Molecular and isotopic compositions of bitumens in Silurian tar sands from the Tarim Basin,NW China: Characterizing biodegradation and hydrocarbon charging in an old composite basin   总被引：1，自引：0，他引：1  

Wanglu Jia  Zhongyao Xiao  Chiling Yu  Ping'an Peng 《Marine and Petroleum Geology》2010

Biodegradation and oil mixing in Silurian sandstone reservoirs of the Tarim Basin, one of the largest composite basins in China, were investigated by analyzing the molecular characteristics and stable carbon isotopic signatures of low-molecular-weight (LMW) saturated hydrocarbons and high-molecular-weight (HMW) asphaltenes. Detection of 25-norhopanes and 17-nortricyclic terpanes in most Silurian tar sands from the Tabei Uplift in the Tarim Basin suggests a much greater degree of biodegradation here than in the Tazhong Uplift. This explains the relatively more abundant tricyclic terpanes, gammacerane, pregnane and diasteranes in tar sands from the Tabei Uplift than in those from the Tazhong Uplift. Hence, care must be taken when assigning oil source correlations using biomarkers in tar sands because of the biodegradation and mixing of oils derived from multiple sources in such an old composite basin. Asphaltenes in the tar sands seem to be part of the oil charge before biodegradation, depending on the relative anti-biodegradation characteristics of asphaltenes, the similarity in carbon isotopic signatures for asphaltenes and their pyrolysates, and the consistent product distribution for flash pyrolysis and for regular steranes in asphaltene pyrolysates, regardless of whether the tar sands were charged with fresh oil. According to the relative distributions of regular steranes and the relatively abundant 1,2,3,4-tetramethylbenzene significantly enriched in ¹³C, the oil sources for asphaltenes in the tar sands might be related to lower Paleozoic marine source rocks formed in euxinic conditions. Nevertheless, the relatively low abundance of gammacerane and C₂₈ regular steranes observed in asphaltene pyrolysates and residual hydrocarbons, within limited samples investigated in this work, made a direct correlation of oils originally charged into Silurian tar sands with those Cambrian source rocks, reported so far, seem not to be possible. Comparison of carbon isotopic signatures of n-alkanes in asphaltene pyrolysates with those of LMW saturated hydrocarbons is helpful in determining if the abundant n-alkanes in tar sands are derived from fresh oil charges after biodegradation. The limited carbon isotopic data for n-alkanes in LMW saturated hydrocarbons from the tar sands can be used to classify oils charged after biodegradation in the composite basin into four distinct groups.  相似文献   

A new method for platform design based on parametric technology     

Yan-Yun Yu  Ming Chen  Yan Lin  Zhuo-Shang Ji 《Ocean Engineering》2010,37(5-6):473-482

A new method for platform design, named parametric platform design method (PPDM), is presented in this paper in order to improve the mobile platform design efficiency. In this method, an integrated parametric system that fully considers the characteristics of the platform is developed, which significantly optimizes the design process with the top–bottom design concept. In the parametric system, the main geometric dimensions are taken as parameters, while the topology between the structure members, the function requirements and the safety requirements are converted into geometric constraints. By geometric constraint solving (GCS), a set of parameters that satisfy all the given constraints are determined, and then the design scheme is obtained by several core algorithms, such as parametric tank subdivision, 3D stability calculation, parametric structure design, FEM preprocessing, etc. The parametric method greatly increases the changeability and the reusability of the platform model, and concurrent design is well supported. As the model is driven by parameters, PPDM is an excellent method for optimization design. As a result, PPDM has incomparable advantages on the design efficiency over traditional methods.  相似文献   

Palaeozoic uplands and unconformity in the North China Block: constraints from zircon LA‐ICP‐MS dating and geochemical analysis of Bauxite     

Yu Wang  Liyun Zhou  Lijun Zhao  Mo Ji  Honglei Gao 《地学学报》2010,22(4):264-273

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Direct observation of complex Tóthian groundwater flow systems in the laboratory     

Xing Liang  Yu Liu  Menggui Jin  Xingchen Lu  Renquan Zhang 《水文研究》2010,24(24):3568-3573

Based on the theory of gravity‐driven groundwater flow systems, we have developed a complex Flow System Sand‐Box Model (FSM). It enables the visual observations of the development and characteristics and temporal evolution of complex Tóthian flow systems in the laboratory. The configuration of the regional, intermediate and local flow systems can be controlled and observed; hydraulic head, flow direction and travel time can be measured; and the scale and shape of the sub‐flow systems as well as the path lines and flow lines can be observed directly. The experiments demonstrate the Tóthian flow systems in a small basin with multiple sources and sinks. Greater local topographic (water table) undulation will lead to larger local flow systems. Greater regional and less local topographic undulation will enhance the development of intermediate and regional flow systems. In homogeneous media, increasing fluid‐potential differences between source and sink increase the spatial scale of the generated flow systems. The FSM is a useful teaching aid and experimental device to study and develop an intuitive insight into gravity‐driven groundwater flow systems. It helps to visualize and understand the hydraulic properties and controlling factors of Tóthian flow systems and may be used to study problems related to the chemical and temperature characteristics of the flow systems as well. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Static bay beach concept for scientists and engineers: A review     

John R.-C. Hsu  M.-J. Yu  F.-C. Lee  Lindino Benedet 《Coastal Engineering》2010

Headland-bay beach (HBB) is one of the most prominent physiographic features on the oceanic margin of many countries in the world. Under the influence of a predominant swell, its curved periphery in natural environment may reach static equilibrium and remains stable without sediment supply from updrift and/or a riverain source within its own embayment. Coastal scientists and engineers have attempted to develop mathematical expressions to quantify this ideal bay shape since the 1940s. As the scenario with depleting sediment supply has become a common reality on many parts of the world coastline in more recent time, some coastal engineers have advocated a rational approach to mimicking the static bay shape found in nature in order to mitigate beach erosion as well as for coastal management. Nowadays, many useful applications have emerged since the publication of the parabolic bay shape equation (PBSE) developed for static equilibrium planform (SEP) in late 1980s. The advance in modern computer technologies and international collaboration has further facilitated the exchange of knowledge and applications of this static bay beach concept (SBBC).  相似文献   

一种胶体光子晶体修饰的光纤     

刘青  王鸣  郭文华  闫海涛  喻平 《海洋学报》2010,32(10):7086-7090

设计了一种胶体光子晶体修饰的光纤. 采用恒温快速蒸发法直接在经切割刀处理后的光纤端面生长胶体晶体,再与另一根切割后的光纤在毛细玻璃管中完成对接,制备成胶体光子晶体修饰的光纤. 用扫描电子显微镜和光谱分析仪对样品的形貌、结构以及光学特性进行分析. 实验结果表明,粒径为640 nm、体积分数约为0.5%的SiO₂胶体微球溶液在60 ℃的情况下沉积,大约12 h后可得到质量较高的胶体光子晶体. 在SEM下,观察到端面的胶体晶体为面心立方(fcc)结构. 透射光谱证明,该结构在(111)面上  相似文献   

胶州湾水体镉的迁移过程和环境本底值结构     

杨东方  陈豫  王虹  杨春茹  郭军辉 《海岸工程》2010,29(4):73-82

根据1979年的胶州湾水域调查资料,分析重金属Cd在胶州湾水域的水平分布、垂直分布和季节变化。研究结果表明:在整个胶州湾水域,水质没有受到任何Cd的污染。在胶州湾和湾口水域只有两个Cd的来源。一个是来源于地壳岩石风化,通过陆地径流把重金属Cd注入胶州湾水域;另一个是来源于海底,经过海洋水流的作用把重金属Cd注入湾口水域。作者提出了重金属在水域的环境本底值结构:基础本底值、陆地径流的输入量和海洋水流的输入量,并且应用于胶州湾水域。作者认为在来源的迁移过程中,有陆地来源迁移和海底来源迁移。根据杨东方的水域迁移过程研究,陆地径流决定了Cd的表、底层质量浓度变化。  相似文献   

U-Pb ages of detrital zircons from modern sediments of the Yangtze River and stages of orogeny in Southeast Asia   总被引：1，自引：0，他引：1  

I. Yu. Safonova  Sh. Rino  Sh. Maruyama 《Doklady Earth Sciences》2010,431(1):280-284

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Abrupt behaviours of streamflow and sediment load variations of the Yangtze River basin,China     

Qiang Zhang  Vijay P. Singh  Chong‐Yu Xu  Xiaohong Chen 《水文研究》2013,27(3):444-452

Monthly sediment load and streamflow series spanning 1963–2004 from four hydrological stations situation in the main stem of the Yangtze River, China, are analysed using scanning t‐test and the simple two‐phase linear regression scheme. Results indicate significant changes in the sediment load and streamflow from the upper reach to the lower reach of the Yangtze River. Relatively consistent positive coherency relations can be detected between streamflow and sediment load in the upper reach and negative coherency in the middle and lower reaches. Interestingly, negative coherency is found mainly for larger time scales. Changes in sediment load are the result mainly of human influence; specifically, the construction of water reservoirs may be the major cause of negative coherency. Accentuating the human influence from the upper to the lower reach results in inconsistent correlations between sediment load and streamflow. Decreasing sediment load being observed in recent years has the potential to alter the topographical properties of the river channel and the consequent development and recession of the Yangtze Delta. Results of this study are of practical significance for river channel management and evaluation of the influence of human activities on the hydrological regimes of large rivers. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Rate and historical change of direct recharge from precipitation constrained by unsaturated zone profiles of chloride and oxygen‐18 in dry river bed of North China Plain     

Ruiqiang Yuan  Xianfang Song  Dongmei Han  Yinghua Zhang  Liang Zhang  Bing Zhang  Xiting Long  Yilei Yu 《水文研究》2012,26(9):1291-1301

Quantifying of direct recharge derived from precipitation is crucial for assessing sustainability of well‐irrigated agriculture. In the North China Plain, the land use is dominated by groundwater‐irrigated farmland where the direct recharge derived from precipitation and irrigation. To characterize the mean rate and historical variance of direct recharge derived from precipitation, unsaturated zone profiles of chloride and δ¹⁸O in the dry river bed of the Beiyishui River were employed. The results show that archival time scale of the profile covers the duration from 1980 to 2002 (corresponding to depths from 5 to 2 m) which is indicated by matching the δ¹⁸O peaks in the isotope profile with the aridity indexes gained by instrumental records of annual precipitation and annual potential evaporation. Using the chloride mass balance method, the mean rate of the direct recharge corresponding to the archival time scale is estimated to be 3·8 ± 0·8 mm year^?1, which accounts for about 0·7% of the long‐term average annual precipitation. Further, the direct recharge rates vary from 2·1 to 6·8 mm year^?1 since 1980. Despite the subhumid climate, the estimate of recharge rates is in line with other findings in semiarid regions. The low rate of direct recharge is considered as a result of the relative dry climate in recent decades. In dry river bed, unsaturated zone profiles of chloride and δ¹⁸O combined with instrumental records could offer valuable information about the direct recharge derived from precipitation during droughts. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献