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41.
Tsushima Island is one of the oldest zinc-lead mining areas in Japan. River water and sediment samples were collected mainly from Taishu area to determine the contamination level of Zn and to clarify its behaviour in the natural system. Among the water samples analysed, 64% exceeded the standard environmental limit of 0.03 µg ml− 1 for Zn. In most cases, Zn concentration in sediment samples also exceeded the standard value, and the concentration varied from 86.75–7490.07 µg g− 1. The mineralogical constituents in sediments were almost similar and quartz had the strongest peak, but the interior part of the ores had many minerals, with galena having the highest proportion. Considering the enrichment factor values (EFc), 12 samples have values of more than 50, indicating a high pollution load for Zn. This study revealed that the sulphide ores, and contaminated sediments, are the possible contamination sources of Shiine River, and Zn dissolution occurred by reactions, such as desorption and ion exchange. 相似文献
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43.
Shoji?NishimotoEmail author Hidekazu?Yoshida Yoshihiro?Asahara Tadahiko?Tsuruta Masayuki?Ishibashi Nagayoshi?Katsuta 《Contributions to Mineralogy and Petrology》2014,167(1):960
Episyenite is a quartz-depleted vuggy rock resulting from hydrothermal alteration of granitic rocks. This is the first report of its existence in an island arc, which is identified in a deep drill core of the Toki Cretaceous granite distributed in central Japan. In order to understand the petrographical features of the episyenite, neutron porosity measurement, geochemical analysis, microscopic observation, and X-ray computed tomography scanning were carried out. The results show remarkably high porosity (35.4 %) due to interconnecting vugs and the removal of quartz, plagioclase, and biotite. The Rb–Sr isotopic results and the paragenetic sequence of secondary minerals in the vugs suggest that the hydrothermal alteration process can be divided into an episyenitization stage and a later hydrothermal stage. At the episyenitization stage (70.6 ± 3.1 Ma) ca. 6 million years after the emplacement of the unaltered granite (76.3 ± 1.5 Ma), dissolution of quartz, biotite, and plagioclase occurred and was followed by the precipitation of albite, vermicular chlorite, and platy calcite. The episyenitization is considered as a local alteration of the Toki granite in an isotopically closed system. At the later hydrothermal stage, illite and secondary quartz precipitated from circulating meteoric-derived water in the dissolution vugs. Superimposing alteration at the later hydrothermal stage is limited, which results in the preservation of the episyenite in an almost primitive condition. 相似文献
44.
Md. Aftabuzzaman Kazuki Yomogida Shota Suzuki Hideko Takayanagi Akimasa Ishigaki Shiki Machida Yoshihiro Asahara Koshi Yamamoto Naoto Hirano Shin-Ichi Sano Shun Chiyonobu Davide Bassi Yasufumi Iryu 《Island Arc》2021,30(1):e12400
Sedimentological, geochemical, and chronological analyses were carried out on 18 carbonate rock samples collected at depths of 938, 1085, and 3354 m on the western slope of Minamitorishima (Marcus Island), which is located near the western margin of the Pacific Plate. Four groups of carbonate rocks were distinguished: a mollusk-rich limestone, a coral-rich dolomite, a foraminiferal-nannofossil packstone, and a phosphatized mudstone/wackestone. The mollusk-rich limestone is characterized by the dominance of bivalves (including rudists) and gastropod shells. Strontium isotope ratios (87Sr/86Sr) and Mesorbitolina ex gr. texana (a large benthic foraminifer) indicate that the shallow-water carbonates were deposited during the late Aptian–early Albian (ca. 123–111 Ma). The coral-rich dolomite is characterized by abundant scleractinian corals and nongeniculate coralline algae associated with encrusting acervulinid foraminifers. The biotic composition is similar to that of the Oligocene–Pleistocene carbonates reported from other seamounts in the northwestern Pacific. Geochemical data show that the coral-rich carbonates were dolomitized at 9.5–6.8 Ma (Tortonian–Messinian) and that normal seawater was the most likely parent fluid. The foraminiferal-nannofossil packstone is a semi-consolidated foraminiferal-nannofossil ooze and was deposited during the Pleistocene (0.99–0.45 Ma). The phosphatized mudstone/wackestone is marked by the absence of macrofossils and the presence of traces of planktic foraminifers. Although its depositional age is not constrained, the Sr isotope ratios indicate that the phosphatization occurred at 33.2–28.9 Ma. After the deposition of the Cretaceous shallow-water carbonates, including the mollusk-rich limestone, Minamitorishima was drowned and its top was covered with a pelagic cap, represented by the mudstone/wackestone. The late Eocene–early Oligocene volcanism (40.2–33.2 Ma) caused episodic uplift and returned the top of Minamitorishima to a shallow-water environment. After the early Oligocene phosphatization of the pelagic cap, coral reefs flourished on the top of this island. The reef limestone was dolomitized during the Tortonian–Messinian. 相似文献
45.
Kohki Yoshida Toru Nakajima Yuki Matsumoto Ai Osaki Lalit Kumar Rai Jarrett W. Cruz Harutaka Sakai 《Island Arc》2021,30(1):e12408
Bengal Fan Miocene sediments were collected during International Ocean Discovery Program Expedition 354 and investigated using petrographic and detrital garnet chemistry analyses. The Miocene Siwalik Group, which is composed of sediments deposited in the Himalayan foreland basin, was also analyzed for comparison with the Bengal Fan data for the provenance change during the Miocene. Our petrographic analyses revealed that the Miocene sediments of the Bengal Fan and Siwalik Group consist predominantly of Higher Himalayan Crystalline (HHC)-derived detritus such as chloritoid, staurolite, sillimanite, and/or kyanite, which appear among the accessory minerals. The chemistry of the detrital garnet varies across the stratigraphy; most of the garnet is rich in almandine and poor in spessartine and pyrope. However, pyrope-rich garnet, which is considered to originate from the HHC core (granulite facies), was found in the lower to upper Miocene deposits. The deposition of HHC-derived detrital garnet began before the Middle Miocene (15 Ma) and before the Late Miocene (10–9 Ma) in the Siwalik Group. The Bengal Fan data, by contrast, indicated that pyrope-rich garnet appeared in the Early Miocene (17.3 Ma) and Late Miocene (8.5–6.5 Ma). We conclude that the Bengal Fan sediments record the erosion of the HHC zone since the Early Miocene that appears in the Siwalik sediments. Furthermore, we found that the HHC-derived inputs decreased from the late Middle Miocene (12 Ma) to the early Middle Miocene (10 Ma) in both the Nepal Himalaya foreland basin and the Bengal Fan. The disappearance of the HHC-derived detritus is probably the result of dilution by Lesser Himalayan detritus, which suggests that the Lesser Himalayan zone, which is composed of metamorphosed and unmetamorphosed sedimentary rocks, was uplifted. 相似文献
46.
We propose a methodology for estimating the residence time of groundwater based on bomb-produced (36)Cl. Water samples were collected from 28 springs and 2 flowing wells located around Mt. Fuji, Central Japan. (36)Cl/Cl ratios in the water samples, determined by accelerator mass spectrometry (AMS), were between 43 × 10(-15) and 412 × 10(-15). A reference time series of the above-background (i.e., bomb-derived) (36)Cl concentration was constructed by linearly scaling the background-corrected Dye-3 data according to the estimated total bomb-produced (36)Cl fallout in the Mt. Fuji area. Assuming piston flow transport, estimates of residence time were obtained by comparing the measured bomb-derived (36)Cl concentrations in spring water with the reference curve. The distribution of (36)Cl-based residence times is basically consistent with that of tritium-based estimates calculated from data presented in previous studies, although the estimated residence times differ between the two tracers. This discrepancy may reflect chlorine recycling via vegetation or the relatively small change in fallout rate, approximately since 1975, which would give rise to large uncertainties in (36)Cl-based estimates of recharge for the period, approximately since 1975. Given the estimated ages for groundwater from flowing wells, dating based on a (36)Cl bomb pulse may be more reliable and sensitive for groundwater recharged before 1975, back as far as the mid-1950s. 相似文献
47.
Geochronological and geochemical constraints on the petrogenesis of high-K granite from the Suffi abad area, Sanandaj-Sirjan Zone, NW Iran 总被引：1，自引：0，他引：1
Hossein Azizi Yoshihiro Asahara Behzad Mehrabi Sun Lin Chung 《Chemie der Erde / Geochemistry》2011,71(4):363-376
The Sanandaj-Sirjan Zone (SSZ) trends northwestward in western Iran on the Precambrian to Paleozoic basement and exposes abundant I-type granitoids and calc-alkaline volcanic rocks that were most active during the Late Jurassic to Upper Cretaceous. The petrogenesis of the granitoids and associated volcanic rocks has been widely related to Neotethyan subduction beneath the Iranian plate. We report a geochronological and geochemical study of the Suffi abad granite (SLG) body that crops outs southeast of Sanandaj within the SSZ and is mainly composed of K-feldspar + quartz + plagioclase ± hornblende. The SLG, which shows a high-K calc-alkaline affinity, has LA-ICPMS zircon U–Pb ages ranging between 149 ± 2 and 144 ± 3 Ma and initial 87Sr/86Sr of ∼0.7024–0.7069 and 143Nd/144Nd of ∼0.5125–0.5127. These value correspond to an ?Nd (145 Ma) of +1.5 and +4.9, suggesting that the SLG originated from the juvenile crust or depleted mantle with a young TDM (650–900 Ma) over the subduction zone beneath the SSZ. Zircon saturation temperatures suggest that crystallization of the zircons, or emplacement of the host magmas, occurred at 560–750 °C, consistent with an intergrowth texture of K-feldspar and quartz that implies crystallization around the K-feldspar-quartz eutectic at lower temperatures. Overall, geochemical data suggest that crystallization of the hornblende and plagioclase played a role in magma differentiation. These data allow us to conclude that the high-K SLG did not originate directly from the juvenile mantle source as do most I-type, calc-alkaline granitoids, but more likely was produced from the partial melting of pre-existing I-type granitoids in the upper continental crust under low pressure conditions. 相似文献
48.
Ryuji Tateyama Eiji Ohtani Hidenori Terasaki Keisuke Nishida Yuki Shibazaki Akio Suzuki Takumi Kikegawa 《Physics and Chemistry of Minerals》2011,38(10):801-807
The compositional dependence on the density of liquid Fe alloys under high pressure is important for estimating the amount
of light elements in the Earth’s outer core. Here, we report on the density of liquid Fe–Si at 4 GPa and 1,923 K measured
using the sink–float method and our investigation on the effect of the Si content on the density of the liquid. Our experiments
show that the density of liquid Fe–Si decreases from 7.43 to 2.71 g/cm3 non-linearly with increasing Si content (0–100 at%). The molar volume of liquid Fe–Si calculated from the measured density
gradually decreases in the compositional range 0–50 at% Si, and increases in the range 50–100 at% Si. It should be noted that
the estimated molar volume of the alloys shows a negative volume of mixing between Fe and Si. This behaviour is similar to
Fe–S liquid (Nishida et al. in Phys Chem Miner 35:417–423, 2008). However, the excess molar volume of mixing for the liquid Fe–Si is smaller than that of liquid Fe–S. The light element
contents in the outer core estimated previously may be an underestimation if we take into account the possible negative value
of the excess mixing volume of iron–light element alloys in the outer core. 相似文献
49.
Lidong Dai Yuki Kudo Kei Hirose Motohiko Murakami Yuki Asahara Haruka Ozawa Yasuo Ohishi Naohisa Hirao 《Physics and Chemistry of Minerals》2013,40(3):195-201
The sound velocities of two aluminum-rich phases in the lower mantle, hexagonal new Al-rich phase (NAL) and its corresponding high-pressure polymorph orthorhombic Ca-ferrite-type phase (CF), were determined with the Brillouin scattering method in a pressure range from 9 to 73 GPa at room temperature. Both NAL and CF samples have identical chemical composition of Na0.4Mg0.6Al1.6Si0.4O4 (40 % NaAlSiO4–60 % MgAl2O4). Infrared laser annealing in the diamond anvil cell was performed to minimize the stress state of the sample and obtain the high-quality Brillouin spectra. The results show shear modulus at zero pressure G 0 = 121.960 ± 0.087 GPa and its pressure derivative G’ = 1.961 ± 0.009 for the NAL phase, and G 0 = 129.653 ± 0.059 GPa and G’ = 2.340 ± 0.004 for the CF phase. The zero-pressure shear velocities of the NAL and CF phases are obtained to be 5.601 ± 0.005 km/sec and 5.741 ± 0.001 km/sec, respectively. We also found that shear velocity increases by 2.5 % upon phase transition from NAL to CF at around 40 GPa. 相似文献
50.
The Misho plutonic complex consists of a series of granitic bodies which range from syenogranite, alkali granite to monzogranites. They include metaluminous to peraluminous compositions. The garnitoid bodies are intruded into the unmetamorphosed late Paleozoic rocks and are located between two dextral, oblique-slip fault systems along which they have been uplifted as a major positive flower structure. The Misho granitoid belongs to the alkaline granitoid series that have been attributed to a Late Permian post-collisional setting. The studied granitoid displays high SiO2 contents between 67.71 and 76.4 wt%. On both FeO/(FeO + MgO) and [(Na2O + K2O) ? CaO] vs. SiO2 diagrams, the samples, plot in the ferroan and alkaline fields, therefore, show an A-type granitoid signature. Trace and rare earth elements distribution patterns for the Misho rocks indicate a distinctive depletion in Nb, Sr, Ba, P, and Ti relative to other trace elements and a greater enrichment in large-ion lithophile elements compared to high field strength elements that are also typical features of A-type granites. The granitoid samples are geochemically similar to typical A2-type granites, e.g., high K2O + Na2O, FeO/MgO, Ga/Al, and Y/Nb values and low CaO, Ba, Sr, and Eu contents. They have initial Sr isotopic ratios in the range >0.712 and negative ε Ndt values of ?1 to ?3.2 for a time of generation of 232 Ma. We suggest that shear zones play an important role in providing suitable conduits for ascending asthenospheric material and heat influx in the lower crust continental. It is proposed that the Misho parental granitoid magmas were produced by the partial melting of the lower crust continental at extensional setting in active continental margin setting that was formed after the collision of the Eurasia plate and Iranian plate following closure of paleo-Tethyan oceanic crust during Middle Jurassic times. 相似文献