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41.
Spatial distribution patterns of total cadmium (Cd) and lead (Pb), their bioavailable fractions and total organic matter in sediment from Anzali wetlands are provided. Total sediment Pb was higher than Cd (34.95 versus 0.024 μg/g dry weight). The geoaccumulation index indicated that the sediment was “uncontaminated”, but some stations were categorized as “unpolluted” to “moderately polluted”. Less than 0.01 of Pb existed in exchangeable and carbonate fractions. The sum of exchangeable and carbonate-bound fractions of Cd was 42%, suggesting that Cd poses high risk to the aquatic ecosystems. Total Cd and Pb exhibited positive relationships with total organic matter. Considering spatial distribution maps of total and bioavailable fractions of metals suggested that high concentrations of metals does not necessarily indicate high bioavailable fraction. The methodologies we used in this study can be in more effective management of aquatic ecosystems, as well as ecological risk assessment of metals, and remediation programs.  相似文献   
42.
Source apportionment of particulate matter <10 µm in diameter (PM10), having considerable impacts on human health and the environment, is of high priority in air quality management. The present study, therefore, aimed at identifying the potential sources of PM10 in an arid area of Ahvaz located in southwest of Iran. For this purpose, we collected 24‐h PM10 samples by a high volume air sampler. The samples were then analyzed for their elemental (Al, As, B, Ba, Be, Ca, Cd, Co, Cr, Cu, Fe, Hg, K, Mg, Mn, Na, Ni, Pb, Se, Si, Sn, Sr, Li, Ti, V, Zn, Mo, and Sb) and ionic (NH, Cl?, NO, and SO) components using inductively coupled plasma optical emission spectrometry and ion chromatography instruments, respectively. Eight factors were identified by positive matrix factorization: crustal dust (41.5%), road dust (5.5%), motor vehicles (11.5%), marine aerosol (8.0%), secondary aerosol (9.5%), metallurgical plants (6.0%), petrochemical industries and fossil fuel combustion (13.0%), and vegetative burning (5.0%). Result of this study suggested that the natural sources contribute most to PM10 particles in the area, followed closely by the anthropogenic sources.  相似文献   
43.
Diffusion coefficients of dense gases in liquids can be measured by considering two-phase binary nonequilibrium fluid mixing in a closed cell with a fixed volume. This process is based on convection and diffusion in each phase. Numerical simulation of the mixing often requires accurate algorithms. In this paper, we design two efficient numerical methods for simulating the mixing of two-phase binary fluids in one-dimensional, highly permeable media. Mathematical model for isothermal compositional two-phase flow in porous media is established based on Darcy’s law, material balance, local thermodynamic equilibrium for the phases, and diffusion across the phases. The time-lag and operator-splitting techniques are used to decompose each convection–diffusion equation into two steps: diffusion step and convection step. The Mixed finite element (MFE) method is used for diffusion equation because it can achieve a high-order and stable approximation of both the scalar variable and the diffusive fluxes across grid–cell interfaces. We employ the characteristic finite element method with moving mesh to track the liquid–gas interface. Based on the above schemes, we propose two methods: single-domain and two-domain methods. The main difference between two methods is that the two-domain method utilizes the assumption of sharp interface between two fluid phases, while the single-domain method allows fractional saturation level. Two-domain method treats the gas domain and the liquid domain separately. Because liquid–gas interface moves with time, the two-domain method needs work with a moving mesh. On the other hand, the single-domain method allows the use of a fixed mesh. We derive the formulas to compute the diffusive flux for MFE in both methods. The single-domain method is extended to multiple dimensions. Numerical results indicate that both methods can accurately describe the evolution of the pressure and liquid level.  相似文献   
44.
During the earthquakes, a number of earth dams have had severe damages or suffered major displacements as a result of liquefaction, thus modeling by computer codes can provide a reliable tool to predict the response of the dam foundation against earthquakes. These modeling can be used in the design of new dams or safety assessments of existing ones. In this paper, on the basis of the field and laboratory tests and by combination of several software packages a seismic geotechnical-based analysis procedure is proposed and verified by comparison with computer model tests and field and laboratory experiences. Verification or validation of the analyses relies to the ability of the applied computer codes. By using the Silakhor earthquake (2006, M s 6.1) as a basis in order to check the efficiency of the proposed framework, the procedure is applied to the Korzan earth dam of Iran which is located in Hamedan Province to analyze and estimate the liquefaction and safety factor. Design and development of a computer code by the authors which was named as the ??Abbas Converter?? with graphical user interface which operates as logic connecter function that can compute and model the soil profiles is the critical point of this study. The results confirmed and proved the ability of the generated computer code on the evaluation of soil behavior during earthquake excitations. Also, this code was able to facilitate this study better than previous ones have, taking over the encountered problem.  相似文献   
45.
A study based on two-dimensional finite element analyses under plane strain condition was performed by PLAXIS code to investigate the behavior of geotextile-reinforced soil above an underground cavity. The effects of depth of single layer, tensile stiffness, number and length of reinforcement layers, and size of cavity on settlement of ground surface and head of cavity have been investigated. Results indicated that when a single layer of reinforcement is used, there is a critical depth at which settlements are maximum. Maximum settlements reduce with increase in stiffness of reinforcement. Also settlements reduce with increase in number and length of reinforcement but there is a critical value for number and length of geotextile which increase more than this certain value has not significant effect on reduction of settlements. Also for a given load and tensile stiffness, increase in length of reinforcement has more effect for higher diameter of cavity.  相似文献   
46.
Simple, rapid, and sensitive spectrophotometric methods have been proposed for the determination of cationic surfactants (CS) as cetyltrimethylammonium bromide (CTAB), dodecyltrimethylammonium (DTAB), and cetylpyridinium bromide (CPB). The methods are based on the effects of CSs on the complexes of Al3+ and Be2+ with Chrome Azurol S (CAS). The optimum reaction conditions such as CAS concentration, metal ion concentration, and pH have been studied and found to be 2.0 × 10?4 mol L?1 CAS, 0.5 mg L?1 Al3+ or 0.4 mg L?1 Be2+ and pH 5.4. The analytical characteristics of the methods such as limit of detections, limit of quantifications, and linear ranges have been obtained. CTAB, CPB, and DTAB could be determined by the Al–CAS complex in the ranges of 0.50–40.00, 0.20–10.00, and 0.40–10.00 µmol L?1, and for the Be–CAS complex in the ranges of 0.08–5.00, 0.08–3.00, and 0.20–6.00 µmol L?1, respectively. The limit of the detections of the method for the determination of CTAB, CPB, and DTAB for the Be–CAS complex has been found as 0.025, 0.024, and 0.061 µmol L?1, respectively. The interfering effect of some anions and cations was also tested. The method was applied to the determination of CS CTAB in conditioner shampoo and water samples.  相似文献   
47.
The Upper Triassic-Middle Jurassic sedimentary succession in the Tabas Basin, with a thickness of about 1600 m, provides a case showing geochemical property changes through the Triassic-Jurassic boundary. The studied section (Kamarmacheh Kuh) is composed of the marine Nayband Formation (Norian-Rhaetian) overlain by siliciclastic sediments of Ab-e-Haji Formation (Lower Jurassic-Aalenian). Detailed geochemical analyses were conducted on selected samples from both formations and the results were used to infer paleo-depositional conditions. Most of the studied samples contain <1 wt% TOC composed mostly of oxidized organic matter with insignificant generative potential. Extract analysis of four representative samples indicate that the rocks also contain minor amounts of preserved algal organic matter along with a secondary contribution of higher plant organic matter from the adjacent watershed. Biomarker analyses show subtle variations in the relative contribution of land plant material that are consistent with the widespread occurrence of coal seams in the upper parts of the Nayband and basal parts of the Ab-e-Haji formations. Although the samples from the Kamarmacheh Kuh Section have low source potential, the extractable hydrocarbons indicate that conditions existed that were conducive to organic matter preservation and that regions of the Tabas Basin with higher primary productivity or lower sedimentation rates may have greater potential.  相似文献   
48.
Burden prediction is a vital task in the production blasting. Both the excessive and insufficient burden can significantly affect the result of blasting operation. The burden which is determined by empirical models is often inaccurate and needs to be adjusted experimentally. In this paper, an attempt was made to develop an artificial neural network (ANN) in order to predict burden in the blasting operation of the Mouteh gold mine, using considering geomechanical properties of rocks as input parameters. As such here, network inputs consist of blastability index (BI), rock quality designation (RQD), unconfined compressive strength (UCS), density, and cohesive strength. To make a database (including 95 datasets), rock samples are used from Iran’s Mouteh goldmine. Trying various types of the networks, a neural network, with architecture 5-15-10-1, was found to be optimum. Superiority of ANN over regression model is proved by calculating. To compare the performance of the ANN modeling with that of multivariable regression analysis (MVRA), mean absolute error (E a), mean relative error (E r), and determination coefficient (R 2) between predicted and real values were calculated for both the models. It was observed that the ANN prediction capability is better than that of MVRA. The absolute and relative errors for the ANN model were calculated 0.05 m and 3.85%, respectively, whereas for the regression analysis, these errors were computed 0.11 m and 5.63%, respectively. Moreover, determination coefficient of the ANN model and MVRA were determined 0.987 and 0.924, respectively. Further, a sensitivity analysis shows that while BI and RQD were recognized as the most sensitive and effective parameters, cohesive strength is considered as the least sensitive input parameters on the ANN model output effective on the proposed (burden).  相似文献   
49.
Spatially enabled bushfire recovery   总被引:1,自引:0,他引:1  
Over the last decade growth in spatial information use for disaster management has been considerable. Maps and spatial data are now recognized as critical elements in each of the four phases of disaster management: mitigation, preparedness, response, and recovery. The use of spatial information to support the phases of mitigation, preparedness and response to bushfires is widely understood. Less attention, however, has been given to the role of spatial information in the recovery. Moreover, the application of the spatially enabled society concept to bushfire recovery has not been explored. This paper explores the role that spatial information plays and could play in the recovery phase of a bushfire disaster. The bushfires in Victoria, Australia that took place during February 2009 are used as the primary case study. It is found that: Spatial information for recovery requires a pre-existing infrastructure; Spatial capacity must be developed across agencies dealing with recovery; Spatially enabled address and parcel information are the key dataset required to support all recovery tasks; Spatial integration of bushfire datasets (spread and intensity) require linking with planning regimes, and Spatial information that is volunteered could be incorporated into recovery activities.  相似文献   
50.
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