Role of Fe(II) and phosphate in arsenic uptake by coprecipitation     

Nita Sahai  Young J. Lee  Huifang Xu  Jean-Francois Gaillard 《Geochimica et cosmochimica acta》2007,71(13):3193-3210

Natural attenuation of arsenic by simple adsorption on oxyhydroxides may be limited due to competing oxyanions, but uptake by coprecipitation may locally sequester arsenic. We have systematically investigated the mechanism and mode (adsorption versus coprecipitation) of arsenic uptake in the presence of carbonate and phosphate, from solutions of inorganic composition similar to many groundwaters. Efficient arsenic removal, >95% As(V) and ∼55% in initial As(III) systems, occurred over 24 h at pHs 5.5-6.5 when Fe(II) and hydroxylapatite (Ca₅(PO₄)₃OH, HAP) “seed” crystals were added to solutions that had been previously reacted with HAP, atmospheric CO_2(g) and O_2(g). Arsenic adsorption was insignificant (<10%) on HAP without Fe(II). Greater uptake in the As(III) system in the presence of Fe(II) was interpreted as due to faster As(III) to As(V) oxidation by molecular oxygen in a putative pathway involving Fe(IV) and As(IV) intermediate species. HAP acts as a pH buffer that allows faster Fe(II) oxidation. Solution analyses coupled with high-resolution transmission electron microscopy (HRTEM), X-ray Energy-Dispersive Spectroscopy (EDS), and X-Ray Absorption Spectroscopy (XAS) indicated the precipitation of sub-spherical particles of an amorphous, chemically-mixed, nanophase, Fe^III[(OH)₃(PO₄)(As^VO₄)]·nH₂O or Fe^III[(OH)₃( PO₄)(As^VO₄)(As^IIIO₃)_minor]·nH₂O, where As^IIIO₃ is a minor component.The mode of As uptake was further investigated in binary coprecipitation (Fe(II) + As(III) or P), and ternary coprecipitation and adsorption experiments (Fe(II) + As(III) + P) at variable As/Fe, P/Fe and As/P/Fe ratios. Foil-like, poorly crystalline, nanoparticles of Fe^III(OH)₃ and sub-spherical, amorphous, chemically-mixed, metastable nanoparticles of Fe^III[(OH)₃, PO₄]·nH₂O coexisted at lower P/Fe ratios than predicted by bulk solubilities of strengite (FePO₄·2H₂O) and goethite (FeOOH). Uptake of As and P in these systems decreased as binary coprecipitation > ternary coprecipitation > ternary adsorption.Significantly, the chemically-mixed, ferric oxyhydroxide-phosphate-arsenate nanophases found here are very similar to those found in the natural environment at slightly acidic to circum-neutral pHs in sub-oxic to oxic systems, such phases may naturally attenuate As mobility in the environment, but it is important to recognize that our system and the natural environment are kinetically evolving, and the ultimate environmental fate of As will depend on the long-term stability and potential phase transformations of these mixed nanophases. Our results also underscore the importance of using sufficiently complex, yet systematically designed, model systems to accurately represent the natural environment.  相似文献   

Atmospheric wave propagations in the mesopause region observed by the OH(8,3) band,NaD, O₂A(8645Å) band and OI 5577 Å nightglow emissions     

H. Takahashi  P.P. Batista  Y. Sahai  B.R. Clemesha 《Planetary and Space Science》1985,33(4):381-384

Simultaneous measurements of the upper mesospheric NaD and OH(8,3) band emissions by meridional scanning photometers, and the OI 5577 Å, O₂ Atmospheric band at 8645 Å, NaD and OH(8,3) band emissions by multi-channel tilting filter type zenith photometers have been carried out at Cachoeira Paulista (22.7°S, 45.0°W), Brazil. On two nights during the period May–August 1983, the meridional scanning observations showed horizontal intensity gradients and phase propagations. The nocturnal intensity variations on one of these occasions 13–14 June 1983, which was a magnetically disturbed night with 4 ?k_p? 8, also showed vertical phase propagation. In this paper, we present these observations and discuss the possible effects of the horizontal wind system and of gravity wave propagation.  相似文献   

Tropical twilight HeI 10830 emission     

N.R. Teixeira  P.D. Angreji  Y. Sahai  B.A. Tinsley  A.B. Christensen 《Planetary and Space Science》1975,23(10):1425-1430

A further year's observation of twilight Hel 10830 Å emission made in Brazil confirms the trend of seasonal variation found earlier. The 10830 intensities taken with concurrent ionosonde data are discussed in the context of recent model calculations of the emission rates. An increase with K_P is attributable to changing production and loss rates of He 2³S with changing thermospheric temperature. The morning intensities being greater than those of the evening can be due to several effects, an important one of which appears to be the much greater loss rate of photoelectron energy to ambient electrons in the evening, arising from the very high evening electron concentrations at the Appleton Anomaly ionization crests.  相似文献   

Teleconnections in recent time and prediction of Indian summer monsoon rainfall     

A. K. Sahai  D. R. Pattanaik  V. Satyan  Alice M. Grimm 《Meteorology and Atmospheric Physics》2003,84(3-4):217-227

Summary The prediction of Indian Summer Monsoon Rainfall (ISMR) is vital for Indian economic policy and a challenge for meteorologists. It needs various predictors among which El Niño-Southern Oscillation (ENSO) is the most important. It has been established by various researchers that ENSO and ISMR relationship is weakening in recent years. It has been also argued that changes in ENSO-ISMR relationship may be due to decadal fluctuations, or it may be the indicative of longer-term trends related to anthropogenic-induced climate changes.In the present communication, an attempt is made to discuss the variability and predictability of ISMR in recent years. It is found that three different indices associated with different regions in the tropics and extra-tropics at different levels of the atmosphere-Asian land mass index represented by geopotential height at upper troposphere (A1), Caribbean-North Atlantic index represented by geopotential height at middle troposphere (A2) and tropical Pacific index at surface level (A3) – have different mechanisms to interact mutually and separately with ISMR in different periods. In recent years ISMR shows weak association with A1 and A3 while strong association with A2. Thus, if these three indices could be combined objectively, they can give rise to the predictability of ISMR. This objective combination is achieved here using Artificial Neural Network (ANN) and a model is developed to predict ISMR. This model has predicted reasonably well during the whole period of consideration (1958–2000) with a correlation coefficient of 0.92 in last 11 years (1990–2000) whereas most of the models fail to predict the variability in recent time.Current affiliation: Department of Physics, Federal University of Parana, Curitiba, Brazil.Received June 2002; revised October 1, 2002; accepted November 12, 2002 Published online: April 10, 2003  相似文献   

The effects of Mg and H on apatite nucleation at silica surfaces     

Nita Sahai 《Geochimica et cosmochimica acta》2003,67(5):1017-1030

Apatite (Ca₁₀[PO₄]₆[OH]₂) precipitation from aqueous solutions involves multiple steps, such as nucleation of a precursor calcium phosphate phase, cluster aggregation, crystal growth, and transformation to apatite, which are affected by the presence of other ions in solution. I report the mechanisms by which two ions common in natural solutions, Mg²⁺ and H⁺, affect heterogeneous calcium phosphate nucleation on the amorphous silica surface.  相似文献   

Diurnal and seasonal variations of the oh (8, 3) airglow band and its correlation with OI 5577 Å     

H. Takahashi  Y. Sahai  B.R. Clemesha  P.P. Batista  N.R. Teixeira 《Planetary and Space Science》1977,25(6):541-547

In this paper the results of OH (8,3) emission intensity and rotational temperature measurements made in the Brazilian sector (23°S) from 1972 to 1974 are presented. Diurnal variations of both the parameters are found to fall into distinct classes, showing significant seasonal effects. A correlative study with the OI 5577 Å emission measured simultaneously is also presented. It is shown that both the phase and amplitude of the major part of the mean nocturnal intensity variations of the two emissions can be explained by the density and temperature perturbations caused by the solar semidiurnal tide. The OH emission is found to increase slightly during magnetic disturbances.  相似文献   

Mesospheric energy loss rates by OH and C2 emissions at 23°S     

P. R. Fagundes  D. Gobbi  H. Takahashi  Y. Sahai 《Annales Geophysicae》1997,15(6):797-804

The nightglow OH(9,4) and O₂ atmospheric (0,1) band emission intensities and their rotational temperatures T(OH) and T(O₂), respectively, observed at Cachoeira Paulista (23° S, 45°W), Brazil, during the period from October 1989 to December 1990, have been analyzed to study the nighttime mesospheric energy loss rates through the radiations from the vibrationally excited OH* and electronically excited O*₂ bands. The total emission rates of the OH Meinel bands, O₂ atmospheric (0,0) and O₂ infrared atmospheric (¹_g) bands were calculated using reported data for the relative band intensities and . It was found that there is a minimum in equivalent energy loss rate by the OH* Meinel bands during December/January (equivalent energy loss rate of 0.39 K/day*, where day* means averaged over the night) and maximum in equivalent energy loss rate during September (equivalent energy loss rate of 0.98 K/day*). Energy loss rate by the O*₂ radiation, on the other hand, is weaker than that by the OH* Meinel bands, showing equivalent energy loss rates of 0.12 K/day* and 0.22 K/day* during January and September, respectively.  相似文献   

Observations of day-to-day variability in precursor signatures to equatorial F-region plasma depletions     

P. R. Fagundes  Y. Sahai  I. S. Batista  M. A. Abdu  J. A. Bittencourt  H. Takahashi 《Annales Geophysicae》1999,17(8):1053-1063

In December 1995, a campaign was carried out to study the day-to-day variability in precursor signatures to large-scale ionospheric F-region plasma irregularities, using optical diagnostic techniques, near the magnetic equator in the Brazilian sector. Three instruments were operated simultaneously: (a) an all-sky (180° field of view) imaging system for observing the OI 630 nm nightglow emission at Alcântara (2.5°S, 44.4°W); (b) a digisonde (256-Lowell) at São Luis (2.6°S, 44.2°W); and (c) a multi-channel tilting filter-type zenith photometer for observing the OI 630 nm and mesospheric nightglow emissions at Fortaleza (3.9°S, 38.4°W). During the period December 14–18, 1995 (summer in the southern hemisphere), a good sequence of the OI 630 nm imaging observations on five consecutive nights were obtained, which are presented and discussed in this study. The observing period was geomagnetically quiet to moderate (Kp = 0+ to 5+ Dst = 18 nT to −37 nT). On four nights, out of the five observation nights, the OI 630 nm imaging pictures showed formations of transequatorial north-south aligned intensity depletions, which are the optical signatures of large-scale ionospheric F-region plasma bubbles. However, considerable day-to-day variability in the onset and development of the plasma depleted bands was observed. On one of the nights it appears that the rapid uplifting of the F-layer in the post-sunset period, in conjunction with gravity wave activity at mesospheric heights, resulted in generation of very strong plasma bubble irregularities. One of the nights showed an unusual formation of north-south depleted band in the western sector of the imaging system field of view, but the structure did not show any eastward movement, which is a normal characteristic of plasma bubbles. This type of irregularity structure, which probably can be observed only by wide-angle imaging system, needs more investigations for a better understanding of its behaviour.  相似文献   

Diabatic heating profiles over the continental convergence zone during the monsoon active spells     

Rajib Chattopadhyay  Sharmila Sur  Susmitha Joseph  A. K. Sahai 《Climate Dynamics》2013,41(1):205-226

The present paper aims to bring out the robust common aspects of spatio-temporal evolution of diabatic heating during the monsoon intraseasonal active phases over the continental tropical convergence zone (CTCZ). The robustness of spatio-temporal features is determined by comparing the two state-of-the art reanalyses: NCEP Climate Forecast System reanalysis and Modern ERA Retrospective Analysis. The inter-comparison is based on a study period of 26 years (1984–2009). The study confirms the development of deep heating over the CTCZ region during the active phase and is consistent between the two datasets. However, the detailed temporal evolution of the vertical structure (e.g., vertical tilts) of heating differs at times. The most important common feature from both the datasets is the significant vertical redistribution of heating with the development of shallow (low level) heating and circulation over the CTCZ region 3–7 days after the peak active phase. The shallow circulation is found to be associated with increased vertical shear and relative vorticity over certain regions in the subcontinent. This increased vertical shear and relative vorticity in the lower levels could be crucial in the sustenance of rainfall after the peak active phase. Model experiments with linear dynamics affirm the role of shallow convection in increasing the lower level circulation as observed.  相似文献   

Restrictions on information dissemination in the context of latest technological developments     

Baldev Sahai 《Journal of the Indian Society of Remote Sensing》1992,20(4):173-174

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