This excursion (the M event) may correlate with the Gulf of Mexico meltwater spike.  相似文献   
69.
Zusammenfassung Eine Neuuntersuchung der Tektonik in den Vilser Alpen und im Hochvogelgebiet, wo die Frage seit langer Zeit diskutiert wird, ob dort die Allgäu- und Lechtal-Decke getrennte Einheiten bilden, oder stratigraphisch untrennbar zusammenhängen, erbrachte eine eindeutige Entscheidung für den Deckenbau. Der Verlauf der Deckengrenze konnte zwischen Hochvogel und Hohenschwangauer Alpen präzisiert werden. Der interne Falten- und Schuppenbau der Lechtal-Decke hat nirgends zur Bildung von tektonisch tieferen Teildekken geführt, die internen Verschuppungen besitzen nur ein geringes Ausmaß.
A new investigation of the tectonics in the Vilser Alps and in the Mt. Hochvogel area where since a long time a discussion was going on if the thrust sheets of Allgäu and Lechtal-Decke are separate units or connected by stratigraphic sequences, a definite decision could be made in favour of the nappe structure in this part of the Northern Calcareous Alps. The internal structure of the Lechtal-Decke thrust sheet is characterized by local imbricate structure which originate from sheared folds.

Résumé On a dicuté depuis longtemps dans les Vilser Alpen et dans la région du Mont Hochvogel le problème, si les nappes de Allgäu et Lechtal-Decke sont des unités separées ou qu'ils forment une partie inséparable par des séquences stratigraphiques. Une nouvelle examen de la tectonique a affirmé la structure de nappes dans cette région des Alpes Calcaires du Nord. La structure intérieure de la nappe de Lechtal-Decke est caracterisée par une structure écaillée locale, qui se developpe de plis cisaillés.

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70.
The results of a research study of the carbon monoxide concentration from California to 90° S, Antarctica are presented. The data both extend and support other research studies of the latitudinal distribution of carbon monoxide in that higher concentrations are evident over the Northern Hemisphere than over the Southern Hemisphere. Carbon monoxide concentrations range between 50 to 60 ppb with a few peaks into the 60s in the latitudinal area south of the ITCZ and values of 80 ppb or higher at latitudes north of Hawaii. A comparison is also made of carbon monoxide and ozone concentrations along the flight tract between California and Antarctica, over the Ellsworth Mountains of Antarctica, and between 78° S and the South Pole. These ozone-carbon monoxide data show statistically significant negative correlations in the upper troposphere and lower stratosphere over Antarctica. It is believed that this is a good indication of mixing across the tropopause.  相似文献   
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