某污染场地土壤苯并(a)芘含量的三维估值及不确定性分析   总被引：3，自引：0，他引：3  

陶欢  廖晓勇  阎秀兰  赵丹  马栋  李鹏 《地理研究》2014,33(10):1857-1865

污染场地修复前的准确评估是开展场地修复行动的基础和前提。建立了一套评估污染场地中污染土方量的三维插值方法,采用该方法模拟了某污染场地土壤苯并(a)芘(BaP)含量的空间分布并分析其不确定性。结果表明：场地地下环境中BaP含量数据服从对数正态分布,土壤中污染严重区域分别位于研究区的西南部和北部。通过普通克里格插值得到的BaP浓度超过0.4 mg·kg^-1的污染羽体积为14134 m³,对应的累积概率为0.585。依据给定变差范围值计算,得出现有收集数据对整个场地的描述程度为65%。基于该三维插值方法能准确地反映场地污染物空间分布特征,其不确定性分析可为补充采样布点及精准评估提供参考。  相似文献   

关中盆地地下水系统分析与地下水资源可持续开发利用对策   总被引：8，自引：2，他引：6       下载免费PDF全文

张茂省  朱立峰  王晓勇 《第四纪研究》2005,25(1):15-22

关中盆地是一个完整的、相对独立的地下水系统,按含水介质的结构组合与空间分布以及地下水循环特 征,文章将关中盆地地下水系统进一步划分为黄土台塬孔隙$C裂隙含水系统、冲积平原孔隙含水系统、秦岭山前洪 积平原孔隙含水系统、渭北岩溶含水系统及基岩裂隙含水系统共5个亚系统和26个更次一级的子系统。在研究 各子系统水文地质特征、分析水资源开发利用现状的基础上,认为区内地下水资源开发利用中存在的问题有:地下 水资源污染与浪费严重,重复利用率低;不合理开采地下水,出现负环境效应;行政区块限制,水资源宏观调配不 够;地下水人工调控力度不够,不能有效地促进生态环境良性循环;对地下水资源的研究、规划和管理滞后等方面。 并针对存在的主要问题,提出了5项水资源可持续开发利用对策,包括节水对策、开源对策、改水对策、增补对策以 及管理对策。  相似文献   

浙江富硒土壤资源调查与评价   总被引：26，自引：0，他引：26       下载免费PDF全文

郦逸根  董岩翔  郑洁  李琰  吴小勇  朱朝晖 《第四纪研究》2005,25(3):323-330

浙江省农业地质环境调查发现,浙北、浙东、浙中地区富硒土壤呈大面积分布。不同类型土壤中,以石灰岩土硒含量最高,黄壤和红壤硒含量次之;不同类型成土母质中,以残坡积物硒含量相对较高;不同类型岩石中,以石英砂岩、硅质岩和中深变质岩硒含量较高,高于中国东部地壳丰度值。富硒土壤主要分布于富硒岩石和煤系地层区。硒多富集在土壤表层,由地表向深部含量迅速下降。根据土壤背景值和硒生态景观分级标准,建立了富硒土壤评价标准,划分硒含量等级区,圈定了浙江省富硒土壤分布。  相似文献   

Denudation History of South China Block and Sediment Supply to Northern Margin of the South China Sea   总被引：1，自引：0，他引：1  

Yan Yi  Hu Xiaoqiong  Lin Ge  Xia Bin  Li Xiaoyong  Remesh Chandra Patel 《中国地质大学学报(英文版)》2009,20(1)

On the basis of apatite fission track (AFT) analyses,this article aims to provide a quantitative overview of Cenozoic morphotectonic evolution and sediment supply to the northern margin of the South China Sea (SCS).Seventeen granite samples were collected from the coast to the inland of the South China block.Plots of AFT age against sample location with respect to the coastline show a general trend of youngling age away from the coast,which implies more prolonged erosion and sediment contribution at the inland of the South China Sea during post break-up evolution.Two-stage fast erosion process,Early Tertiary and Middle Miocene,is deduced from simulated cooling histories.The first fast cooling and denudation during Early Tertiary are recorded by the samples along the coast (between 70 and 60 Ma) and the inland (between 50 and 30 Mu),respectively.This suggests initial local erosion and deposition in the northern margin of the SCS during Early Tertiary.Fast erosion along the coast ceased since ca.50 Ma,while it had lasted until ca.30 Ma inland,indicating that the erosion was transferred from the local coastal zone initially toward the continental interior with unified subsidence of the northern margin,which resulted in the formation of a south-dipping topography of the continental margin.The thermal stosis in the South China block since ca.30 Mu must det'me the time at which the northern margin became dynamically disconnected from the active rifting and stretching that was taking place to the south.The lower erosion rate is inconsistent with higher sedimentary rate in the Pearl River Mouth basin during Late Oligocene (ca.25 Ma).This indicates that the increased sedimentation in the basin is not due to the erosion of the granite belt of the South China block,but perhaps points to the westward propagation of the paleo-Pearl River drainage related to the uplift of the eastern margin of Tibet plateau and southward jumping of spreading axis of the South China Sea.The socond erosion acceleration rate of the Middle Miocene (ca.14 Ma) cooling could have been linked to the long-distance effect of uplift of the Tibet plateau or due to the enhanced East Asian monsoon.  相似文献   

Distribution of dissolved inorganic nitrogen over the continental slope of the Yellow Sea and East China Sea     

张璇  石晓勇  温婷婷  张传松  韩秀荣 《中国海洋湖沼学报》2013,31(1):227-236

Based on survey data from April to May 2009, distribution and its influential factors of dissolved inorganic nitrogen (DIN) over the continental slopes of the Yellow Sea (YS) and East China Sea (ECS) are discussed. Influenced by the Changjiang (Yangtze) River water, alongshore currents, and the Kuroshio current off the coast, DIN concentrations were higher in the Changjiang River estuary, but lower (<1 μmol/L) in the northern and eastern YS and outer continental shelf area of the ECS. In the YS, the thermocline formed in spring, and a cold-water mass with higher DIN concentration (about 11 μmol/L) formed in benthonic water around 123.2°E. In Changjiang estuary (around 123°E, 32°N), DIN concentration was higher in the 10 m layer; however, the bottom DIN concentration was lower, possibly influenced by mixing of the Taiwan Warm Current and offshore currents.  相似文献   

Fluorescence discrimination and determination technique for phytoplankton composition by Coif2 wavelet packet     

DUAN Yali  SU Rongguo  SHI Xiaoyong  WANG Xiulin  ZHU Chenjian  SUN Yan 《中国海洋大学学报(英文版)》2013,12(1):53-62

An in vivo fluorescence discrimination technique for phytoplankton population was developed by using Wavelet packet transform, cluster analysis and non-negative least squares. The technique was used to analyze water samples from different sea regions. For simulative mixtures, when dominant species account for 60%, 70%, 80%, 90% at the division level, the correct discrimination ratios (CDRs) are 83.0%, 99.1%, 99.7% and 99.9% with the relative contents of 58.5%, 68.4%, 77.7% and 86.3%, respectively; when the algae dominance are 60%, 70%, 80%, 90%, 100% at the genus level, the CDRs are 86.1%, 94.9%, 95.2%, 96.8% and 96.7%, respectively. For laboratory mixtures, the CDRs are 88.1% and 78.4% at the division and genus level, respectively. For field samples, the CDRs were 91.7% and 80% at the division and genus level, respectively (mesocosm experiments), and the CDRs were 100% and 66.7% at the division and genus level, respectively (Jiaozhou Bay). The fluorometric technique was used to estimate the phytoplankton community composition and relative abundance of different classes for the April 2010 cruise in the Yellow Sea with the results agreeing with those in published papers by other authors.  相似文献   

湘江中下游农田土壤和蔬菜的重金属污染   总被引：11，自引：0，他引：11  

王莉霞  郭朝晖  肖细元  陈同斌  廖晓勇  宋杰  武斌 《地理学报(英文版)》2008,18(3):353-362

A total of 219 agricultural soil and 48 vegetable samples were collected from the midstream and downstream of the Xiangjiang River（the Hengyang-Changsha section）in Hunan Province.The accumulation characteristics,spatial distribution and potential risk of heavy metals in the agricultural soils and vegetables were depicted.There are higher accumulations of heavy metals such as As,Cd,Cu,Ni,Pb and Zn in agricultural soils,and the contents of Cd（2.44 mg kg^-1 ）,Pb（65.00 mg kg^-1 ）and Zn（144.13 mg kg^-1 ）are 7.97,3.69 and 1.63 times the corresponding background contents in soils of Hunan Province,respectively. 13.2%of As,68.5%of Cd,2.7%of Cu,2.7%of Ni,8.7%of Pb and 15.1%of Zn in soil samples from the investigated sites exceeded the maximum allowable heavy metal contents in the China Environmental Quality Standard for Soils（GB15618-1995,Grade Ⅱ）.The pollution characteristics of multi-metals in soils are mainly due to Cd.The contents of As,Cd,Cu,Pb and Zn in vegetable soils are significantly higher than the contents in paddy soils.95.8%, 68.8%,10.4%and 95.8%of vegetable samples exceeded the Maximum Levels of Contaminants in Foods（GB2762-2005）for As,Cd,Ni and Pb concentrations,respectively.There are significantly positive correlations between the concentrations of Cd,Pb and Zn in vegetables and the concentrations in the corresponding vegetable soils（p〈0.01）.It is very necessary to focus on the potential risk of heavy metals for food safety and human health in agricultural soils and vegetables in the midstream and downstream of the Xiangjiang River,Hunan Province of China.  相似文献   

中国东部玄武岩风化土壤的粘土矿物及碳 汇地球化学研究     

都凯  陈旸  季峻峰  李慧  龙晓泳  陈骏 《高校地质学报》2012,18(2):256-272

     玄武岩风化是大气CO2 的一个主要碳汇过程,气候条件是影响玄武岩风化和固碳速率的重要因素。该文选择中国东 部不同气候带的新生代玄武岩典型风化剖面,进行了粘土矿物和常量元素分析。结果显示,在内蒙古-海南岛的采样区间内, 随着气候条件由干冷向暖湿转化,风化剖面中粘土矿物组合呈现蒙脱石+ 伊利石+ 高岭石→蒙脱石+ 高岭石→高岭石+ 三水 铝石的转变。剖面中土壤元素得失状况也显示出相应的规律,由于存在粉尘输入与风化淋滤作用的综合影响,在干冷的内 蒙古地区,粉尘对于Ca,K,Na,Si 等元素的输入量大于这些元素的淋失量;在山东地区,Ca,K,Na 元素开始快速淋失, 大于粉尘的输入量;在苏皖地区,Si 元素的淋失量开始小于粉尘输入量;而在湿热的海南地区,风化作用强烈,Si显示出 大量淋失的特点,碱性元素几乎全部流失。根据元素的相对得失率和北方粉尘平均组分的校正,初步估算了研究区内玄武 岩风化对大气CO2 的消耗速率,其数值在5.37~181.00 t（km2·a）之间,与Dessert 等（2003）的研究结果大致相当。  相似文献   

陕西汉中梁山二叠系乐平统底部吴家坪组王坡页岩新认识   总被引：5，自引：0，他引：5  

郭俊锋  宋祖晨  肖良  李相传  郑亚娟  姚肖永  周雪柔 《地质论评》2017,63(5):1169-1179

陕西汉中梁山瓜德鲁普统—乐平统界线(GLB)附近的吴家坪组底部王坡页岩段长期以来被认为是古风化壳沉积,代表了茅口期后暴露于地表风化剥蚀的产物。最近对该地层进行了重新研究,采集了系列岩石和化石样品,进行了X射线衍射、古生物学、岩相学和岩石学分析。X射线衍射分析表明该粘土层主要矿物成分为蒙脱石71%,片沸石23%,石英6%,暗示其物质来源于火山玻璃。岩相学分析显示岩石主要由蚀变矿物组成,具有蚀变残留玻屑凝灰质结构,其中蒙脱石、片沸石保留了原岩中的玻屑的塑性形态。粘土层中大量腕足动物化石暗示其为海相环境。研究结果表明王坡页岩是典型的斑脱岩,并非风化壳和长期剥蚀的产物,而是峨眉山大火成岩省火山喷发时火山灰在海相环境下沉积、蚀变的产物。火山灰在正常浅海沉积时对海洋生态系统造成严重破坏,导致了包括腕足动物在内的海洋生物的生存危机。  相似文献   

Geological and Geochemical Constraints on the Newly Discovered Yangchongli Gold Deposit in Tongling Region, Lower Yangtze Metallogenic Belt   总被引：3，自引：0，他引：3  

DUAN Liu’an  GU Huangling  YANG Xiaoyong 《《地质学报》英文版》2017,91(6):2078-2108

The newly discovered Yangchongli gold deposit is a unique independent gold deposit in the Tongling ore-cluster region controlled by the tectonic alteration firstly discovered in the Lower Yangtze Metallogenic Belt(LYMB). The host magmatic rocks mainly consist of monzodiorite and K-feldspar granite. The LA-ICP-MS U-Pb zircons dating yielded weighted mean ~(206)Pb/~(238)U ages of 140.7 ± 1.8 Ma and 126.4 ± 1.2 Ma for the monzodiorite and K-feldspar granite, respectively. Monzodiorites are enriched in Sr, Ba, Rb, and depleted in Y, Yb with high Sr/Y and La/Yb ratios, similar to the geochemical features of adakite, considered as products of differentiation of mafic magmas originating from lithospheric mantle melt/fluids caused by metasomatism during paleo-Pacific Plate subduction in the Mesozic. In contrast, the compositions of K-feldspar granites are A-type granites, indicating an extensional tectonic background. Gold ores hosted in the fracture zone occurred as quartz vein within cataclastic rock. Sulfur and lead isotopes from pyrites show crust-mantle mixing characteristics. Metal components from strata also took part in the gold mineralization, and resulted from two episodes of magmatism that were probably related to tectonic transition from a compressive to an extensional setting between 140–126 Ma, which led to the Mesozoic large-scale polymetallic mineralization events in eastern China.  相似文献