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71.
72.
A new method for the speciation of Fe and Mn at mineral surfaces is proposed using X-ray absorption fine structure in conversion electron yield mode (CEY-XAFS). This method generally reflects information on the species at the sub-μm scale from the particle surface due to the limited escape depth of the inelastic Auger electron. The surface sensitivity of this method was assessed by experiments on two samples of granite showing different degrees of weathering. The XANES spectra of the Fe-K and Mn-K edge clearly gave different information for CEY and fluorescence (FL) modes. These XANES spectra of Fe and Mn show a good fit upon application of least-squares fitting using ferrihydrite/MnO2 and biotite as the end members. The XANES spectra collected by CEY mode provided more selective information on the secondary phases which are probably present at the mineral surfaces. In particular, CEY-XANES spectra of Mn indicated the presence of Mn oxide in unweathered granite despite a very small contribution of Mn oxide being indicated by FL-XANES and selective chemical-extraction analyses. Manganese oxide could not be detected by micro-beam XANES (beam size: 5 × 5 μm2) in unweathered granite, suggesting that Mn oxide thinly and ubiquitously coats mineral surface at a sub-μm scale. This information is important, since Mn oxide can be the host for various trace elements. CEY-XAFS can prove to be a powerful tool as a highly sensitive surface speciation method. Combination of CEY and FL-XAFS will help identify minor phases that form at mineral surfaces, but identification of Fe and Mn oxides at mineral surfaces is critical to understand the migration of trace elements in water-rock interaction.  相似文献   
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74.
The High-Energy Transient Experiment (HETE) is designed for the multiwavelengths study of Gamma-Ray Bursts (GRBs) in UV, X-ray and gamma-ray range with three scientific instruments. The X-ray instrument, Wide-field X-ray Monitor (WXM), consists of four units of one-dimensional position sensitive gas proportional counters and two perpendicularly oriented one-dimensional coded apertures. The WXM has a wide FOV of 1.5 steradian together with the capability to locate GRBs with 10 arcmin accuracy, and covers photon energies of 2 to 25 keV with an energy resolution of typically 18 % at 6 keV, measuring wide band spectra together with the gamma-ray spectrometer (FREGATE). The coded X-ray image will be deconvolved on board and the GRB location will be provided to the UV camera within 1 sec . GRB locations will also be broadcast in real time to ground-based observers for follow-up observations.  相似文献   
75.
Abstract Temporal–spatial variations in Late Cenozoic volcanic activity in the Chugoku area, southwest Japan, have been examined based on 108 newly obtained K–Ar ages. Lava samples were collected from eight Quaternary volcanic provinces (Daisen, Hiruzen, Yokota, Daikonjima, Sambe, Ooe–Takayama, Abu and Oki) and a Tertiary volcanic cluster (Kibi Province) to cover almost all geological units in the province. Including published age data, a total of 442 Cenozoic radiometric ages are now available. Across‐arc volcanic activity in an area approximately 500 km long and 150 km wide can be examined over 26 million years. The period corresponds to syn‐ and post‐back‐arc basin opening stages of the island arc. Volcanic activity began in the central part of the rear‐arc ca 26 Ma. This was followed by arc‐wide expansion at 20 Ma by eruption at two rear‐arc centers located at the eastern and western ends. Expansion to the fore‐arc occurred between 20 and 12 Ma. This Tertiary volcanic arc was maintained until 4 Ma with predominant alkali basalt centers. The foremost‐arc zone activity ceased at 4 Ma, followed by quiescence over the whole arc between 4 and 3 Ma. Volcanic activity resumed at 3 Ma, covering the entire rear‐arc area, and continued until the present to form a Quaternary volcanic arc. Adakitic dacite first occurred at 1.7 Ma in the middle of the arc, and spread out in the center part of the Quaternary volcanic arc. Alkali basalt activities ceased in the area where adakite volcanism occurred. Fore‐arc expansion of the volcanic arc could be related to the upwelling and expansion of the asthenosphere, which caused opening of the Japan Sea. Narrowing of the volcanic zone could have been caused by progressive Philippine Sea Plate subduction. Deeper penetration could have caused melting of the slab and resulted in adakites. Volcanic history in the Late Cenozoic was probably controlled by the history of evolution of the upper mantle structure, coinciding with back‐arc basin opening and subsequent reinitiation of subduction.  相似文献   
76.
The present study offers a two-dimensional horizontal wave propagation and morphodynamic model for muddy coasts. The model can be applied on a general three-dimensional bathymetry of a soft muddy coast to calculate wave damping, fluid mud mass transport and resulting bathymetry change under wave actions. The wave propagation model is based on time-dependent mild slope equations including the wave energy dissipation due to the wave-mud interaction of bottom mud layers as well as the combined effects of the wave refraction, diffraction and breaking. The constitutive equations of the visco-elastic–plastic model are adopted for the rheological behavior of fluid mud. The mass transport velocity within the fluid mud layer is calculated combining the Stokes’ drift, the mean Eulerian velocity and the gravity-driven mud flow. The results of the numerical model are compared against a series of conducted wave basin experiments, wave flume experiments and field observations. Comparisons between the computed results with both the field and laboratory data reveal the capability of the proposed model to predict the wave transformation and mud mass transport.  相似文献   
77.
The results of subsurface gas monitoring by application of gas chromatography (GC) to the gas composition of bubbles associated with groundwater for seismogeochemical studies are reported. An automated gas monitoring system was used to determine gas compositions in a 500-m borehole at the Haruno Crustal Movement Observation Site (HOS), central Japan during period 1, from December 1999 to December 2000. The average ± two standard deviation (2SD) compositions of gases in this period were He = 82 ± 29 ppmV, H2 = 170 ± 62 ppmV, Ar = 0.05 ± 0.07%, N2 = 50 ± 8%, and CH4 = 45 ± 6%. A new automated gas monitoring system equipped with a micro-GC was installed in the borehole at the HOS, and gas bubbles from the borehole were monitored during period 2, from December 2006 to March 2007. The average ± two standard deviation (2SD) compositions of gases in this period were He = 8 ± 7 ppmV, H2 = 13 ± 15 ppmV, Ar = 0.6 ± 0.3%, N2 = 66 ± 7%, and CH4 = 14 ± 14%. The gas concentration ratios (He/Ar, H2/Ar, N2/Ar, and CH4/Ar) fluctuated significantly over time and repeatedly showed abrupt spike-like increases during period 2. The gas compositions obtained in period 1 and 2 were markedly different. Over the period from 2006 to 2007, the gas bubbles were depleted in He, H2, and CH4 of deep origin, but enriched in Ar and N2 of atmospheric origin. This difference can be interpreted as being due to an irreversible change of the aquifer/gas system. The present deep component in the HOS gas is estimated to have composition He = 63 ppmV, H2 = 37 ppmV, Ar = 0.17%, N2 = 63%, and CH4 = 37%. The new monitoring system is able to analyze the gas composition using a smaller volume of sample gas and with greater precision than the previous system. During the 3-month monitoring period 2, the separation capacity of the capillary column of the micro-GC was sufficiently maintained to determine gas-chromatographic peak areas for the five gaseous species examined. This study confirms that the new monitoring system with micro-GC is promising for continuous subsurface gas monitoring for earthquake prediction studies.  相似文献   
78.
This paper presents a methodology for tsunami risk assessment, which was applied to a case study in Kamakura, Japan. This methodology was developed in order to evaluate the effectiveness of a risk-reducing system against such hazards, also aiming to demonstrate that a risk assessment is possible for these episodic events. The tsunami risk assessment follows these general steps: (1) determination of the probability of flooding, (2) calculation of flood scenarios, (3) assessment of the consequences and (4) integration into a risk number or graph. The probability of flooding was approximated based on the data provided by local institutes, and the flood scenarios were modeled in 1D using the Simulating WAves till SHore model. Results showed that a tsunami in Kamakura can result in thousands of casualties. Interventions such as improvements in evacuation systems, which would directly reduce the number of casualties, would have a large influence in risk reduction. Although this method has its limits and constraints, it illustrates the value it can add to existing tsunami risk management in Japan.  相似文献   
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