A study on the interaction between ferric ion and silicic acid in hydrosphere: Si-containing ferruginous deposits formed in neutral hot spring waters     

Gaowa Naren  Akane Miyazaki  Motoyuki Matsuo  BAI Shuqin  Kotaro Yonesu  Yoshihiro Okaue  Takushi Yokoyama 《中国地球化学学报》2013,32(1):27-34

Five ferruginous deposit samples formed from neutral hot springs were analyzed to determine whether they consisted of a mixture of silica, hydrous iron oxide or iron silicate by differential thermal analysis (DTA), infrared (IR) spectroscopy, powder X-ray diffraction (XRD), and 57Fe Mssbauer spectroscopy. The Si/Fe atomic ratios of the deposits ranged from 0.25 to 0.45, and were smaller than those of hisingerite (12), but apparently close to those of siliceous ferrihydrite (0.250.5). Si was confirmed to be present as monomeric or oligomeric silicate from the Si-O stretching vibration frequencies on the IR spectra. Judging from the results of DTA, which minerals starting to produce after heating, and a relationship between Si-O stretching vibration frequency and Si/Fe atomic ratio proposed by Henmi et al. (1981), all the deposits in this study were concluded to be mixtures of various siliceous ferri-hydrites with low and high Si/Fe atomic ratios. Moreover, by comparing the chemical properties of hot spring waters, the formation conditions of siliceous ferrihydrite were also discussed.  相似文献   

Global mantle heterogeneity and its influence on teleseismic regional tomography     

Dapeng Zhao  Yoshihiro Yamamoto  Takahiro Yanada 《Gondwana Research》2013,23(2):595-616

A new global P-wave tomography model is determined using a flexible-grid parameterization. This new model better reveals the mantle structure under the polar regions than the previous tomographic models. The subducting slabs are generally imaged clearly as high-velocity (high-V) zones. The young slabs are still subducting in the upper mantle and the mantle transition zone (MTZ), whereas the old and ancient slabs are either stagnant in the MTZ or have subducted down to the lower mantle, even reaching the core-mantle boundary. Low-velocity (low-V) anomalies are generally revealed in the mantle under the hotspot regions. It seems that a variety of mantle upwelling (plumes) exist. Some strong plumes are visible in the whole mantle under the long-living hotspots, such as those in south-central Pacific, Africa, Hawaii and Iceland, whereas weak plumes are visible in only some depth range under the minor hotspots. Under the intraplate volcanoes in East Eurasia, Bering Sea and West Alaska, significant low-V anomalies are revealed in the upper mantle, which may reflect hot and wet upwelling associated with corner flows in the big mantle wedge (BMW) above the stagnant Pacific slab in the MTZ and perhaps deep slab dehydration as well. The subduction-triggered magmatism in the BMW may be a new class of mantle plumes. We also used the new global model to investigate the influence of whole-mantle heterogeneity on the determination of upper-mantle tomography under Japan with a teleseismic inversion method. The results show that the mantle heterogeneities outside the target volume of regional tomography can cause significant changes (~ 0.2-0.4 s) to the observed relative travel-time residuals of a distant earthquake. The pattern of regional tomography remains the same even after correcting for the whole-mantle heterogeneity, but there are some changes in the amplitude of velocity anomalies in the regional tomography. Hence it is necessary to correct for the mantle heterogeneities outside the target volume so as to obtain a better regional tomography.  相似文献   

Damper placement optimization in a shear building model with discrete design variables: a mixed‐integer second‐order cone programming approach     

Yoshihiro Kanno 《地震工程与结构动力学》2013,42(11):1657-1676

Supplemental damping is known as an efficient and practical means to improve seismic response of building structures. Presented in this paper is a mixed‐integer programming approach to find the optimal placement of supplemental dampers in a given shear building model. The damping coefficients of dampers are treated as discrete design variables. It is shown that a minimization problem of the sum of the transfer function amplitudes of the interstory drifts can be formulated as a mixed‐integer second‐order cone programming problem. The global optimal solution of the optimization problem is then found by using a solver based on a branch‐and‐cut algorithm. Two numerical examples in literature are solved with discrete design variables. In one of these examples, the proposed method finds a better solution than an existing method in literature developed for the continuous optimal damper placement problem. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Accurate Measurements of the Brightness of the White-Light Corona at the Total Solar Eclipses on 1 August 2008 and 22 July 2009     

Yoichiro Hanaoka  Yoshihiro Kikuta  Jun Nakazawa  Kouji Ohnishi  Kazuo Shiota 《Solar physics》2012,279(1):75-89

We measured the brightness of the white light corona at the total solar eclipses on 1 August 2008 and 22 July 2009, when solar activity was at its lowest in one hundred years. After careful calibration, the brightness of the corona in both eclipses was evaluated to be approximately 0.4×10^?6 of the total brightness of the Sun, which is the lowest level ever observed. Furthermore, the total brightness of the K+F-corona beyond 3R _⊙ in both eclipses is lower than some of the previous measurements of the brightness of the F-corona only. Our accurate measurements of the coronal brightness provide not only the K-corona brightness during a period of very low solar activity but also a reliable upper limit of the brightness of the F-corona.  相似文献   

Age,geochemistry, and emplacement of the ~40-Ma Baneh granite–appinite complex in a transpressional tectonic regime,Zagros suture zone,northwest Iran     

Hossein Azizi  Sepideh Hadad  Robert J. Stern  Yoshihiro Asahara 《International Geology Review》2019,61(2):195-223

The Baneh plutonic complex is situated in the Zagros suture zone of northwest Iran between the Arabian and Eurasian plates. This complex is divided into granite and appinite groups. Zircon U–Pb dating shows that granites crystallized 41–38 million years ago but appinites experience more protracted magmatic evolution, from at 52 to 38 Ma. Whole-rock chemical compositions show significant major and trace element variations between the two lithologies. Granitic rocks are more evolved, with high contents of SiO₂ (62.4–77.0 wt%), low contents of TiO₂ (0.25 wt%), MgO (0.05–1.57 wt%), and Fe₂O₃ (0.40–4.06 wt%) and high contents of Na₂O + K₂O (≈10 wt%). In contrast, appinites have low contents of SiO₂ (51.0–57.0 wt%) and K₂O (<2.1 wt%) and high Fe₂O₃ (6.4–9.35 wt%), MgO (2.0–9.9 wt%), and Mg number (Mg# = 35–76). The concentration of rare earth elements in the appinites is higher than in granitic rocks, making it difficult to form granites solely by fractionation of appinite magma. (⁸⁷Sr/⁸⁶Sr)_i and ε_Nd(40 Ma) in both groups are similar, from 0.7045 to 0.7061 and ?1.2 to +2.6, except for a primitive gabbroic dike with ε_Nd(40 Ma) = +9.9. Appinites show mainly typical I-type characteristics, but granites have some S-type characteristics. The sigmoidal shape of the Baneh pluton and its emplacement into deformed Cretaceous shales and limestone showing kink bands, asymmetric and recumbent folds in a broad contact zone, with pervasive ductile to brittle structures in both host rocks and intrusion, indicate that magma emplacement was controlled by a transpressional tectonic regime, perhaps developed during early stages in the collision of Arabia and Eurasian plates.  相似文献   

New evidence for Jurassic continental rifting in the northern Sanandaj Sirjan Zone,western Iran: the Ghalaylan seamount,southwest Ghorveh     

Hossein Azizi  Fatemeh Nouri  Robert J. Stern  Marie Azizi  Federico Lucci  Yoshihiro Asahara 《International Geology Review》2020,62(13-14):1635-1657

ABSTRACT

We address the growing controversy about the tectonic setting in which Jurassic magmatism of Iran occurred: arc or continental rift. In the Ghorveh area of the northern Sanandaj Sirjan zone (SaSZ), the Ghalayan metabasites are interlayered with marble and schist and locally cut by acidic dikes. Zircon U-Pb dating of the metabasitic rocks shows that these crystallized at ca. 145–144 Ma ago in the Late Jurassic (Tithonian). This complex was metamorphosed in the lower greenschist facies, however, some protolithic structures such as pillow lava and primary minerals are preserved. The metabasites are tholeiites with low SiO₂ (45.6–50.5 wt.%), moderate Al₂O₃ (11.3–17.0 wt.%), and high TiO₂ (0.7–2.9 wt.%) and Fe₂O₃ (9.4–14.1 wt.%). The Ghalayan metabasites are enriched in Light rare earth elements (LREEs) without significant Nb, Ta, Pb, Sr and Ba anomalies, similar to modern continental intra-plate tholeiitic basalts such as Afar and East African rifts. The Ghalaylan metabasites show wide ranges for ⁸⁷Sr/⁸⁶Sr_(i) (0.7039–0.7077) and positive ε_Nd(t) values (+0.1 to +4.6). These isotopic compositions are similar to those expected for slightly depleted subcontinental lithospheric mantle sources. Independently built discrimination diagrams indicate an intra-continental rifting regime for the source of Jurassic metabasites in the northern SaSZ. Geochemical and tectonic evidence suggests that rifting or a mantle plume was responsible for volcanic activity in the Upper Jurassic SaSZ. Considering the variation of ages of basaltic volcanism along the SaSZ, we suggest that Ghalayan basaltic magmatism reflected a submarine volcano that formed as part of the late stage continental rift, similar to Afar in the East African Rift system. Our results indicate that an extensional tectonic regime dominated SaSZ tectonics in the Middle to Late Jurassic.  相似文献   

Geochemical and Sr–Nd isotopic constraints on the genesis of the Soheyle-PaKuh granitoid rocks (central Urumieh-Dokhtar magmatic belt,Iran)     

Fatemeh Sarjoughian  Somayeh Javadi  Hossein Azizi  Wenli Ling  Yoshihiro Asahara  David Lentz 《International Geology Review》2020,62(13-14):1769-1795

ABSTRACT

Soheyle-Pakuh granitoid rocks, with a variety of quartz diorite, quartz monzodiorite, granodiorite, tonalite, and granite, have been emplaced into the Tertiary volcanic rocks in the Urumieh-Dokhtar magmatic arc in central Iran. Zircon U–Pb dating yields an age of 39.63 ± 0.93 Ma for the crystallization of this body. Whole-rock compositions show that SiO₂ changes from 52.31 to 65.78 wt.% and Al₂O₃ varies from 15.54 to 18.24 wt.%, as well as high concentrations of large-ion lithophile elements (LILE, e.g. Cs, Rb, Ba, and K) and quite low contents of high field strength elements (HFSE, e.g. Nb, Ti, P), as expected in I-type arc granitoids formed in an active continental margin setting. Initial ratios of ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd exhibit ranges 0.7043–0.7047 and 0.51284 to 0.51287, respectively, with positive εNd_(t) from +4.9 to +5.5 with a young TDM1 age (483–674 Ma); this tracer isotopic data suggesting that the SPG originated from juvenile basaltic crust derived from depleted mantle (~90%) with variable contributions from undepleted mantle and approximately 10% old lower crust, despite diverse processes (e.g. magma mixing and fractional crystallization) during their evolution and emplacement into a local extensional setting within the continental margin arc. The isotopic data are similar to those of other Phanerozoic granitoids of the Central Asian Orogenic Belt and corroborate melting of predominantly mantle-derived juvenile crustal protoliths and indicating extensive addition of new continental crust, during Cambrian-Neoproterozoic time, in the suprasubduction zone beneath the central Urumieh-Dokhtar magmatic arc. Generation of these types of granitoids favours a model whereby rollback and (or) break-off of a subducted slab with subsequent lithospheric extension triggered by mantle upwelling, heat advection, and underplating resulting in melting of the central UDMA mantle-derived juvenile lower continental crust in the Late Eocene.  相似文献   

Spatial variation in the crustal anisotropy and its temporal variation associated with a moderate-sized earthquake in the Tokai region, central Japan     

Atsushi Saiga  Yoshihiro Hiramatsu  Toru Ooida  Koshun Yamaoka 《Geophysical Journal International》2003,154(3):695-705

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Chemical Features of White Micas from the Piemonte Calc-schists, Western Alps and Implications for K–Ar Ages of Metamorphism     

Hiroyuki Takeshita  Chitaro Gouzu  Tetsumaru Itaya   《Gondwana Research》2004,7(2):457-466

Anomalously large chemical ranges in muscovite-paragonite and muscovite-celadonite systems are observed in white micas from the Piemonte calcschists in the Chisone valley area, internal western Alps. The petrographical and chemical observations on white mica strongly suggest that most mica crystals with high Na/K ratios in the chlorite zone are of detrital origin, and were derived from the pre-Alpine high-temperature metamorphic sequence such the Caledonian and/or Variscan. Submicroscopic muscovite (Ms) - paragonite (Pg) composite aggregates occur in the chlorite zone and their EPMA analyses give an apparent chemical composition range from Ms_0.6Pg_0.4 to Ms_0.2Pg_0.8. In the rutile zone, the paragonite content of the white micas is less than 20%, suggesting that the white micas have been homogenized during the Alpine metamorphism even if detrital white micas existed.Metamorphic mica is also very heterogeneous. The total range in Si content becomes wider with increasing of metamorphic grade: 3.22–3.39 pfu for the chlorite zone, 3.07–3.45 pfu for the chloritoid zone and 3.06–3.59 pfu for the rutile zone. This clearly indicates that the micas have experienced significant retrogressive chemical reactions during cooling and exhumations of the host schists.The detrital white mica in the chlorite zone has not reset well in its K-Ar system during the Alpine subduction-related metamorphism. The wide range of the white mica K-Ar ages from 115 to 41 Ma must be due to a mixture of various amounts of detrital white mica in the separates. This feature is also observed in the chloritoid zone though the age variation is not so large as that in the chlorite zone. In contrast, the mica in the rutile zone, which was higher than 450°C, has been reset completely during Alpine HP metamorphism.  相似文献   

A Study on the Formation of Smectite in Silica Scales Precipitated from Geothermal Water: The Effect of Magnesium     

Yoshinobu Aramaki    Takushi Yokoyama  Yoshihiro Okaue  Akira Imai  Koichiro Watanabe 《Resource Geology》2005,55(3):281-284

Abstract. Silica scales containing large amounts of smectite were recently found in the pipelines for geothermal water at a geothermal power plant. To elucidate the mechanism of smectite formation, seven silica scale samples were characterized by powder X-ray diffraction, chemical analysis and ²⁷A1 MAS NMR. Smectite was present in samples with MgO levels above 10 wt% and Al₂O₃ levels below 10 wt%. In ²⁷A1 MAS NMR spectra, peaks assigned to both tetrahedrally and octahedrally coordinated aluminum (Al(4) and Al(6)) were observed for Mg-rich samples, whereas a peak due to Al(4) alone appeared in Mg-poor samples. From these observation and comparison between ²⁷A1 MAS NMR spectra for synthesized precipitates of Al₂O₃-SiO₂ containing MgO and not containing MgO, it is concluded that magnesium plays an important role in the stabilization of Al(6), and results in the formation of smectite  相似文献