Factors controlling regional spatial distribution of 53 elements in coastal sea sediments in northern Japan: Comparison of geochemical data derived from stream and marine sediments     

Atsuyuki Ohta  Noboru ImaiShigeru Terashima  Yoshiko TachibanaKen Ikehara  Hajime KatayamaAtsushi Noda 《Applied Geochemistry》2010

In all, 53 elements were analyzed in 1406 coastal sea sediment samples collected from an area off Hokkaido and the Tohoku region of Japan during a nationwide marine geochemical mapping project. The spatial distribution patterns of the elemental concentrations in coastal seas along with the existing geochemical maps in terrestrial areas were used to define natural geochemical background variation and mass transport processes. The terrestrial area is covered by mafic volcanic rocks and accretionary complexes associated with ophiolite, which has small amounts of felsic volcanic rocks and granite. The spatial distribution patterns of elements enriched in mafic lithologies such as Fe (Total Fe₂O₃) and Sc in marine environments are influenced by adjoining terrestrial materials. The spatial distribution patterns of Cr and Ni concentrations, which are highly abundant in ultramafic rocks on land, are used to evaluate the mass transport from land to the sea and the dispersive processes caused by oceanic currents. The scale of mass transport by oceanic currents occurs up to a distance of 100–200 km from the coast along the coastal areas. The regional differences of elements rich in felsic lithologies such as K (K₂O), Nb and La in marine sediments are determined mainly by the relative proportion of minerals and lithic fragments enriching felsic materials to those associated with mafic materials. The spatial distribution of elemental concentration is not always continuous between the land areas and coastal sea areas. That difference is interpreted as resulting from (1) transportation of marine sediments by oceanic currents and storm waves, (2) contribution of volcanic materials such as tephra, (3) occurrence of shell fragments and foraminifera tests and (4) distribution of relict sediments of the last glacial age and early transgression age. Contamination with Cu, Zn, Cd, As, Mo, Sn, Sb, Hg, Pb and Bi was not observed in marine environments because the study area has little anthropogenic activity. Terrestrial materials are the dominant source for these metals. The Mo, Cd, Sn, Sb, Hg, Pb and Bi are abundant in silty and clayey sediments locally because of early diagenetic processes, authigenic precipitation and organic substances associated with these elements. The spatial distribution of As concentration shows exceptions: it is concentrated in some coarse and fine sands on the shelf. The enrichment is explained by adsorption of As, sourced from a coal field, to Fe hydroxide.  相似文献   

A pair of behind-the-limb solar flares of 1984 May 21     

Kosugi  Takeo 《Solar physics》1987,113(1-2):295-298

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Time variations of hard X-ray bursts observed with the Solar X-ray Telescope aboard Hinotori (with a movie)     

Takeo Kosugi  Saku Tsuneta 《Solar physics》1983,86(1-2):333-338

We have developed a new method for synthesizing hard X-ray maps from the raw data of the Solar X-ray Telescope (SXT) aboard Hinotori. Using this method we analyzed five typical SXT events and summarized their images in a movie with a time resolution of about 8 s (half spin period of the satellite). The movie clearly shows that (1) three different classes of bursts, i.e., the gradual thermal burst, the multiple impulsive burst, and the extended outburst, have different structures and show quite different variations from each other, and that (2) the source of the extended outburst is located in the corona above 10⁴ km and its shape appears to be a large loop.  相似文献   

Measurement of methane flux over an evergreen coniferous forest canopy using a relaxed eddy accumulation system with tuneable diode laser spectroscopy detection     

Ayaka Sakabe  Ken Hamotani  Yoshiko Kosugi  Masahito Ueyama  Kenshi Takahashi  Akito Kanazawa  Masayuki Itoh 《Theoretical and Applied Climatology》2012,109(1-2):39-49

Very few studies have conducted long-term observations of methane (CH₄) flux over forest canopies. In this study, we continuously measured CH₄ fluxes over an evergreen coniferous (Japanese cypress) forest canopy throughout 1?year, using a micrometeorological relaxed eddy accumulation (REA) system with tuneable diode laser spectroscopy (TDLS) detection. The Japanese cypress forest, which is a common forest type in warm-temperate Asian monsoon regions with a wet summer, switched seasonally between a sink and source of CH₄ probably because of competition by methanogens and methanotrophs, which are both influenced by soil conditions (e.g., soil temperature and soil moisture). At hourly to daily timescales, the CH₄ fluxes were sensitive to rainfall, probably because CH₄ emission increased and/or absorption decreased during and after rainfall. The observed canopy-scale fluxes showed complex behaviours beyond those expected from previous plot-scale measurements and the CH₄ fluxes changed from sink to source and vice versa.  相似文献   

Growth stimulation and inhibition of natural phytoplankton communities by model organic ligands in the western subarctic Pacific     

Yoshiko Kondo  Shigenobu Takeda  Jun Nishioka  Mitsuhide Sato  Hiroaki Saito  Koji Suzuki  Ken Furuya 《Journal of Oceanography》2013,69(1):97-115

The influence of organic ligands on natural phytoplankton growth was investigated in high-nitrate low-chlorophyll (HNLC) waters and during a phytoplankton bloom induced by a mesoscale iron enrichment experiment (SEEDS II) in the western subarctic Pacific. The growth responses of the phytoplankton in the treatments with iron complexed with model ligand were compared with those with inorganic iron or a control. Desferrioxamine B and protoporphyrin IX were used as models for hydroxamate-type siderophore and tetrapyrrole-type cell breakdown ligand, respectively. In the HNLC water, iron associated with protoporphyrin IX especially stimulated smaller phytoplankton (<10 μm) growth, 1.5-fold more than did inorganic iron. Surprisingly, only the addition of protoporphyrin IX stimulated small phytoplankton growth, suggesting that these cell breakdown ligands might be more bioavailable for them. The protoporphyrin IX’s stimulatory effect on small phytoplankton was not observed during bloom decline phase. The growth of phytoplankton was inhibited in the treatment with desferrioxamine B-complexed iron, suggesting its low bioavailability for the natural phytoplankton community. Its inhibitory effects were particularly pronounced in pico-eukaryotic phytoplankton. During the iron-induced bloom, the phytoplankton’s iron-stress response gradually increased with the desferrioxamine B concentration, suggesting that the competition for iron complexation between natural ligands and desferrioxamine B affected phytoplankton growth. However, the pico-eukaryotes did seem better able to utilize the desferrioxamine B-complexed iron during the bloom-developing phase. These results indicate that the iron bioavailability for phytoplankton differs between bloom-developing and bloom-decline phases.  相似文献   

Inducing mineral precipitation in groundwater by addition of phosphate     

Wright KE  Hartmann T  Fujita Y 《Geochemical transactions》2011,12(1):8-13

Background

Induced precipitation of phosphate minerals to scavenge trace elements from groundwater is a potential remediation approach for contaminated aquifers. The success of engineered precipitation schemes depends on the particular phases generated, their rates of formation, and their long term stability. The purpose of this study was to examine the precipitation of calcium phosphate minerals under conditions representative of a natural groundwater. Because microorganisms are present in groundwater, and because some proposed schemes for phosphate mineral precipitation rely on stimulation of native microbial populations, we also tested the effect of bacterial cells (initial densities of 10⁵ and 10⁷ mL^-1) added to the precipitation medium. In addition, we tested the effect of a trace mixture of propionic, isovaleric, formic and butyric acids (total concentration 0.035 mM).

Results

The general progression of mineral precipitation was similar under all of the study conditions, with initial formation of amorphous calcium phosphate, and transformation to poorly crystalline hydroxylapatite (HAP) within one week. The presence of the bacterial cells appeared to delay precipitation, although by the end of the experiments the overall extent of precipitation was similar for all treatments. The stoichiometry of the final precipitates as well as Rietveld structure refinement using x-ray diffraction data indicated that the presence of organic acids and bacterial cells resulted in an increasing a and decreasing c lattice parameter, with the higher concentration of cells resulting in the greatest distortion. Uptake of Sr into the solids was decreased in the treatments with cells and organic acids, compared to the control.

Conclusions

Our results suggest that the minerals formed initially during an engineered precipitation application for trace element sequestration may not be the ones that control long-term immobilization of the contaminants. In addition, the presence of bacterial cells appears to be associated with delayed HAP precipitation, changes in the lattice parameters, and reduced incorporation of trace elements as compared to cell-free systems. Schemes to remediate groundwater contaminated with trace metals that are based on enhanced phosphate mineral precipitation may need to account for these phenomena, particularly if the remediation approach relies on enhancement of in situ microbial populations.  相似文献   

Snow ripples and their contribution to the mass transport in drifting snow     

Kenji Kosugi  Kouichi Nishimura  Norikazu Maeno 《Boundary-Layer Meteorology》1992,59(1-2):59-66

Morphological characteristics of snow ripples formed by drifting snow were investigated as functions of wind velocity in a cold wind tunnel at -15 °C. Wave-length, wave height and migration rate of snow ripples increased from 5 to 20 cm, 3 to 5 mm and 1 to 8 cm/min, respectively, with increasing wind velocity from 5 to 7 m/s. Measured size distributions of snow particles in snow ripples showed sorting of large particles in ridges, suggesting that the snow ripple migration is caused by creeping of large particles. The snow drift rate caused by creep, that is, by the ripple migration, was estimated to amount, at least, to 6% of the total snow drift rate.  相似文献   

Response of a phytoplankton community to nutrient addition under different CO2 and pH conditions     

Takeo Hama  Tomoki Inoue  Risa Suzuki  Hiroto Kashiwazaki  Shigeki Wada  Daisuke Sasano  Naohiro Kosugi  Masao Ishii 《Journal of Oceanography》2016,72(2):207-223

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The Hard X-ray Telescope (HXT) for the SOLAR-A mission     

T. Kosugi  K. Makishima  T. Murakami  T. Sakao  T. Dotani  M. Inda  K. Kai  S. Masuda  H. Nakajima  Y. Ogawara  M. Sawa  K. Shibasaki 《Solar physics》1991,136(1):17-36

The Hard X-ray Telescope (HXT) is a Fourier-synthesis imager; a set of spatially-modulated photon count data are taken from 64 independent subcollimators and are Fourier-transformed into an image by using procedures such as the maximum entropy method (MEM) or CLEAN. The HXT takes images of solar flares simultaneously in four energy bands, nominally 15 (or 19)–24, 24–35, 35–57, and 57–100 keV, with an ultimate angular resolution as fine as 5 arc sec and a time resolution 0.5 s. Each subcollimator has a field of view wider than the solar disk. The total effective area of the collimator/detector system reaches 70 cm², about one order of magnitude larger than that of the HINOTORI hard X-ray imager. Thanks to these improvements, HXT will for the first time enable us to take images of flares at photon energies above 30 keV. These higher-energy images will be compared with lower-energy ones, giving clues to the understanding of nonthermal processes in solar flares, i.e., the acceleration and confinement of energetic electrons. It is of particular importance to specify the acceleration site with regard to the magnetic field figuration in a flaring region, which will be achieved by collaborative observations between HXT and the Soft X-ray Telescope on board the same mission.After the launch the name of SOLAR-A has been changed to YOHKOH.  相似文献   

The Kiryu Experimental Watershed: 50-years of rainfall-runoff data for a forest catchment in central Japan     

Masanori Katsuyama  Nobuhito Ohte  Yoshiko Kosugi  Makoto Tani 《水文研究》2021,35(3):e14104

The Kiryu Experimental Catchment (KEW) is a small (5.99 ha) forest catchment located in Shiga Prefecture, central Japan (34°58′ N, 136°00′ E; www.bluemoon.kais.kyoto-u.ac.jp/kiryu/contents.html ). Around this area, forest devastation occurred from ca. 1250 to ca. 150 years ago because of overuse of forest and timbers. Then, hillside forestation was carried out for more than 100 years to prevent soil erosion and support the timber industry, and consequently, most of this area is now covered with plantation forests mainly by Chamaecyparis obtusa Sieb. et Zucc. (Japanese cypress) planted around 1960's. This plantation forest is not actively managed. The KEW is one of the leading experimental forests with long-term monitoring data in Japan. Research in the KEW began in 1967 to elucidate the hydrological and biogeochemical processes in the forested catchment in relation to climate, geology, soil, and vegetation growth. Since then, the long-term hydrological data of precipitation, runoff and sediment transport are continuously monitoring. In this study, we provide the data and preliminarily discuss the rainfall–runoff patterns and sediment transport through 50 years in the KEW. The annual precipitation and the maximum daily rainfall have been greater than the average over the last decade. In response to the rainfall patterns, the ratio of annual direct runoff to precipitation was also larger in the last decade. The sediment transport in this decade was consequently larger than the preceding decades. Our data presented here suggest that a close relationship exists between the climate condition, rainfall–runoff response, sediment dynamics, as well as a slowly progressing change of forest condition.  相似文献