Supported TiO2 on Kaolin,Cordierite, and Calcite for Photocatalytic Removal of Dyes from Wastewater     

Amal M. Ibrahim  Doaa M. El‐Mekkawi  Mohamed M. Selim 《洁净——土壤、空气、水》2020,48(4)

Kaolin, cordierite, and calcite are investigated as supports for TiO₂. The prepared TiO₂/support samples are examined for the removal of organic dyes from wastewater. The samples are preliminarily investigated to identify the optimal loaded system using synthetic wastewater containing methylene blue (MB). Data indicate that the investigated support significantly affects the photocatalytic activity of the supported TiO₂. Low photocatalytic activity toward MB degradation is observed upon using TiO₂/calcite when compared to the unsupported TiO₂. Interaction between calcite and titania species probably occurrs to produce the less photoactive CaTiO₃ amorphous species. Anatase TiO₂ is obtained upon using kaolin and cordierite as supports. The low photocatalytic performance of the TiO₂/kaolin sample is also observed. A high concentration of MB on TiO₂/kaolin surfaces blocks the photoactive sites. TiO₂/cordierite shows the highest photocatalytic activity compared to the unsupported TiO₂ as well as the other TiO₂/support samples. Rigid cordierite particles suppress the agglomeration of TiO₂ particles during the preparation, leading to a high exposed surface of TiO₂ towards light illumination. TiO₂/cordierite is investigated for the removal of organic dye from real wastewater collected from a textile dyeing factory. Color removal of up to 46% is achieved upon UV irradiation.  相似文献   

A risk‐based life cycle cost strategy for optimal design and evaluation of control methods for nonlinear structures          下载免费PDF全文

Omar El‐Khoury  Abdollah Shafieezadeh  Ehsan Fereshtehnejad 《地震工程与结构动力学》2018,47(11):2297-2314

The lack of direct correspondence between control objectives and hazard risks over the lifetime of systems is a key shortcoming of current control techniques. This along with the inability to objectively analyze the benefits and costs of control solutions compared with conventional methods has hindered widespread application of control systems in seismic regions. To address these gaps, this paper offers 2 new contributions. First, it introduces risk‐based life cycle–cost (LCC) optimal control algorithms, where LCC is incorporated as the performance objective in the control design. Two strategies called risk‐based linear quadratic regulator and unconstrained risk‐based regulator are subsequently proposed. The considered costs include the initial cost of the structure and control system, LCC of maintenance, and probabilistically derived estimates of seismic‐induced repair costs and losses associated with downtime, injuries, and casualties throughout the life of the structure. This risk‐based framework accounts for uncertainties in both system properties and hazard excitations and uses outcrossing rate theory to estimate fragilities for various damage states. The second contribution of this work is a risk‐based probabilistic framework for LCC analysis of existing and proposed control strategies. The proposed control designs are applied to the nonlinear model of a 4‐story building subjected to seismic excitations. Results show that these control methods reduce the LCC of the structure significantly compared with the status quo option (benefits of up to $1 351 000). The advancements offered in this paper enhance the cost‐effectiveness of control systems and objectively showcase their benefits for risk‐informed decision making.  相似文献   

Seismic response of rocking frames with top support eccentricity          下载免费PDF全文

Amitabh Dar  Dimitrios Konstantinidis  Wael El‐Dakhakhni 《地震工程与结构动力学》2018,47(12):2496-2518

The seismic response of rocking frames that consist of a rigid beam freely supported on rigid freestanding rectangular piers has received recent attention in the literature. Past studies have investigated the special case where, upon planar rocking motion, the beam maintains contact with the piers at their extreme edges. However, in many real scenarios, the beam‐to‐pier contact lies closer to the center of the pier, affecting the overall stability of the system. This paper investigates the seismic response of rocking frames under the more general case which allows the contact edge to reside anywhere in‐between the center of the pier and its extreme edge. The study introduces a rocking block model that is dynamically equivalent to a rocking frame with vertically symmetric piers of any geometry. The impact of top eccentricity (ie, the distance of the contact edge from the pier's vertical axis of symmetry) on the seismic response of rocking frames is investigated under pulse excitations and earthquake records. It is concluded that the stability of a top‐heavy rocking frame is highly influenced by the top eccentricity. For instance, a rocking frame with contacts at the extreme edges of the piers can be more seismically stable than a solitary block that is identical to one of the frame's piers, while a rocking frame with contacts closer to the centers of the piers can be less stable. The concept of critical eccentricity is introduced, beyond which the coefficient of restitution contributes to a greater reduction in the response of a frame than of a solitary pier.  相似文献   

Rare Earth Elements Around the Barakah Nuclear Power Plant,UAE     

Al Rashdi  Mouza Rashid  El Tokhi  Mohamed  Alaabed  Sulaiman  El Mowafi  Walid  Arabi  Alya A. 《Natural Resources Research》2020,29(6):4149-4160

Natural Resources Research - Rare earth element (REE) contamination has major consequences for the environment and humans. Some forms of REEs have more serious environmental impacts than others. It...  相似文献   

Impact of shorebird predation on intertidal macroinvertebrates in a key North African Atlantic wintering site: an experimental approach     

L Joulami  R El Hamoumi  Z Daief  H Bazairi 《African Journal of Marine Science》2019,41(1):1-9

Shorebirds, as migratory aquatic birds and top predators in intertidal ecosystems, can be affected by global environmental changes and escalations in local impacts on coastal lagoons and estuarine trophic networks. Many shorebirds winter in North African Atlantic coastal sites, most likely because these locations provide constant and reliable food supplies with less energy costs in comparison with the wintering sites of northern Europe. Although more information is available for other important southern coastal sites (e.g. Saharan Atlantic coastal desert and Guinean mangroves coast), very little information is available for the North African Atlantic coast. Here, we focus on the impact of shorebird predation on benthic macroinvertebrates in a major wintering site in this area—Sidi Moussa coastal lagoon, Morocco—using an exclosure experiment. For most of the macroinvertebrate species there was no significant effect of the exclusion of shorebird predation. Overall, our results do not show evidence that predation by shorebirds influenced the overall standing biomass of the benthic community. This may indicate that the benthic productivity is high enough to provide constant and reliable food supplies for non-breeding shorebirds.  相似文献   

An Acheulian site near Bir Kiseiba in the Darb el Arba'in Desert,Egypt     

C. Vance Haynes  T. A. Maxwell  A. El Hawary  K. A. Nicoll  S. Stokes 《Geoarchaeology》1997,12(8):819-832

A small concentration of Acheulian cleavers and handaxes within the driest region on Earth adds to the increasing evidence that the eastern Sahara was considerably more verdant during the Middle Pleistocene than it is today. The similarities to stone artifact assemblages of Acheulian sites in sub-Saharan Africa and in the Levant support the evidence for the movement of hominids, utilizing the Kombewa lithic technology, between Africa and the Middle East during the Middle Pleistocene. © 1997 John Wiley & Sons, Inc.  相似文献   

Field behavior of pre-bored grouted planted nodular pile embedded in deep clayey soil     

Zhou  Jia-jin  Gong  Xiao-nan  Zhang  Ri-hong  Hesham El Naggar  M.  Wang  Kui-hua 《Acta Geotechnica》2020,15(7):1847-1857

Acta Geotechnica - This paper presents the results of field tests performed to investigate the behavior of pre-bored grouted planted nodular (PGPN) pile embedded in deep clayey soil. The test piles...  相似文献   

Palynological,palynofacies, paleoenvironmental and organic geochemical studies on the Upper Cretaceous succession of the GPTSW-7 well,North Western Desert,Egypt     

Salah Y. El Beialy  Haytham S. El Atfy  Michael S. Zavada  Essam M. El Khoriby  Ramadan H. Abu-Zied 《Marine and Petroleum Geology》2010

The present study of the Abu Roash and Bahariya formations in well GPTSW-7 refines our understanding of the subsurface Cretaceous of the north Western Desert of Egypt. Our investigations are based on the palynological analyses of 71 cuttings samples, of which 24 have also been analyzed for geochemistry, in addition to 3 sidewall cores analyzed for vitrinite reflectance (R_o).  相似文献   

Hydrothermal alteration of plagioclase in granitic rocks from Proterozoic basement of SE Sweden     

S. Morad  M. A. K. El‐Ghali  M. A. Caja  M. Sirat  K. Al‐Ramadan  H. Mansurbeg 《Geological Journal》2010,45(1):105-116

Petrographic examinations and electron microprobe analyses of Proterozoic granitic rocks, SE Sweden aimed to characterize and unravel the mechanisms and conditions of plagioclase alterations. These alterations include saussuritization, albitization and replacement of plagioclase by K‐feldspar. The hydrothermal alterations, which are inferred to have occurred at ca. 250–400°C, resulted in concomitant formation of Al‐rich titanite, epidote, calcite, pumpellyite, prehnite and iron oxides. Replacement of plagioclase by K‐feldspar occurs in red‐stained zones, which have developed close to thin fractures owing to the precipitation of tiny Fe‐oxide pigment particles within the altered plagioclase, whereas saussuritized plagioclase has less systematic spatial relationships to these fractures. Albitization of plagioclase occurred in rocks that are poor in biotite compared to rocks that suffered extensive saussuritization. The chemical and textural characterization of various types of plagioclase alterations allows elucidation of the granitic hydrothermal systems. Features of feldspar alteration in the granitic rocks are similar to those encountered in feldspathic sandstones and should hence be considered in studies on diagenetic changes of siliciclastic successions during basin evolution. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Analytical solution for distributed torsional low strain integrity test for pipe pile     

Yunpeng Zhang  Guosheng Jiang  Wenbing Wu  M. Hesham El Naggar  Hao Liu  Minjie Wen  Kuihua Wang 《国际地质力学数值与分析法杂志》2022,46(1):47-67

Low strain integrity tests (LSITs) are the most popular non-destructive methods for pile testing. However, traditional LSITs have encountered unprecedented challenges as the need for long pile and existing pile testing keeps multiplying. Compared to traditional longitudinal excitations, the torsional wave is less influenced by the velocity attenuation effect and can be subjected at the pile shaft for existing piles. Distributed torsional LSIT is proposed in this article with the presentation of the corresponding analytical solutions that exhibiting the velocity responses along the pile shaft. The solution is verified with previous simplified theoretical and rigorous finite element method (FEM) answers. At the end, the application of this method is exhibited through the identification of necking and concrete segregation defects on pipe piles, which shows the advantage of this method on long pile testing.  相似文献