A new type of orthopyroxenite xenolith from Takashima, Southwest Japan: silica enrichment of the mantle by evolved alkali basalt     

Shoji Arai  Yohei Shimizu  Tomoaki Morishita  Yoshito Ishida 《Contributions to Mineralogy and Petrology》2006,152(3):387-398

We found fine-grained Fe-rich orthopyroxene-rich xenoliths (mainly orthopyroxenite) containing partially digested dunite fragments of Group I from Takashima, Southwest Japan. Orthopyroxenite veinlets, some of which contain plagioclase at the center, also replace olivine in dunite and wehrlite xenoliths of Group I. This shows high reactivity with respect to olivine of the melt involved in orthopyroxenite formation, indicating its high SiO₂ activity. The secondary orthopyroxene of this type is characterized by low Mg# [= Mg/(Mg + total Fe) atomic ratio] (down to 0.73) and high Al₂O₃ contents (5–6 wt%). It is different in chemistry from other secondary orthopyroxenes found in peridotite xenoliths derived from the mantle wedge. Clinopyroxenes in the Fe-rich orthopyroxenite show a convex-upward REE pattern with a crest around Sm. This pattern is strikingly similar to that of clinopyroxenes of Group II pyroxenite xenoliths and of phenocrystal and xenocrystal clinopyroxenes, indicating involvement of similar alkali basaltic melts. The Fe-rich orthopyroxenite xenoliths from Takashima formed by reaction between evolved alkali basalt melt and mantle olivine; alkali basalt initially slightly undersaturated in silica might have evolved to silica-oversaturated compositions by fractional crystallization at high-pressure conditions. The Fe-rich orthopyroxenites occur as dikes within the uppermost mantle composed of dunite and wehrlite overlying pockets of Group II pyroxenites. The orthopyroxene-rich pyroxenites of this type are possibly common in the uppermost mantle beneath continental rift zones where alkali basalt magmas have been prevalent.  相似文献   

Chromitite and peridotite from Rayat, northeastern Iraq, as fragments of a Tethyan ophiolite     

Sabah A.  Ismail  Shoji  Arai  Ahmed H.  Ahmed  Yohei  Shimizu 《Island Arc》2009,18(1):175-183

Ophiolitic rocks (chromitites and serpentinized peridotites) were petrologically examined in detail for the first time from Rayat, in the Iraqi part of the Zagros thrust zone, an ophiolitic belt. Almost all the primary silicates have been altered out, but chromian spinel has survived from alteration and gives information about the primary petrological characteristics. The protolith of the serpentinite was clinopyroxene-free harzburgite with chromian spinel of intermediate Cr# (= Cr/[Cr + Al] atomic ratio) of 0.5 to 0.6. The harzburgite with that signature is the most common in the mantle section of the Tethyan ophiolites such as the Oman ophiolite, and is the most suitable host for chromitite genesis. Except for one sample, which has Cr# = 0.6 for spinel, the Cr# of spinel is high, around 0.7, in chromitite. The variation in Cr# of spinel in chromitite observed here has been also reported in the Oman ophiolite. The peridotite with chromitite pods exposed at Rayat was derived from an ophiolite similar in petrological character to the Oman ophiolite, one of the typical Tethyan ophiolites (fragments of Tethyan oceanic lithosphere). This result is consistent with the previous interpretation based on geological analysis.  相似文献   

Dissolved iron and zinc in Sagami Bay and the Izu-Ogasawara Trench     

Hajime Obata  Jun Nishioka  Taejin Kim  Kazuhiro Norisuye  Shigenobu Takeda  Yohei Wakuta  Toshitaka Gamo 《Journal of Oceanography》2017,73(3):333-344

Using a clean seawater sampling system for trace metals onboard the R. V. Shinsei-Maru, newly launched in 2013, we investigated the vertical distributions of dissolved iron and zinc in Sagami Bay and the Izu-Ogasawara Trench. We applied appropriate clean sampling and filtering processes for trace metals, so that uncontaminated seawater samples were successfully collected. The distribution of zinc in the trench area was similar to that of silicate and the same as that previously reported in the subtropical North Pacific. There were spatial variations in the iron (Fe) distribution in the trench areas. We used previously reported information about biogeochemical cycling in the trench area, and found that Fe has a residence time of 29 years in the water column. The short residence time of Fe (29 years) corresponds to the vertical variations of dissolved Fe in the water column.  相似文献   

Cell contact-dependent lethal effect of the dinoflagellate Heterocapsa circularisquama on phytoplankton–phytoplankton interactions     

Yasuhiro Yamasaki  Yanan Zou  Jyoji Go  Tomoyuki Shikata  Yukihiko Matsuyama  Kiyohito Nagai  Yohei Shimasaki  Kenichi Yamaguchi  Yuji Oshima  Tatsuya Oda  Tsuneo Honjo 《Journal of Sea Research》2011,65(1):76-83

We used bi-algal culture experiments to investigate and verify the roles of growth interaction between Heterocapsa circularisquama and Prorocentrum dentatum in monospecific bloom formation. Growth of H. circularisquama was slightly inhibited when inoculated at 10² cells mL^–1 along with P. dentatum at 10⁴ cells mL^–1. In other combinations of inoculation densities, P. dentatum density rapidly decreased to extremely low levels in the presence of H. circularisquama. We used a mathematical model to simulate growth and interactions of H. circularisquama and P. dentatum in bi-algal cultures. The model indicates that one species will always inhibit the growth of the other and that the relative initial cell densities of the species are critical in determining the outcome. When cultured together under conditions without cell contact, growth of H. circularisquama and P. dentatum was not inhibited. As with P. dentatum, the growth of Heterosigma akashiwo and Skeletonema costatum was inhibited in intact cell suspensions with H. circularisquama, but a nontoxic species, Heterocapsa triquetra, did not affect the growth of P. dentatum or the other species. Similarly, cell suspensions of H. circularisquama showed hemolytic activity toward rabbit erythrocytes, but those of H. triquetra did not. In addition, the cell-free supernatant of H. circularisquama cultures showed no significant hemolytic activity. These results suggest that H. circularisquama causes lethality in P. dentatum by direct cell contact in which live-cell-mediated hemolytic activity might be a contributing factor.  相似文献   

Encystment and excystment of <Emphasis Type="Italic">Gyrodinium instriatum</Emphasis> Freudenthal et Lee     

Tomoyuki Shikata  Sou Nagasoe  Tadashi Matsubara  Yasuhiro Yamasaki  Yohei Shimasaki  Yuji Oshima  Takuji Uchida  Ian R. Jenkinson  Tsuneo Honjo 《Journal of Oceanography》2008,64(3):355-365

In the present study, we have investigated the conditions influencing encystment and excystment in the dinoflagellate Gyrodinium instriatum under laboratory conditions. We incubated G. instriatum in modified whole SWM-3 culture medium and in versions of modified SWM-3 from which NO₃ ⁻, PO₄ ³⁻, NO₃ ⁻ + PO₄ ³⁻, or Si had been omitted and observed encystment. Percentage encystment was high in the media without N and without P, while the percentage encystment in the medium lacking both N and P was highest. Moreover, to investigate N or P concentration which induced the encystment, Gyrodinium instriatum was also incubated in media with different concentrations of inorganic N and P; the concentrations of NO₂ ⁻ + NO₃ ⁻ and PO₄ ³⁻ were measured over time. The precursors of cysts appeared within 2 or 3 days of a decrease in NO₂ ⁻ + NO₃ ⁻ or PO₄ ³⁻ concentration to values lower than 1 μM or 0.2 μM, respectively. When cysts produced in the laboratory were incubated, we observed excystment after 8–37 days, without a mandatory period of darkness or low temperature. We incubated cysts collected from nature at different temperatures or in the dark or light and observed excystments. Natural cysts excysted at temperatures from 10 to 30°C, in both light and dark, but excystment was delayed at low temperatures. These studies indicate that G. instriatum encysts in low N or P concentration and excysts over a wide temperature range, regardless of light conditions, after short dormancy periods.  相似文献   

Tributyltin in blood of marine fish collected from a coastal area of northern Kyushu, Japan     

Miki S  Ikeda K  Oba Y  Satone H  Honda M  Shimasaki Y  Onikura N  Arakawa O  Oshima Y 《Marine pollution bulletin》2011,62(11):2533-2536

We investigated levels of the pollutant tributyltin (TBT) in blood of pufferfishes (six species), Japanese sea perch, red sea bream, Japanese common goby, Japanese flounder, rockfish, conger eel, and sea mullet collected off the coast of northern Kyushu, Japan. We found considerable levels of TBT (1.4-190 ng/mL) accumulated in the blood of these fish. Blood TBT concentrations were 1.3-22.5 times liver concentrations and 4.9-78 times muscle concentrations, except in conger eel and mullet. We detected TBT (16-111 ng/mL-blood) in the plasma of the fine-patterned puffer (Takifugupoecilonotus) year-round, without any apparent seasonal trend. These results suggest that fish inhabiting coastal areas of Kyushu, Japan, continue to be contaminated with TBT.  相似文献   

High-pressure Raman studies and heat capacity measurements on the MgSiO<Subscript>3</Subscript> analogue CaIr<Subscript>0.5</Subscript>Pt<Subscript>0.5</Subscript>O<Subscript>3</Subscript>     

Shigeto Hirai  Yohei Kojima  Hiroaki Ohfuji  Norimasa Nishiyama  Tetsuo Irifune  Stephan Klemme  Geoffrey Bromiley  J. Paul Attfield 《Physics and Chemistry of Minerals》2011,38(8):631-637

Raman spectroscopy and heat capacity measurements have been used to study the post-perovskite phase of CaIr_0.5Pt_0.5O₃, recovered from synthesis at a pressure of 15 GPa. Laser heating CaIr_0.5Pt_0.5O₃ to 1,900 K at 60 GPa produces a new perovskite phase which is not recoverable and reverts to the post-perovskite polymorph between 20 and 9 GPa on decompression. This implies that Pt-rich CaIr_1−xPt_xO₃ perovskites including the end member CaPtO₃ cannot easily be recovered to ambient pressure from high P–T synthesis. We estimate an increase in the thermodynamic Grüneisen parameter across the post-perovskite to perovskite transition of 34%, of similar magnitude to those for (Mg,Fe)SiO₃ and MgGeO₃, suggesting that CaIr_0.5Pt_0.5O₃ is a promising analogue for experimental studies of the competition in energetics between perovskite and post-perovskite phases of magnesium silicates in Earth’s lowermost mantle. Low-temperature heat capacity measurements show that CaIrO₃ has a significant Sommerfeld coefficient of 11.7 mJ/mol K² and an entropy change of only 1.1% of Rln2 at the 108 K Curie transition, consistent with the near-itinerant electron magnetism. Heat capacity results for post-perovskite CaIr_0.5Rh_0.5O₃ are also reported.  相似文献   

Significance of an amorphous SiO2 phase in a pseudomorph after coesite enclosed in garnet from ultrahigh‐pressure eclogite,Su–Lu Belt,eastern China          下载免费PDF全文

Tomoki Taguchi  Akira Miyake  Masaki Enami  Yohei Igami 《Journal of Metamorphic Geology》2018,36(7):843-854

Here, we report the first discovery of an amorphous SiO₂ phase (APSI phase) in a pseudomorph after coesite included in garnet from an ultrahigh‐pressure (UHP) eclogite from the Su–Lu metamorphic belt, eastern China. Using transmission electron microscopy, Raman spectroscopy and selected area electron diffraction, we show that the internal structure of the pseudomorph consists of an APSI phase with nano/submicrocrystalline particles of quartz and a polycrystalline K‐bearing fibrous sheet‐silicate phase (KFSS phase). The APSI phase‐bearing aggregates included in the garnet might have formed by reactions involving a supercritical fluid during exhumation by the following processes: (1) the development of radial cracks within the host garnet by the phase transition of coesite to quartz; (2) the decomposition of a part of the pseudomorph following infiltration of supercritical fluid; (3) the precipitation of the KFSS phase from the fluid phase during subsequent exhumation and cooling, which was likely promoted by a change in the metamorphic fluid from supercritical and/or subcritical to aqueous fluid; and (4) the rapid precipitation of the APSI phase under a metastable (non‐equilibrium) state, such as quenching, during a later stage of the exhumation. Whether the APSI phase generally formed during exhumation and survived widely throughout the Su‐Lu terrane is unknown. However, the presence of the APSI phase in a UHP eclogite provides new insight into the geodynamic phenomena occurring at continental collision zones.  相似文献   

Physical property anisotropy of foliated fault rocks: Study from the Nobeoka Thrust,Shimanto Belt,southwest Japan          下载免费PDF全文

Mari Hamahashi  Wataru Tanikawa  Yohei Hamada  Yoshitaka Hashimoto  Saneatsu Saito  Gaku Kimura 《Island Arc》2018,27(5)

To investigate the physical property anisotropies of foliated fault rocks in subduction zones, the hanging wall phyllites and footwall cataclasites exhumed along the Nobeoka Thrust, a fossilized out‐of‐sequence‐thrust in the Shimanto Belt, Japan, was focused. Discrete physical property (electric resistivity, P‐ and S‐wave velocities, and porosity) measurements were conducted employing geologic coordinates (depth‐parallel direction, strike direction, and maximum dip direction of foliation), using the core samples obtained from the Nobeoka Thrust Drilling Project and compared the data to borehole geophysical logs. A higher sample P‐wave velocity (Vp), lower S‐wave velocity (Vs), higher Vp/Vs, and lower sample porosity and resistivity compared to the logs, are inferred to have been caused by the larger sampling scale of the logs and lower fluid saturation of the borehole. The phyllites and cataclasites exhibited substantial vertical and horizontal anisotropy of Vp (0.4–17.3 % and 2.7–13.8 %, respectively), Vs (0.5–56 % and 7.7–43 %, respectively), and resistivity (0.9–119 % and 2.0–65.9 %, respectively). The physical property anisotropies are primarily affected by the dip angles of foliation. The fault rocks that have gentler dip angles exhibit a higher Vp in the strike and maximum dip direction and a lower Vp in the depth‐parallel direction. In contrast, the fault rocks that have steeply dipping structures show a higher Vp in the strike and depth‐parallel directions with a lower velocity in the maximum dip direction. Resistivity anisotropy show a trend opposite to that of the Vp in relation to the dip angles. Our results show lower Vp anisotropy than those obtained in previous studies, which measured wave speeds perpendicular or parallel to foliation under confining pressure. This study highlights the significance of dip angles on vertical properties in geophysical surveys across foliated fault rocks.  相似文献   

Elastic impedance based facies classification using support vector machine and deep learning     

Yohei Nishitsuji  Russell Exley 《Geophysical Prospecting》2019,67(4):1040-1054

Machine learning methods including support-vector-machine and deep learning are applied to facies classification problems using elastic impedances acquired from a Paleocene oil discovery in the UK Central North Sea. Both of the supervised learning approaches showed similar accuracy when predicting facies after the optimization of hyperparameters derived from well data. However, the results obtained by deep learning provided better correlation with available wells and more precise decision boundaries in cross-plot space when compared to the support-vector-machine approach. Results from the support-vector-machine and deep learning classifications are compared against a simplified linear projection based classification and a Bayes-based approach. Differences between the various facies classification methods are connected by not only their methodological differences but also human interactions connected to the selection of machine learning parameters. Despite the observed differences, machine learning applications, such as deep learning, have the potential to become standardized in the industry for the interpretation of amplitude versus offset cross-plot problems, thus providing an automated facies classification approach.  相似文献