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101.
Transient release of Ni,Mn and Fe from mixed metal sulphides under oxidising and reducing conditions
C. Naylor W. Davison M. Motelica-Heino L. M. van der Heijdt G. A. van den Berg 《Environmental Earth Sciences》2012,65(7):2139-2146
The potential release of metals from anoxic sediments exposed to oxygen was investigated by using a synthetic preparation
of metal sulphides dominated by solid phase FeS. The technique of DGT (diffusive gradients in thin-films) was used to measure
sulphide and Fe, Mn and Ni in the anoxic metal-sulphide slurry, which had a pH of 6.4. Speciation calculations based on these
data showed there was moderate supersaturation with respect to amorphous FeS in the solution phase. Measurements made using
DGT with a range of diffusion layer thicknesses showed that when Fe, Mn and Ni are removed from solution there is fairly rapid
(minutes) release from the solid phase, that is reasonably well sustained. This presumed desorptive release will be responsible
for elevated concentrations of some metals in solution when sediments are resuspended. Oxidation of the slurry by bubbling
with air rapidly (hours) removed Fe, Mn and Ni from the pore water solution. While Fe concentrations in solution remained
low after the removal, Mn and Ni were transiently released. These results were consistent with initial rapid oxidation of
Fe(II) to oxyhydroxides, which remove Mn(II) and Ni by adsorption. The slower oxidation of FeS then releases Mn and Ni, but
these too are eventually removed by adsorption to iron oxyhydroxides. These data suggest that oxidation of metal sulphides
will contribute to the release of metals from sediment disturbed by dredging or remedial aeration, but it is likely to be
short lived, with complete removal within a day. 相似文献
102.
Aaron M. McCright 《Climatic change》2011,104(2):243-253
I offer some theoretical insights to help us better understand the moderator effect of political orientation that Larry Hamilton
and others have found in recent years. Reflexive modernization theory highlights an emerging tension between those who direct
attention to the negative consequences of industrial capitalism such as climate change (e.g., the scientific community and
environmental organizations) and those who defend the economic system against such critiques (e.g., the conservative movement).
Political divisions in the American public increasingly map onto these societal divisions between critics and defenders of
the industrial capitalist order—especially for the issue of climate change. This alignment is facilitated by increased polarization
among political elites and balkanization of the news media. Strong evidence of the moderator effect is consistent with the
expectations of information processing theory and elite cues hypothesis from political science. Recent empirical findings
in political psychology and neuroscience also seem pertinent for explaining this moderator effect. I end by outlining a few
implications for climate change research and communication. 相似文献
103.
Earthquake motion is one of the extreme loads acting on large dams. Dam owners and regulators must therefore ensure that dams
are safely operated and present minimal risk to the public in case of extreme loads such as floods and earthquakes. Owners
of many dams or officials in charge of dam safety programs may consider comparative assessment of the seismic risk associated
with their dams and establish priorities for detailed evaluation. South Africa has in excess of 100 large state-owned dams
and the characteristics of these dams have been used to perform a basic seismic hazard assessment and rank the vulnerability
of these dams from the lowest to highest. One of the most decisive factors that contributes to the risk of a dam is the wall
type; with gravity and earthfill dams being the most vulnerable to earthquake motion. Another aspect that needs further investigation
is the downstream hazard potential which, if known to a better degree of accuracy, can provide more reasonable estimates of
the risk factors. 相似文献
104.
Our objective is to understand general causes of different river channel patterns. In this paper we compare an empirical stream power‐based classification and a physics‐based bar pattern predictor. We present a careful selection of data from the literature that contains rivers with discharge and median bed particle size ranging over several orders of magnitude with various channel patterns and bar types, but no obvious eroding or aggrading tendency. Empirically a continuum is found for increasing specific stream power, here calculated with pattern‐independent variables: mean annual flood, valley gradient and channel width predicted with a hydraulic geometry relation. ‘Thresholds’, above which certain patterns emerge, were identified as a function of bed sediment size. Bar theory predicts nature and presence of bars and bar mode, here converted to active braiding index (Bi). The most important variables are actual width–depth ratio and nonlinearity of bed sediment transport. Results agree reasonably well with data. Empirical predictions are somewhat better than bar theory predictions, because the bank strength is indirectly included in the empirical prediction. In combination, empirical and theoretical prediction provide partial explanations for bar and channel patterns. Increasing potential‐specific stream power implies more energy to erode banks and indeed correlates to channels with high width–depth ratio. Bar theory predicts that such rivers develop more bars across the width (higher Bi). At the transition from meandering to braiding, weakly braided rivers and meandering rivers with chutes are found. Rivers with extremely low stream power and width–depth ratios hardly develop bars or dynamic meandering and may be straight or sinuous or, in case of disequilibrium sediment feed, anastomosing. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
105.
Aaron J. Cavosie John W. Valley Noriko T. Kita Michael J. Spicuzza Takayuki Ushikubo Simon A. Wilde 《Contributions to Mineralogy and Petrology》2011,162(5):961-974
The oxygen isotope ratios (δ18O) of most igneous zircons range from 5 to 8‰, with 99% of published values from 1345 rocks below 10‰. Metamorphic zircons
from quartzite, metapelite, metabasite, and eclogite record δ18O values from 5 to 17‰, with 99% below 15‰. However, zircons with anomalously high δ18O, up to 23‰, have been reported in detrital suites; source rocks for these unusual zircons have not been identified. We report
data for zircons from Sri Lanka and Myanmar that constrain a metamorphic petrogenesis for anomalously high δ18O in zircon. A suite of 28 large detrital zircon megacrysts from Mogok (Myanmar) analyzed by laser fluorination yields δ18O from 9.4 to 25.5‰. The U–Pb standard, CZ3, a large detrital zircon megacryst from Sri Lanka, yields δ18O = 15.4 ± 0.1‰ (2 SE) by ion microprobe. A euhedral unzoned zircon in a thin section of Sri Lanka granulite facies calcite
marble yields δ18O = 19.4‰ by ion microprobe and confirms a metamorphic petrogenesis of zircon in marble. Small oxygen isotope fractionations
between zircon and most minerals require a high δ18O source for the high δ18O zircons. Predicted equilibrium values of Δ18O(calcite-zircon) = 2–3‰ from 800 to 600°C show that metamorphic zircon crystallizing in a high δ18O marble will have high δ18O. The high δ18O zircons (>15‰) from both Sri Lanka and Mogok overlap the values of primary marine carbonates, and marbles are known detrital
gemstone sources in both localities. The high δ18O zircons are thus metamorphic; the 15–25‰ zircon values are consistent with a marble origin in a rock-dominated system (i.e.,
low fluid(external)/rock); the lower δ18O zircon values (9–15‰) are consistent with an origin in an external fluid-dominated system, such as skarn derived from marble,
although many non-metasomatized marbles also fall in this range of δ18O. High δ18O (>15‰) and the absence of zoning can thus be used as a tracer to identify a marble source for high δ18O detrital zircons; this recognition can aid provenance studies in complex metamorphic terranes where age determinations alone
may not allow discrimination of coeval source rocks. Metamorphic zircon megacrysts have not been reported previously and appear
to be associated with high-grade marble. Identification of high δ18O zircons can also aid geochronology studies that seek to date high-grade metamorphic events due to the ability to distinguish
metamorphic from detrital zircons in marble. 相似文献
106.
We have performed experiments to evaluate Au solubility in natural, water-saturated basaltic melts as a function of oxygen fugacity. Experiments were carried out at 1000 °C and 200 MPa, and oxygen fugacity was controlled at the fayalite-magnetite-quartz (FMQ) oxygen fugacity buffer and FMQ + 4. All experiments were saturated with a metal-chloride aqueous solution loaded initially as a 10 wt% NaCl eq. fluid. The stable phase assemblage at FMQ consists of basalt melt, olivine, clinopyroxene, a single-phase aqueous fluid, and metallic Au. The stable phase assemblage at FMQ + 4 consists of basalt melt, clinopyroxene, magnetite-spinel solid solution, a single-phase aqueous fluid, and metallic Au. Silicate glasses (i.e., quenched melt) and their contained crystalline material were analyzed by using both electron probe microanalysis (EPMA) and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). Measured Au concentrations in the quenched melt range from 4.8 μg g−1 to 0.64 μg g−1 at FMQ + 4, and 0.54 μg g−1 to 0.1 μg g−1 at FMQ. The measured solubility of Au in olivine and clinopyroxene was consistently below the LA-ICP-MS limit of detection (i.e., 0.1 μg g−1). These melt solubility data place important limitations on the dissolved Au content of water-saturated, Cl- and S-bearing basaltic liquids at geologically relevant fO2 values. The new data are compared to published, experimentally-determined values for Au solubility in dry and hydrous silicate liquids spanning the compositional range from basalt to rhyolite, and the effects of melt composition, oxygen fugacity, pressure and temperature are discussed. 相似文献
107.
108.
T. K. Croat T. Berg T. Bernatowicz E. Groopman M. Jadhav 《Meteoritics & planetary science》2013,48(4):686-699
Transmission electron microscope (TEM) investigations have revealed Os, Ru, Mo‐rich refractory metal nuggets within four different presolar graphites, from both the high‐density (HD) Murchison (MUR) and low‐density (LD) Orgueil (ORG) fractions. Microstructural and chemical data suggest that these are direct condensates from the gas, rather than forming later by exsolution. The presolar refractory metal nugget (pRMN) compositions are variable (e.g., from 8 < Os atom% < 77), but follow the same chemical fractionation trends as isolated refractory metal nuggets (mRMNs) previously found in meteorites (Berg et al. 2009). From these compositions one can infer a temperature of last equilibration with the gas of 1405–1810 K (e.g., Berg et al. 2009 at approximately 100 dyne cm?2 pressure), which implies that the host graphites form over roughly the same range (in agreement with predictions) and that the pRMNs are chemically isolated from the gas when captured by graphite. Further, the pRMN compositions give evidence that HD graphites form at a higher T than LD ones. Chemical and phase similarities with the isolated mRMNs suggest that the mRMNs also condense directly from a gas, although from the early solar nebula rather than a presolar environment. Although the pRMNs themselves are too small for detection of isotopic anomalies, NanoSIMS isotopic measurements of their host graphites confirm a presolar origin for the assemblages. The two pRMN‐containing LD graphites show evidence of a supernova (SN) origin, whereas the stellar origins of the pRMNs in HD graphite are unclear, because only less‐diagnostic 12C enrichments are detectable (as is commonly true for HD graphites). 相似文献
109.
Michael P. Callahan Aaron S. Burton Jamie E. Elsila Eleni M. Baker Karen E. Smith Daniel P. Glavin Jason P. Dworkin 《Meteoritics & planetary science》2013,48(5):786-795
The investigation into whether Mars contains signatures of past or present life is of great interest to science and society. Amino acids and nucleobases are compounds that are essential for all known life on Earth and are excellent target molecules in the search for potential Martian biomarkers or prebiotic chemistry. Martian meteorites represent the only samples from Mars that can be studied directly in the laboratory on Earth. Here, we analyzed the amino acid and nucleobase content of the shergottite Roberts Massif (RBT) 04262 using liquid chromatography‐mass spectrometry. We did not detect any nucleobases above our detection limit in formic acid extracts; however, we did measure a suite of protein and nonprotein amino acids in hot‐water extracts with high relative abundances of β‐alanine and γ‐amino‐n‐butyric acid. The presence of only low (to absent) levels of several proteinogenic amino acids and a lack of nucleobases suggest that this meteorite fragment is fairly uncontaminated with respect to these common biological compounds. The distribution of straight‐chained amine‐terminal n‐ω‐amino acids in RBT 04262 resembled those previously measured in thermally altered carbonaceous meteorites (Burton et al. 2012; Chan et al. 2012). A carbon isotope ratio of ?24‰ ± 6‰ for β‐alanine in RBT 04262 is in the range of reduced organic carbon previously measured in Martian meteorites (Steele et al. 2012). The presence of n‐ω‐amino acids may be due to a high temperature Fischer‐Tropsch‐type synthesis during igneous processing on Mars or impact ejection of the meteorites from Mars, but more experimental data are needed to support these hypotheses. 相似文献
110.
J. de Vries M. H. G. Jacobs A. P. van den Berg M. Wehber C. Lathe C. A. McCammon W. van Westrenen 《Physics and Chemistry of Minerals》2013,40(9):691-703
Iron-rich orthopyroxene plays an important role in models of the thermal and magmatic evolution of the Moon, but its density at high pressure and high temperature is not well-constrained. We present in situ measurements of the unit-cell volume of a synthetic polycrystalline end-member orthoferrosilite (FeSiO3, fs) at simultaneous high pressures (3.4–4.8 GPa) and high temperatures (1,148–1,448 K), to improve constraints on the density of orthopyroxene in the lunar interior. Unit-cell volumes were determined through in situ energy-dispersive synchrotron X-ray diffraction in a multi-anvil press, using MgO as a pressure marker. Our volume data were fitted to a high-temperature Birch–Murnaghan equation of state (EoS). Experimental data are reproduced accurately, with a $\varDelta P$ Δ P standard deviation of 0.20 GPa. The resulting thermoelastic parameters of fs are: V 0 = 875.8 ± 1.4 Å3, K 0 = 74.4 ± 5.3 GPa, and $\frac{{\text d}K}{{\text d}T} = -0.032 \pm 0.005\,\hbox{GPa K}^{-1}$ d K d T = - 0.032 ± 0.005 GPa K - 1 , assuming ${K}^{\prime}_{0} = 10 $ K 0 ′ = 10 . We also determined the thermal equation of state of a natural Fe-rich orthopyroxene from Hidra (Norway) to assess the effect of magnesium on the EoS of iron-rich orthopyroxene. Comparison between our two data sets and literature studies shows good agreement for room-temperature, room-pressure unit-cell volumes. Preliminary thermodynamic analyses of orthoferrosilite, FeSiO3, and orthopyroxene solid solutions, (Mg1?x Fe x ) SiO3, using vibrational models show that our volume measurements in pressure–temperature space are consistent with previous heat capacity and one-bar volume–temperature measurements. The isothermal bulk modulus at ambient conditions derived from our measurements is smaller than values presented in the literature. This new simultaneous high-pressure, high-temperature data are specifically useful for calculations of the orthopyroxene density in the Moon. 相似文献