Modeling the risk of nitrate leaching and nitrate runoff loss from intensive farmland in the Baiyangdian Basin of the North China Plain   总被引：2，自引：0，他引：2  

Rui Wang  Zhaofei Liu  Zhijun Yao  Yuping Lei 《Environmental Earth Sciences》2014,72(8):3143-3157

The water movement and soil nitrogen cycle of the Baiyangdian Basin were simulated, and the risk of nitrate leaching and nitrate runoff loss from intensive farmland was assessed by using the distributed hydrological soil and water assessment tool (SWAT) in this study. The model assessment showed that SWAT was able to simulate water and nitrate movement in the region with satisfactory results. The modeling analysis indicated that fertilizer application was the overriding source of soil nitrogen and might result in a large amount of nitrate accumulation in soils; this nitrate might be lost by leaching or runoff driven by water movement. In 2009, nitrate nitrogen leaching represented 19.5 % of the total amount of nitrogen fertilizer application, while nitrate nitrogen runoff represented 1.7 % only. Thus, it showed that the nitrate leaching was the main approach of soil nitrogen movement in farmland because of strong percolation. It also showed a significant variation of nitrate leaching from different soil depths, with the largest amount leached from surface soil layers and the smallest amount leached from lower soil layers. Therefore, it could be further revealed that the nitrate concentration was very low at soil layers lower than the root zone of crops (1.2 m). Validated by groundwater observations, groundwater pollution by nitrate derived from fertilizers was not serious because of the deep groundwater level in the study plain. However, the risk of groundwater pollution would increase significantly if precipitation increased.  相似文献   

Impact of impoundment on groundwater seepage in the Three Gorges Dam in China based on CFCs and stable isotopes     

Lei Zhang  Duoxing Yang  Yaowei Liu  Yongtai Che  Dajun Qin 《Environmental Earth Sciences》2014,72(11):4491-4500

It is a common concern that the groundwater flow field caused by the Three Gorges Dam changes the regional seismic activity and environment. The changes in the seepage region could be effectively reflected through the analysis of the groundwater age using chlorofluorocarbons (CFC)-based techniques. In this study, the influences of the reservoir water on groundwater and the seepage region boundary of the reservoir were investigated using CFCs, stable isotopes, and water level in groundwater, reservoir water, and spring water during the water storage process of the Three Gorges Reservoir. The results show that the water supplied by the groundwater is older, whereas the water supplied by the reservoir and the springs is younger. With an increase in the water level of the reservoir, the water in well W3, which is located at the vice dam of the head region, becomes older due to the reservoir loading effect, whereas the water in well W4 become younger due to the lateral seepage of reservoir water. This finding indicates that the groundwater seepage regions in wells W3 and W4, which are located at upstream of the reservoir, are all influenced by the Three Gorges Reservoir. In contrast, the sampling points in the northern section of the Xiannvshan fault zone, which is farther from the dam, did not exhibit any direct hydraulic connection between the groundwater and the reservoir water; thus, the reservoir seepage effects may not affect the northern part of the Xiannvshan fault zone. These research results provide important reference data that can be used to analyze the effects of the Three Gorges reservoir storage on the regional environment.  相似文献   

汉江流域硫铁矿区厚子河支流水质评价研究          下载免费PDF全文

代贞伟  王磊  贺小黑  伏永朋  潘伟  章昱 《中国地质调查》2014,6(5):83-88

为查明厚子河不同区域河水受硫铁矿污染的程度,在厚子河支流4个典型河流断面采集水样,开展水质全分析测试,并采用单因子评价法和综合水质标识指数法进行评价分析。研究结果表明: (1)运用单因子评价法对硫铁矿区厚子河水质评价的结果无差异,均为劣Ⅴ类水; 而运用综合水质标识指数法的评价结果显示,距离硫铁矿开采区由近及远的4个断面HZ001、HZ002、HZ003、HZ004的综合水质标识指数逐渐下降,水质类别分别为劣Ⅴ类且黑臭、劣Ⅴ类但不黑臭、Ⅳ类、Ⅲ类,符合现场调查的实际情况,能够反映距离污染源越远时河水水质趋好的总体态势; (2)综合水质标识指数法不仅可以客观反映同一河流各个断面所处的综合水质类别、同一水质类别中受污染的不同程度以及与水环境功能区类别的比较结果,而且能够实现对劣V类水质污染程度的精细划分,相较于单因子评价法更加客观、科学、全面,适用于矿山开采等重污染区域河流断面水质污染情况的研判。  相似文献   

基于地层结构组合的第四纪地质单元划分研究——以皖江经济带沿江丘陵平原区为例          下载免费PDF全文

苏晶文  龚建师  李运怀  李云峰  王毅  董长春  杨洋  叶永红  魏峰  朱春芳  王睿  蔡磊 《中国地质调查》2014,6(5):28-35

为支撑地质条件复杂地区的水文地质、工程地质和环境地质调查研究,在皖江经济带沿江丘陵平原区通过系统分析第四纪地层的岩性、结构、构造等组合,以地貌以及第四系成因、沉积相和沉积物物源为指标,结合已有区域第四纪研究成果以及年代地层和岩石地层划分标准,进行皖江沿江丘陵平原区“第四纪地质单元”划分,共划分出冲积-湖积平原地质单元、洪积-坡积岗地地质单元和残积-剥蚀丘陵地质单元3个一级地质单元,总结了7种类型第四纪地层结构组合及其特征,为区域水文地质和工程地质调查与研究奠定了基础。  相似文献   

新疆北部扎河坝坳陷上二叠统沉积环境          下载免费PDF全文

文磊  孙相灿  周新桂  易立  李清瑶  高永进  龚晓星  郭坤 《中国地质调查》2014,6(4):17-23

扎河坝坳陷位于阿尔泰造山带与准噶尔盆地之间,属于中亚造山带的一部分,自早古生代以来经历了准噶尔洋盆的打开和闭合等阶段,富含煤炭和金属矿产,也具有一定的油气勘探前景。研究区火山岩和含煤层系发育,地表风化剥蚀严重,对研究其地层发育特征和沉积环境起到了一定的制约。对扎河坝坳陷新富地1井岩芯样品开展沉积岩微量元素测试,分析结果表明,扎河坝坳陷上二叠统为温暖湿润的淡水沉积环境,表明扎河坝坳陷晚二叠世经历了火山活动和陆相淡水沉积2个阶段,印证了准噶尔洋由俯冲消减向陆内阶段转换的过程。该研究对恢复研究区构造演化及沉积古地理特征具有重要意义。  相似文献   

云南省江城地区盐盆地重力勘探与深部找钾启示          下载免费PDF全文

刘璎  郑绵平  于常青  张震  高磊 《中国地质调查》2014,6(6):88-97

云南省江城勐野井钾盐矿是目前我国发现的唯一固体钾盐矿。该地区地质构造复杂,近几年通过野外地质、地球物理及钻井勘探 ,认为钾盐来自深部侏罗系,并沿断裂构造带挤压塑流到表层,可能在深部还存在大面积的“盐源”。为实现找矿突破,亟须了解控制盐矿形成的构造及围岩的三维结构特征。通过对江城地区高精度重力数据位场分离、边缘检测、3D物性反演的地球物理处理与解释,获得了勐野井地区江城湖盆的基底变化、断裂展布等地质信息,确定了研究区构造格架、地下密度体的三维分布与岩盐矿的关系,推断在勐野井矿区西北深部可能还有侏罗系盐岩甚至钾盐的存在,该地区将是未来找矿工作的重点。研究成果为江城地区下一步钾盐矿勘查提供了线索和依据。  相似文献   

Vanadium and niobium behavior in rutile as a function of oxygen fugacity: evidence from natural samples   总被引：1，自引：0，他引：1  

Lei?Liu  Yilin?XiaoEmail author  Sonja?Aulbach  Dongyong?Li  Zhenhui?Hou 《Contributions to Mineralogy and Petrology》2014,167(6):1026

Vanadium occurs in multiple valence states in nature, whereas Nb is exclusively pentavalent. Both are compatible in rutile, but the relationship of V–Nb partitioning and dependence on oxygen fugacity (expressed as fO₂) has not yet been systematically investigated. We acquired trace-element concentrations on rutile grains (n = 86) in nine eclogitic samples from the Dabie-Sulu orogenic belt by laser ablation inductively coupled plasma mass spectrometry (LA–ICP–MS) and combined them with published results in order to assess the direct and indirect effects of oxygen fugacity on the partitioning of V and Nb into rutile. A well-defined negative correlation between Nb (7–1,200 ppm) and V concentrations (50–3,200 ppm) was found, documenting a competitive relationship in the rutile crystal that does not appear to be controlled by bulk rock or mineral compositions. Based on the published relationship of ^RtD_V and V valence with ?QFM, we suggest that the priority order of V incorporation into rutile is V⁴⁺ > V³⁺ > V⁵⁺. The inferred Nb–V competitive relationship in rutile from the Dabie-Sulu orogenic belt could be explained by decreasing fO₂ due to dehydration reactions involving loss of oxidizing fluids during continental subduction: The increased proportion of V³⁺ (expressed as V³⁺/∑V) and attendant decrease in ^RtD_V is suggested to lead to an increase in rutile lattice sites available for Nb⁵⁺. A similar effect may be observed under more oxidizing conditions. When V⁵⁺/∑V increases, ^RtD_V shows a dramatic decline and Nb concentration increases considerably. This is possibly documented by rutile in highly metasomatized and oxidized MARID-type (MARID: mica–amphibole–rutile–ilmenite–diopside) mantle xenoliths from the Kaapvaal craton, which also show a negative V–Nb covariation. In addition, their Nb/Ta covaries with V concentrations: For V concentrations <1,250 ppm, Nb/Ta ranges between 35 and 45, whereas for V > 1,250 ppm, Nb/Ta is considerably lower (5–15). This relationship is mainly controlled by a change in Nb concentrations, suggesting that the indirect dependence of ^RtD_Nb on fO₂, which is not mirrored in ^RtD_Ta, can exert considerable influence on rutile Nb–Ta fractionation.  相似文献   

Paragenesis and geochemistry of ore minerals in the epizonal gold deposits of the Yangshan gold belt,West Qinling,China   总被引：13，自引：0，他引：13  

Nan Li  Jun Deng  Li-Qiang Yang  Richard J. Goldfarb  Chuang Zhang  Erin Marsh  Shi-Bin Lei  Alan Koenig  Heather Lowers 《Mineralium Deposita》2014,49(4):427-449

Six epizonal gold deposits in the 30-km-long Yangshan gold belt, Gansu Province are estimated to contain more than 300 t of gold at an average grade of 4.76 g/t and thus define one of China's largest gold resources. Detailed paragenetic studies have recognized five stages of sulfide mineral precipitation in the deposits of the belt. Syngenetic/diagenetic pyrite (Py₀) has a framboidal or colloform texture and is disseminated in the metasedimentary host rocks. Early hydrothermal pyrite (Py₁) in quartz veins is disseminated in metasedimentary rocks and dikes and also occurs as semi-massive pyrite aggregates or bedding-parallel pyrite bands in phyllite. The main ore stage pyrite (Py₂) commonly overgrows Py₁ and is typically associated with main ore stage arsenopyrite (Apy₂). Late ore stage pyrite (Py₃), arsenopyrite (Apy₃), and stibnite occur in quartz ± calcite veins or are disseminated in country rocks. Post-ore stage pyrite (Py₄) occurs in quartz ± calcite veins that cut all earlier formed mineralization. Electron probe microanalyses and laser ablation-inductively coupled plasma mass spectrometry analyses reveal that different generations of sulfides have characteristic of major and trace element patterns, which can be used as a proxy for the distinct hydrothermal events. Syngenetic/diagenetic pyrite has high concentrations of As, Au, Bi, Co, Cu, Mn, Ni, Pb, Sb, and Zn. The Py₀ also retains a sedimentary Co/Ni ratio, which is distinct from hydrothermal ore-related pyrite. Early hydrothermal Py₁ has high contents of Ag, As, Au, Bi, Cu, Fe, Sb, and V, and it reflects elevated levels of these elements in the earliest mineralizing metamorphic fluids. The main ore stage Py₂ has a very high content of As (median value of 2.96 wt%) and Au (median value of 47.5 ppm) and slightly elevated Cu, but relatively low values for other trace elements. Arsenic in the main ore stage Py₂ occurs in solid solution. Late ore stage Py₃, formed coevally with stibnite, contains relatively high As (median value of 1.44 wt%), Au, Fe, Mn, Mo, Sb, and Zn and low Bi, Co, Ni, and Pb. The main ore stage Apy₂, compared to late ore stage arsenopyrite, is relatively enriched in As, whereas the later Apy₃ has high concentrations of S, Fe, and Sb, which is consistent with element patterns in associated main and late ore stage pyrite generations. Compared with pyrite from other stages, the post-ore stage Py₄ has relatively low concentrations of Fe and S, whereas As remains elevated (2.05～3.20 wt%), which could be interpreted by the substitution of As^? for S in the pyrite structure. These results suggest that syngenetic/diagenetic pyrite is the main metal source for the Yangshan gold deposits where such pyrite was metamorphosed at depth below presently exposed levels. The ore-forming elements were concentrated into the hydrothermal fluids during metamorphic devolatilization, and subsequently, during extensive fluid–rock interaction at shallower levels, these elements were precipitated via widespread sulfidation during the main ore stage.  相似文献   

微波等离子体炬质谱技术快速鉴别天然石材与人造石材   总被引：1，自引：1，他引：0  

周炜  熊海龙  杨美玲  陈焕文  屈颖  张兴磊  方小伟 《岩矿测试》2014,33(6):782-788

天然石材主要有大理石、花岗岩等;人造石材多以不饱和聚酯树脂为基料,添加适量的无机物粉料和添加剂固化制成。由于石材种类繁多,并且各种石材的岩体所含矿物成分也有差异,当前很少应用化学成分分析方法准确、快速鉴别天然和人造石材,仅有的红外光谱法由于对待测物纯度的要求较高而具局限性。本文基于微波等离子体炬源(MPT)同时具有热解吸与强电离能力,能在短时间内离子化待测物的特点,采用微波等离子体炬质谱(MPT-MS)技术,无需样品复杂预处理直接对天然与人造石材进行分析,获得正离子检测模式下在m/z 50~1000之间的石材的指纹谱图,并运用化学计量学的主成分分析(PCA)方法处理所获取的数据,实现了不同建筑石材的区分。结果表明,MPT-MS能够获得石材丰富的指纹谱图,结合PCA方法能够快速鉴别天然石材与人造石材,天然石材中解吸出的物质主要为CO₂和H₂O的团簇分子;而人造石材中解吸出的主要成分为有机物(人为添加的黏合剂等)。本研究采用的MPT-MS技术无需采用喷雾、激光、基质和加热等方法辅助,并且无需对石材进行任何复杂的处理即可进行质谱分析,从而获取石材表面及内部物质的质谱信息,为快速直接鉴定石材样品提供了一种新的质谱分析方法。  相似文献   

Accumulated Deformation Behavior and Computational Model of Water-Rich Mudstone Under Cyclic Loading     

Cheng-hua Shi  Zu-de Ding  Ming-feng Lei  Li-min Peng 《Rock Mechanics and Rock Engineering》2014,47(4):1485-1491

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