Importance of geochemical transformations in determining submarine groundwater discharge-derived trace metal and nutrient fluxes     

Aaron J. Beck  Yoko Tsukamoto  Antonio Tovar-Sanchez  Miguel Huerta-Diaz  Henry J. Bokuniewicz  Sergio A. Sañudo-Wilhelmy 《Applied Geochemistry》2007

Seasonal (Spring and Summer 2002) concentrations of dissolved (<0.22 μm) trace metals (Ag, Al, Co, Cu, Mn, Ni, Pb), inorganic nutrients (NO₃, PO₄, Si), and DOC were determined in groundwater samples from 5 wells aligned along a 30 m shore-normal transect in West Neck Bay, Long Island, NY. Results show that significant, systematic changes in groundwater trace metal and nutrient composition occur along the flowpath from land to sea. While conservative mixing between West Neck Bay water and the groundwaters explains the behavior of Si and DOC, non-conservative inputs for Co and Ni were observed (concentration increases of 10- and 2-fold, respectively) and removal of PO₄ and NO₃ (decreases to about half) along the transport pathway. Groundwater-associated chemical fluxes from the aquifer to the embayment calculated for constituents not exhibiting conservative behavior can vary by orders of magnitude depending on sampling location and season (e.g. Co, 3.4 × 10²– 8.2 × 10³ μmol d⁻¹). Using measured values from different wells as being representative of the true groundwater endmember chemical composition also results in calculation of very different fluxes (e.g., Cu, 6.3 × 10³ μmol d⁻¹ (inland, freshwater well) vs. 2.1 × 10⁵ μmol d⁻¹(seaward well, S = 17 ppt)). This study suggests that seasonal variability and chemical changes occurring within the subterranean estuary must be taken into account when determining the groundwater flux of dissolved trace metals and nutrients to the coastal ocean.  相似文献   

Euv Spectroscopy of the Sunspot Region Noaa 7981 Using Soho – II. Velocities and Line Profiles     

Brynildsen  N.  Brekke  P.  Fredvik  T.  Haugan  S. V. H.  Kjeldseth-Moe  O.  Maltby  P.  Harrison  R. A.  Pike  C. D.  Rimmele  T.  Thompson  W. T.  Wilhelm  K. 《Solar physics》1998,179(2):279-312

We have studied the dynamics in the sunspot transition region between the chromosphere and the corona and investigated the extension of the flow field into the corona. Based on EUV spectra of a medium size sunspot and its surroundings, NOAA 7981, observed with CDS and SUMER on SOHO, we derive line-of-sight velocities and study the line profiles for a series of emission lines.The flow field in the low corona is found to differ markedly from that in the transition region. In the transition region the relative line-of-sight velocity shows an upflow in the umbra and relatively large areas with downflow that cover part of the penumbra. The spatial extent of these areas with upflow and downflow increases with increasing temperature in the transition region, but the whole flow field changes character as the temperature increases from the upper transition region to the low corona. Based on a calibration of the SUMER wavelength scale we find that the entire sunspot transition zone appears to be moving downwards towards the chromosphere. The relation between this finding and the general tendency for transition-region lines to show a net red shift is discussed.Several of the transition-region spectral line profiles are observed to show two line components with Gaussian shape and line-of-sight velocities that differ markedly. Several of the line profiles that are composed of two spectral line components occur close to the dividing line between up- and downflow. A discussion of this observation is presented. In small regions with spatial extent of a few arc sec we detect enhanced continuum emission underlying explosive events. The similarities between explosive events with continuum emission and the moustaches observed in H close to sunspots are so striking that we are tempted to introduce the notation transition-region moustaches.  相似文献   

EUV Full-Sun Imaging and Pointing Calibration of the SOHO Coronal Diagnostic Spectrometer     

William Thompson  Martin Carter 《Solar physics》1998,178(1):71-83

Although the field of view of the Normal Incidence Spectrometer (NIS) of the Coronal Diagnostic Spectrometer (CDS) is 4×4 arc min, it is possible to observe the full solar disk by forming a mosaic of images taken in succession. This paper describes just such a study which has been used to collect images of the Sun simultaneously in six wavelengths between 304 Ú and 630 Ú, and with a temperature coverage between 5×10⁴ K and 2.5×10⁶ K. A representative sample of the resulting images is presented. These data can be used to explore the origin of solar EUV variability, and examine large-scale solar features. Another use of these data is to calibrate the pointing of the CDS Offset Pointing System (OPS), by comparing them against the SOHO Extreme ultraviolet Imaging Telescope (EIT) full-disk images taken at the same time. Many joint observations are made with CDS and other SOHO instruments, and calibration of the pointing is crucial to the co-pointing of the instruments, and to the analyses of these data. Coalignment is done by fitting to a cross-correlation function, using an IDL procedure which can be applied to any CDS/NIS data set. The accuracy of an individual coalignment can be demonstrated to be in the range 1–2 arc sec. The overall accuracy of the OPS calibration is ±5 arc sec, mainly attributable to measurement error in the actuator positions. An onboard Spartan Intermediate Sun Sensor of the Lockheed design, which was intended to provide greater pointing accuracy, exhibits a time-varying calibration, possibly due to a gradual loss of sensitivity.  相似文献   

The breakdown of potassium feldspar at high water pressures   总被引：1，自引：0，他引：1  

Pauline Thompson  Ian Parsons  Colin M. Graham  Brian Jackson 《Contributions to Mineralogy and Petrology》1998,130(2):176-186

The equilibrium position of the reaction between sanidine and water to form “sanidine hydrate” has been determined by reversal experiments on well characterised synthetic starting materials in a piston cylinder apparatus. The reaction was found to lie between four reversed brackets of 2.35 and 2.50 GPa at 450 °C, 2.40 and 2.59 GPa at 550 °C, 2.67 and 2.74 GPa at 650 °C, and 2.70 and 2.72 GPa at 680 °C. Infrared spectroscopy showed that the dominant water species in sanidine hydrate was structural H₂O. The minimum quantity of this structural H₂O, measured by thermogravimetric analysis, varied between 4.42 and 5.85 wt% over the pressure range of 2.7 to 3.2 GPa and the temperature range of 450 to 680 °C. Systematic variation in water content with pressure and temperature was not clearly established. The maximum value was below 6.07 wt%, the equivalent of 1 molecule of H₂O per formula unit. The water could be removed entirely by heating at atmospheric pressure to produce a metastable, anhydrous, hexagonal KAlSi₃O₈ phase (“hexasanidine”) implying that the structural H₂O content of sanidine hydrate can vary. The unit cell parameters for sanidine hydrate, measured by powder X-ray diffraction, were a = 0.53366 (±0.00022) nm and c = 0.77141 (±0.00052) nm, and those for hexasanidine were a = 0.52893 (±0.00016) nm and c = 0.78185 (±0.00036) nm. The behaviour and properties of sanidine hydrate appear to be analogous to those of the hydrate phase cymrite in the equivalent barium system. The occurrence of sanidine hydrate in the Earth would be limited to high pressure but very low temperature conditions and hence it could be a potential reservoir for water in cold subduction zones. However, sanidine hydrate would probably be constrained to granitic rock compositions at these pressures and temperatures. Received: 6 May 1997 / Accepted: 2 October 1997  相似文献   

Detection of the Lower Boundary of Stellar Convective Envelopes from Seismic Data     

Mário J.P.F.G. Monteiro  Jørgen Christensen-Dalsgaard  Michael J. Thompson 《Astrophysics and Space Science》1998,261(1-4):41-42

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Noble gases in the earth's mantle     

D.P. Thompson  A.R. Basu  E.W. Hennecke  O.K. Manuel 《Physics of the Earth and Planetary Interiors》1978,17(2):98-107

The abundances and isotopic compositions of noble gases in two samples from ultramafic xenoliths in alkali basalt, a young kaersutitic amphibole separated from a peridotite xenolith from Dish Hill, California and an ancient whole-rock lherzolite xenolith from Baja California, are reported and compared with the results of analyses on other mantle samples. In addition to previously recognized excesses of ³He and ¹²⁹Xe, our results indicate that ambient gases in the mantle show a general enrichment of the lighter-mass nonradiogenic isotopes of Ar, Kr and Xe, and Ar with ⁴⁰Ar/³⁶Ar = 3 · 10².  相似文献   

Model systems for anatexis of pelitic rocks     

Alan Bruce Thompson  Robert J. Tracy 《Contributions to Mineralogy and Petrology》1979,70(4):429-438

Subsolidus and melting reactions involving calcic plagioclase in pelitic assemblages in the K-Na-Ca model system occur at higher temperatures than their K-Na counterparts. For the most calcic plagioclase compositions observed in high-grade pelitic rocks (An₂₅-An₄₀) the equilibria are rarely extended by more than 30 ° C above those in KA1O₂-NaAlO₂-Al₂O₃-SiO₂-H₂O, although all discontinuities in facies inferred for the K-Na system are continuously displaced when they involve Ca-bearing plagioclase. The maximum pressure-temperature overlap between muscovite dehydration and initial melting reactions occurs in the pressure range of 4–6 kbar between about 640 ° and 720 ° C. This provides optimum conditions for anatectic melt generation in felsic rocks of the appropriate compositions progressively metamorphosed in kyanite-sillimanite facies series. Progressive regional metamorphism at pressures of 2–4 kbar, corresponding to andalusite-sillimanite facies series, shows little overlap between muscovite dehydration and initial melting reactions. Consequently anatectic melt generation in andalusite-sillimanite facies series would require the participation of biotite in dehydration-melting reactions. Felsic intrusive rock in andalusite-sillimanite terranes could have risen upward from their anatectic sites in high grade kyanite-sillimanite facies series at depth. Many andalusite-sillimanite facies series terranes culminating in migmatites could represent upward movement of kyanite-sillimanite facies series rocks to shallower depths with uplift rates faster than cooling rates.  相似文献   

A reinterpretation of the entrainment process in some laboratory experiments     

Rory O. R. Y. Thompson 《Dynamics of Atmospheres and Oceans》1979,4(1):45-55

Pollard et al. (1973) proposed a closure hypothesis for the entrainment process in the stress-mixed layer of a stratified fluid. Some laboratory experiments suitable for testing the hypothesis were carried out by Kantha et al. (1977) and by Kato and Phillips (1969). In the early period of each experiment, before side-wall friction becomes important, these experiments support the closure hypothesis, with a critical Froude number close to 1, perhaps F = 1.2 ± 0.2.  相似文献   

Turbulence Measurements above a Pine Forest   总被引：1，自引：0，他引：1  

N. Thompson 《Boundary-Layer Meteorology》1979,16(3):293-310

Eddy fluxes of momentum, sensible and latent heat, and turbulence spectra measured over the Thetford Forest during 10 days in the Spring of 1973 are described. The measured total heat flux (H + λE) for 122 20-min periods agreed closely on average with independent estimates from an energy balance method. There was evidence that the energy balance data gave small systematic overestimates of available energy during the hours before noon, compensated by slight underestimates for the remainder of the day. A comparison of measured wind speeds and friction velocities in neutral stability confirmed the validity of the aerodynamic method for estimating momentum fluxes at heights of a few roughness lengths above the canopy. In stable conditions the log-linear wind profile $U=(u_{?t}/k)({? ln}((z-d)/z_{0})+←pha(z-d-z_{0})/L)$ with α = 3.4 ± 0.4 provided a good fit to the data. Spectra in unstable conditions were generally more sharply peaked than those measured by other workers over smoother terrain: differences were less marked in the case of vertical velocity in stable conditions. Temperature spectra in these stable conditions showed high energy at relatively low wavenumbers, and wT cospectra showed a cospectral gap; both of these results were associated with an intermittent sawtooth structure in the temperature fluctuations.  相似文献   

Pollution records from sediments of three lakes in New York State     

M. Wahlen  R.C. Thompson 《Geochimica et cosmochimica acta》1980,44(2):333-339

Sediment core segments from Sylvan Lake, Lake Champlain and Lake Canadarago were dated radiometrically with ²¹⁰Pb and ¹³⁷Cs. Their respective sedimentation rates were determined to be 0.11, 0.14 and 0.52 g cm^?2 yr^?1. For the two lakes of lower sedimentation the variations of selected elemental abundances as function of depth were analyzed. Two groupings were found: Al, K, Ti, Rb and Zr were correlated among themselves but reflected different variations in the input of terrigenous erosion material to the lakes. The Cu, Zn and Pb correlated among themselves showed similar depth dependence with increasing concentrations toward the top which can be attributed to cultural pollution. Recent ‘excess’ fluxes to the sediments above the natural contribution by clastic material were derived for the location of the cores, which for Cu, Zn and Pb amounted to 3.8, 24 and 16 μg cm^?2 yr^?1 respectively for Sylvan Lake and 4.9, 20 and 16 μg cm^?2 yr^?1 for Lake Champlain. The corresponding ²¹⁰Pb flux was 3.3 and 2.3 dpm cm^?2 yr^?1, respectively for the two lakes.Approximate residence times in the water column were obtained for trace metals at the Lake Champlain location. Short residence times estimated for Pb (< 0.15 yr) and Cu (< 0.4 yr) indicate fast removal, whereas those for Zn (1.0 ± 0.3 yr) and Cr (2.0 ± 0.5 yr) appeared to be dominated by the water residence time.  相似文献