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111.
偏振激发能量色散X荧光法在地球化学分析中应用及其与波长色散X荧光法的比较 总被引:1,自引:0,他引:1
偏振激发能量色散X射线荧光光谱(P-EDXRF)技术是20世纪末出现的新分析技术。国内采用X-Lab2000型仪器的初步研究表明,在总计数时间为600秒时,可以对近30种元素进行定量,检出限为0.5-30μg/g,与国际上发表的文献值基本一致。本工作通过约100个实际样品分析,并与波长色散X射线荧光法(WDXRF)分析结果的比较,对P-EDXRF的分析性能进行了评价。与WDXRF相比,P-EDXRF法具有分析速度快、设备购置费用低、运行成本低、全谱同时采集(有利于发现元素含量异常)等优点,因此特别适合地球化学填图样品的快速分析。而WDXRF在精度要求较高的分析中更具竞争力。 相似文献
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介绍了东海大桥钻孔灌注桩基础的施工技术 ,对一些关键技术做了详细说明 ,还讨论了海上钻孔灌注桩施工成孔设备的选择及所用的淡水泥浆的配制 相似文献
115.
Irregularly shaped (IRS) particles widely exist in many engineering and industrial fields. The macro physical and mechanical properties of the particle system are governed by the interaction between the particles in the system. The interaction between IRS particles is more complicated because of their complex geometric shape with extremely irregular and co‐existed concave and convex surfaces. These particles may interlock each other, making the sliding and friction of IRS particles more complex than that of particles with regular shape. In order to study the interaction of IRS particles more efficiently, a refined method of constructing discrete element model based on computed tomography scanning of IRS particles is proposed. Three parameters were introduced to control the accuracy and the number of packing spheres. Subsequently, the inertia tensor of the IRS particle model was optimized. Finally, laboratory and numerical open bottom cylinder tests were carried out to verify the refined modeling method. The influence of particle shape, particle position, and mesoscopic friction coefficient on the interaction of particles was also simulated. It is noteworthy that with the increase of mesoscopic friction coefficient, the fluidity of IRS particle assembly decreases, and intermittent limit equilibrium state may appear. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
116.
Fan Zhang Xiong Xiao Lijie Wang Chen Zeng Zhengliang Yu Guanxing Wang Xiaonan Shi 《水文研究》2021,35(8):e14330
Climate factors play critical roles in controlling chemical weathering, while chemically weathered surface material can regulate climate change. To estimate global chemical weathering fluxes and CO2 balance, it is important to identify the characteristics and driving factors of chemical weathering and CO2 consumption on the Tibetan Plateau, especially in glaciated catchments. The analysis of the hydro-geochemical data indicated that silicate weathering in this area was inhibited by low temperatures, while carbonate weathering was promoted by the abundant clastic rocks with fresh surfaces produced by glacial action. Carbonate weathering dominated the riverine solute generation (with a contribution of 58%, 51%, and 43% at the QiangYong Glacier (QYG), the WengGuo Hydrological Station (WGHS), and the lake estuary (LE), respectively). The oxidation of pyrite contributed to 35%, 42%, and 30% of the riverine solutes, while silicate weathering contributed to 5%, 6%, and 26% of the riverine solutes at the QYG, WGHS, and LE, respectively. The alluvial deposit of easily weathering fine silicate minerals, the higher air temperature, plant density, and soil thickness at the downstream LE in comparison to upstream and midstream may lead to longer contact time between pore water and mineral materials, thus enhancing the silicate weathering. Because of the involvement of sulfuric acid produced by the oxidation of pyrite, carbonate weathering in the upstream and midstream did not consume atmospheric CO2, resulting in the high rate of carbonate weathering (73.9 and 75.6 t km−2 yr−1, respectively, in maximum) and potential net release of CO2 (with an upper constraint of 35.6 and 35.2 t km−2 yr−1, respectively) at the QYG and WGHS. The above results indicate the potential of the glaciated area of the Tibetan Plateau with pyrite deposits being a substantial natural carbon source, which deserves further investigation. 相似文献
117.
New magnetostratigraphic and pedostratigraphic investigations of loess deposits in north‐east China and their implications for regional environmental change during the Mid‐Pleistocene climatic transition 下载免费PDF全文
118.
Efficient estimation of flood forecast prediction intervals via single‐ and multi‐objective versions of the LUBE method 下载免费PDF全文
Lei Ye Jianzhong Zhou Hoshin V. Gupta Hairong Zhang Xiaofan Zeng Lu Chen 《水文研究》2016,30(15):2703-2716
Prediction intervals (PIs) are commonly used to quantify the accuracy and precision of a forecast. However, traditional ways to construct PIs typically require strong assumptions about data distribution and involve a large computational burden. Here, we improve upon the recent proposed Lower Upper Bound Estimation method and extend it to a multi‐objective framework. The proposed methods are demonstrated using a real‐world flood forecasting case study for the upper Yangtze River Watershed. Results indicate that the proposed methods are able to efficiently construct appropriate PIs, while outperforming other methods including the widely used Generalized Likelihood Uncertainty Estimation approach. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
119.
Piecewise prediction model for watershed‐scale erosion and sediment yield of individual rainfall events on the Loess Plateau,China 下载免费PDF全文
Yu Guo‐Qiang Zhang Mao‐Sheng Li Zhan‐Bin Li Peng Zhang Xia Cheng Sheng‐Dong 《水文研究》2014,28(21):5322-5336
Establishing a universal watershed‐scale erosion and sediment yield prediction model represents a frontier field in erosion and soil/water conservation. The research presented here was conducted on the Chabagou watershed, which is located in the first sub‐region of the hill‐gully area of the Loess Plateau, China. A back‐propagation artificial neural model for watershed‐scale erosion and sediment yield was established, with the accuracy of the model, then compared with that of multiple linear regression. The sensitivity degree of various factors to erosion and sediment yield was quantitatively analysed using the default factor test. On the basis of the sensitive factors and the fractal information dimension, the piecewise prediction model for erosion and sediment yield of individual rainfall events was established and further verified. The results revealed the back‐propagation artificial neural network model to perform better than the multiple linear regression model in terms of predicting the erosion modulus, with the former able to effectively characterize dynamic changes in sediment yield under comprehensive factor conditions. The sensitivity of runoff erosion power and runoff depth to the erosion and sediment yield associated with individual rainfall events was found to be related to the complexity of surface topography. The characteristics of such a hydrological response are thus closely related to topography. When the fractal information dimension is greater than the topographic threshold, the accuracy of prediction using runoff erosion power is higher than that of using runoff depth. In contrast, when the fractal information dimension is smaller than the topographic threshold, the accuracy of prediction using runoff depth is higher than that of using runoff erosion power. The developed piecewise prediction model for watershed‐scale erosion and sediment yield of individual rainfall events, which introduces runoff erosion power and runoff depth using the fractal information dimension as a boundary, can be considered feasible and reliable and has a high prediction accuracy. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
120.
The effect of expansion ratio on the critical Reynolds number in single fracture flow with sudden expansion 下载免费PDF全文
Flow in a single fracture (SF) is an important research subject in groundwater hydrology, hydraulic engineering, radioactive nuclear waste repository and geotechnical engineering. An abruptly changing aperture is a unique type of SF. This study discusses the relation between the values of the critical Reynolds number (Rec) for the onset of symmetry breaking of flow and the expansion ratio (E) of SF, which is defined as the ratio between the outlet (D) and inlet (d) apertures. This study also investigates the effect of inlet aperture d on Rec for flow in an SF with abruptly changing apertures (SF‐ACA) using the finite volume method. Earlier numerical and experimental results showed that flow is symmetric in respect to the central plane of the SF‐ACA at small Reynolds number (Re) but becomes asymmetric when Re is sufficiently large. Our simulations show that the value of Rec decreases with the increasing E, and the relationship between the logarithm of Rec and E can be described accurately using either a quadratic polynomial function or a logarithmic function. However, the relationship of Rec and d for a given E value is vague, and Rec becomes even less sensitive to d when E increases. This study also reveals that the hydraulic gradient (J) and flow velocity (v) follow a super‐linear relationship that can be fitted almost perfectly by the Forchheimer equation. The inertial component (Ji) of J increases monotonically with Re, whereas the viscous component (Jv) of J decreases monotonically with Re. The Re value corresponding to equal inertial and viscous components of J (named as the transitional point Re) decreases when E increases, and such a transitional point Re should be closely related to the critical Reynolds number Rec, although a rigorous theoretical proof is not yet available. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献