Iodine in Chinese coals and its geochemistry during coalification     

Daishe Wu  Haiwen Deng  Baoshan Zheng  Wuyi Wang  Xiuyi Tang  Huayun Xiao 《Applied Geochemistry》2008,23(8):2082-2090

To determine the I distribution in Chinese coals, a nationwide survey was undertaken based on the distribution, periods of formation, rank and production yields of various coal deposits. A total of 305 coal samples were collected and their I contents were determined by catalytic spectrophotometry with pyrohydrolysis. The geochemistry of I during coalification (including both peat diagenesis and coal metamorphism) was assessed. It was found that the I contents of Chinese coals range from 0.04 mg kg^–1 to 39.5 mg kg^–1 and exhibit a lognormal distribution, with a geometric mean of 1.27 mg kg^–1. Statistical correlation analysis and the observation that I contents increase with coal rank indicate that coal I is chalcophile in nature, and not generally organically bound. When peat developed into lignite through diagenesis, 95–99.9% of the original I was lost. The composition and structure of clay minerals present in the coal were controlled by the original depositional environment. The higher the I content of coals, the more likely the original sediments were affected by a marine environment. Iodine contents increased from lignite through sub-bituminous and bituminous coals to anthracite. This indicates that coal absorbed excess I from hydrothermal fluids during metamorphism (including geothermal metamorphism and telemagmatic metamorphism). The telemagmatic metamorphism was caused by magmatic activities that depended on the specific geological structure of the region. In China, most high-rank coals were formed by telemagmatic metamorphism.  相似文献   

Extreme oxygen isotope signature of meteoric water in magmatic zircon from metagranite in the Sulu orogen, China: Implications for Neoproterozoic rift magmatism   总被引：4，自引：0，他引：4  

Jun Tang  Yong-Fei Zheng  Bing Gong  Tian-Shan Gao  Fu-Yuan Wu 《Geochimica et cosmochimica acta》2008,72(13):3139-3169

Unusual ¹⁸O depletion, with δ¹⁸O values as negative as −10‰ to −4‰ relative to VSMOW, was reported in zircons from ultrahigh-pressure eclogite-facies metamorphic rocks in the Dabie-Sulu orogenic belt, China. But it is critical for the negative δ¹⁸O zircons to be distinguished between magmatic and metamorphic origins, because the ¹⁸O depletion can be acquired by high-T eclogite-facies metamorphism of meteoric-hydrothermally altered low δ¹⁸O rocks. While zircon O diffusion kinetics has placed a reasonable constraint on this, zircon trace element compositions can provide a straightforward distinction between the magmatic and metamorphic origins. This paper reports our finding of unusual ¹⁸O depletion in zircon from granitic gneiss in the northeastern end of the Sulu orogen. Zircon δ¹⁸O values vary from −7.8‰ to −3.1‰ along a profile of 50 m length at Zaobuzhen. They are close to extremely low δ¹⁸O values of −9.0‰ to −5.9‰ for metagranite at Qinglongshan and adjacent areas in the southwestern end of the Sulu orogen. CL imaging suggests that the low δ¹⁸O zircons at Zaobuzhen are primarily of magmatic origin, but underwent different degrees of metamorphic modification. Zircon U-Pb dating yields middle Neoproterozoic ages of 751 ± 27 to 779 ± 25 Ma for protolith crystallization and Triassic ages of 214 ± 10 to 241 ± 33 Ma for metamorphic resetting. However, no metamorphic modification occurs in zircon REE patterns that only indicate magmatic recrystallization and hydrothermal alteration, respectively. Thus, the negative δ¹⁸O zircons are interpreted as crystallizing from negative δ¹⁸O magmas due to melting of meteoric-hydrothermally altered negative δ¹⁸O rocks in an active rift setting at about 780 Ma. The variation in zircon δ¹⁸O values indicates considerable O isotope heterogeneity in its granitic protolith. Zircon Lu-Hf isotope analyses give positive ε_Hf(t) values of 1.6-4.1 and Hf model ages of 1.18-1.30 Ga. This suggests that the granitic protolith was derived from the mid-Neoproterozoic reworking of late Mesoproterozoic juvenile crust. The metagranites at Zaobuzhen and Qinglongshan, about 450 km apart, are two known occurrences of the unusually low δ¹⁸O zircons below −6‰ so far reported in the Sulu orogen. They are similar to each other in both protolith and metamorphic ages, so that they share the same nature of both Neoproterozoic protolith and Triassic metamorphism. Therefore, the locally negative δ¹⁸O zircons may register centers of low δ¹⁸O magmatism during the supercontinental rifting.  相似文献   

Refertilization of ancient lithospheric mantle beneath the central North China Craton: Evidence from petrology and geochemistry of peridotite xenoliths     

Yan-Jie Tang  Hong-Fu Zhang  Ji-Feng Ying  Jin Zhang  Xiao-Ming Liu 《Lithos》2008,101(3-4):435-452

The petrology and geochemistry of peridotite xenoliths in the Cenozoic basalts from Fanshi, the central North China Craton (NCC), provide constraints on the evolution of sub-continental lithospheric mantle. These peridotite xenoliths are mainly spinel-facies lherzolites with minor harzburgites. The lherzolites are characterized by low forsterite contents in olivines (Fo < 91) and light rare earth element (LREE) enrichments in clinopyroxenes. In contrast, the harzburgites are typified by high-Fo olivines (> 91), high-Cr# spinels and clinopyroxenes with low abundances of heavy REE (HREE). These features are similar to those from old refractory lithospheric mantle around the world, and thus interpreted to be relics of old lithospheric mantle. The old lithospheric mantle has been chemically modified by the influx of melts, as evidenced by the Sr–Nd isotopic compositions of clinopyroxenes and relatively lower Fo contents than typical Archean lithospheric mantle (Fo > 92.5). The Sr–Nd isotopic compositions of harzburgites are close to EM1-type mantle, and of the lherzolites are similar to bulk silicate earth. The latter could be the result of recent modification of old harzburgites by asthenospheric melt, which is strengthened by fertile compositions of minerals in the lherzolites. Therefore, the isotopic and chemical heterogeneities of the Fanshi peridotite xenoliths reflect the refertilization of ancient refractory lithospheric mantle by massive addition of asthenospheric melts. This may be an important mechanism for the lithospheric evolution beneath the Central NCC.  相似文献   

The geochemical characteristics and origin of crude oils in the Kekeya Oilfield,Xinjiang, China   总被引：2，自引：2，他引：0  

Youjun Tang  Ling Zan  Dujie Hou  Zhongyao Xiao 《中国地球化学学报》2008,27(4):420-423

GC/MS and GC/MS/MS techniques were employed to describe the characteristics of biomarker assemblages in two sets of hydrocarbon source rocks, Jurassic and Permian, in southwestern Tarim, and the parameters for the classification of the two sets of hydrocarbon source rocks have been established. It is found that diahopane and C30-unknown terpane are abundant in Permian samples, the contents of diahopane in Jurassic samples are relatively low, and terpenoids have been detected in Jurassic samples but not in Permian source rock samples. Kekeya crude oils are abundant in diahopane and C30-unknown terpane. The results of fine oil-rock correlation indicated that Kekeya crude oils were derived mainly from the Permian hydrocarbon source rocks. However, a small amount of diterpenoid was detected in the crude oils, indicating that the Jurassic hydrocarbon source rocks also made a certain contribution to Kekeya crude oils.  相似文献   

Dynamical downscaling of regional climate over eastern China using RSM with multiple physics scheme ensembles     

Peishu  Zong  Jianping  Tang  Shuyu  Wang  Lingyun  Xie  Jianwei  Yu  Yunqian  Zhu  Xiaorui  Niu  Chao  Li 《Theoretical and Applied Climatology》2017,129(3-4):1263-1277

Theoretical and Applied Climatology - The parameterization of physical processes is one of the critical elements to properly simulate the regional climate over eastern China. It is essential to...  相似文献   

A peak-cluster assessment method for the identification of upland planation surfaces     

Li-Yang Xiong  Guo-An Tang  Ye-Qing Qian 《International journal of geographical information science》2017,31(2):387-404

Residual upland planation surfaces serve as strong evidence of peneplains during long intervals of base-level stability in the peneplanation process. Multi-stage planation surfaces could aid the calculation of uplift rates and the reconstruction of upland plateau evolution. However, most planation surfaces have been damaged by crustal uplift, tectonic deformation, and surface erosion, thus increasing the difficulty in automatically identifying residual planation surfaces. This study proposes a peak-cluster assessment method for the automatic identification of potential upland planation surfaces. It consists of two steps: peak extraction and peak-cluster characterization. Three critical parameters, namely, landform planation index (LPI), peak elevation standard deviation, and peak density, are employed to assess peak clusters. The proposed method is applied and validated in five case areas in the Tibetan Plateau using a Shuttle Radar Topography Mission digital elevation model (SRTM DEM) with 3 arc-second resolution. Results show that the proposed method can effectively extract potential planation surfaces, which are found to be stable with different resolutions of DEM data. A significant planation characteristic can be obtained in the relatively flat areas of the Gangdise–Nyainqentanglha Mountains and Qaidam Basin. Several vestiges of potential former planation areas are also extracted in the hilly-gully areas of the western part of the Himalaya Mountains, the northern part of the Tangula–Hengduan Mountains, and the northeastern part of the Kunlun–Qinling Mountains despite the absence of significant topographical features characterized by low slope angles or low terrain reliefs. Vestiges of planation surfaces are also identified in these hilly-gully upland areas. Hence, the proposed method can be effectively used to extract potential upland planation surfaces not only in flat areas but also in hilly-gully areas.  相似文献   

HBV相关肝病患者外周血NK细胞PD-1、Tim-3表达及意义     

赵小瑜  周妮  汤永志  林希  陈华忠  朱坚胜 《寒旱区科学》2017,9(5):51-54,59

目的 了解HBV相关肝病患者外周血NK细胞表面PD-1、Tim-3的表达情况,探讨PD-1和Tim-3的表达与血清HBV-DNA载量的相关情况。方法 选择HBV感染相关肝病患者74例,其中CHB患者30例,LC患者24例,HCC患者20例,健康对照18例。应用流式细胞术检测NK细胞表面PD-1、Tim-3表达,荧光定量PCR检测HBV-DNA量,ELISA法检测细胞因子分泌水平。统计各组患者PD-1和Tim-3的表达率,比较各组差异,分析其与病情的相关性。结果 CHB、LC、HCC组外周血NK细胞表面PD-1和Tim-3的表达率分别为34.46%±7.31%、59.09%±12.35%、61.49%±15.26%和19.18%±6.05%、28.64%±11.20%、31.24%±11.85%,均高于对照组（P<0.01）,LC组和HCC组明显高于CHB组（P<0.01）,LC组和HCC组比较无统计学差异。在CHB组,PD-1的表达率与HBV-DNA呈负相关关系（R=-0.437,P=0.033）。CHB、LC、HCC各组血清中细胞因子TNF-α和IFN-γ水平分别为0.66±0.63、0.75±0.66、0.85±0.71和1.76±0.88、1.83±1.23、1.60±0.53,均低于健康对照组（P<0.01）。结论 HBV相关肝病患者NK细胞表面PD-1、Tim-3表达均增加,且与病情严重程度有关,增加表达的PD-1与血清HBV-DNA载量存在负相关性,HBV肝病各组血清TNF-α、IFN-γ分泌减少。  相似文献   

Frost-heave properties of saturated compacted silty clay under one-side freezing condition     

HongYan M  Feng Zhang  DeCheng Feng  KangWei Tang 《寒旱区科学》2017,9(3):273-279

In seasonally frozen regions, the frost-heave properties of soil play a significant role in its upper-structure performance and durability. To investigate the frost-heave behaviors of saturated, compacted silty clay soil widely used as subgrade material, a series of one-side freezing tests was carried out; and the freezing depth and frozen front effected by the compactness, temperature, overburden pressure, and water-supply condition were analyzed and discussed. The results show that the moving speed of the frozen front and growth rate of the frozen depth are positively correlated. The frost heave is maximum in the frost-heave stability condition. The frost ratio of saturated soil is proportional to the water supply and cooling temperature under a one-side freezing condition. The frost ratio of saturated soil is inversely proportional to the initial compactness of the soil specimen and the overburden pressure.  相似文献   

GPS及AVHRR资料在浅海潮间带测量中的应用   总被引：1，自引：0，他引：1       下载免费PDF全文

范德新  杨亚新  尹成华  汤建国 《气象》2001,27(3):19-22

通过利用GPS及渔探器实测，并进行潮位订正，获得南通浅海海域大量测点的高程资料，通过对多时相各通道NOAA卫星照片进行筛选，挑选能反映浅海地貌的通道资料，从中读取各测点相对应的灰度值，在此基础上利用分级线性回归，建立不同高程范围内的高程，灰度线性回归方程，确定不同高程的灰度阈值，从而测量出南通市浅海海域不同高程以上的潮间带面积，分布。  相似文献   

中国大气本底条件下不同地区地面臭氧特征   总被引：20，自引：1，他引：20  

丁国安  徐晓斌  罗超  汤洁  向荣彪  颜鹏  王木林  李兴生 《气象学报》2001,59(1):88-96

分析了晴天和阴天时瓦里关本底台、临安和龙凤山本底站地面 O3浓度的特点。晴天时 ,临安站地面 O3有明显日变化 ,以春季最大 (42 .9× 1 0 - 9) ,夏季最小 (2 0 .3× 1 0 - 9) ;龙凤山站日变化更规则 ,秋季最大 (约 2 7× 1 0 - 9) ;瓦里关本底台除了夏季有微弱日变化外 ,其它季节没有明显的日变化 ,日较差也很小 ,但夏季地面 O3浓度显著高於冬季 ;夏季晴天瓦里关地面O3浓度要比龙凤山、临安高 2 0× 1 0 - 9以上。阴天时 ,临安和龙凤山站除了日变化不很规则和日较差较小外 ,其它大致与晴天相同。阴天时瓦里关不仅没有日变化 ,而且日较差更小 ,但夏季地面 O3仍然高於冬季。太阳总辐射和 NOx 浓度是控制龙凤山和临安晴天和阴天地面O3浓度的决定性因子 ,它在不同季节和地区发挥着重要作用。夏季青藏高原周围地区气流向高原输送作用 ,是形成夏季瓦里关地面 O3高值以及微弱日变化的主要原因。在美国 MaunaLoa基准站也曾观测到类似的输送影响。O3在低对流层随垂直高度增加的分布特征 ,决定了东西部测点地面 O3的差异  相似文献