Nb–Ta fractionation induced by fluid‐rock interaction in subduction‐zones: constraints from UHP eclogite‐ and vein‐hosted rutile from the Dabie orogen,Central‐Eastern China     

J. HUANG  Y. XIAO  Y. GAO  Z. HOU  W. WU 《Journal of Metamorphic Geology》2012,30(8):821-842

Niobium and Ta concentrations in ultrahigh‐pressure (UHP) eclogites and rutile from these eclogites and associated high pressure (HP) veins were used to study the behaviour of Nb–Ta during dehydration and fluid‐rock interaction. Samples were collected through a ～2 km profile at the Bixiling complex in the Dabie orogenic belt, Central‐Eastern China. All but one eclogite away from veins (EAVs) display nearly constant Nb/Ta ratios ranging from 16.1 to 19.2, with an average of 16.9 ± 0.8 (2 SE), similar to that of their gabbroic protolith from the Yangtze Block. Nb/Ta ratios of rutile from the EAVs range from 12.7 to 25.3 among different individual grains, with the average values close to those of the corresponding bulk rocks. These observations show that Nb and Ta were not significantly fractionated by prograde metamorphism up to eclogite facies when no significant fluid‐rock interaction occurs. In contrast, Nb/Ta ratios of rutile from eclogites close to veins (ECVs) are highly variable from 17.8 to 49.8, which are systematically higher (by up to 17) than those of rutile from the veins. These observations demonstrate that Nb and Ta were mobilized and fractionated during localized fluid flow and intensive fluid‐rock interaction. This is strongly supported by Nb/Ta zoning patterns in single rutile grains revealed by in situ LA‐ICP‐MS analysis. Ratios of Nb/Ta in the ECV‐hosted rutile decrease gradually from cores towards rims, whereas those in the EAV‐hosted rutile are nearly invariable. Furthermore, the vein rutile shows Nb/Ta zoning patterns that are complementary to those in rutile from their immediate hosts (ECVs), suggesting an internal origin for the vein‐forming fluids. The Nb/Ta ratios of such fluids evolved from low values at the early stage of subduction to higher values at later supercritical conditions with increased temperature and pressure. Quantitative modelling was conducted to constrain the compositional evolution of metamorphic fluids during dehydration and fluid‐rock interaction focusing on Nb–Ta distribution. The modelling results based on our proposed multistage fluid phase evolution path can essentially reproduce the natural observations reported in the present study.  相似文献   

Holocene cool‐water carbonate and terrigenous sediments from southern Spencer Gulf,South Australia     

M. K. Fuller  Y. Bone  V. A. Gostin  C. C. Von Der Borch 《Australian Journal of Earth Sciences》2013,60(4):353-363

Holocene sediments from southern Spencer Gulf are cool‐water carbonate‐rich gravels and sands, dominated by molluscs and Bryozoa. Five sedimentary fades are recognized: (i) molluscan gravel; (ii) branching coralline‐algal gravel, associated with shallow partially protected environments; (iii) molluscan‐biyozoan sand; (iv) mixed bioclastic sand, representative of the deeper central region of the lower gulf; and (v) bryozoan gravel, an isolated fades developed in a semi‐protected micro‐environment. The southern gulf is characterized by complex oceanographic conditions together with variations in water depth and substrate. The sediments share the characteristics of both the southern shelf and upper Spencer Gulf. Grain‐size distribution and sedimentary facies are controlled by a combination of all the above processes. Past sea level fluctuations are recognized from sea floor strand‐line deposits. The relic component of the palimpsest sediments has eroded from the Pleistocene aeolianite dunes. The sediments, therefore, reflect both the modern marine and past environments.  相似文献   

Estimation of land surface evapotranspiration over the Heihe River basin based on the revised three‐temperature model     

Xinping Luo  Keli Wang  Hao Jiang  Jia Sun  Qingliang Zhu 《水文研究》2012,26(8):1263-1269

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Stage level,volume and time‐frequency information content of Lake Tana using stochastic and wavelet analysis methods     

Y. Chebud  A. Melesse 《水文研究》2013,27(10):1475-1483

Lake Tana is the largest fresh water body situated in the north‐western highlands of Ethiopia. In addition to its ecological services, it serves for local transport, electric power generation, fishing, recreational purposes, and source of dry season irrigation water supply. Evidence shows that the lake has dried at least once at about 15,000–17,000 before present owing to a combination of high evaporation and low precipitation events. Past attempts to understand and simulate historical fluctuation of Lake Tana based on simplistic water balance approach of inflow, outflow, and storage have failed to capture well‐known events of drawdown and rise of the lake that have happened in the last 44 years. This study tested different stochastic methods of lake level and volume simulation for supporting Lake Tana operational planning decision support. Three stochastic methods (perturbations approach, Monte Carlo methods, and wavelet analysis) were employed for lake level and volume simulation, and the results were compared with the stage level measurements. Forty‐four years of daily, monthly, and mean annual lake level data have shown a Gaussian variation with goodness of fit at 0.01 significant levels of the Kolmogorov–Smirnov test. The stochastic simulations predicted the lake stage level of the 1972, 1984, and 2002/2003 historical droughts 99% of the time. The information content (frequency) of fluctuation of Lake Tana for various periods was resolved using Wigner's Time‐Frequency Decomposition method. The wavelet analysis agreed with the perturbations and Monte Carlo simulations resolving the time (1970s, 1980s, and 2000s) in which low frequency and high spectral power fluctuation has occurred. The Monte Carlo method has shown its superiority for risk analysis over perturbation and deterministic method whereas wavelet analysis reconstructed historical record of lake stage level at daily and monthly time scales. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Trace‐element signatures of apatites in granitoids from the Mt Isa Inlier,northwestern Queensland     

E. A. Belousova  S. Walters  W. L. Griffin  S. Y. O'Reilly 《Australian Journal of Earth Sciences》2013,60(4):603-619

The concentrations of trace elements in apatite from granitoid rocks of the Mt Isa Inlier have been investigated using the laser‐ablation inductively coupled plasma‐mass spectrometry (ICP‐MS) microprobe. The results indicate that the distribution of trace elements (especially rare‐earth elements (REE), Sr, Y, Mn and Th) in apatite strongly reflects the chemical characteristics of the parental rock. The variations in the trace‐element concentrations of apatite are correlated with parameters such as the SiO₂ content, oxidation state of iron, total alkalis and the aluminium saturation index (ASI). The relative enrichment of Y, HREE and Mn and the relative depletion of Sr in the apatites studied reflect the degree of fractionation of the host granite. Apatites from strongly oxidised plutons tend to have higher concentrations of LREE relative to MREE. Manganese concentrations are higher in apatite from reduced granitoids because Mn²⁺substitutes directly for Ca²⁺. The La/Ce ratio of apatite is well‐correlated with the whole‐rock K²O and Na²O contents, as well as with the oxidation state and ASI. Because apatite trace‐element composition reflects the chemistry of the whole rock, it can be a useful indicator mineral for the recognition of mineralised granite suites, where particular mineralisation styles are associated with granitoids that have specific geochemical fingerprints.  相似文献   

Geodynamic modelling of the Century deposit,Mt Isa Province,Queensland     

A. Ord  B. E. Hobbs  Y. Zhang  G. C. Broadbent  M. Brown  G. Willetts 《Australian Journal of Earth Sciences》2013,60(6):1011-1039

This paper is concerned with an example of quantitative modelling of orebody formation as a guide to reducing the risk for future mineral exploration. Specifically, the paper presents a detailed 3–D numerical model for the formation of the Century zinc deposit in northern Queensland. The model couples fluid flow with deformation, thermal transport and chemical reactions. The emphasis of the study is a systems approach where the holistic mineralising system is considered rather than concentrating solely on the mineral deposit. In so doing the complete plumbing system for mineralisation is considered with a view to specifying the critical conditions responsible for the ore deposit occurring where it does and having the size and metal grades that are observed. The numerical model is based on detailed geological, tectonic, isotopic and mineralogical data collected over the past 20 years. The conclusions are that the Century zinc deposit is located where it is because of the following factors: (i) a thermal anomaly is associated with the Termite Range Fault due to advection of heat from depth by fluid flow up the Termite Range Fault; (ii) bedding‐plane fissility in the shale rocks hosting the Century zinc deposit has controlled the wavelength and nature of D₁ folding in the vicinity of the deposit and has also controlled increases in permeability due to hydrofracture of the shales; such hydrofracture is also associated with the production of hydrocarbons as these shales passed through the ‘oil‐window’; (iii) Pb–Zn leached from crustal rocks in the stratigraphic column migrated up along faults normal to the Termite Range Fault driven by topographic relief associated with inversion at the end of the Isan Orogeny; these fluids mixed with H₂S derived at depth moving up the Termite Range Fault to mix with the crustal fluids to precipitate Pb–Zn in a plume downstream from the point of mixing. Critical factors to be used as exploration guides are high temperatures, carbonaceous fissile shales now folded into relatively tight D₁ folds, fault‐controlled plumbing systems that enable fluid mixing, depletion of metals upstream of the deposit and,in particular,a very wide Fe‐depletion halo upstream of the deposit.  相似文献   

Constitutive approach for rate‐sensitive anisotropic structured clays     

Sean D. Hinchberger  Guangfeng Qu  K. Y. Lo 《国际地质力学数值与分析法杂志》2010,34(17):1797-1830

This paper describes a constitutive approach to model the behavior of rate‐dependent anisotropic structured clay. Rate‐sensitivity is modeled using overstress viscoplasticity. Clay structure is treated as a viscous phenomenon whereby the viscosity of the undisturbed structured clay is initially very high and the viscosity degrades or decreases with plastic straining until the intrinsic or residual viscosity is reached. A microstructure tensor approach is used to make the structured viscosity anisotropic; whereas, the intrinsic viscosity is assumed to be isotropic. The behavior of the constitutive model is compared with the measured response of two clays (Gloucester and St. Vallier clay) from Eastern Canada during triaxial compression tests on specimens trimmed at different orientations to the vertical. The comparisons show that the constitutive framework is able to describe the anisotropic and rate‐sensitive response of both clays. The response of the model is also examined for the more general case of anisotropic consolidated triaxial compression and extension. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Wave attenuation in the marginal ice zone during LIMEX     

Antony K. Liu  Paris W. Vachon  Chin Y. Peng  A.S. Bhogal 《大气与海洋》2013,51(2):192-206

Abstract

During the Labrador Ice Margin Experiments, LIMEX ‘87 in March 1987 and LIMEX ‘89 in March and April 1989, the Canada Centre for Remote Sensing (CCRS) CV‐580 aircraft collected synthetic aperture radar (SAR) image data over the marginal ice zone off the east coast of Newfoundland, Canada. One aspect of these experimental programs was the observation of ocean waves penetrating into the marginal ice zone (MIZ). Based upon directional wavenumber spectra derived from SAR image data, the wave attenuation rate is estimated using SAR image spectra and compared with predictions from a model developed by Liu and Mollo‐Christensen (1988). The wave and ice conditions were considerably different in LIMEX ‘87 and LIMEX ‘89. However, the model‐data comparisons are very good for all ice conditions observed. Both the model and the SAR‐derived wave attenuation rates show a characteristic roll‐over at high wavenumbers. A model for the eddy viscosity is proposed, using dimensional analysis, as a simple function of ice roughness and wave‐induced velocity. Eddy viscosities derived from SAR and wave buoy data for the wave attenuation rate show a trend that is consistent with the proposed model.  相似文献   

Statistically downscaled probabilistic multi‐model ensemble projections of precipitation change in a watershed     

Muhammad Z. Hashmi  Asaad Y. Shamseldin  Bruce W. Melville 《水文研究》2013,27(7):1021-1032

This paper presents the development of a probabilistic multi‐model ensemble of statistically downscaled future projections of precipitation of a watershed in New Zealand. Climate change research based on the point estimates of a single model is considered less reliable for decision making, and multiple realizations of a single model or outputs from multiple models are often preferred for such purposes. Similarly, a probabilistic approach is preferable over deterministic point estimates. In the area of statistical downscaling, no single technique is considered a universal solution. This is due to the fact that each of these techniques has some weaknesses, owing to its basic working principles. Moreover, watershed scale precipitation downscaling is quite challenging and is more prone to uncertainty issues than downscaling of other climatological variables. So, multi‐model statistical downscaling studies based on a probabilistic approach are required. In the current paper, results from the three well‐reputed statistical downscaling methods are used to develop a Bayesian weighted multi‐model ensemble. The three members of the downscaling ensemble of this study belong to the following three broad categories of statistical downscaling methods: (1) multiple linear regression, (2) multiple non‐linear regression, and (3) stochastic weather generator. The results obtained in this study show that the new strategy adopted here is promising because of many advantages it offers, e.g. it combines the outputs of multiple statistical downscaling methods, provides probabilistic downscaled climate change projections and enables the quantification of uncertainty in these projections. This will encourage any future attempts for combining the results of multiple statistical downscaling methods. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Formation of intracratonic basins by lithospheric shortening and phase changes: a case study from the ultra‐deep East Barents Sea basin     

Sébastien Gac  Ritske S. Huismans  Nina S. C. Simon  Yuri Y. Podladchikov  Jan Inge Faleide 《地学学报》2013,25(6):459-464

The origin of large subsidence in intracratonic basins is still under debate. We propose a new and self‐consistent model for the formation of those basins, where lithospheric shortening/buckling triggers metamorphism and densification of crustal mafic heterogeneities. We use a forward thermo‐mechanical finite element technique to evaluate this mechanism for the typical example of the East Barents Sea basin (EBB) where a very large and compensated subsidence, accommodating an up to 20‐km‐thick sediment succession, is observed. The lower crust in the dynamic model is modelled with petrologic‐consistent densities for a wet mafic gabbroic composition that depend on pressure and temperature taking into account dehydration at high PT conditions. The model successfully explains the main characteristics of the EBB, notably the large anomalous and fast subsidence during the Late Permian–Early Triassic, its present‐day geometry and the absence of a significant gravity anomaly.  相似文献