The superstructure of plagioclase feldspars     

Yoshiharu Nakajima  Nobuo Morimoto  Masao Kitamura 《Physics and Chemistry of Minerals》1977,1(2):199-212

A modulation function representing the position and density of (Na, Ca) atoms in the superstructure of the e-plagioclase has been derived from the average structures of different plagioclase and a general modulation theory. Based on this function the superstructure of bytownite (An₇₃) has been studied with the single crystal X-ray method. The cell dimensions by Megaw's axes are a=7.946(3)A, b=67.09(2)A, c=12.236(4)A, α=39.03(1)°, β=45.63(1)° and γ=59.63(1)°. Z=18(Na, Ca) Al(Al, Si)Si₂O₈. The initial phase factor of the modulation function for bytownite has been obtained from the intensity data of the satellite reflections. This modulation function indicates a coherent small-scale alternation of the Na-rich and Ca-rich bands in the superstructure. This superstructure has been refined by applying the albite and anorthite structures to the Na-rich and Ca-rich bands, respectively. The change of the superstructure of the e-plagioclase due to the compositional change has been described based on the movements of the satellites in reciprocal space. The direction of the coherent small-scale intergrowth of the anorthite-like and albite-like bands is perpendicular to the t vector. The thickness of the intergrowth is 1/|t|. Both direction and thickness change regularly from An₇₅ to An₂₅.  相似文献   

Content and behavior of fluorine in Japanese quaternary volcanic rocks and petrogenetic application     

Ken-Ichi Ishikawa  Satoshi Kanisawa  Ken-Ichiro Aoki 《Journal of Volcanology and Geothermal Research》1980,8(2-4)

Fluorine contents in about 160 representative Quaternary volcanic rocks and 15 hornblende and biotite phenocrysts in a calc-alkali series in Japan have been determined by a selective ion-electrode method. Tholeiites have the lowest contents and the narrowest range (58–145 ppm), while alkali basalts have the highest contentws and the widest range (301–666 ppm), high-alumina basalts have intermediate values (188–292 ppm). F contents in basalts clearly increase from east to west across the Japanese Islands, as do alkalies, P₂O₅ REE, U, Th and H₂O.The volcanic rocks studied are divided into two groups on the basis of F: (1) witt, increasing % SiO₂ or advancing fractionation, F contents show either progressive enrichment; or (2) with increasing fractionation, F contents show rather constant values. The former is produced by fractionation of anhydrous phases from basalt to mafic andesite magmas; the tholeiite series of Nasu volcanic zone (outer zone), northeastern, Japan is a typical example. The latter group is derived through separation of amphibole-bearing phases from basaltic magmas at various depths from upper mantle (about 30 km) to upper crust; the alkali series in southwestern Japan and the calc-alkali series of Chokai volcanic zone (inner zone), northeastern Japan, are examples.  相似文献   

Timing of Himalayan ultrahigh-pressure metamorphism: sinking rate and subduction angle of the Indian continental crust beneath Asia   总被引：28，自引：0，他引：28  

Y. Kaneko  I. Katayama  H. Yamamoto  K. Misawa  M. Ishikawa  H. U. Rehman  A. B. Kausar  K. Shiraishi 《Journal of Metamorphic Geology》2003,21(6):589-599

Coesite relics were discovered as inclusions in clinopyroxene in eclogite and as inclusions in zircon in felsic and pelitic gneisses from Higher Himalayan Crystalline rocks in the upper Kaghan Valley, north‐west Himalaya. The metamorphic peak conditions of the coesite‐bearing eclogites are estimated to be 27–32 kbar and 700–770 °C, using garnet–pyroxene–phengite geobarometry and garnet–pyroxene geothermometry, respectively. Cathodoluminescence (CL) and backscattered electron (BSE) imaging distinguished three different domains in zircon: inner detrital core, widely spaced euhedral oscillatory zones, and thin, broadly zoned outermost rims. Each zircon domain contains a characteristic suite of micrometre‐sized mineral inclusions which were identified by in situ laser Raman microspectroscopy. Core and mantle domains contain quartz, apatite, plagioclase, muscovite and rutile. In contrast, the rim domains contain coesite and minor muscovite. Quartz inclusions were identified in all coesite‐bearing zircon grains, but not coexisting with coesite in the same growth domain (rim domain). ²⁰⁶Pb/²³⁸U zircon ages reveal that the quartz‐bearing mantle domains and the coesite‐bearing rim were formed at c. 50 Ma and 46.2 ± 0.7 Ma, respectively. These facts demonstrate that the continental materials were buried to 100 km within 7–9 Myr after initiation of the India–Asia collision (palaeomagnetic data from the Indian oceanic floor supports an initial India‐Asia contact at 55–53 Ma). Combination of the sinking rate of 1.1–1.4 cm year^?1 with Indian plate velocity of 4.5 cm year^?1 suggests that the Indian continent subducted to about 100 km depth at an average subduction angle of 14–19°.  相似文献   

Petrology, geochemistry and paleogeographic reconstruction of the East Sulawesi Ophiolite, Indonesia     

Ade Kadarusman  Sumio Miyashita  Shigenori Maruyama  Christopher D. Parkinson  Akira Ishikawa 《Tectonophysics》2004,392(1-4):55

The East Sulawesi Ophiolite (ESO) is tectonically dismembered and widely distributed in Central and East Sulawesi. It comprises, from base to top, residual mantle peridotite and mafic–ultramafic cumulate through layered to isotropic gabbro, to sheeted dolerites and basaltic volcanic rocks. Residual peridotite is dominantly spinel lherzolite intercalated with harzburgite and dunite. Ultramafic rocks from different locations display significant differences in rock composition and mineral. However, the clinopyroxene of peridotite displays REE pattern similarities with those of mid-ocean ridge (MOR) origin, rather than those of suprasubduction zone (SSZ) origin. The gabbroic unit consists of massive gabbro, layered gabbro, mafic and ultramafic cumulate and anorthosite. The observed crystallization sequence of gabbroic unit, which is olivine→(spinel)→plagioclase→clinopyroxene→(orthopyroxene)→(hornblende), and the mineral chemistry data indicate that the ESO gabbro has similarities with MOR setting.Major and trace element geochemistry of basalt and dolerite suggests MOR, oceanic plateau and minor SSZ origins. A possible oceanic plateau origin is supported by the following: (i) the 15-km thickness is comparable with the thickness of oceanic plateau rather than normal oceanic lithosphere; (ii) there are no or only minor olivine phenocrysts in the basalt; and (iii) predominance of aphyric texture in the basalts. The REE pattern of ESO basalt exhibits N-MORB-like signatures. However, a negative Nb anomaly in the trace element spider diagram may be attributed to mantle heterogeneity of an OPB source.The geochemical variations and disparities for both peridotite and basalt and the noncogenetic relationship between crust and mantle sections in several locations suggest that the ESO may have been formed at one tectonic setting and was later overprinted by magmatism in different environments through its birth to emplacement. A possible Cretaceous origin of an oceanic plateau component of the ESO is indicated on the basis of calculated paleopositions using plate trajectory analyses together with previously published paleolatitude data. The ESO can be traced back to the proximity of the presently active region of the SW Pacific Superplume.  相似文献   

Crustal thermal regime inferred from magnetic anomaly data and its relationship to seismogenic layer thickness: The Japanese islands case study   总被引：2，自引：0，他引：2  

Akiko Tanaka  Yuzo Ishikawa 《Physics of the Earth and Planetary Interiors》2005,152(4):257-266

The seismogenic layer thickness correlates with surface heat flow beneath the Japanese islands. However, this correlation is shown at restricted area, where seismic activity is high. In order to overcome this spatial limitation, we used another approach to estimate the regional thermal structure in the crust beneath the Japanese islands with more uniform coverage. The bottom depths of the magnetized crust determined from the spectral analysis of residual magnetic anomalies is generally interpreted as the level of the Curie point isotherm. We applied this method to estimate the crustal thermal structure in square windows of 2.125° × 2.125°. The obtained depths ranging from 11 to 30 km with average value of 18 km, correlate with the seismogenic layer thickness. It suggests that the Curie point depth is a useful indicator of the crustal thermal structure in these regions.  相似文献   

Underground oil storage facilities in Japan     

Toshiaki Makita  Yoshiharu Miyanaga  Keiji Iguchi  Teruyoshi Hatano 《Engineering Geology》1993,35(3-4):191-198

In Japan, three underground crude-oil storage facilities with a total capacity of 5 million kl are under construction as a chain of the national oil storage project. Because the NATM method was used in this project, we applied a systematic work control system, consisting ofin situ measurements and engineering geological observations, including an original rock-mass classification system. The classification system used can be slightly modified depending upon site-specific geological conditions and the purposes of the facilities such as, i.e., an artificial water sealing system.  相似文献   

Meteorological features in Adélie Land during the austral summer season     

Nobuyoshi Ishikawa  Yuji Kodama  Gerd Wendler 《Pure and Applied Geophysics》1990,132(3):439-455

Intensive meteorological observations were carried out at three sites along the slope of Adélie Land, Antarctica, with the goal of documenting summertime meteorological features of the katabatic zone. Three observational sites were placed at 5 km (D10), 110 km (D47), and 210 km (D57) from the coast, and frequency distributions of meteorological parameters were obtained at each site. Some meteorological features at D47 and D57 (interior sites) were different than at D10 (the coastal site); namely, mean air temperatures averaged for the whole observational period showed more pronounced diurnal variations at the interior sites than at the coastal site. These variations could be represented by sinusoidal curves. Wind speeds also showed diurnal variations, whose extremes appeared several hours later than the temperature extremes. The prevailing wind direction for all sites was southerly, about 30° east of the fall line, with small variations in wind direction. The strength and the height of temperature inversions were examined in two different layers (0 to 50 m, 50 to 300 m) at D47. A strong, shallow inversion layer formed at night, however, completely vanished during the day. On the other hand, an upper level inversion whose strength was weak persisted. The katabatic characteristics of the surface wind found at D47 in summer could be due to this upper level temperature inversion.A contribution to I.A.G.O. (Interaction-Atmosphere-Glace-Ocean).  相似文献   

Feldspar dissolution rates measured using phase-shift interferometry: Implications to CO₂ underground sequestration     

M. Sorai  T. Ohsumi  M. Ishikawa  K. Tsukamoto 《Applied Geochemistry》2007,22(12):2795

To assess CO₂ underground sequestration from a geochemical viewpoint, the anorthite dissolution rate, which is an important parameter of risk analysis, was measured in a CO₂–water system. The authors sought to obtain precise dissolution rate data in a short time observing a crystal surface on a nanoscale. For this purpose, phase-shift interferometry was applied. Using this method, uncertainty of the reactive surface area that is imparted on calculation of the dissolution rate constant can also be avoided. The time-course profile of vertical retreat of the surface revealed that the anorthite dissolution process changes from the initial transient state to a later steady state, which is consistent with results of numerous precedent studies. The transient dissolution rate depends strongly on local features (e.g., density of defects, variation of chemical compositions) of the crystal surface, rather than on temperature. Therefore, it is very important to determine the original properties of the anorthite surface for the examination of subsequent dissolution process. Contrary to general expectations, the anorthite dissolution can alter the physical properties of reservoir rock immediately after CO₂ injection. The simple estimation using the anorthite dissolution rate obtained in this study, which was done as a test case for the CO₂ underground sequestration project conducted by RITE, revealed that porosity of reservoir rock increased about 2% (23–23.4%) of initial values during 60 a. That change in physical property in such a short time might enhance the diffusion of injected CO₂ and formation water, and therefore accelerate further geochemical reactions. Results of this study demonstrate that the geochemical water–rock interaction, which is generally regarded as a longer-term phenomenon than various physical processes, can also affect the reservoir system from the initial stage.  相似文献   

Spectral similarity between scalars at very low frequencies in the unstable atmospheric surface layer over the Tibetan plateau   总被引：1，自引：7，他引：1  

Jun Asanuma  Ichiro Tamagawa  Hirohiko Ishikawa  Yaoming Ma  Taiichi Hayashi  Yongqiang Qi  Jiemin Wang 《Boundary-Layer Meteorology》2007,122(1):85-103

Similarity between temperature and water vapour was investigated in the Fourier domain by using their coherency spectra, defined as the correlation coefficient between their Fourier modes, and the relative efficiency of their vertical transport. The class-averaged values of these indices were computed from the turbulence measurements over sparse grasslands on the Tibetan plateau during the intensive observations of GEWEX (Global Energy and Water Experiment) Asian Monsoon Experiment (GAME). It was found that the energy-containing eddies at scales up to 100z (z being height) are characterised by well-maintained similarity between these scalars. The scalars are highly correlated with each other, and their transport efficiencies are almost equal within this scale range. In contrast, similarity was not always maintained at scales larger than 1000z. Detailed analyses showed that this breakdown of similarity occurs occasionally or sporadically, suggesting that it is caused by events whose average return period is not much smaller than the current averaging time, i.e. 30 min. We speculate that entrainment of drier and warmer air at the top of the atmospheric boundary layer caused the scalar dissimilarity at this scale range.  相似文献   

Radiative characteristics in a Japanese forested drainage basin during snowmelt     

H. Nakabayashi  N. Ishikawa  Y. Kodama 《水文研究》1999,13(2):157-167

Radiative characteristics in a forested drainage basin during the snowmelt season were examined in order to better understand and predict snowmelt runoff in the basin. A method for estimating net radiation in a forest (R_nf) was presented using the total sky view factor (P) and the sun path sky view factor (Q). Solar radiation, albedo, atmospheric radiation and air temperature observed at an open site were also required. The total and the sun path sky view factors were determined from all‐sky photographs. Q was expressed as a linear function of P for 0·15<P<0·86 regardless of forest type. For P<0·15, Q was set to zero, and for P>0·86, Q was equal to unity. The short‐wave radiation budget at the forest floor (S_nf) increased with P, whereas the long‐wave radiation budget (L_nf) decreased with P. R_nf increased with P for 0·15<P<0·86, and changed little with P for P<0·15 and P>0·86, as the increase in S_nf was offset by the decrease in L_nf . The forest effect on R_nf was diminished under cloudy or high albedo conditions, because S_nf was easily offset by L_nf . This estimation method was extended to the whole basin, and R_nf was obtained over a watershed covered by trees. At the beginning of the snowmelt season when the albedo remained high, the forest effect became null because the decrease in S_nf was balanced by the increase in L_nf . As the albedo gradually lowered with the advance of the snowmelt season, the decrease in S_nf owing to forest covers exceeded the increase in L_nf , and the forest effect to decrease R_nf became evident. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献