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61.
J.Michael Moldowan Wolfgang K. Seifert Edward Arnold Jon Clardy 《Geochimica et cosmochimica acta》1984,48(8):1651-1661
Two C28H48-pentacyclic triterpanes were isolated from Monterey shale. X-ray crystallography of a crystal containing both compounds proved their structures as 17β,18α,21α(H)-28,30-bisnorhopane and 17β,18α,21β(H)-28,30-bisnorhopane. Several differences are found between 28,30-bisnorhopanes and the regular hopanes. Unlike the regular hopane epimers, for practical purposes the three epimeric 28,30-bisnorhopanes [17α,21β(H)-, 17β,21α(H)-, and 17β,21β(H)-]cannot be distinguished by their mass spectra. Special conditions are needed to separate them by gas chromatography. The diagenetically first-formed epimer is thought to be 17α,21β(H)- because it predominates in immature shales. The order of thermodynamic stability is 17β,2lα(H) < > 17α,21β(H) > 17β,21β(H), and all three epimers are present in petroleum. 25,28,30-Trisnorhopanes can be analyzed in similar fashion and are found to have similar thermodynamic characteristics. The percent of the ring D/E cis epimer of 28,30-bisnorhopane and/or 25,28,30-trisnorhopane is a useful maturation parameter similar to the 20S/20R sterane ratio. Evidence indicates 25-demethylation of 28,30-bisnorhopane to 25,28,30-trisnorhopane during advanced stages of biodegradation. Hence, percent ring cis 25,28,30-trisnorhopane has an application to maturation assessment in heavily biodegraded oils. 相似文献
62.
Ocean Dynamics - Meeresoptische Messungen auf der Forschungsplattform “Nordsee” haben gezeigt, daß dort während schwerer Stürme, hauptsächlich durch den Einfluß... 相似文献
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65.
Wolfgang Friedrich Müller Yusof Vojdan-Shemshadi Horst Pentinghaus 《Physics and Chemistry of Minerals》1987,14(3):235-237
Transmission electron microscopic study of synthetic CaAl2Ge2O8-feldspar revealed two types of antiphase domains: type “b”-antiphase domains with the displacement vector 1/2 [110] and type “c”-antiphase domains with the displacement vector 1/2 [111]. The “b”-domains were on the order of 0.1 μm in size, while the “c”-domains displayed wall to wall distances mostly between 0.1 and 1 μm. The formation of the two types of antiphase domains is due to reductions in translational symmetry associated with the phase transitions \(C\bar 1 \to I\bar 1 \to P\bar 1\) . The antiphase domain textures of CaAl2Ge2O8-feldspar are very similar to the textures found in natural and synthetic anorthite, CaAl2Si2O8. 相似文献
66.
Karl Brunnacker Manfred Löscher Wolfgang Tillmanns Brigitte Urban 《Quaternary Research》1982,18(2):152-173
Thirteen glacial terraces are known from the western part of the northern Alpine foothills between the Lech and Iller Rivers. In the Lower Rhine region of West Germany, a similar number of terraces are capped by interglacial floodloams and soils. Whereas the environment during individual interglaciations did not differ substantially, the glaciations were progressively more severe. The Main Terrace system of the Rhine may be an exception. The duration of the Quaternary, starting at the base of Praetiglian, is estimated at approximately 2 million yr by paleomagnetic dating. The major cold-warm climatic cycles of the earliest Pleistocene lasted approximately 100,000 yr, the same as those of the Brunhes Chron. The intervening Main Terrace system has not yet been climatically subdivided. Correlation with the Netherlands is possible because of an abundance of paleobotanic and paleomagnetic evidence. In the Alpine foothills, stratigraphically useful indicators of warm climates are missing, but analogies in terrace development permit comparison with the Lower Rhine and Danube. The terrace sequence in the Alpine foothills is incomplete, as are those along most of the other rivers in Europe. Some of the older terraces may have been eroded. 相似文献
67.
Impacts of Present and Future Climate Change and Climate Variability on Agriculture in the Temperate Regions: North America 总被引:2,自引:0,他引:2
The potential impact of climate variability and climate change on agricultural production in the United States and Canada
varies generally by latitude. Largest reductions are projected in southern crop areas due to increased temperatures and reduced
water availability. A longer growing season and projected increases in CO2 may enhance crop yields in northern growing areas. Major factors in these scenarios analyzes are increased drought tendencies
and more extreme weather events, both of which are detrimental to agriculture. Increasing competition for water between agriculture
and non-agricultural users also focuses attention on water management issues. Agriculture also has impact on the greenhouse
gas balance. Forests and soils are natural sinks for CO2. Removal of forests and changes in land use, associated with the conversion from rural to urban domains, alters these natural
sinks. Agricultural livestock and rice cultivation are leading contributors to methane emission into the atmosphere. The application
of fertilizers is also a significant contributor to nitrous oxide emission into the atmosphere. Thus, efficient management
strategies in agriculture can play an important role in managing the sources and sinks of greenhouse gases. Forest and land
management can be effective tools in mitigating the greenhouse effect. 相似文献
68.
Cosmas Kongnyuy Shang Muharrem Satir Emmanuel Nkonguin Nsifa Jean-Paul Liégeois Wolfgang Siebel Heiner Taubald 《International Journal of Earth Sciences》2007,96(5):817-841
We present a geochemical and isotopic study that, consistent with observed field relations, suggest Sangmelima late Archaean
high-K granite was derived by partial melting of older Archaean TTG. The TTG formations are sodic-trondhjemitic, showing calcic
and calc-alkalic trends and are metaluminous to peraluminous. High-K granites in contrast show a potassic calc-alkaline affinity
that spans the calcic, calc-alkalic, alkali-calcic and alkalic compositions. The two rock groups (TTG and high-K granites)
on the other hand are both ferroan and magnesian. They have a similar degree of fractionation for LREE but a different one
for HREE. Nd model ages and Sr/Y ratios define Mesoarchaean and slab-mantle derived magma compositions respectively, with
Nb and Ti anomalies indicating a subduction setting for the TTG. Major and trace element in addition to Sr and Nd isotopic
compositions support field observations that indicate the derivation of the high-K granitic group from the partial melting
of the older TTG equivalent at depth. Geochemical characteristics of the high-K granitic group are therefore inherited features
from the TTG protolith and cannot be used for determining their tectonic setting. The heat budget required for TTG partial
melting is ascribed to the upwelling of the mantle marked by a doleritic event of identical age as the generated high-K granite
melts. The cause of this upwelling is related to linear delamination along mega-shear zones in an intracontinental setting. 相似文献
69.
Unnaturally high hydraulic gradients below dam sites enhance dissolutional widening of fractures in limestone. A model is
presented which suggests that under unfavorable conditions, leakage rates could become unbearably high during the lifetime
of the dam. At the beginning when water is impounded, leakage rates are low and increase slowly. A positive feedback loop,
however, causes a sudden dramatic increase of leakage within a few years. Deep grouting becomes necessary to prevent such
failures. Inefficiencies in grouting may leave some open fractures in the grouting curtain. These fractures widen faster than
pathways below the grouting curtain, and reduce the effect of the grouted region located below. Therefore, open fractures
act in a similar way as reduction of the grouting depth. 相似文献
70.
Fukun Chen Xiang-Hui Li Xiu-Li Wang Qiu-Li Li Wolfgang Siebel 《International Journal of Earth Sciences》2007,96(6):1179-1194
The Baoshan block of the Tethyan Yunnan, southwestern China, is considered as northern part of the Sibumasu microcontinent.
Basement of this block that comprises presumably greenschist-facies Neoproterozoic metamorphic rocks is covered by Paleozoic
to Mesozoic low-grade metamorphic sedimentary rocks. This study presents zircon ages and Nd–Hf isotopic composition of granites
generated from crustal reworking to reveal geochemical feature of the underlying basement. Dating results obtained using the
single zircon U–Pb isotopic dilution method show that granites exposed in the study area formed in early Paleozoic (about
470 Ma; Pingdajie granite) and in late Yanshanian (about 78–61 Ma, Late Cretaceous to Early Tertiary; Huataolin granite).
The early Paleozoic granite contains Archean to Mesoproterozoic inherited zircons and the late Yanshanian granite contains
late Proterozoic to early Paleozoic zircon cores. Both granites have similar geochemical and Nd–Hf isotopic charateristics,
indicating similar magma sources. They have whole-rock T
DM(Nd) values of around 2,000 Ma and zircon T
DM(Hf) values clustering around 1,900–1,800 and 1,600–1,400 Ma. The Nd–Hf isotopic data imply Paleoproterozoic to Mesoproterozoic
crustal material as the major components of the underlying basement, being consistent with a derivation from Archean and Paleoproterozoic
terrains of India or NW Australia. Both granites formed in two different tectonic events similarly originated from intra-crustal
reworking. Temporally, the late Yanshanian magmatism is probably related to the closure of the Neotethys ocean. The early
Paleozoic magmatism traced in the Baoshan block indicates a comparable history of the basements during early Paleozoic between
the SE Asia and the western Tethyan belt, such as the basement outcrops in the Alpine belt and probably in the European Variscides
that are considered as continental blocks drifting from Gondwana prior to or simultaneously with those of the SE Asia. 相似文献