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41.
42.
The influence of salinity on the solubility of Zn and Cd sulphides in the Scheldt estuary 总被引:2,自引:0,他引:2
In the estuary of the river Scheldt, where an oxygen gradient exists in addition to the salinity gradient, redox processes will be of major importance for trace metal mobilisation. In this study, the influence of salinity and pH on the redox processes of dissolved Zn and Cd sulphides is investigated together with the effects on the ratio of the dissolved Zn and Cd concentrations. The speciation of these metals is calculated with the chemical equilibrium programme
+. Zn sulphides are oxidised at lower oxygen concentrations than Cd sulphides, due to lower stability constants, causing a sudden increase or peak in the dissolved Zn/Cd ratio. The formation of dissolved Cd chloride complexes when oxidation occurs at high salinities (S=15) increases the mobility of Cd, causing a decrease in the Zn/Cd peak of the total dissolved concentrations. The peak is three to four times smaller at S=15 than when oxidation occurs at S=2. The simple model calculations compare very well with field data. The Scheldt estuary is suitable to illustrate these calculations. In the 1970s, the anoxic part of the estuary reached S=15–20, but since the early 1980s it has dropped to S=2–10. Historic data on metals in the estuary from 1978, 1987 and the 1990s were used to compare with the equilibrium calculations. The increase of the dissolved Zn/Cd peak at low salinity as a consequence, of the decreasing anoxic region is confirmed well by the data. The good agreement between model calculations and field data is a proof of the extreme importance of redox processes for the solubility of Zn and Cd sulphides in the estuary. 相似文献
43.
James W. Murray Robert Leborgnelt Yves Dandonneau 《Deep Sea Research Part II: Topical Studies in Oceanography》1997,44(9-10)
This special issue is the third and final volume containing results from the JGOFS Process Study in the equatorial Pacific. Most of the Study in the equational Pacific. Most of the contributions evolved either from the US JGOFS workshop in 1994 on the equatorial Pacific in Scottsdale, AZ or from the NATO Advanced Research Workshop on the Carbon Cycle of the Equatorial Pacific in 1995 in Noumea, New Caledonia. 相似文献
44.
With the development of high-resolution multibeam echosounder systems (MBES) for surveying shallow-water areas a new tool is available to monitor rapid changes in seabed morphology as, e.g., caused by the dumping of dredge spoil in coastal waters. In this study, four data sets of repeated bathymetric surveys with a MBES were processed and analyzed. The data were collected in a 1.94-km2 dumping site in the outer Weser Estuary (German Bight). Between June and December 1998, 2.6 million m3 of dredged sediment were deposited there. The bathymetric maps generated in the course of this study reveal features such as subaqueous dunes, scour holes, and mounds of dumped dredge spoil. The mean water depth decreased by about 1 m during the dumping period. Furthermore, difference grids showing changes in sediment volume allowed a calculation of the sediment budget for the monitored area. After a time period of only 5 months, 0.5 million m3 of the originally dumped 2.6 million m3 of dredge spoil had already been removed from the dumping site. 相似文献
45.
E. Cocheret de la Morinire B. J. A. Pollux I. Nagelkerken G. van der Velde 《Estuarine, Coastal and Shelf Science》2003,57(5-6):1079-1089
The spatial size distribution of grunts and snappers have previously indicated the separation of juveniles in nursery habitats from the adults on the coral reef. This implies life cycle migrations from nursery habitats (such as seagrass beds and mangroves) to the coral reef. If diet shifts are related to such migrations, then the diets of these fish must change before or around the fish size at which such migrations take place. A wide size range of juveniles of two grunt species (Haemulon sciurus and Haemulon flavolineatum) and of two snapper species (Lutjanus apodus and Ocyurus chrysurus) were caught in seagrass beds and mangroves, and their gut contents identified and quantified. Regression analysis between fish size and dietary importance of small crustaceans showed a negative relationship in all four species. Positive relations were found for H. sciurus, L. apodus and O. chrysurus between fish length and the dietary importance of decapods, and for L. apodusand O. chrysurus between fish length and prey fish importance. Critical changes in the fish diets with fish size were examined by application of a Canonical Correspondence Analysis (CCA). The CCA yielded three clusters of size-classes of fishes with similar diets, and application of a Mantel test showed that each of these clusters had significantly different diets, and that each cluster diet was significantly specialised. The size at which a fish species ‘switched’ from one cluster to another was compared with size-at-maturity data and with the typical size at which these species migrate from the nursery habitats to the coral reef. H. sciurus and H. flavolineatum may be prompted to migrate from the nursery habitats to coral reef habitats because of dietary changes, or because of the development of the gonads. For L. apodus and O. chrysurus, a dietary changeover forms a more likely explanation for nursery-to-reef migrations than does sexual maturation because these species reach maturity at sizes much larger than the maximum size of individuals found in nursery habitats. Although other factors may theoretically initiate or promote the migration patterns, the results of this study indicate that ontogenetic dietary changes may crucially influence the nursery-to-coral reef migrations of these reef fish species. 相似文献
46.
Matsumoto Takeshi Goslin Jean Lagabrielle Yves Ruellan Etienne Tanahashi Manabu 《Marine Geophysical Researches》1997,19(1):37-53
A surface ship gravity survey was carried out in the northern part of the North Fiji Basin during the NOFI cruise by the R/V l'Atalante in August-September, 1994. The two ridges inside the study area, the South Pandora Ridge and the Tripartite Ridge, present different structures and states of isostatic equilibrium in terms of gravity anomaly and its tectonic implications. The former is supported by a restoring force of an imaginary elastic plate in the crust and the latter by the Airy type isostasy. These characteristics can be derived from the difference in magmatic activity, as influenced by the difference in lithospheric structure. The latter is characterised by greater active magmatism and hydrothermalism underneath the ridge than the former. Such a difference in the magmatic activity and the horizontal scale of the shallow subsurface structure is derived from the difference in the stiffness or viscosity of the lithosphere beneath the two ridges. 相似文献
47.
Mauffret Alain Leroy Sylvie Vila Jean-Marie Hallot Erwan Mercier de Lépinay Bernard Duncan Robert A. 《Marine Geophysical Researches》2001,22(1):17-45
Using the diving submersible survey NAUTICA we investigated the central part of the Caribbean large igneous province (CLIP) to observe and sample internal portions of this proposed oceanic plateau. Most of the samples are gabbroic and doleritic rocks; basalts are scarce. Radiometric dating by 40Ar/39Ar incremental heating experiments indicate that the intrusive rocks are Campanian in age (81–75 Ma). In some places these intrusive rocks underlie older Santonian (85–83 Ma) extrusive basaltic rocks, suggesting that the Campanian rocks represent a sill injection and an underplating episode. Results of the diving program supplemented by information from ODP and DSDP drilling sites document a 20 m.y. period (94–75 Ma) of igneous activity in the submerged portion of the Caribbean large igneous province (CLIP). In the northern part of the Beata Ridge late Campanian and/or post Campanian uplift is documented by prominent Maastrichtian (71–65 Ma) erosion and the establishment of a Paleocene-middle Eocene (65–49 Ma) carbonate platform. During and after the uplift an extensional period is indicated by seismic images and the subsidence (3 km depth) of the carbonate platform. Paleocene ages (55–56 Ma) determined on some volcanic samples are attributed to localised decompression mantle melting that accompanied the extension. We document a prolonged period of magmatic and tectonic events that do not fit with the current models of short-lived plateau formation during mantle plume initiation but shares many similarities with the constructional histories of other oceanic large igneous provinces. 相似文献
48.
49.
Jean-Marie Auzende Eiichi Honza Xavier Boespflug Satendra Deo Jean-Philippe Eissen Jun Hashimoto Philippe Huchon Junichiro Ishibashi Yo Iwabuchi Philip Jarvis Masato Joshima Kiyoyuki Kisimoto Yasuto Kuwahara Yves Lafoy Tsuyoshi Matsumoto Jean-Pierre Maze Kiyohiko Mitsuzawa Hiroyasu Monma Takeshi Naganuma Yukihiro Nojiri Suguru Ohta Kiyoshi Otsuka Yoshihisa Okuda Hélène Ondreas Akira Otsuki Etienne Ruellan Myriam Sibuet Manabu Tanahashi Takeo Tanaka Tetsuro Urabe 《Marine Geophysical Researches》1990,12(4):269-283
The aim of the Japanese-French Kaiyo 87 cruise was the study of the spreading axis in the North Fiji Basin (SW Pacific). A
Seabeam and geophysical survey allowed us to define the detailed structure of the active NS spreading axis between 16° and
22° S and its relationships with the left lateral motion of the North Fiji Fracture Zone. Between 21° S and 18°10′ S, the
spreading axis trends NS. From 18°10 S to 16°40 S the orientation of the spreading axis changes from NS to 015°. North of
16°40′ S the spreading axis trends 160°. These two 015° and 160° branches converge with the left lateral North Fiji fracture
zone around 16°40′ S to define an RRFZ triple junction. Water sampling, dredging and photo TV deep towing give new information
concerning the hydrothermal activity along the spreading axis. The discovery of hydrothermal deposits associated with living
communities confirms this activity. 相似文献
50.
Submersible investigations with the ROV Victor 6000 of some pockmark structures on the seafloor of the Congo deep-sea fan
have shown that they are active venting sites of methane-rich fluids, associated with abundant fauna and carbonate crusts.
Moreover, methane hydrates have been observed both outcropping and deep in the sediments in the centre of the “Regab” giant
pockmark. Authigenic carbonates, mostly calcite sometimes mixed with aragonite, are cementing the sedimentary matrix components
and fauna; diatoms are abundant but only as moulds, indicating that biogenic silica dissolution occurred in situ synchronous
with carbonate precipitation. The occurrence of diagenetic barite and pyrite in some carbonate crusts demonstrates that they
can be formed either within the sulphate/methane transition zone or deeper in sulphate-depleted sediments. The oxygen isotopic
compositions of the diagenetic carbonates (3.17–6.01‰ V-PDB) indicate that precipitation occurred with bottom seawater mixed
with a variable contribution of water from gas hydrate decomposition. The very low carbon isotopic compositions of the diagenetic
carbonates (−57.1 to −27.75‰ V-PDB) demonstrate that carbon derives mostly from the microbial oxidation of methane. 相似文献