Electron spin resonance of stabilized free radicals in sedimentary organic matter     

Zeev Aizenshtat  Ida Pinsky  Baruch Spiro   《Organic Geochemistry》1986,9(6)

Electron spin resonance (ESR) is evaluated as a method to study the thermal degradation of sedimentary organic matter which consists mainly of kerogen. Whole rock and separated kerogen samples were pyrolysed stepwise (ambient to 700°C at 50°C increments), extracted and analysed for elemental composition and ESR spectra at each step. Whole rock samples give rise to complex spectra which include those of paramagnetic metals and are therefore unsuitable in most cases for this purpose.The ESR parameters g value, ΔH and N_g differ for different types of immature organic matter. An increase in N_g,shift of g value to 2.0026–2.0028 and reduction in h are the main trends during pyrolysis and in natural heating of sedimentary organic matter.The peak generations of liquid and gaseous hydrocarbons coincide with maxima of free radical density. ESR spectroscopy in combination with complementary geochemical characterization of the sedimentary organic matter can serve to indicate maturity with respect to peak oil-gas generation.  相似文献   

Fine structure of laboratory wind-wave surfaces studied using an optical method     

Naoto Ebuchi  Hiroshi Kawamura  Yoshiaki Toba 《Boundary-Layer Meteorology》1987,39(1-2):133-151

The fine structure of laboratory wind-wave surfaces was investigated using an optical method. Several characteristic structures, closely associated with wind speed and the stage of development of the waves, are described. A parallel light, incident on the wind-wave surface, was backscattered by specular facets perpendicular to the incident angle. These specular facets, which represented the fine structures, were photographed and quantitatively analyzed by image processing techniques.For wind speeds ranging from 3.6 to 13.6 m s^–1, different types of small-scale undulations appeared: a three-dimensional rhombic structure; a train of capillary waves on the forward face with wavelengths gradually decreasing with distance from the crest, and a streaky structure on the backward face in the direction of the wind; and random and wide-spreading irregularities covering the whole wind-wave surface. The spatial scales and temporal variation of the undulations are described.  相似文献   

Low frequency electrical impedance of partially molten gabbro: The effect of melt geometry on electrical properties     

Hiroki Sato  Yoshiaki Ida 《Tectonophysics》1984,107(1-2)

Electrical impedance of partially molten gabbro was measured as a function of the frequency of the applied electric field. The impedance of the partially molten gabbro was mainly controlled by the volume and geometry of partial melt, which were observed with an optical microscope study of the quenched sample. The experimental results are interpreted by a theory that formulates the electrical property of rocks containing partial melt, taking ionic diffusion in the melt into account. The theory evaluates the contributions from two types of melt-geometry distributed in the rock matrix, namely:

1. (a) nearly isolated melt pockets, and

2. (b) connected melt along grain boundaries.

According to the theory, connected melt mainly contributes to the increase of net conductivity, while melt pockets increase displacement current and cause the frequency dependence of impedance. The characteristic ionic diffusivity in melt pockets was determined from the peak frequency of the imaginary part of impedance. The magnitude of diffusion coefficient is estimated to be of the order of 10⁻⁷ to 10⁻⁶ cm²/sec. This suggests that sodium, iron, magnesium and/or calcium ions mainly carry the electric charge in partial melt. The observed frequency dependence of impedance is considered to reflect ionic polarization in melt pockets due to the migration of these alkali ions toward solid-melt interfaces.The present experimental and theoretical work suggests that electrical properties of the earth's upper mantle may involve an intrinsic frequency dependence associated with ionic diffusion in the frequency range of geomagnetic observation, if a partial melt zone exists. The analysis of the earth's conductivity structure may be inadequate if such intrinsic frequency dependence of mantle media is neglected.  相似文献   

Far-Field Tsunami Potential and a Real-Time Forecast System for the Pacific Using the Inversion Method   总被引：1，自引：0，他引：1  

Koike  Nobuaki  Kawata  Yoshiaki  Imamura  Fumihiko 《Natural Hazards》2003,29(3):425-436

Estimating tsunami potential is anessential part of mitigating tsunami disasters. Weproposed a new method to estimate the far-fieldtsunami potential by assuming faultmodels on the Pacific Rim. We find thata tsunami that generates in the areas wherethere is no tsunami in the history can damagethe Japanese coast. This shows that it isimportant to estimate tsunami potential byassuming fault models other than the pastearthquake data.Another important activity to mitigate tsunamidisasters is to provide appropriatewarnings to coastal communities when dangerfrom a tsunami is imminent. We applied anew inversion method using wavelet transformto a part of the real-time tsunami forecastsystem for the Pacific. Because this inversionmethod does not require fault location, it ispossible to analyze a tsunami in real timewithout all seismic information. In order tocheck the usability of the system, anumerical simulation was executed assuming anearthquake at sea off Taiwan. The correlationcoefficient for the estimated initialwaveform to the assumed one was calculatedto be 0.78. It takes 90 min to capturetime-series waveform data from tsunamigauges and 5 sec to estimate the 2-D initialwaveform using the inversion method. After that,it takes 2 minutes to forecast thetsunami heights at the Japanese coast. Since thesum of these times is less than the 105minutes transit time of the tsunami fromTaiwan to Japan, it is possible to give a warningto the residents before the tsunami attacksthe Japanese coast. Comparing the tsunamiheights forecasted by this system with thosecalculated by the fault model, the averageerror was 0.39 m. The average error ofthe arrival time was 0.007 min.  相似文献   

Pan-African Alkali Granitoids from the Sør Rondane Mountains, East Antarctica     

Zilong Li  Yoshiaki Tainosho  Jun-ichi Kimura  Kazuyuki Shiraishi  Masaaki Owada 《Gondwana Research》2003,6(4):595-605

Alkali granitoids (500-550 Ma) representing a prominent Pan-African magmatic event are widely distributed in the Sør Rondane Mountains, Dronning Maud Land, East Antarctica. Geochemically, they are granitic to syenitic in composition and show an alkaline affinity of A-type granites. They are characterized by high K₂O+Na₂O (7-13 wt%) and K₂O/Na₂O (1-2), low to intermediate Mg#, wide ranges of SiO₂ (45-78 wt%), Sr (20-6500 ppm) and Ba (40-13000 ppm) and have Nb and Ti depletion in the primitive mantle normalized diagram. The granitoids are subdivided into Group I granites, Group II granites, Lunckeryggen Syenitic Complex and Mefjell Plutonic Complex. The Group I granites have higher Mg#, Sr/Ba, Sr/Y, (La/Yb)_N and LREE/HREE, lower A/CNK, SREE and initial ⁸⁷Sr/⁸⁷Sr ratios and lack Eu anomalies compared to those with negative Eu anomalies in the Group II granites. The syenitic rocks from the Mefjell Plutonic Complex are higher in alkali, Ga, Zr, Ba, and have lower Mg#, Rb, Sr, Nb, Y, F and LREE/HREE with positive Eu anomaly, whereas the granites from the Mefjell Plutonic Complex have high LREE/HREE ratios with negative Eu anomaly. The Lunckeryggen syenitic rocks have intermediate Mg#, higher K₂O, P₂O₅, TiO₂, Fe₂O₃/FeO, Ba, Sr/Y and LREE/HREE ratios with lack of Eu anomalies and are lower in Al₂O₃, Ga, Y, Nb and Rb/Sr ratios. Based on chemical characteristics combined with isotopic data, we suggest that the Lunckeryggen syenitic body and Group I granitic bodies may be derived from the mantle-derived hot basic magma by fractional crystallization with minor assimilation. We also suggest that the Group II granites may be derived from assimilation with crustal rocks to varing degrees and then fractional crystallization in higher crustal levels (ACF model). The Mefjell Plutonic Complex seems to be derived from a heterogenetic magma source compared with other granitoids from the Sør Rondane Mountains. The syenitic rocks in the Mefjell Plutonic complex have a unique source (iron-enriched) and have a chemical affinity with the charnockites in Gjelsvikjella and western Mühlig-Hofmannfjella, but not like the Yamato syenites in adjacent areas.  相似文献   

Map projection errors in the Weber problem     

Yoshiaki Ohsawa  Hirofumi Kagaya  Takeshi Koshizuka 《Journal of Geographical Systems》2002,4(3):325-342

 When demand points are given as a planar map where projection method is explicitly stated, we usually know the latitudes and longitudes of these points from the map. Then we can solve the Weber problem on the globe, and we do not suffer from errors. This paper analyses how cylindrical projections cause distortion in the Weber problem when demands are distributed on the Northern Hemisphere. First, we demonstrate that planar solutions are always located south of the spherical solution if the Mercator projection, the equirectangular projections with standard parallels near the demands, or the equal-area projection with the same characteristic is chosen. Second, we verify that this geographical tendency is inclined to hold when the demand points, are distributed symmetrically, widely or toward the north. Received: 15 August 2001 / Accepted: 20 April 2002 This paper was partially written while the first author was visiting the Department of Geography at the Catholic University of Louvain, Louvain-la-Neuve, Belgium [1993–1994]. He is grateful for the hospitality of this department. An earlier version of this paper was presented in 1994 at the Seventh Meeting of the European Operational Research Working Group on Locational Analysis in Brussels, and in 1996 at the Fifth World Congress of the Regional Science Association International in Tokyo. The authors would also like to thank the participants as well as three anonymous referees for their constructive comments.  相似文献   

Large strain analysis of some geomechanics problems by the finite element method     

Yoshiaki Yamada  Abdalla S. Wifi 《国际地质力学数值与分析法杂志》1977,1(3):299-318

This paper presents a rational approach to the finite strain analysis of elastic-plastic materials. An updated incremental finite element technique was applied to problems of shallow foundations of homogeneous as well as multilayer soils. This was based on a variational principle which is suitable for such problems.  相似文献   

Eigenvalues and eigenvectors for hybrid coordinate equations of motion for flexible spacecraft     

Yoshiaki Ohkami  Peter Likins 《Celestial Mechanics and Dynamical Astronomy》1979,19(4):359-390

Literal characterizations are developed for the eigenvalues and eigenvectors of a system of linear time-invariant equations which describes the attitude motion of flexible spacecraft in terms of hybrid coordinates. The eigenproblem is shown to reduce to that of a symmetric and positive definite matrix of lower dimension. For the zero damping case, both analytical and minimax characterization methods prove to be useful in localizing the eigenvalues, and eigenvectors for systems of large dimension are obtained explicitly in terms of a 3×1 matrix whose elements are available from a system of three algebraic equations provided.  相似文献   

Investigation of cutting methods for small samples of Hayabusa and future sample return missions     

Masayuki Uesugi  Ryo Noguchi  Tooru Matsumoto  Junya Matsuno  Takashi Nagano  Akira Tsuchiyama  Shigenori Harada  Kaori Yokoyama  Yoshiaki Yodo  Noboru Takeda  Toru Yada  Shogo Yakame  Yuzuru Karouji  Yukihiro Ishibashi  Masanao Abe  Tatsuaki Okada  Akio Fujimura  Mitsuru Ebihara  Fumio Kitajima  Keisuke Nagao  Tomoki Nakamura  Hiroshi Naraoka  Takaaki Noguchi  Ryuji Okazaki  Hisayoshi Yurimoto 《Meteoritics & planetary science》2014,49(7):1186-1201

We report the investigation of cutting methods for Hayabusa samples. The purpose of our study is to explore the possibility of applying multiple analyses to a single particle effectively. We investigated the cutting performance of a blade dicing saw, laser, focused ion beam (FIB), and physical breaking by microindenter. Cutting performance was examined by estimating the aspect ratio of the cut slit, i.e., depth over width of the slit. We also investigated the possible contamination and sample damage by cutting. The result of the investigation shows that we can cut the samples from <50 μm to 500 μm using those methods with aspect ratios from 10 to 20, although they would introduce some contamination or damage to the samples. Our investigations also provide an important basis for the analysis of samples obtained by future sample return missions.  相似文献   

The Scutum ring ofHii regions     

Toshihiro Handa  Yoshiaki Sofue 《Astrophysics and Space Science》1986,119(1):127-130

A ring of compact radio continuum sources was found atl=24°.6b=0°.0, which we call the Scutum ring. Radio continuum,Hi line, and CO line observations are suggested that it is a star-forming region triggered by an expanding diffuseHii region.Paper presented at the IAU Third Asian-Pacific Regional Meeting, held in Kyoto, Japan, between 30 September–6 October, 1984.NRO, a branch of the Tokyo Astronomical Observatory, University of Tokyo, is a cosmic radio observing facility open for outside users.  相似文献