Carbon isotopes and petrography of kerogens in ∼3.5-Ga hydrothermal silica dikes in the North Pole area, Western Australia     

Yuichiro Ueno  Hideyoshi Yoshioka  Yukio Isozaki 《Geochimica et cosmochimica acta》2004,68(3):573-589

More than 600 specimens of ∼3.5 Ga-old hydrothermal silica dikes from the North Pole area, Pilbara craton, Western Australia, have been studied petrographically. The kerogens in 44 samples have been analyzed isotopically (C and N) and chemically (C, N, and H). The silica dikes are composed mainly of fine-grained silica (modal abundance: >97%) and are classified into two types by minor mineral assemblages: B(black)-type and G(gray)-type. The B-type silica dikes contain kerogen (0.37 to 6.72 mgC/g; average 2.44 mgC/g, n = 21) and disseminated sulfides, dominantly pyrite and Fe-poor sphalerite. In some cases, carbonate and apatite are also present. Their silica-dominated and sulfide-poor mineral assemblages suggest precipitation from low-temperature reducing hydrothermal fluid (likely 100-200°C). On the other hand, the G-type silica dikes are sulfide-free and concentrations of kerogen are relatively low (0.05 to 0.41 mgC/g; average 0.17 mgC/g, n = 13). They typically contain Fe-oxide (mainly hematite) which commonly replaces cubic pyrite and rhombic carbonate. Some G-types occur along secondary quartz veins. These textures indicate that the G-type silica dikes were formed by postdepositional metasomatism (oxidation) of the B-types, and that the B-types probably possess premetasomatic signatures. The δ¹³C values of kerogen in the B-types are −38.1 to −33.1‰ (average −35.9‰, n = 21), which are ∼4‰ lower than those of the G-types (−34.5 to −30.0‰; average −32.2‰, n = 19), and ∼6‰ lower than bedded chert (−31.2 to −29.4‰; average −30.5‰, n = 4). This indicates the preferential loss of ¹²C during the metasomatism (estimated fractionation factor: 0.9985). Considering the metasomatic effect on carbon isotopes with probably minor diagenetic and metamorphic overprints, we conclude that the original δ¹³C values of the kerogen in the silica dikes would have been heterogeneous (∼5‰) and at least some material had initial δ¹³C values of ≤ −38‰. The inferred ¹³C-depletions of organic carbon could have been produced by anaerobic chemoautotrophs such as methanogen, but not by aerobic photoautotrophs. This is consistent with the estimated physical and chemical condition of the hydrothermal fluid, which was probably habitable for anaerobic and thermophilic/hyperthermophilic chemoautotrophs. Alternatively, the organic matter may have been possibly produced by abiological reaction such as Fischer-Tropsch Type (FTT) synthesis under the hydrothermal condition. However, the estimated condition is inconsistent with the presence of the effective catalysts for the FTT reaction (i.e., Fe-Ni alloy, magnetite, and hematite). These lines of evidence suggest the possible existence of biosphere in the ∼3.5 Ga sub-seafloor hydrothermal system.  相似文献   

The influence of ENSO on the equatorial Atlantic precipitation through the Walker circulation in a CGCM     

Wataru Sasaki  Takeshi Doi  Kelvin J. Richards  Yukio Masumoto 《Climate Dynamics》2015,44(1-2):191-202

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Computer-aided design of bus route maps     

Yukio Sadahiro  Takahito Tanabe  Maxime Pierre  Koichi Fujii 《制图学和地理信息科学》2016,43(4):361-376

The bus route map is a diagram that aims to convey necessary information for map readers to find an appropriate way of moving from an origin to a destination. Design of bus route map is a complicated and time-consuming task that requires careful consideration of readability and aesthetics. This paper proposes a new computational method for designing bus route maps. The method helps us to reduce six types of undesirable elements in bus route maps, i.e., gap, shift, crossing, overlap, misalignment, and acute bend. The method consists of two phases: line layout phase determines the relative order of bus routes on each road segment and map layout phase calculates the actual position of bus routes drawn on a map. This paper applies the method to the design of bus route maps of Chiba City, Japan. The result supports the effectiveness of the method as well as reveals open topics for future research.  相似文献   

High-reliability zircon separation for hunting the oldest material on Earth: An automatic zircon separator with image-processing/microtweezers-manipulating system and double-step dating     

Yukio Isozaki  Shinji Yamamoto  Shuhei Sakata  Hideyuki Obayashi  Takafumi Hirata  Ken-ichi Obori  Toshinori Maebayashi  Satoshi Takeshima  Toshikazu Ebisuzaki  Shigenori Maruyama 《地学前缘(英文版)》2018,9(4):1073-1083

Despite the recent development in radiometric dating of numerous zircons by LA-ICPMS, mineral separation still remains a major obstacle, particularly in the search for the oldest material on Earth. To improve the efficiency in zircon separation by an order of magnitude, we have designed/developed a new machine-an automatic zircon separator(AZS). This is designed particularly for automatic pick-up of100 μm-sized zircon grains out of a heavy mineral fraction after conventional separation procedures. The AZS operates in three modes:(1) image processing to choose targeted individual zircon grains out of all heavy minerals spread on a tray,(2) automatic capturing of the individual zircon grains with microtweezers, and(3) placing them one-by-one in a coordinated alignment on a receiving tray. The automatic capturing was designed/created for continuous mineral selecting without human presence for many hours. This software also enables the registration of each separated zircon grain for dating, by recording digital photo-image, optical(color) indices, and coordinates on a receiving tray. We developed two new approaches for the dating; i.e.(1) direct dating of zircons selected by LA-ICPMS without conventional resin-mounting/polishing,(2) high speed U-Pb dating, combined with conventional sample preparation procedures using the new equipment with multiple-ion counting detectors(LA-MIC-ICPMS).With the first approach, Pb-Pb ages obtained from the surface of a mineral were crosschecked with the interior of the same grain after resin-mounting/polishing. With the second approach, the amount of time required for dating one zircon grain is ca. 20 s, and a sample throughput of 150 grains per hour can be achieved with sufficient precision(ca. 0.5%).We tested the practical efficiency of the AZS, by analyzing an Archean Jack Hills conglomerate in Western Australia with the known oldest(4.3 Ga) zircon on Earth. Preliminary results are positive; we were able to obtain more than 194 zircons that are over 4.0 Ga out of ca. 3800 checked grains, and 9 grains were over 4300 Ma with the oldest at 4371 ± 7 Ma. This separation system by AZS, combined with the new approaches, guarantees much higher yield in the hunt for old zircons.  相似文献   

Book reviews     

Yukio Fujinawa  A. V. Koloskov  Gerardo G. Tango  Lech Stefaníak  Douglas R. Schmitt  Kei Katsumata  Vernon F. Cormier  Wladislaw Lyatsky  Krzysztof Haman  P. Vincent  Konrad Bajer  Henryk Piwkowski 《Pure and Applied Geophysics》1991,136(2-3):343-367

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Carbon isotopic fractionation during the CO₂ exchange process between air and sea water under equilibrium and kinetic conditions     

Hisayuki Inoue  Yukio Sugimura 《Geochimica et cosmochimica acta》1985,49(11):2453-2460

Carbon isotopic fractionation during the air/sea exchange process is not fully understood at present. Information on the equilibrium and kinetic fractionation factors is an essential requirement, together with the value of the CO₂ partial pressure, for understanding the carbon cycle in the atmosphere and marine environments. Using a specially designed countercurrent equilibrator system, the fractionation factors between gaseous CO₂ and dissolved inorganic carbon in sea water were determined under both kinetic and equilibrium conditions. The following results were obtained: kinetic fractionation factor for air to sea (α_as) is 0.998 at 288.2 K; kinetic fractionation factor for sea to air (α_sa) is 0.990; equilibrium fractionation factor (α_eq) is 0.991 at pH = 8.3 and 288.2 K. From these results, the carbon isotopic ratio of CO₂ passed through the air/ sea interface is estimated to be about ?10 %. for air to sea and ?8 %. for sea to air when CO₂ exchange takes place between air (δ¹³C = ?8 %.) and surface sea water (δ¹³C = 2 %.) at 288.2 K.  相似文献   

Excess²²⁸Th in the airborne dust: an indicator of continental dust from the East Asian deserts     

Katsumi Hirose  Yukio Sugimura 《Earth and Planetary Science Letters》1984,70(1):110-114

Thorium isotopes in the airborne dust collected at Tsukuba Science City in Japan from January 1981 to December 1982 show clear seasonal variations. Especially²²⁸Th in the airborne particles have a typical maximum cincentration between February and April, which is about an order of magnitude higher than during the remainder of the year. According to the result of size distribution of thorium isotope-bearing particles in the air, about 53% of²²⁸Th is associated with the particles less than 1.6 μm aerodynamic diameter. These results reveal that²²⁸Th in the airborne particles is present in fine soily matters originating from the East Asian deserts.  相似文献   

Book reviews     

Mark S. T. Bukowinski  Philip E. Wannamaker  Manfred Koch  Yukio Fujinawa  Dr. Pradeep Talwani  D. Möhlmann  Andrew H. Knoll  Lucia Lovison-Golob  Krzysztof Haman  Hanna Pawłowska  Henryk Piwkowski  Dr. Anthony Dore  Nguyen Xuan Huy  Edward R. Cook  Jan Błecki  Jacek Leliwa-Kopystynski  Magdalena Sroczynska-Kozuchowska 《Pure and Applied Geophysics》1993,140(1):139-177

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On the age difference between the oldest Population I and the extreme Population II stars     

Hideyuki Saio  Yukio Shibata  Mahiro Simoda 《Astrophysics and Space Science》1977,47(1):151-162

The age difference between the oldest Population I stars and the extreme Population II stars is investigated by comparison of observational H-R diagrams with theoretical results using the common input physics and computer program for both Populations. Chemical compositions adopted for Population I and II stars are,X=0.7 andZ=0.02, andX=2×10^–4, respectively. Evidence collected indicates that the open cluster NGC 188 and the globular cluster M92 are the representative samples of the oldest Population I and extreme Population II stars, respectively. Comparison between the observed H-R diagrams and theoretical isochrones in terms of the luminosity of the subgiant region and the turnoff point for NGC 188 and M92, respectively, then suggests that there is a significant age difference between Population I and II objects. The uncertainty of the oxygen abundance in the extreme Population II stars and its effect on their age determination is briefly discussed.  相似文献   

Influence of relative density,particle shape,and stress path on the plane strain compression behavior of granular materials     

Li Zhuang  Yukio Nakata  Uk-Gie Kim  Dongwook Kim 《Acta Geotechnica》2014,9(2):241-255

Two types of stress path-controlled plane strain compression tests were performed on both loose and dense specimens of angular and sub-angular sands and two rounded glass beads with different particle sizes. Digital image correlation method was used to analyze local deformation developments, especially shear band patterns. The material behavior in response to shearing has been found to be dependent on the relative density, particle shape, and stress path. The results of analysis on local deformation developments showed that the onset of shear bands occurred prior to their peak strengths in both dense and loose specimens. The growth rates of local maximum shear strain along a shear band were approximately consistent with an increasing global axial strain after the onset of shear band. The shear band width was influenced by both the mean particle size and the particle shape. The measured shear band inclination angles were in between those estimated by Coulomb’s and Roscoe’s formulas.  相似文献