Distribution coefficient of Mg ions between calcite and solution at 10–50°C     

Tamotsu Oomori  Hiroshi Kaneshima  Yoko Maezato  Yasushi Kitano   《Marine Chemistry》1987,20(4)

The distribution coefficient (λ_Mg) of Mg²⁺ ions between calcite and solution was found to be 0.012 ± 0.001 (10°C), 0.014 ± 0.001 (15°C), 0.019 ± 0.001 (25°C), 0.024 ± 0.001 (30°C), 0.027 ± 0.001 (35°C) and 0.040 + 0.003 (50°C). This indicates a remarkable dependence on temperature. The effect of the Mg²⁺/Ca²⁺ molar ratio in a parent solution on λ_Mg for calcite is small, where the molar ratio lies in the range 0.04-2. However, the λ_Mg value for aragonite tends to decrease with increasing Mg²⁺/Ca²⁺ ratio in the parent solution. The largest Mg content of calcite in the Ca(HCO₃)₂-Mg²⁺ → calcite system is around 2 mol% in the temperature range 10–50°C. Neither homogeneous nor heterogeneous distribution laws hold for aragonite precipitation, and the temperature effect on the coprecipitation of Mg²⁺ ions with aragonite is very small.  相似文献   

Introduction to special issue on natural halocarbons in the atmosphere     

Lucy?J.?CarpenterEmail authorView author&#;s OrcID profile  Yoko?Yokouchi  Elliot?L.?Atlas 《Journal of Atmospheric Chemistry》2017,74(2):141-143

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Robustness,uncertainties, and emergent constraints in the radiative responses of stratocumulus cloud regimes to future warming   总被引：1，自引：0，他引：1  

Yoko Tsushima  Mark A. Ringer  Tsuyoshi Koshiro  Hideaki Kawai  Romain Roehrig  Jason Cole  Masahiro Watanabe  Tokuta Yokohata  Alejandro Bodas-Salcedo  Keith D. Williams  Mark J. Webb 《Climate Dynamics》2016,46(9-10):3025-3039

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Changes in paleoseismic studies of active faults in Japan since the 1995 Kobe earthquake     

Yoko Ota 《Journal of Geodynamics》2000,29(3-5)

This paper discusses recent progress of onshore active faults studies in Japan, especially since the 1995 destructive Kobe earthquake, when the number of trenching studies, which are essential for the reconstruction of onshore paleoearthquakes, has rapidly increased. The timing and repeat interval of paleoearthquakes are here reviewed for the Miura Peninsula, south of Tokyo and the Awaji Island and Kobe-Osaka area, in central Japan, where trenching have been carried out very intensively in the last few years.  相似文献   

Comparison of FT‐IR spectra of bulk and acid insoluble organic matter in chondritic meteorites: An implication for missing carbon during demineralization     

Yoko Kebukawa  Conel M. O'D. Alexander  George D. Cody 《Meteoritics & planetary science》2019,54(7):1632-1641

Past studies of the various separable carbonaceous fractions have been unable to account for all of C in primitive chondrites. In particular, up to 20–50% of the C is lost during acid leaching of bulk samples even after the C in carbonates and soluble organic matter is accounted for. To try to better characterize the nature of this “missing C,” we have compared the bulk infrared (IR) absorption spectra of a number of primitive chondrites with those of their previously reported insoluble organic matter (IOM). The aliphatic C–H stretching bands, in particular, allow us to compare the molecular structures of bulk C with that of IOM. The spectral differences between bulk C and IOM reflect “missing C” phases that were lost during acid leaching, although we cannot completely exclude the possibility that the OM was modified after demineralization. Comparing IR spectra of bulk meteorite powder and IOM suggests that the missing C varies in its molecular structure, and that mildly thermally metamorphosed type 3 chondrites tend to be richer in an aliphatic fraction with lower CH₂/CH₃ ratios, relative to IOM, compared to aqueously altered carbonaceous chondrites (CI/CM/CR). The missing C is most likely released from acid‐labile functional groups, such as esters, acetals, and amides, during demineralization, although it cannot be ruled out that some fraction of the missing C is in small grains that are difficult to recover from suspension, or in water‐soluble compounds trapped in phyllosilicates.  相似文献   

Further characterization of carbonaceous materials in Hayabusa‐returned samples to understand their origin     

Masayuki Uesugi  Motoo Ito  Hikaru Yabuta  Hiroshi Naraoka  Fumio Kitajima  Yoshinori Takano  Hajime Mita  Yoko Kebukawa  Aiko Nakato  Yuzuru Karouji 《Meteoritics & planetary science》2019,54(3):638-666

Carbonaceous materials in the sample catcher of the Hayabusa spacecraft were assigned as category 3 particles. We investigated the category 3 particles with a suite of in situ microanalytical methods. Possible contaminants collected from the cleanrooms of the spacecraft assembly and extraterrestrial sample curation center (ESCuC) were also analyzed in the same manner as category 3 particles for comparison. Our data were integrated with those of the preliminary examination team for category 3 particles. Possible origins for the category 3 particles include contamination before and after the operation of the Hayabusa spacecraft.  相似文献   

Heating experiments of the Tagish Lake meteorite: Investigation of the effects of short‐term heating on chondritic organics     

Queenie H. S. Chan  Aiko Nakato  Yoko Kebukawa  Michael E. Zolensky  Tomoki Nakamura  Jessica A. Maisano  Matthew W. Colbert  James E. Martinez  A. L. David Kilcoyne  Hiroki Suga  Yoshio Takahashi  Yasuo Takeichi  Kazuhiko Mase  Ian P. Wright 《Meteoritics & planetary science》2019,54(1):104-125

We present in this study the effects of short‐term heating on organics in the Tagish Lake meteorite and how the difference in the heating conditions can modify the organic matter (OM) in a way that complicates the interpretation of a parent body's heating extent with common cosmothermometers. The kinetics of short‐term heating and its influence on the organic structure are not well understood, and any study of OM is further complicated by the complex alteration processes of the thermally metamorphosed carbonaceous chondrites—potential analogues of the target asteroid Ryugu of the Hayabusa2 mission—which had experienced posthydration, short‐duration local heating. In an attempt to understand the effects of short‐term heating on chondritic OM, we investigated the change in the OM contents of the experimentally heated Tagish Lake meteorite samples using Raman spectroscopy, scanning transmission X‐ray microscopy utilizing X‐ray absorption near edge structure spectroscopy, and ultraperformance liquid chromatography fluorescence detection and quadrupole time of flight hybrid mass spectrometry. Our experiment suggests that graphitization of OM did not take place despite the samples being heated to 900 °C for 96 h, as the OM maturity trend was influenced by the heating conditions, kinetics, and the nature of the OM precursor, such as the presence of abundant oxygenated moieties. Although both the intensity of the 1s?σ* exciton cannot be used to accurately interpret the peak metamorphic temperature of the experimentally heated Tagish Lake sample, the Raman graphite band widths of the heated products significantly differ from that of chondritic OM modified by long‐term internal heating.  相似文献   

Spatial distribution of organic matter in the Bells CM2 chondrite using near‐field infrared microspectroscopy     

Yoko KEBUKAWA  Satoru NAKASHIMA  Michio ISHIKAWA  Kento AIZAWA  Tsutomu INOUE  Keiko NAKAMURA‐MESSENGER  Michael E. ZOLENSKY 《Meteoritics & planetary science》2010,45(3):394-405

Abstract– Distributions of organic functional groups as well as inorganic features were analyzed in the Bells (CM2) carbonaceous chondrite using near‐field infrared (NFIR) spectroscopy. NFIR spectroscopy has recently been developed to enable infrared spectral mapping beyond the optical diffraction limit of conventional Fourier transform infrared microspectroscopy. NFIR spectral mapping of the Bells 300 nm thick sections on Al plates for 7.5 × 7.5 μm² areas showed some C‐H‐rich areas which were considered to represent the organic‐rich areas. Heterogeneous distributions of organic matter as well as those of inorganic phases such as silicates (Si‐O) were observed with 1 μm spatial resolution. The NFIR mappings of aliphatic C‐H (2960 and 2930 cm^?1) and structural OH (3650 cm^?1) confirm that organic matter is associated with phyllosilicates as previously suggested. The NFIR mapping method can provide 1 μm spatial distribution of organic functional groups and their association with minerals. High local sensitivity of NFIR enables us to find organic‐rich areas and to characterize them by their aliphatic CH₂/CH₃ ratios. The aliphatic CH₂/CH₃ ratio of Bells is slightly higher than Murchison, similar to Orgueil, and lower than literature values of IDPs and cometary dust particles.  相似文献   

Validation of TRMM Precipitation Radar satellite data over Indonesian region     

Rakhmat Prasetia  Abd. Rahman As-syakur  Takahiro Osawa 《Theoretical and Applied Climatology》2013,112(3-4):575-587

Research has been conducted to validate monthly and seasonal rain rates derived from the Tropical Rainfall Measuring Mission Precipitation Radar (PR) using rain gauge data analysis from 2004 to 2008. The study area employed 20 gauges across Indonesia to monitor three Indonesian regional rainfall types. The relationship of PR and rain gauge data statistical analysis included the linear correlation coefficient, the mean bias error (MBE), and the root mean square error (RMSE). Data validation was conducted with point-by-point analysis and spatial average analysis. The general results of point-by-point analysis indicated satellite data values of medium correlation, while values of MBE and RMSE tended to indicate underestimations with high square errors. The spatial average analysis indicated the PR data values are lower than gauge values of monsoonal and semi-monsoonal type rainfall, while anti-monsoonal type rainfall was overestimated. The validation analysis showed very good correlation with the gauge data of monsoonal type rainfall, high correlation for anti-monsoonal type rainfall, but medium correlation for semi-monsoonal type rainfall. In general, the statistical error level of monthly seasonal monsoonal type conditions is more stable compared to other rainfall types. Unstable correlations were observed in months of high rainfall for semi-monsoonal and anti-monsoonal type rainfall.  相似文献   

Evaluation of various satellite sensors for waterline extraction in a coral reef environment: Majuro Atoll, Marshall Islands   总被引：4，自引：0，他引：4  

Hiroya Yamano  Hiroto Shimazaki  Tsuneo Matsunaga  Albon Ishoda  Caleb McClennen  Hiromune Yokoki  Kazuhiko Fujita  Yoko Osawa  Hajime Kayanne 《Geomorphology》2006,82(3-4):398-411

The ability of five satellite sensor bands (IKONOS band 4, Terra ASTER bands 3 and 4, and Landsat ETM+ bands 4 and 5) was examined to extract the waterline at coral reef coasts (Majuro Atoll, Marshall Islands) using different wavelength regions (near infrared [NIR] and shortwave infrared [SWIR]) and different spatial resolutions (4, 15, and 30 m). After performing georeferencing and normalization of the images, density slicing was used to extract the waterline. Comparisons of extracted waterline positions with ground-level data for eight transects and global positioning system (GPS) tracks of the island shorelines showed that NIR bands were superior to SWIR bands because of the characteristics of the coral reef coasts, including a lack of foam and suspended sediments (which can affect the NIR wavelength region, if present) and the presence of remnant water on reef flats during low tide (which can affect the SWIR wavelength region). A linear relationship was found between the estimation errors of waterline positions and the spatial resolutions of the NIR sensors. Analysis on estimation errors and image costs showed that Terra ASTER band 3 was the most cost-effective sensor for extracting waterlines with reasonable accuracy. The results serve as general guidelines for using satellite-derived data to estimate intertidal topography and detect and monitor shorelines in coral reef environments.  相似文献