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51.
During the early part of a seismic swarm preceding eruption and caldera formation at Miyakejima Volcano, discoloured sea surfaces were observed 1.5 km off the western coast of Miyakejima on 27 June 2000. A later survey of the area using a multi-beam side scan sonar and a remotely operated small submarine revealed four craters of 20–30 m diameter aligned east-west in a 100×10–30 m area on the seafloor, with hot water at 140°C being released from one of the centres. Each crater consists of submarine spatter overlain in part by scoria lapilli. Dredged spatter from the craters was fresh, and there was no evidence of activity of marine organisms on the spatter surface, indicating that the discoloured sea surface resulted from magmatic eruption on the seafloor. This eruption occurred when a westward-propagating seismic swarm, initiated beneath Miyakejimas summit, passed through the area. Finding new magma on the seafloor demonstrates that this seismic swarm was associated with intruding magma, moving outward from beneath Miyakejima. Submarine spatter shows flattened shapes with a brittle crust formed by cooling in water, and its composition is aphyric andesite of 54 wt% SiO2. The spatter is similar in whole rock and mineral composition to spatter erupted in 1983. However, the wide range of Cl in melt inclusions in plagioclase of the 27 June submarine spatter shows that it is not simply a remnant of the 1983 magma, which has only high Cl melt inclusions in plagioclase. The mixed character of melt inclusions suggests involvement of a magma with low Cl melt inclusions. The magma erupted explosively on 18 August from Miyakejimas summit, considered as the second juvenile magma in this eruption, contains low Cl melt inclusions in plagioclase. Based on these observations and the eruption sequence, we present the following model: (1) A shallow magma chamber was filled with a remnant of 1983 magma that had evolved to a composition of 54–55 wt% SiO2. (2) Injection of the 18 August magma into this chamber generated a mixed magma having a wide range of Cl in melt inclusions contained plagioclase. The magma mixing might have occurred shortly before the submarine eruption and could have been a trigger for the initiation of the removal of magma from the chamber as an extensive dyke, which eventually led to caldera subsidence.Editorial responsibility: S Nakada, T Druitt  相似文献   
52.
A survey of the quality of groundwater across a broad area of the North China Plain, undertaken in 1998 to 2000, indicates that nitrate pollution is a serious problem affecting the drinking water for a vast population. The use of nitrogen (N)-fertilizer in agriculture has greatly increased over the past 20 years to meet the food needs of the rapidly expanding population. During the study, 295 water samples were collected from wells and springs to determine the water chemistry and the extent of nitrate pollution. High concentrations of nitrate, especially in a recharge area along the western side, but also in the vicinity of Beijing and locally in other parts of the plain, pose a serious problem for the drinking water supply. In places, the nitrate concentration exceeds the maximum for safe drinking water of 45 mg/L. The intense use of N-fertilizer and the widespread use of untreated groundwater for crop irrigation contribute greatly to the problem, but no doubt the disposal of industrial and municipal waste into streams and infiltrating the aquifer also contribute to the problem; however, the lack of data prevents evaluation of those sources. In the recharge area, nitrate is found at depths of as much as 50 m. Near Beijing, relatively high concentrations of nitrate occur at depths of as much as 80 m. In the discharge area, in the vicinity of the Yellow River, high concentrations of nitrate occur at depths of <8 m.

Electronic Supplementary Material Supplementary Material is available in the online version of this article at
Resumen Contaminacíon de nitratos a causa de prácticas agrícolas en diferentes zonas hidrogeológicas del sistema de flujo regional de aguas subterráneas en la planice del norte de China. Un estudio de la calidad del agua subterránea en una zona amplia de la planice del norte de China se llevó a cabo entre 1998 y el año 2000. Este estudio indica que la contaminación de nitratos es un problema grave que afecta el agua potable de una vasta población. El uso de fertilizantes a base de nitratos en la agricultura ha aumentado considerablemente durante los últimos 20 años para satisfacer las necesidades alimentices de la creciente población. Durante el estudio, se tomaron 295 muestras de pozos de agua y manantiales para determinar la química de las aguas y el grado de contaminación por nitratos. Altas concentraciones de nitratos, especialmente en una zona de recarga a lo largo del lado oeste, asì como en la cercanía a Pekín y en zonas locales en otras partes de la planicie, presentan un problema serio al sumunistro de agua potable. En ciertos lugares, la concentracióon de nitratos excede el nivel máximo de seguridad para el agua potable 45 mg NO3/L. El intenso uso de fertilizantes de nitratos y el abundante uso de agua subterránea sin tratamiento para la irrigación de cultivos contribuyen sustancialmente al problema. Sin embargo, sin lugar a dudas, la descarga de deshechos industriales y municipales en arroyos y en el acuífero también contribuyen al problema. La falta de datos impide la evalución de dichas fuentes. En la zona de recarga se encuentran nitratos hasta los 50 m de profundidad. Cerca a Pekín, concentraciones relativamente altas de nitrato ocurren hasta los 80 m de profunidad. En las zonas de descarga afectadas por el Río Amarillo las concentraciones altas de nitrato se encuentran solamente a menos de 8m de profundidad.

Resumé Une campagne dévaluation de la qualité de leau souterraine entreprise entre 1998 et 2000 à travers une vaste étendue de la plaine du nord en Chine indique que la pollution par les nitrates est un problème sérieux qui affecte la qualité de leau souterraine pour une abondante population. Lutilisation de fertilisants azotés pour lagriculture a augmenté considérablement durant les 20 dernières années afin de rencontrer les besoins alimentaires dune population à forte croissance. Lors de cette étude, 295 échantillons deau ont été prélevés dans des puits et sources naturelles afin de déterminer la composition chimique de leau souterraine ainsi que létendue de la pollution par les nitrates. Des concentrations élevées de nitrates, en particulier dans une zone de recharge le long de la limite ouest de la plaine, mais aussi dans la région de Beijing et sporadiquement dans la plaine, posent de sérieux problèmes à la consommation de leau souterraine. A certains endroits, la concentration en nitrates excède la valeur maximale acceptée pour la consommation qui est de 45 mg NO3/L. Lutilisation intensive de fertilisants azotés ainsi que lutilisation répandue deau souterraine non traitée pour lirrigation contribuent pour beaucoup au problème, mais il ne fait pas de doute que le rejet des déchets municipaux et industriels dans les rivières et aquifères y est aussi pour quelque chose. Par contre, le manque de donnés ne permet pas dévaluer la contribution de chacune de ces sources. Dans la zone de recharge, les nitrates se retrouvent à des profondeurs allant jusquà 50 m. Près de Beijing, des concentrations relativement élevées de nitrate ont été mesurées à des profondeurs allant jusquà 80 m. Enfin, dans la zone démergence affectée par la rivière Jaune, les fortes concentrations se retrouvent à une profondeur maximale de 8 m.
  相似文献   
53.
The contaminant-induced cytochrome P450 (CYP) members in minke whale (Balaenoptera acutorostrata) can be potential biomarkers of the contaminant exposure and toxic effects. In this study, we constructed a cDNA library from the liver of minke whale from the North Pacific, and further screened a total of 6930 clones randomly selected in the library for the isolation of cDNA clones encoding novel members of CYP superfamily. The screening revealed the isolation of six novel CYP cDNA clones that are classified into CYP1A, CYP2C, CYP2E, CYP3A, CYP4, and CYP4A subfamilies. The BLAST homology search using the partial cDNA fragments of four CYP subfamilies (CYP1A, CYP2C, CYP2E and CYP4A) demonstrated that the minke whale CYPs were most closely related to pig CYPs (81-91%). Identification of multiple CYP genes in marine mammal species such as minke whale will provide new insights into the metabolic or toxicological functions of individual CYP members.  相似文献   
54.
The mechanism and rate of water exchange were investigated in Kabira Cove, Ishigaki Island, in the southernmost part of Japanese islands, near Taiwan. During observations in the summers of 1976 and 1977, a larger proportion of the salt transport into the bay was derived from the so-called “tidal trapping effect”. In the latter period of observation carried out after heavy rain brought by a seasonal typhoon under annual mean tidal conditions, the turnover time, i.e. the scale of replacement of the whole bay water with the open sea water, is estimated to be 3.6 days. Based on these observational results, a concept of the tidal trapping due to coupling of the actions of tides and buoyancy in a vertical two-dimensional field with a sill at the bay mouth is proposed. Considering the topographical, hydrometeorological and geographical conditions of the cove, it is inferred that this water exchange process tends to be formed in Kabira Cove in summer except during neap tides.  相似文献   
55.
The year-to-year change in characteristics of water exchange between Lake Hamana, a semi-enclosed bya, and the adjacent open sea is investigated.The destruction of the bay mouth by a typhoon in 1953 and subsequent stabilization work on the bay mouth from 1954 to 1973 resulted in an increase in the tidal prism volume of the bay (Mazda, 1983). In the present paper, a simple model has been constructed in which the magnitude of water exchange depends on the tidal prism, and using this model, the year-to-year increase in salinity of the bay water after 1953 can be well explained. Consequently, it can be said that the salinity increase after 1953 is a result of a progressive increase in water exchange caused by successive changes in topography of the bay mouth.The extent of water exchange in Lake Hamana, which varies seasonally, has increased gradually since 1953, and became stable after about 1967. For instance, at present the turnover time of the bay for exchange with open sea water reaches a maximum (2.9 months) in January and a minimum (0.9 month) in October, while in 1955 it is estimated to have been about 2.5 times that at the present time.  相似文献   
56.
For a vertical two-dimensional field with a sill at a bay entrance, the tidal exchange mechanism is discussed.The schematic model is proposed as follows. The tidal trapping effect which is detected at the entrance section,i. e., the material transport due to the phase difference between the tidal periodic constituent of material concentration and tidal current at the entrance section, results because the oscillatory tidal flow at the sill entrance induces a gravitational flow along the sill slope inside the entrance. Accordingly, the tidal trapping effect depends largely upon the difference in water density between the bay and open sea and the density stratification in the bay.This model is supported by the observations at Kabira Cove (Okinawa Pref.) and Lake Hamana (Shizuoka Pref.) in 1976 through 1984. In addition, based on this model, in the case of Lake Hamana, the activity of the tidal exchange is inferred to change seasonally.  相似文献   
57.
Episyenite is a quartz-depleted vuggy rock resulting from hydrothermal alteration of granitic rocks. This is the first report of its existence in an island arc, which is identified in a deep drill core of the Toki Cretaceous granite distributed in central Japan. In order to understand the petrographical features of the episyenite, neutron porosity measurement, geochemical analysis, microscopic observation, and X-ray computed tomography scanning were carried out. The results show remarkably high porosity (35.4 %) due to interconnecting vugs and the removal of quartz, plagioclase, and biotite. The Rb–Sr isotopic results and the paragenetic sequence of secondary minerals in the vugs suggest that the hydrothermal alteration process can be divided into an episyenitization stage and a later hydrothermal stage. At the episyenitization stage (70.6 ± 3.1 Ma) ca. 6 million years after the emplacement of the unaltered granite (76.3 ± 1.5 Ma), dissolution of quartz, biotite, and plagioclase occurred and was followed by the precipitation of albite, vermicular chlorite, and platy calcite. The episyenitization is considered as a local alteration of the Toki granite in an isotopically closed system. At the later hydrothermal stage, illite and secondary quartz precipitated from circulating meteoric-derived water in the dissolution vugs. Superimposing alteration at the later hydrothermal stage is limited, which results in the preservation of the episyenite in an almost primitive condition.  相似文献   
58.
Biogenic opal content and mass accumulation rate (MAR) at IODP Expedition 323 Site U1343 were found to fluctuate consistently, generally being high under warm conditions and low under cold conditions during the last 2.4 Ma. Continuous wavelet transform analysis of the normalized biogenic opal content indicates that export production in the Bering Sea varied predominantly at 41-ka periodicity before 1.25 Ma, and shifted to 100-ka periodicity at the onset of the Mid-Pleistocene Transition (MPT; 1.25–0.7 Ma). The 100-ka cycles dominated until the Holocene. Export production in the Bering Sea decreased markedly in the Bering Sea two times during the MPT: the first occurred at the beginning of the MPT (1.25 Ma) and the second in the middle of the MPT (0.9 Ma). These decreases coincided with both increases in the relative abundance of sea-ice diatoms and decreases in the warm-water diatom species Neodenticula seminae, indicating that reductions in export production in the Bering Sea during the MPT were associated with climate cooling. Decreases in export production in the Bering Sea during the MPT were most likely associated with the increased influence of polar/Arctic domains on the high-latitude North Pacific.  相似文献   
59.
The headwater catchments of the Yellow River basin generate over 35% of the basin's total stream flow and play a vital role in meeting downstream water resources requirements. In recent years the Yellow River has experienced significant changes in its hydrological regime, including an increased number of zero‐flow days. These changes have serious implications for water security and basin management. We investigated changes in stream flow regime of four headwater catchments since the 1950s. The rank‐based non‐parametric Mann–Kendall test was used to detect trends in annual stream flow. The results showed no significant trend for the period 1956 to 2000. However, change‐point analysis showed that a significant change in annual stream flow occurred around 1990, and hence the stream‐flow data can be divided into two periods: 1956–1990 and 1991–2000. There was a considerable difference in average annual stream flow between the two periods, with a maximum reduction of 51%. Wet‐season rainfall appears to be the main factor responsible for the decreasing trend in annual stream flow. Reductions in annual stream flow were associated with decreased interannual variability in stream flow. Seasonal stream flow distribution changed from bimodal to unimodal between the two periods, with winter stream flow showing a greater reduction than other seasons. Daily stream flow regime represented by flow duration curves showed that all percentile flows were decreased in the second period. The high flow index (Q5/Q50) reduced by up to 28%, whereas the reduction in the low flow index (Q95/Q50) is more dramatic, with up to 100% reduction. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   
60.
The Asian monsoon is one of the largest climatic systems in the world, but age of its onset has been estimated differently ranging from the late Eocene to the Quaternary. We investigated the sedimentology and stable isotopic compositions of the upper Eocene Jiuziyan Formation, a terrestrial limestone unit in the Jianchuan basin, Yunnan Province in China. This limestone formation is restricted in several localities in the central part of the basin. Previously, this has been characterized as palustrine carbonate and the transition to the sublacustrine deposit of the overlying Shuanghe Formation was interpreted as the appearance of wetter climate during the late Eocene. Our observations of macro- and microfacies revealed sedimentary fabrics indicating rapid CaCO3 precipitation, such as dendritic calcite and calcified reed stems, which are unlikely to develop in a simple lacustrine setting. High carbonate content (mostly >90 %) and restricted distribution of the Jiuziyan limestone indicate a depositional setting spatially limited and isolated from clastic influx. These findings, together with clearly higher δ13C values (−0.7 ‰ to +6.9 ‰) and lower δ18O values (−14.6 ‰ to −10.5 ‰) than those of the Shuanghe Formation, indicate that the limestone was mainly travertine, carbonate formed from endogenic spring water. The elevated δ13C resulted from a large amount of CO2 degassing from spring water with high pCO2. In addition, the occurrence of centimeter-scale lamination coupled with cyclic changes in δ13C and δ18O is almost identical with the modern annually-laminated travertine reported from Baishuitai in northern Yunnan Province, implying comparable amplitude of seasonal temperature and precipitation changes to the record of the modern travertine at Baishuitai. Our results do not contradict the previous interpretation of late Eocene wetting and additionally suggest the existence of the late Eocene monsoon climate in the Jianchuan basin.  相似文献   
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