Recent disruptions in the timing and intensity of precipitation in Calakmul,Mexico     

Sofia Mardero  Birgit Schmook  Zachary Christman  Sarah E. Metcalfe  Betsab&#; De la Barreda-Bautista 《Theoretical and Applied Climatology》2020,140(1):129-144

This study addresses changes in the timing and intensity of precipitation from 1982 to 2016 from three meteorological stations around Calakmul, Mexico, a landscape balancing biodiversity conservation and smallholder agricultural production. Five methods were used to assess changes in precipitation: the Mann-Kendall test of annual and wet season trends; a fuzzy-logic approach to determine the onset of the rainy season; the Gini Index and Precipitation Concentration Index (PCI) to evaluate the temporal distribution of precipitation; Simple Precipitation Intensity Index (SDII) to evaluate precipitation intensity; and the Rainfall Anomaly Index (RAI) to identify the deficit or surplus of rainfall compared with the long-term mean. Overall, rainfall trends in Calakmul over this period indicate a slight increase, though results of the indices (Gini, SDII, PCI) all indicate that rainfall has become more intense and more unevenly distributed throughout the year. There was no significant trend in the onset date of rainfall or the RAI overall, though there were more pronounced crests and troughs from 2004 to 2016. Higher interannual variability and more pronounced rainfall anomalies, both positive and negative, suggest that rainfall in the Calakmul region has become more extreme. This research informs for management and livelihood strategies in the local region and offers insights for analyses of regional patterns of seasonal precipitation events in tropical landscapes worldwide.  相似文献   

Latitudinal variations of HCN, HC₃N, and C₂N₂ in Titan's stratosphere derived from Cassini CIRS data     

N.A. Teanby  P.G.J. Irwin  C.A. Nixon  B. Bézard  N.E. Bowles  L. Fletcher  F.W. Taylor 《Icarus》2006,181(1):243-255

Mid- and far-infrared spectra from the Composite InfraRed Spectrometer (CIRS) have been used to determine volume mixing ratios of nitriles in Titan's atmosphere. HCN, HC₃N, C₂H₂, and temperature were derived from 2.5 cm⁻¹ spectral resolution mid-IR mapping sequences taken during three flybys, which provide almost complete global coverage of Titan for latitudes south of 60° N. Three 0.5 cm⁻¹ spectral resolution far-IR observations were used to retrieve C₂N₂ and act as a check on the mid-IR results for HCN. Contribution functions peak at around 0.5-5 mbar for temperature and 0.1-10 mbar for the chemical species, well into the stratosphere. The retrieved mixing ratios of HCN, HC₃N, and C₂N₂ show a marked increase in abundance towards the north, whereas C₂H₂ remains relatively constant. Variations with longitude were much smaller and are consistent with high zonal wind speeds. For 90°-20° S the retrieved HCN abundance is fairly constant with a volume mixing ratio of around 1 × 10⁻⁷ at 3 mbar. More northerly latitudes indicate a steady increase, reaching around 4 × 10⁻⁷ at 60° N, where the data coverage stops. This variation is consistent with previous measurements and suggests subsidence over the northern (winter) pole at approximately 2 × 10⁻⁴ m s⁻¹. HC₃N displays a very sharp increase towards the north pole, where it has a mixing ratio of around 4 × 10⁻⁸ at 60° N at the 0.1-mbar level. The difference in gradient for the HCN and HC₃N latitude variations can be explained by HC₃N's much shorter photochemical lifetime, which prevents it from mixing with air at lower latitude. It is also consistent with a polar vortex which inhibits mixing of volatile rich air inside the vortex with that at lower latitudes. Only one observation was far enough north to detect significant amounts of C₂N₂, giving a value of around 9 × 10⁻¹⁰ at 50° N at the 3-mbar level.  相似文献   

Some challenges of an "upside down" nitrogen budget--science and management in Greenwich Bay, RI (USA)     

DiMilla PA  Nixon SW  Oczkowski AJ  Altabet MA  McKinney RA 《Marine pollution bulletin》2011,62(4):672-680

When nutrients impact estuarine water quality, scientists and managers instinctively focus on quantifying and controlling land-based sources. However, in Greenwich Bay, RI, the estuary opens onto a larger and more intensively fertilized coastal water body (Narragansett Bay). Previous inventories of nitrogen (N) inputs to Greenwich Bay found that N inputs from Narragansett Bay exceeded those from the local watershed, suggesting that recent efforts to reduce local watershed N loads may have little effect on estuarine water quality. We used stable isotopes of N to characterize watershed and Narragansett Bay N sources as well as the composition of primary producers and consumers throughout Greenwich Bay. Results were consistent with previous assessments of the importance of N inputs to Greenwich Bay from Narragansett Bay. As multiple N sources contribute to estuarine water quality, effective management requires attention to individual sources commensurate with overall magnitude, regardless of the political complications that may entail.  相似文献   

Synoptic and meteorological conditions during extreme snow cover ablation events in the Great Lakes Basin     

Zachary J. Suriano 《水文研究》2020,34(8):1949-1965

Snow cover ablation in the Great Lakes basin is a common and hydrologically important process during the cold season, contributing to a majority of the basin's runoff, and less frequent, extreme ablation events are highly impactful due to an increased flooding risk and warrant specific investigation. A brief climatology of extreme ablation events is presented, where extreme is considered within the top 5% of the distribution. Using synoptic classification techniques, individual weather patterns associated with extreme snow ablation in the Great Lakes basin are isolated. A single pattern deemed the most influential in generating extreme ablation events, southerly flow-1, is examined in detail, and three case studies are presented to determine the meteorological conditions and surface energy fluxes responsible for ablation. Over 75% of extreme events are associated with southerly flow patterns that predominantly ablate snow with sensible heat fluxes, while rain-on-snow patterns induce the remaining extreme events from 1980–2009. Type southerly flow-1 is responsible for 45% of the extreme events and is characterized by strong southerly advection of warm air into the basin, where sensible heat fluxes of 45–125 Wm⁻² are responsible for the majority of energy transfer into the snowpack. When compared with an average ablation event, an extreme ablation event for southerly flow-1 exhibits air temperatures, dew point temperatures, and wind speeds that are 3.8°C, 3.0°C, and 1.2 ms⁻¹ warmer and faster than an average event, indicating a greater potential for larger ablation.  相似文献   

Discharge responses associated with rapid snow cover ablation events in the Susquehanna and Wabash River basins     

Zachary J. Suriano  Gina R. Henderson  Daniel J. Leathers 《自然地理学》2020,41(1):70-82

ABSTRACT

In the mid-latitudes, snow plays a critical role in regional hydroclimate, with snow ablation variability in ephemeral regions representing an area of essential research. Due to a lack of historical snow-water-equivalent data in the eastern United States, recent research has substituted daily snow depth changes for ablation. These studies, however, do not explicitly examine if such a substitution yields a snowmelt hydrological signal, an important component of water resource management. As such, this study evaluates if ablation events, as defined as a daily snow depth decrease, subsequently result in increased river discharge within two similarly sized watersheds in the eastern United States: the Wabash and Susquehanna River basins. For both basins, >75% of snow ablation events resulted in a positive river discharge response (increase in discharge) at a 3-day lag. Furthermore, results show a significant and positive relationship between ablation event frequency and seasonal discharge response, such that an increase (decrease) in seasonal snow ablation event frequency yields an increase (decrease) in associated seasonal river discharge at a 3-day lag. These relationships indicate that inter-diurnal decreases in snow depth do carry hydrological implications, adding confidence that such a definition of ablation is appropriate for climatological applications.  相似文献   

Manganese thermometer for mantle peridotites     

J. S. Delaney  J. V. Smith  J. B. Dawson  P. H. Nixon 《Contributions to Mineralogy and Petrology》1979,71(2):157-169

The temperature dependence of the Mn-Mg distribution between garnet and clinopyroxene, originally proposed by Carswell, was confirmed by Shimizu and Allègre (1978) using ion microprobe and electron microprobe data. High precision electron microprobe analyses of a larger set of 52 Iherzolites from S. Africa and Malaita, Solomon Islands show considerable scatter in the temperature dependence of this distribution, and correlation with the CaO content of the garnet is indicated. A new distribution coefficient is based on the reaction: $$\begin{gathered} \operatorname{Mn} _{\text{2}} \operatorname{Si} _2 \operatorname{O} _6 {\text{ + }}\operatorname{CaAl} _{2/3} \operatorname{SiO} _4 {\text{ + }}\operatorname{MgAl} _{2/3} \operatorname{SiO} _4 \hfill \\ {\text{Mn - pyroxene grossular pyrope}} \hfill \\ {\text{ }} \rightleftharpoons \operatorname{CaMgSi} _2 \operatorname{O} _6 {\text{ + }}2\operatorname{MnAl} _{2/3} \operatorname{SiO} _4 \hfill \\ {\text{ diopside spessartine}} \hfill \\ \end{gathered} $$ It was calibrated against temperature determined from two independent thermometers (Wells pyroxene and O'Neill-Wood garnet-olivine) for Iherzolitic assemblages, and shown to to be sensitive to within + 50 °C for most specimens in the range 900 °– 1,300 ° C. This distribution coefficient appears independent of pressure within the uncertainty of the available data, and has the potential to be a third independent thermometer for use in garnet Iherzolites and possibly eclogites.  相似文献   

Technical note: Conditions for using the floating chamber method to estimate air-water gas exchange     

James N. Kremer  Scott W. Nixon  Betty Buckley  Patrick Roques 《Estuaries and Coasts》2003,26(4):985-990

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The H.T. Odum synthesis essay, a new section in estuaries     

Carlos M. Duarte  Scott Nixon  Stephen Threlkeld 《Estuaries and Coasts》2005,28(1):1-1

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Corundum inclusions in diamonds—discriminatory criteria and a corundum compositional dataset     

Mark T. Hutchison  Peter H. Nixon  Simon L. Harley 《Lithos》2004,77(1-4):273-286

Mineral inclusions of corundum are reported from diamonds from alluvial deposits of tributaries of the Rio Aripuanã, Juina, Brazil. We present the first recorded occurrence of sapphire as an inclusion in diamond and expand on the database of ruby and white corundum inclusions. Ruby inclusions are found to occur both as isolated and touching grains with aluminous pyroxene and associated with ferropericlase. Mineral chemistry and phase relations place the origin of such ruby-bearing diamonds within the lower mantle at 770 km. Mineral associations indaving other corundum inclusions were not observed; hence, their depth of origin is less certain.

Compositions of corundum samples were characterised by electron and ion microprobe. Given the scarcity of literature data, corundum samples from a variety of other geological settings were also analysed. Samples comprised corundums associated with granitic emplacement, metasomatism, amphibolite-facies and granulite-facies rocks, gem and industrial synthetic origins and carmine-coloured corundums recovered from kimberlite drill cores.

In addition to variable amounts of Cr, Fe, Ti, Mg and Si, measurable quantities of other transition elements and high field strength elements were also detected. Corundums from similar geological settings show very similar compositions and are easily distinguishable from other settings. Irrespective of locality, rubies from Norwegian, Tanzanian and Kenyan amphibolite-facies rocks are compositionally indistinguishable. Additionally, corundums from metasomatised zones associated with contact metamorphism from Arizona and Japan were very similar, particularly characterised by unusually high abundance of mobile Zr and Nb (tens of ppm). All Juina inclusions are particularly distinguishable from other corundums by high concentrations of Ni (18–171 ppm weight), typically at least an order of magnitude enriched over the same corundum varietal types from elsewhere. Furthermore, the sapphire inclusion exhibited much larger ratios of Ga and Ge to HFSE elements compared to otherwise similar samples, and ruby inclusions are distinguished by high Mg/Fe ratios (0.27–1.56 by weight). Compositional differences between inclusions in diamonds and corundums from other settings in addition to corundum's physical and chemical durability suggest that with the employment of rapid identification tools such as energy dispersive spectrometry (EDS) and laser-ICPMS, corundum has promise as an indicator of diamond prospectivity.  相似文献   

A review of mantle xenoliths and their role in diamond exploration     

Peter H. Nixon 《Journal of Geodynamics》1995,20(4)

An historical introduction to the geotherm and its significance for the existence of a diamond window at the base of the peridotite lithosphere is followed by a brief survey of types of mantle zenoliths (low T, high T and metasomatized peridotites, megacrysts or discrete nodules, eclogites and less common varieties). The similarities of eclogite xenoliths to the subducted eclogites with graphitized diamonds in the peridotite massif of Beni Bousera, northern Morocco, are reviewed. Diamond-bearing peridotite (Archaean harzburgite and lherzolite) and eclogite xenoliths are rare, having suffered excessive disaggregation. They do not necessarily relate proportionately to the types of diamonds in the host kimberlite/lamproite.Batches of single mineral species from disaggregated diamondiferous xenoliths, particularly garnets, form a realistic approach to diamond exploration. Nickel thermometry applied to Cr pyropes, developed by Griffin et al. (1989) Contr. Miner. Petrol. 103, 199–203, and barometry dependent upon Cr content in notional coexisting spinels, provide a realistic appreciation of the extent of the diamond window. Sodium and K pressure “indicators” in eclogitic garnets and clinopyroxenes are reviewed, but estimates are affected by mantle processes (metasomatism) and amounts of coexisting P and Ti.Metasomatic processes in the basal lithosphere are sourced in the underlying asthenospheric (megacryst) magmas. Depending on the degree and type of interaction they can result in the destruction of ancient diamonds or the growth of new peridotitic diamonds. Partial destruction or replacement of mineral indicators may also result and Cr garnets acquire distinctive quantifiable trace element signatures. High T minerals encapsulated in diamond are either relict from former ambient high T conditions or the result of localized thermal highs emanating from asthenospheric magmas (or plume/diapir).It is concluded that the fullest significance of the geochemistry (sensuo lato) of the diamondiferous debris erupted by kimberlites and lamproites, can only be made by reference to complementary geophysical, structural and isotopic studies of the surrounding cratonic country rocks. Thus, tectonothermal events which punctuate the varied evolutionary histories of cratons—plume migration, rifting, subduction/overthrusting, delamination, cratonization, flood basalt generation, regional metamorphism and metasomatism, etc.—can be manifested in the deep lithosphere environment, and cannot be divorced from questions of diamond formation and survival.  相似文献