Improving strategies with constraints regarding non-Gaussian statistics in a three-dimensional variational assimilation method     

Norihisa?UsuiEmail author  Shiro?Ishizaki  Yosuke?Fujii  Masafumi?Kamachi 《Journal of Oceanography》2011,67(3):253-262

We assess validity of a Gaussian error assumption, the basic assumption in data assimilation theory, and propose two kinds of constraints regarding non-Gaussian statistics. In the mixed water region (MWR) off the east coast of Japan exhibiting complicated frontal structures, a probability density function (PDF) of subsurface temperature shows double peaks corresponding to the Kuroshio and Oyashio waters. The complicated frontal structures characterized by the temperature PDF sometimes cause large innovations, bringing about a non-Gaussianity of errors. It is also revealed that assimilated results with a standard three-dimensional variational (3DVAR) scheme have some issues in MWR, arising from the non-Gaussianity of errors. The Oyashio water sometimes becomes unrealistically cold. The double peaks seen in the observed temperature PDF are too smoothed. To improve the assimilated field in MWR, we introduce two kinds of constraints, J _c1 and J _c2, which model the observed temperature PDF. The constraint J _c1 prevents the unrealistically cold Oyashio water, and J _c2 intends to reproduce the double peaks. The assimilated fields are significantly improved by using these constraints. The constraint J _c1 effectively reduces the unrealistically cold Oyashio water. The double peaks in the observed temperature PDF are successfully reproduced by J _c2. In addition, not only subsurface temperature but also whole level temperature and salinity (T–S) fields are improved by adopting J _c1 and J _c2 to a multivariate 3DVAR scheme with vertical coupled T–S empirical orthogonal function modes.  相似文献   

Ab initio calculations of the Fe(II) and Fe(III) isotopic effects in citrates,nicotianamine, and phytosiderophore,and new Fe isotopic measurements in higher plants     

Frédéric Moynier  Toshiyuki Fujii  Kun Wang  Julien Foriel 《Comptes Rendus Geoscience》2013,345(5-6):230-240

Iron is one of the most abundant transition metal in higher plants and variations in its isotopic compositions can be used to trace its utilization. In order to better understand the effect of plant-induced isotopic fractionation on the global Fe cycling, we have estimated by quantum chemical calculations the magnitude of the isotopic fractionation between different Fe species relevant to the transport and storage of Fe in higher plants: Fe(II)-citrate, Fe(III)-citrate, Fe(II)-nicotianamine, and Fe(III)-phytosiderophore. The ab initio calculations show firstly, that Fe(II)-nicotianamine is ～3‰ (⁵⁶Fe/⁵⁴Fe) isotopically lighter than Fe(III)-phytosiderophore; secondly, even in the absence of redox changes of Fe, change in the speciation alone can create up to ～1.5‰ isotopic fractionation. For example, Fe(III)-phytosiderophore is up to 1.5‰ heavier than Fe(III)-citrate₂ and Fe(II)-nicotianamine is up to 1‰ heavier than Fe(II)-citrate. In addition, in order to better understand the Fe isotopic fractionation between different plant components, we have analyzed the iron isotopic composition of different organs (roots, seeds, germinated seeds, leaves and stems) from six species of higher plants: the dicot lentil (Lens culinaris), and the graminaceous monocots Virginia wild rye (Elymus virginicus), Johnsongrass (Sorghum halepense), Kentucky bluegrass (Poa pratensis), river oat (Uniola latifolia), and Indian goosegrass (Eleusine indica). The calculations may explain that the roots of strategy-II plants (Fe(III)-phytosiderophore) are isotopically heavier (by about 1‰ for the δ⁵⁶Fe) than the upper parts of the plants (Fe transported as Fe(III)-citrate in the xylem or Fe(II)-nicotianamine in the phloem). In addition, we suggest that the isotopic variations observed between younger and older leaves could be explained by mixing of Fe received from the xylem and the phloem.  相似文献   

Nuclear field shift in natural environments     

Frédéric Moynier  Toshiyuki Fujii  Gregory A. Brennecka  Sune G. Nielsen 《Comptes Rendus Geoscience》2013,345(3):150-159

The nuclear field shift (NFS) is an isotope shift in atomic energy levels caused by a combination of differences in nuclear size and shape and electron densities at the nucleus. The effect of NFS in isotope fractionation was theoretically established by Bigeleisen in 1996 [Bigeleisen J. (1996) J. Am. Chem. Soc. 118:3676–3680] and has been analytically measured in laboratory chemical exchange reactions. More recently, some isotopic variations of heavy elements (Hg, Tl, U) measured in natural systems as well as isotopic anomalies measured for lower-mass elements in meteorites have been attributed to the NFS effect. These isotopic variations open up new and exciting fields of investigations in Earth sciences. In this paper, we review the different natural systems in which NFS has been proposed to be the origin of isotopic variations.  相似文献   

SHRIMP zircon and EPMA monazite dating of granitic rocks from the Maizuru terrane, southwest Japan: Correlation with East Asian Paleozoic terranes and geological implications   总被引：1，自引：0，他引：1  

Masahiro  Fujii  Yasutaka  Hayasaka  Kentaro  Terada 《Island Arc》2008,17(3):322-341

Abstract The Maizuru terrane, distributed in the Inner Zone of southwest Japan, is divided into three subzones (Northern, Central and Southern), each with distinct lithological associations. In clear contrast with the Southern zone consisting of the Yakuno ophiolite, the Northern zone is subdivided into the western and eastern bodies by a high-angle fault, recognized mainly by the presence of deformed granitic rocks and pelitic gneiss. This association suggests an affinity with a mature continental block; this is supported by the mode of occurrence, and petrological and isotopic data. Newly obtained sensitive high mass-resolution ion microprobe (SHRIMP) zircon U–Pb ages reveal the intrusion ages of 424 ± 16 and 405 ± 18 Ma (Siluro–Devonian) for the granites from the western body, and 249 ± 10 and 243 ± 19 Ma (Permo–Triassic) for the granodiorites from the eastern body. The granites in the western body also show inherited zircon ages of around 580 and 765 Ma. In addition, electron probe microanalysis (EPMA) monazite U–Th–total Pb dating gives around 475–460 Ma. The age of intrusion, inherited ages, mode of occurrence, and geological setting of the Siluro–Devonian granites of the Northern zone all show similarities with those of the Khanka Massif, southern Primoye, Russia, and the Hikami granitic rocks of the South Kitakami terrane, Northeast Japan. We propose that both the Siluro–Devonian and Permo–Triassic granitic rocks of the Northern zone are likely to have been juxtaposed through the Triassic–Late Jurassic dextral strike-slip movement, and to have originated from the Khanka Massif and the Hida terrane, respectively. This study strongly supports the importance of the strike-slip movement as a mechanism causing the structural rearrangement of the Paleozoic–Mesozoic terranes in the Japanese Islands, as well as in East Asia.  相似文献   

Development of a GPGPU-parallelized hybrid finite-discrete element method for modeling rock fracture     

Daisuke Fukuda  Mojtaba Mohammadnejad  Hongyuan Liu  Sevda Dehkhoda  Andrew Chan  Sang-Ho Cho  Gyeong-Jo Min  Haoyu Han  Jun-ichi Kodama  Yoshiaki Fujii 《国际地质力学数值与分析法杂志》2019,43(10):1797-1824

The hybrid finite-discrete element method (FDEM) is widely used for engineering applications, which, however, is computationally expensive and needs further development, especially when rock fracture process is modeled. This study aims to further develop a sequential hybrid FDEM code formerly proposed by the authors and parallelize it using compute unified device architecture (CUDA) C/C++ on the basis of a general-purpose graphics processing unit (GPGPU) for rock engineering applications. Because the contact detection algorithm in the sequential code is not suitable for GPGPU parallelization, a different contact detection algorithm is implemented in the GPGPU-parallelized hybrid FDEM. Moreover, a number of new features are implemented in the hybrid FDEM code, including the local damping technique for efficient geostatic stress analysis, contact damping, contact friction, and the absorbing boundary. Then, a number of simulations with both quasi-static and dynamic loading conditions are conducted using the GPGPU-parallelized hybrid FDEM, and the obtained results are compared both quantitatively and qualitatively with those from either theoretical analysis or the literature to calibrate the implementations. Finally, the speed-up performance of the hybrid FDEM is discussed in terms of its performance on various GPGPU accelerators and a comparison with the sequential code, which reveals that the GPGPU-parallelized hybrid FDEM can run more than 128 times faster than the sequential code if it is run on appropriate GPGPU accelerators, such as the Quadro GP100. It is concluded that the GPGPU-parallelized hybrid FDEM developed in this study is a valuable and powerful numerical tool for rock engineering applications.  相似文献   

Effect of divalent cations on the kinetics of Fe(III) complexation by organic ligands in natural waters     

Manabu Fujii  Andrew L. Rose  Tatsuo Omura 《Geochimica et cosmochimica acta》2008,72(5):1335-1349

We have investigated the kinetics of Fe(III) complexation by several organic ligands including fulvic acid, citrate and ethylenediaminetetraacetic acid (EDTA). Particular attention was given to examination of the effect of competitive divalent cations (Me: Ca²⁺ and Mg²⁺) at concentrations typical of seawater on the complexation rate. All experiments were conducted in 0.5 M NaCl solution buffered with 2 mM bicarbonate at pH 8.0 in the absence and presence of Me (25 μM-250 mM). The rate constants of complex formation determined by using the competitive ligand (5-sulfosalicylic acid) method combined with visible spectrophotometry ranged from 3.3 × 10⁴ to 3.2 × 10⁶ M⁻¹ s⁻¹. The mechanism of complexation was then examined based on a kinetic model. When EDTA was used as a ligand, Me at concentrations comparable to the ligand markedly retarded the rate of iron complex formation due to the predominance of an adjunctive pathway (where iron-ligand complex is formed via direct association of iron to Me-ligand complex). In contrast, the competing effect of Me on iron complexation by citrate and fulvic acid was observed only when the Me concentration was in excess of the ligand by more than a factor of 10-1000. The kinetic model suggests that iron complexation by fulvic acid occurs predominantly via a disjunctive pathway (where iron complexation by ligand occurs after dissociation of Me from Me-ligand complex) at concentrations of divalent cations and natural organic matter typical of natural waters including seawater and freshwater.  相似文献   

Changes in the lower limit of mountain permafrost between 1973 and 2004 in the Khumbu Himal, the Nepal Himalayas   总被引：2，自引：0，他引：2  

Kotaro Fukui  Yoshiyuki Fujii  Yutaka Ageta  Katsuhiko Asahi 《Global and Planetary Change》2007,55(4):251-256

Because the Khumbu Himal of the Nepal Himalayas lacks long-term climate records from weather stations, mountain permafrost degradation serves as an important indicator of climate warming. In 1973, the permafrost lower limit was estimated to be 5200–5300 m above sea level (ASL) on southern-aspect slopes in this region. Using ground-temperature measurements, we examined the mountain permafrost lower limit on slopes with the same aspect in 2004. The results indicate that the permafrost lower limit was 5400–5500 m ASL in 2004. The permafrost lower limit was estimated to be 5400 to 5500 m on slopes with a southern aspect in the Khumbu Himal in 1991 using seismic reflection soundings. Thus, it is possible that the permafrost lower limit has risen 100–300 m between 1973 and 1991, followed by a stable limit of 5400 to 5500 m over the last decade. An increase in mean annual air temperature of approximately 0.2 to 0.4 °C from the 1970s to the 1990s has indicated a rise in the permafrost lower limit of 40 to 80 m at the Tibetan Plateau. The rise in the mountain permafrost lower limit in the Khumbu Himal exceeds that of the Tibetan Plateau, suggesting the possibility of greater climate warming in the Khumbu Himal.  相似文献   

Estrogenic activity in sediments contaminated by nonylphenol in Tokyo Bay (Japan) evaluated by vitellogenin induction in male mummichogs (Fundulus heteroclitus)     

Kurihara R  Watanabe E  Ueda Y  Kakuno A  Fujii K  Shiraishi F  Hashimoto S 《Marine pollution bulletin》2007,54(9):1315-1320

Estrogenic activity was determined in sediments collected from Tokyo Bay. Sampling was performed at five stations including the site near the sewage treatment plant. The most estrogenic sediment collected near the sewage treatment plant was fractionated into ten fractions using normal-phase high-performance liquid chromatography. Chemical analysis was carried out for each fraction and nonylphenol (NP, 20,700 ng g⁻¹ dry wt) was detected at a higher concentration than estron (2.39 ng g⁻¹ dry wt) and 17β-estradiol (<0.7 ng g⁻¹ dry wt). Furthermore, each fraction was administered to male mummichogs (Fundulus heteroclitus), and vitellogenin (Vtg) was measured after two weeks. The induction of Vtg was observed; this estrogenic potency could be attributed to the NP content in this fraction. This is the first report to suggest that the high NP concentration in the sediments from Tokyo Bay has the potential to induce Vtg in wild fish.  相似文献   

Compaction and fragmentation of porous gypsum targets from low-velocity impacts     

Yuichi Fujii 《Icarus》2009,201(2):795-801

We performed low-velocity impact experiments of gypsum spheres with porosity ranging from 0 to 61% and diameter ranging from 25 to 83 mm. The impact velocity was from 0.2 to 22 m/s. The target was an iron plate. The outcome of gypsum spheres with porosity 31-61% was different from those of non-porous ice [Higa M., Arakawa, M., Maeno, N., 1996. Planet. Space Sci. 44, 917-925; Higa M., Arakawa, M., Maeno, N., 1998. Icarus 133, 310-320] and non-porous gypsum. In between the intact and fragmentation modes, the outcome of the non-porous ice and gypsum was crack growth at the impact point. However, the outcome of the porous gypsum was compaction. We found that the restitution coefficients of the porous gypsum spheres were all in a similar range, in spite of the difference of the porosity and size at impact velocities up to about 10 m/s where they begin to be fragmented in pieces. Moreover, there is not a large difference between the restitution coefficient of porous and non-porous gypsum. These results collectively indicate that restitution coefficient of gypsum spheres of cm-size is not strongly dependent upon the porosity and compaction process.  相似文献   

Nuclear field shift effect as a possible cause of Te isotopic anomalies in the early solar system—An alternative explanation of Fehr et al. (2006 and 2009)     

Frédéric Moynier  Toshiyuki Fujii  Francis Albarède 《Meteoritics & planetary science》2009,44(11):1735-1742

Abstract— We explore the possibility that Te isotopic anomalies measured in Ca‐Al‐rich inclusions (Fehr et al. 2009) and in leachates of carbonaceous chondrites (Fehr et al. 2006) may be due to mass‐independent effects controlled by nuclear field shift rather than to nucleosynthetic processes. Fehr et al.'s spectrum of mass‐independent anomalies of Te isotopes shows a smooth correlation with mass number and nuclear charge distribution. Ratios of even to odd isotopes, as the ¹²⁵Te/¹²⁶Te ratio used by these authors for normalization are particularly prone to nuclear field shift effects. We show that the alternative normalization of isotopic ratios to ¹³⁰Te/¹²⁶Te strongly reduces the trend of isotopic fractionation with mass number, leaving only ¹²⁵Te as truly anomalous. For both normalizations (¹²⁵Te/¹²⁶Te and ¹³⁰Te/¹²⁶Te), Fehr et al.'s results fit the theory of Bigeleisen (1996), which suggests that the nuclear field shift effect can potentially account for the observed Te isotope abundances, as an alternative to nucleosynthetic processes. We propose that these mass‐independent effects may be acquired during accretion of sulfides from the solar nebula.  相似文献