High temperature infrared spectra of hydrous microcrystalline quartz   总被引：1，自引：0，他引：1  

Hiraku Yamagishi  Satoru Nakashima  Yuki Ito 《Physics and Chemistry of Minerals》1997,24(1):66-74

A series of in-situ high temperature infrared (IR) measurements of water in an agate sample and in a milky quartz has been conducted in order to understand the nature of water in silica at high temperatures (50–700?°C) and the dehydration behavior. IR absorption bands of water molecules trapped in the milky quartz showed a systematic decrease in intensities and a shift from 3425?cm^?1 at 50?°C toward 3590?cm^?1 at 700?°C without any loss of water. This indicates a change in IR absorption coefficients corresponding to different polymeric states of water at different temperatures. The broad 3430?cm^?1 band in the agate sample also showed a systematic decrease in IR intensity and a band shift toward higher frequency with increasing temperature (～700?°C). This indicates that the agate sample also contains fluid inclusion-like water. For this agate sample, a dehydration of loosely hydrogen-bonded molecular water occurred at lower temperatures (<200?°C). At higher temperatures (>400?°C), sharp bands around 3660 and 3725?cm^?1 (3740?cm^?1 at 50?°C) due to surface silanols, appeared. This indicates dehydration of H₂O molecules that are hydrogen bonded to surface silanols. SiOH species in the agate are divided into three groups, namely SiOH group located at structural defects, surface silanols hydrogen bonded to each other and free surface silanols. Former two dehydrate below 700?°C and the dehydration rate of the SiOH at structural defects is faster than the other. IR spectra show that SiOH species decrease continuously even after the dehydration of most of H₂O molecules. All these results provide realistic bases for the change in physicochemical states of different OH species in silica at high temperatures.  相似文献   

Timing and Duration of Hydrothermal in the Oligocene Hamad Cauldron, SW Japan: Evidence from K-Ar Ages of Sericites     

Teyruyoshi Imaoka    Kazuo Nakashima  Testumaru Itaya  Toshinori Okada 《Resource Geology》2001,51(1):55-62

Abstract: Crystallinity, chemical compositions and K-Ar ages of sericites in highly-sericitized granites and associated fissure-filling veins were examined to delineate the timing and duration of the hydrothermal activity in the Oligocene Hamada cauldron in the San-in district, SW Japan. Sericite separates (>2 μm) from the highly-sericitized granites consist mainly of 2M₁ polytype having high crystallinity and low Kübler indices of 0.22–0.35, while those in the fissure-filling veins have lower 2M₁/1Md ratios and crystallinity, and high Kübler indices of 0.29–0.35. This suggests that the sericites in highlysericitized granites were formed at a higher temperature than the vein sericites.
Sericites from the highly-sericitized granites of the Kumogi pluton give K-Ar ages of 30.0±0.7, 30.4±0.7, 30.6±0.7, 30.6±0.7, 32.1±0.7, 32.3±0.7 and 33.0±0.7 Ma (1), while those of the central plutons, 33.8±0.7 and 33.8±0.7 Ma. Sericites in the fissure-filling veins of the Kumogi granite give K-Ar ages of 31.0±0.7, 31.5±0.7, 31.6±0.7, 31.7±0.7 and 32.3±0.7 Ma. Biotite separates from the fresh Kumogi granite give K-Ar ages of 31.7±0.8, 32.0±0.8, 32.7±0.7 and 33.5±0.7 Ma. The K-Ar age data revealed that the hydrothermal alteration began at about 33 Ma and ended by about 30 Ma and that the period of sericite alteration was nearly synchronous with the cooling of the granite intrusions in the Hamada cauldron.
Despite intense hydrothermal alteration, the Oligocene granitoids have not accompanied with any economic base metal mineralization. The bulk chemical analyses of sericite separates in the veins indicate that the post-magmatic fluids were originally barren in heavy metals.  相似文献   

Displacement behavior of CH4 adsorbed on coals by injecting pure CO2, N2, and CO2–N2 mixture     

Sohei Shimada  Huoyin Li  Yoshito Oshima  Kazuhide Adachi 《Environmental Geology》2005,49(1):44-52

Gas adsorption isotherms of Akabira coals were established for pure carbon dioxide (CO₂), methane (CH₄), and nitrogen (N₂). Experimental data fit well into the Langmuir model. The ratio of sorption capacity of CO₂, CH₄, and N₂ is 8.5:3.5:1 at a lower pressure (1.2 MPa) regime and becomes 5.5:2:1 when gas pressure increases to 6.0 MPa. The difference in sorption capacity of these three gases is explained by differences in the density of the three gases with increasing pressure. A coal–methane system partially saturated with CH₄ at 2.4 MPa adsorption pressure was experimentally studied. Desorption behavior of CH₄ by injecting pure CO₂ (at 3.0, 4.0, 5.0, and 6.0 MPa), and by injecting the CO₂–N₂ mixture and pure N₂ (at 3.0 and 6.0 MPa) were evaluated. Results indicate that the preferential sorption property of coal for CO₂ is significantly higher than that for CH₄ or N₂. CO₂ injection can displace almost all of the CH₄ adsorbed on coal. When modeling the CH₄–CO₂ binary and CH₂–CO₂–N₂ ternary adsorption system by using the extended Langmuir (EL) equation, the EL model always over-predicted the sorbed CO₂ value with a lower error, while under-predicting the sorbed CH₄ with a higher error. A part of CO₂ may dissolve into the solid organic structure of coal, besides its competitive adsorption with other gases. According to this explanation, the EL coefficients of CO₂ in EL equation were revised. The revised EL model proved to be very accurate in predicting sorbed ratio of multi-component gases on coals.  相似文献   

Metamorphic Environments around the Cretaceous Kurihashi Pluton in the Kitakami Mountains, NE Japan: in Comparison to the Ganidake Pluton - Kamaishi Skarn Metasomatism     

Kazuhiro Sasaki    Kazuo Nakashima  Satoshi Kanisawa 《Resource Geology》2005,55(2):111-122

Abstract. Many granitic plutons of Early Cretaceous age are intruded on various scales in the Kitakami Mountains. The stock‐type Ganidake pluton accompanies enormous Fe‐Cu mineralization of the Kamaishi deposits, whereas the Kurihashi pluton accompanies less mineralization. To elucidate the cause of these differences, the metamorphic conditions and redox state of the contact metamorphic aureole around the Kurihashi pluton have been examined by the petrochemical study and gas analysis of the metamorphic rocks. A typical mineral assemblage in the pelitic rocks in the lowest‐grade part is biotite‐muscovite‐chlorite‐quartz‐plagio‐clase‐graphite, which occur more than 2 km away from the contact point with the Kurihashi pluton. Graphite disappears at the 1550 m point, and cordierite and garnet appear in the middle and highest‐grade parts, respectively. A typical mineral assemblage in the tuffaceous rocks in the lower‐grade part is chlorite‐actinolite‐biotite‐quartz‐plagioclase. Actinolite changes into hornblende near to the pluton. The CO₂/CH₄ ratios obtained in measurements by gas chromatography exceeds 100 in the pelitic rocks at the contact point with the pluton. The ratios decrease and become less than 0.1 with distance from the pluton. Equilibrium temperatures calculated from a garnet‐biotite pair in the pelitic rock and a hornblende‐plagioclase pair in the tuffaceous rock are 640d? and 681 d?C at the contact point, respectively. The log?o₂ values among these metamorphic aureoles estimated from the CO₂/CH₄ ratios are slightly lower than the FMQ‐buffer. Redox states of the contact metamorphic aureole are kept in an intermediate condition between oxidized magma of the Kurihashi pluton and graphite‐bearing pelitic country rocks. Judging from these metamorphic conditions around the Kurihashi pluton and from the re‐evaluation of the previous knowledge about contact metasomatism around the Ganidake pluton, the Kurihashi metamorphism has occurred at higher temperatures and dry conditions than the Ganidake metasomatism. These differences in the metamorphic conditions and presence or absence of a large limestone mass around the pluton might be the principal reasons why the Kurihashi pluton accompanies less mineralization and the Ganidake pluton accompanies gigantic Kamaishi skarn mineralization.  相似文献   

Determination of Multiple Trace Element Compositions in Thin (> 30 μm) Layers of NIST SRM 614 and 616 Using Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry (LA-ICP-MS)     

Tomoaki Morishita  Yoshito Ishida  Shoji Arai  Miki Shirasaka 《Geostandards and Geoanalytical Research》2005,29(1):107-122

To understand and/or avoid small-scale chemical heterogeneities within geological materials prepared as normal thin sections, in situ multiple trace element determination coupled with the simultaneous microscopic observation of the sample during analysis is preferable. We have examined fifty trace elements in thin (< 30 μm) layers of the NIST SRM 614 and 616 glass reference materials by LA-ICP-MS using different pit diameters and internal standard elements (Ca and Si). Compositional heterogeneities of Tl, Bi, As and Cd were found in NIST SRM 614 and 616 at the spatial resolution of ca. 10 0 μm. Except for these elements, the RSDs of six determinations for most elements were better than 10% in NIST SRM 614 when ablation diameters were < 50 μm. The measured concentrations for most elements in NIST SRM 614 and 616 agree with previous values in the literature at the 95% confidence level with the exception of W and Bi. New LA-ICP-MS data for K, As and Cd are also reported. The results support the view that the latest LA-ICP-MS is a powerful and flexible analytical technique for the determination of multiple ultra-trace element compositions in geological materials prepared as normal thin sections of the type that has been used for polarising optical microscopic observations since the end of the 19th century.  相似文献   

Online test using displacement–force mixed control     

Peng Pan  Masayoshi Nakashima  Hiroshi Tomofuji 《地震工程与结构动力学》2005,34(8):869-888

This paper proposes an online test technique that employs mixed control of displacement and force. Two types of mixed control, ‘displacement–force combined control’ and ‘displacement–force switching control’ are proposed. In displacement–force combined control, one jack is operated by displacement‐control, and another is operated by force‐control. Validity of the combined control technique is demonstrated by a series of online tests applied to a base‐isolated structure subjected to horizontal and vertical ground motions simultaneously. The substructuring technique is employed in the tests, and the base‐isolation layer is tested, with the rest of the structure modeled in the computer. Displacement‐control and force‐control were adopted for simulating the horizontal and vertical response, respectively. Both displacement‐ and force‐control were implemented successfully despite interference between the two jacks. Earthquake responses of the base‐isolated structure involving the effects of varying axial forces on the horizontal hysteretic behavior of the base‐isolation layer were simulated. In the displacement–force switching control, the jack was operated by displacement‐control when the test specimen was flexible but switched to force‐control once the specimen became stiff. Validity of the switching control technique was also checked by a series of online tests applied to the base‐isolated structure subjected to vertical ground motions. Switching between displacement‐control and force‐control was achieved when the axial force applied to the base‐isolation layer changed from tension to compression or from compression to tension. Both the displacement‐ and force‐control were successful even with many rounds of switching. The test revealed that large accelerations occurred on the floor immediately above the base‐isolation layer at the instants when the axial force of the base‐isolation layer changed from tension to compression. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Online hybrid test by internet linkage of distributed test‐analysis domains     

Peng Pan  Motohide Tada  Masayoshi Nakashima 《地震工程与结构动力学》2005,34(11):1407-1425

Online hybrid tests (called the online tests), particularly when combined with substructuring techniques, are able to conduct large‐scale tests. An extension of this technique is to combine multiple loading tests conducted in remote locations and to integrate the tests with large numerical analysis codes. In this study, a new Internet online test system is developed in which a physical test is conducted in one place, the associated numerical analysis is performed in a remote location, and the two locations communicate over the Internet. To implement the system, a technique that links test and analysis domains located at different places is proposed, and an Internet data exchange interface is devised to allow data communication across Internet. A practical method that utilizes standard protocols implemented by operating systems for sharing files and folders is adopted to ensure stable and robust communication between remotely located servers that commonly protect themselves by strict firewalls. To combine the online test with a finite element program formulated in an incremental form and adopting an implicit integration scheme, a tangent stiffness prediction procedure is proposed. In this procedure, a tangent stiffness is estimated based on a few previous steps of experimental data. Using the system devised, tests on a base‐isolated structure were carried out. Here, the base‐isolation layer was taken as the tested part and tested in Kyoto University, Japan, and the superstructure was modelled by means of a finite element program and analysed in a computer located in Osaka University. A series of physical Internet online tests were carried out, with the integration time interval and the method of tangent stiffness prediction as the major parameters. The tests demonstrated that the Internet communication was very stable and robust, without malfunctions. The proposed method of stiffness prediction was effective even when the experimental hysteresis curves exhibited complex behaviour, thereby ensuring accurate simulation for the earthquake response of the entire structure. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Energy dissipation behaviour of shear panels made of low yield steel     

Masayoshi Nakashima  Satoshi Iwai  Mamoru Iwata  Toru Takeuchi  Shinzo Konomi  Takashi Akazawa  Kazuhiro Saburi 《地震工程与结构动力学》1994,23(12):1299-1313

This paper presents the results of a pilot test conducted for evaluating the energy dissipation behaviour of shear panels made of low yield steel whose 0.2 per cent offset yield stress is 120 MPa. A total of six full-scale shear panels were tested with the loading condition, stiffener spacing, and magnitude of axial force as test variables. The shear panels tested yielded at a shear force that is approximately 1/3 of the yield shear force of equivalent shear panels made of common mild steel. Shear panels with proper stiffener arrangement exhibited stable hysteresis, thus ensuring large energy dissipation capacity. Sufficient strain hardening was observed in the shear panels tested, with their energy dissipation capacity about 1.5 times larger than that of an equivalent linear-elastic and perfect-plastic system. Plate buckling did not lead the shear panels to immediate degradation in their energy dissipation capacity. Post-buckling resistance was found to be a subject that requires further studies for quantifying the performance of shear panels made of low yield stress steel as hysteretic dampers.  相似文献   

Thermodynamic analyses of equilibria involving olivine,orthopyroxene and garnet     

Toshisuke Kawasaki  Yoshito Matsui 《Geochimica et cosmochimica acta》1983,47(10):1661-1679

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Seismic performance and new design procedure for chevron‐braced frames     

Edoardo M. Marino  Masayoshi Nakashima 《地震工程与结构动力学》2006,35(4):433-452

The paper is concerned with the seismic design of steel‐braced frames in which the braces are configured in a chevron pattern. According to EuroCode 8 (EC8), the behaviour factor q, which allows for the trade‐off between the strength and ductility, is set at 2.5 for chevron‐braced frames, while 6.5 is assigned for most ductile steel moment‐resisting frames. Strength deterioration in post‐buckling regime varies with the brace's slenderness, but EC8 adopts a unique q value irrespective of the brace slenderness. The study focuses on reevaluation of the q value adequate for the seismic design of chevron‐braced frames. The present EC8 method for the calculation of brace strength supplies significantly different elastic stiffnesses and actual strengths for different values of brace slenderness. A new method to estimate the strength of a chevron brace pair is proposed, in which the yield strength (for the brace in tension) and the post‐buckling strength (for the brace in compression) are considered. The new method ensures an identical elastic stiffness and a similar strength regardless of the brace slenderness. The advantage of the proposed method over the conventional EC8 method is demonstrated for the capacity of the proposed method to control the maximum inter‐storey drift. The q values adequate for the chevron‐braced frames are examined in reference to the maximum inter‐storey drifts sustained by most ductile moment‐resisting frames. When the proposed method is employed for strength calculation, the q value of 3.5 is found to be reasonable. It is notable that the proposed method does not require larger cross‐sections for the braces compared to the cross‐sections required for the present EC8 method. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献